TW201307545A - Band-shaped lubricating material for dry wiredrawing and process for producing same - Google Patents
Band-shaped lubricating material for dry wiredrawing and process for producing same Download PDFInfo
- Publication number
- TW201307545A TW201307545A TW101124915A TW101124915A TW201307545A TW 201307545 A TW201307545 A TW 201307545A TW 101124915 A TW101124915 A TW 101124915A TW 101124915 A TW101124915 A TW 101124915A TW 201307545 A TW201307545 A TW 201307545A
- Authority
- TW
- Taiwan
- Prior art keywords
- wire
- acid
- lubricating material
- salt
- belt
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C9/00—Cooling, heating or lubricating drawing material
- B21C9/005—Cold application of the lubricant
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/46—Lubricating compositions characterised by the base-material being a macromolecular compound containing sulfur
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
- C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/02—Carbon; Graphite
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/22—Carboxylic acids or their salts
- C10M105/24—Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
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- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
- C10M107/04—Polyethene
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- C—CHEMISTRY; METALLURGY
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C10M2201/043—Sulfur; Selenenium; Tellurium
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- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
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- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
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- C10M2201/085—Phosphorus oxides, acids or salts
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- C10M2201/087—Boron oxides, acids or salts
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- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
- C10M2201/103—Clays; Mica; Zeolites
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C10M2205/0225—Ethene used as base material
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- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C10M2205/0245—Propene used as base material
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- C10M2205/043—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene used as base material
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- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/0406—Ethers; Acetals; Ortho-esters; Ortho-carbonates used as base material
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- C10M2207/1213—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms used as base material
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- C10M2209/0625—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate used as base material
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
- Metal Extraction Processes (AREA)
Abstract
Description
本發明係關於一種拉拔如線材或桿材之母材進行縮徑而伸線時,防止因其母材與模頭之直接接觸產生之燒傷,用以維持安定之加工狀態所使用的帶狀乾式伸線用潤滑材。 The present invention relates to a belt shape for preventing a burn caused by direct contact between a base material and a die when drawing a base material such as a wire rod or a rod material to reduce the diameter, and for maintaining a stable processing state. Lubricating material for dry wire.
使鋼鐵或非鐵金屬等之金屬製的粗徑之線材或桿材之母材從如模頭之型鋼的孔拉拔,而縮徑成細徑之線材或桿材等而使之塑性變形之伸線加工時,汎用粉粒之乾式伸線用潤滑劑。此乾式伸線用潤滑劑係防止母材與模頭直接接觸而燒傷,成為易滑動,而可維持安定之加工狀態所使用者。 A wire of a large diameter or a base material of a rod made of a metal such as steel or non-ferrous metal is drawn from a hole of a steel such as a die, and is reduced in diameter to a wire or a rod of a small diameter to be plastically deformed. When the wire is processed, the lubricant for the dry wire of the powder is used. This dry-type lubricant is a user that prevents the base material from being in direct contact with the die and burns, and is easy to slide, and can maintain a stable processing state.
例如,於專利文獻1中揭示一種含有飽和脂肪酸之金屬鹽、與非含硼之水溶性無機縮合化合物及/或其縮合前驅化合物之非含硼酸鹽的乾式伸線用潤滑劑。由如此之飽和脂肪酸之金屬鹽、無機物及添加劑所構成之乾式伸線用潤滑劑係形成粉末狀或顆粒狀之形狀。此粉末狀或顆粒狀之乾式伸線用潤滑劑係可在高溫、高壓、高速之嚴苛的伸線加工條件下使用,且亦可對應於從細徑至粗徑之線徑的縮徑、或低速至高速之線速,故可被廣泛地使用。 For example, Patent Document 1 discloses a non-borate-containing dry wire lubricant containing a metal salt of a saturated fatty acid, a non-boron-containing water-soluble inorganic condensation compound, and/or a condensation precursor thereof. The lubricant for dry-stretching composed of a metal salt, an inorganic substance, and an additive of such a saturated fatty acid is formed into a powdery or granular shape. The powdery or granular dry wire lubricant can be used under high temperature, high pressure, high speed and severe wire drawing processing conditions, and can also correspond to a diameter reduction from a small diameter to a large diameter. Or low speed to high speed wire speed, so it can be widely used.
粉末狀或顆粒狀之乾式伸線用潤滑劑係如圖4所示般,伸線加工時,大量投入於模頭箱3之中,其一部分被 與線材2一起拉入模頭4,對線材2形成潤滑被膜6,防止線材2與模頭4之直接接觸。被投入於模頭箱3之乾式伸線用潤滑劑10係其大概2成左右與線材2一起被模頭4拉入並被消耗,但其餘係藉加工熱,乾式伸線用潤滑劑10被一部分分解,成為碳化物,潤滑能降低,或線材2或模頭4等之摩耗粉混在一起,為確保伸線之品質,故無法使用。因此,使其殘餘全量不得不廢棄。 The lubricant for the dry type wire for powder or granules is as shown in Fig. 4. When the wire is processed, a large amount is injected into the die box 3, and a part thereof is Pulling the die 4 together with the wire 2 forms a lubricating film 6 to the wire 2 to prevent direct contact of the wire 2 with the die 4. The dry-type lubricant 10 to be used in the die box 3 is pulled by the die 4 and consumed by about 20% of the wire 2, but the rest is processed by the heat, and the dry-type lubricant 10 is Some of them are decomposed into carbides, and the lubricating energy is lowered, or the powders of the wire 2 or the die 4 are mixed together, and the quality of the wire is ensured, so that it cannot be used. Therefore, the total amount of residuals has to be discarded.
近年之社會情勢係朝考量資源之再活用等地球環境之社會遷移,故如此之大量消耗、大量廢棄問題正被重視。又,因為粉末狀或顆粒狀,引起使用時之粉塵等造成的作業環境惡化、作業者之健康被害、環境污染等之問題。進一步,依加工形狀而必須分開使用或調整乾式伸線用潤滑劑之粒子形狀,在作業者側及生產者側為非效率性。從如此之問題點,維持加工性及生產性,同時並謀求作業環境的改善,尋求考量地球環境,非粉末形狀之革新的乾式伸線用潤滑材。 In recent years, the social situation is the social migration of the global environment, such as the re-use of resources, so the problem of such large consumption and a large amount of waste is being taken seriously. Further, in the form of powder or granules, problems such as deterioration of the working environment due to dust during use, damage to the health of the operator, and environmental pollution are caused. Further, depending on the shape to be processed, it is necessary to separately use or adjust the particle shape of the lubricant for dry wire drawing, which is inefficient on the operator side and the producer side. In order to improve the workability and productivity, and to improve the working environment, we are looking for a lubricant for dry-type wire that is innovative in the global environment and non-powder shape.
[專利文獻1]特開2010-111767號公報 [Patent Document 1] JP-A-2010-111767
本發明係為解決前述之課題而成者,故目的在於提供 一種帶狀乾式伸線用潤滑材,其係與習知之粉末狀或顆粒狀之乾式伸線用潤滑劑同樣地,不僅可在高溫、高壓、高速之嚴苛伸線加工條件下使用,亦可以應付從細徑至粗徑之廣泛線徑的縮徑、或低速至高速之廣泛線速,不限定於加工形狀,潤滑性、追隨性、展黏性、附著性、耐熱性、加工性、作業性、安全性、耐久性、生產性等之功能性優異,為考量作業環境之改善及地球環境之革新;其製造方法;及使用其之伸線方法。 The present invention has been made to solve the aforementioned problems, and the object is to provide The lubricating material for the belt-shaped dry type stretching wire is used not only in the high-temperature, high-pressure, high-speed and severe wire drawing processing conditions, but also in the conventional powdery or granular dry wire lubricant. It is not limited to the processing shape, but also the lubrication shape, the follow-up property, the adhesion, the adhesion, the heat resistance, the workability, and the work, which are suitable for reducing the diameter of a wide diameter from a small diameter to a large diameter or a wide line speed from a low speed to a high speed. It is excellent in functionality, safety, durability, productivity, etc., and is an improvement in the working environment and an innovation in the global environment; a manufacturing method thereof; and a wire drawing method using the same.
為達成前述之目的而成之如申請專利範圍第1項之帶狀乾式伸線用潤滑材,其特徵係由含有飽和脂肪酸之金屬鹽10~90重量%、與熱塑性樹脂10~90重量%之膜所構成。 A lubricating material for a belt-shaped dry wire for a purpose of achieving the above-mentioned object is characterized in that the metal salt containing a saturated fatty acid is 10 to 90% by weight and the thermoplastic resin is 10 to 90% by weight. Made up of membranes.
申請專利範圍第2項之帶狀乾式伸線用潤滑材,其係如申請專利範圍第1項之帶狀乾式伸線用潤滑材,其中前述飽和脂肪酸為酪酸、己酸、辛酸、壬酸、癸酸、十一碳酸、月桂酸、肉豆蒄酸、棕櫚酸、硬脂酸、花生酸、山萮酸、掬焦油酸(lignoceric acid)、蟲蠟酸(Cerotic acid)、褐煤酸(Montanic acid)、及/或蜂蠟酸(melissic acid)。 The lubricating material for the belt-shaped dry-type wire of the second aspect of the patent application is the lubricating material for the band-shaped dry wire for the first aspect of the patent application, wherein the saturated fatty acid is butyric acid, caproic acid, caprylic acid, citric acid, Capric acid, eleven carbonic acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid, lignoceric acid, Cerotic acid, montanic acid ), and / or melissic acid.
申請專利範圍第3項之帶狀乾式伸線用潤滑材,其係如申請專利範圍第1或2項者,其中前述熱塑性樹脂為聚乙烯、聚丙烯、聚苯乙烯、丙烯腈/苯乙烯共聚合樹脂、乙烯/醋酸乙烯酯共聚合樹脂、丙烯腈/丁二烯/苯乙烯共聚 合樹脂、甲基丙烯酸樹脂、氯乙烯、聚醯胺、聚縮醛、聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、甲基戊烯、聚碳酸酯、聚苯硫醚、聚醚醚酮、聚四氟乙烯、聚醚醯亞胺、聚芳酸酯、聚碸、聚醚碸、及/或聚醯胺醯亞胺。 The lubricating material for the band-shaped dry wire drawing of the third aspect of the patent application is as claimed in claim 1 or 2, wherein the thermoplastic resin is polyethylene, polypropylene, polystyrene, acrylonitrile/styrene. Polymer resin, ethylene/vinyl acetate copolymer resin, acrylonitrile/butadiene/styrene copolymerization Resin, methacrylic resin, vinyl chloride, polyamine, polyacetal, polyethylene terephthalate, polybutylene terephthalate, methylpentene, polycarbonate, polyphenylene sulfide Polyetheretherketone, polytetrafluoroethylene, polyetherimide, polyarylate, polyfluorene, polyether oxime, and/or polyamidoximine.
申請專利範圍第4項之帶狀乾式伸線用潤滑材,其係如申請專利範圍第1~3項之中任一項者,其中前述金屬鹽為鋰鹽、鈉鹽、鉀鹽、鈣鹽、鎂鹽、鋁鹽、鋅鹽、鋇鹽、及/或其等之複合金屬鹽。 The lubricating material for the band-shaped dry type wire of the fourth aspect of the patent application is the one of the first to third aspects of the patent application, wherein the metal salt is a lithium salt, a sodium salt, a potassium salt or a calcium salt. a composite metal salt of a magnesium salt, an aluminum salt, a zinc salt, a cerium salt, and/or the like.
申請專利範圍第5項之帶狀乾式伸線用潤滑材,其係申請專利範圍第1~4項中任一項者,其中含有硼酸、硼酸鹽、磷酸鹽、硫酸鹽、碳酸鹽、硝酸鹽、消石灰、氧化鈦、滑石、雲母、石墨、二硫化鉬、層狀複水氧化物、及/或硫。 The lubricating material for the band-shaped dry wire for applying the patent scope 5, which is one of the patent claims 1 to 4, which contains boric acid, borate, phosphate, sulfate, carbonate, nitrate , hydrated lime, titanium oxide, talc, mica, graphite, molybdenum disulfide, layered rehydrated oxide, and/or sulfur.
一種申請專利範圍第6項之帶狀乾式伸線用潤滑材之製造方法,其特徵係使飽和脂肪酸之金屬鹽10~90重量%、與熱塑性樹脂10~90重量%加熱混煉,再製膜,形成帶狀。 A method for producing a lubricating material for a strip-shaped dry wire according to the sixth aspect of the invention, characterized in that a metal salt of a saturated fatty acid is heated in an amount of 10 to 90% by weight and 10 to 90% by weight of a thermoplastic resin, and then a film is formed. Form a ribbon.
一種申請專利範圍第7項之伸線方法,其特徵係於應被伸線處理之母材,被覆如申請專利範圍第1項之帶狀乾式伸線用潤滑材,同時一邊使其母材通過模頭孔,一邊拉拔,俾進行縮徑,伸線。 A method for drawing a wire according to item 7 of the patent application, characterized in that the base material to be subjected to the wire drawing treatment is coated with the lubricating material for the band-shaped dry wire for the first application of the patent scope, while the base material is passed through The die hole is pulled at one side, and the boring is performed to reduce the diameter and stretch the wire.
申請專利範圍第8項之伸線方法,係申請專利範圍第7項者,其中於前述母材以前述帶狀乾式伸線用潤滑材捲繞或挾住,進行前述被覆。 The method of claim 8, wherein the method of claim 7 is the method of claim 7, wherein the base material is wound or caught by the lubricating material for the strip-shaped dry wire, and the coating is performed.
如申請專利範圍第9項之伸線方法,係申請專利範圍第7~8項中任一項者,其中使前述帶狀乾式伸線用潤滑材以輥輪導引而捲繞於前述母材,進行前述被覆。 The method of claim 9, wherein the method of claim 7 or claim 8, wherein the lubricating material for the strip-shaped dry wire is guided by a roller and wound around the base material , carry out the aforementioned coating.
如申請專利範圍第10項之伸線方法,係如申請專利範圍第7~9項中任一項者,其中前述母材為金屬製。 For example, in the method of claim 10, the method of claim 10 is the method of claim 7, wherein the base material is made of metal.
本發明之帶狀乾式伸線用潤滑材係不限定於加工形狀,與加工伸線等應被加工之母材一起被拉入於模頭,於母材形成潤滑被膜,可防止母材與模頭之直接接觸產生的燒傷,維持安定之加工狀態。又,在伸線加工條件中可在高溫、高壓、高速之嚴苛條件下使用,且亦可對應於從細徑至粗徑之寬廣線徑的縮徑、或低速至高速之寬廣線速。 The lubricating material for the belt-shaped dry type yarn of the present invention is not limited to the processed shape, and is drawn into the die together with the base material to be processed such as the processed strand, and a lubricating film is formed on the base material to prevent the base material and the mold. The burn caused by the direct contact of the head maintains the stable processing state. Further, in the wire drawing processing conditions, it can be used under severe conditions of high temperature, high pressure, and high speed, and can also correspond to a reduced diameter of a wide wire diameter from a small diameter to a large diameter, or a wide linear velocity from a low speed to a high speed.
又,相較於一次之使用量為大量,未使用盡而如產生近8成之大量廢棄物的非生產性之習知粉末狀或顆粒狀的乾式伸線用潤滑劑,此帶狀乾式伸線用潤滑材係帶狀,故使一次之使用量抑制至少量,同時並非大量消耗、大量廢棄,可顯現潤滑性、追隨性、展黏性、附黏性、耐熱性、加工性、耐久性等優異之功能效果,並可使用盡。進一步,一般必須使母材之線材中的線徑之縮徑為數階段時,每一階段必須有乾式伸線用潤滑劑,但此帶狀乾式伸線用潤滑材係只在初次,或間隔,只使用於線材表面形成充分的潤滑被膜而可維持其效果,故可謀求生產效率及費用對效果之提昇。 In addition, compared with the use of a large amount in one time, the non-productive powder-like or granular dry-type wire lubricant which produces nearly 80% of the waste is used, and the band-like dry stretch is used. Since the line is made of a lubricating material, it is used in a single amount, and it is not used in a large amount, and is not consumed in a large amount, and is discarded in a large amount, and exhibits lubricity, followability, adhesion, adhesion, heat resistance, workability, and durability. Excellent functional effects and use. Further, in general, when the diameter of the wire diameter in the wire of the base material is several stages, the lubricant for the dry wire must be used in each stage, but the lubricating material for the belt-shaped dry wire is only used for the first time, or at intervals. It is possible to maintain a sufficient effect by forming a sufficient lubricating film on the surface of the wire, and it is possible to improve production efficiency and cost.
本發明之帶狀乾式伸線用潤滑材係不引起因粉末狀或顆粒狀而產生之粉塵造成的作業環境惡化、作業者之健康被害或環境污染,可安全地使用,同時並考量地球環境者。 The lubricating material for the belt-shaped dry wire according to the present invention is a safety material which is not caused by dust generated by powder or granules, which is deteriorated in the working environment, the health of the operator, or environmental pollution, and can be safely used, and the earth environment is considered. .
若依本發明之帶狀乾式伸線用潤滑材的製造方法,可簡便且效率地製造可顯現潤滑性、追隨性、展黏性、附黏性、耐熱性、加工性、耐久性等優異之功能效果的膜狀之帶狀乾式伸線用潤滑材。 According to the method for producing a lubricating material for a belt-shaped dry wire according to the present invention, it is possible to easily and efficiently produce excellent lubricity, followability, spreadability, adhesion, heat resistance, workability, durability, and the like. A lubricating material for a film-like belt-like dry wire for functional effects.
若依本發明之伸線方法,使用帶狀乾式伸線用潤滑材,可縮徑而應伸線之被加工母材確實地塑性變形,再度,即使不賦予帶狀乾式伸線用潤滑材,亦可反覆進行縮徑,故有效率。 According to the wire drawing method of the present invention, the lubricating material for the belt-shaped dry type wire can be used, and the base material to be processed which can be reduced in diameter can be reliably plastically deformed, and again, even if the lubricating material for the belt-shaped dry wire is not provided, It can also be reduced in diameter, so it is efficient.
1為帶狀乾式伸線用潤滑材,2為線材,3為模頭箱,4為模頭,5為模頭孔,6為潤滑被膜,7a、7b、7c係一對的輥輪,10為乾式伸線用潤滑劑。 1 is a lubricating material for a belt-shaped dry wire, 2 is a wire, 3 is a die box, 4 is a die, 5 is a die hole, 6 is a lubricating film, 7a, 7b, 7c are a pair of rollers, 10 It is a lubricant for dry wire.
以下,詳細說明有關用以實施本發明之形態,但本發明之範圍係不限定於此等之形態。 Hereinafter, the form for carrying out the invention will be described in detail, but the scope of the invention is not limited thereto.
本發明之帶狀乾式伸線用潤滑材係飽和脂肪酸之金屬鹽10~90重量%、與熱塑性樹脂10~90重量%被均一地混 煉而含有之膜所構成,形成為帶形狀者。 The lubricating material for the strip-shaped dry wire of the present invention is 10 to 90% by weight of a metal salt of a saturated fatty acid, and is uniformly mixed with 10 to 90% by weight of a thermoplastic resin. The film is formed by refining and formed into a shape.
構成飽和脂肪酸之金屬鹽之飽和脂肪酸係碳數3~29,為直鏈狀、分枝鏈狀、或環狀之飽和脂肪酸。具體上可舉例如酪酸、己酸、辛酸、壬酸、癸酸、十一碳酸、月桂酸、肉豆蒄酸、棕櫚酸、硬脂酸、花生酸、山萮酸、掬焦油酸(lignoceric acid)、蟲蠟酸(Cerotic acid)、褐煤酸(Montanic acid)、蜂蠟酸(melissic acid)。其中,宜為工業上容易取得之肉豆蒄酸、棕櫚酸、硬脂酸。 The saturated fatty acid constituting the metal salt of a saturated fatty acid has a carbon number of 3 to 29 and is a linear, branched, or cyclic saturated fatty acid. Specific examples thereof include butyric acid, caproic acid, caprylic acid, capric acid, capric acid, undecanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid, and tartaric acid (lignoceric acid). ), Cerotic acid, Montanic acid, Melissic acid. Among them, it is preferably industrially easy to obtain myristic acid, palmitic acid, and stearic acid.
構成飽和脂肪酸金屬鹽的金屬鹽係可舉例如鋰鹽、鈉鹽、鉀鹽、鈣鹽、鎂鹽、鋁鹽、鋅鹽、鋇鹽、及/或其等之複合金屬鹽。其中宜為鋰鹽、鈉鹽、鉀鹽、鈣鹽、鎂鹽、鋁鹽、鋇鹽。鈉鹽為水溶性,在母材之表面處理中必須以水進行洗淨之步驟的電鍍用母材之加工條件可適宜使用。另外,鈣鹽為非水溶性,可以不須要電鍍處理或水洗步驟之母材的加工條件適宜使用。又,從提昇帶狀乾式伸線用潤滑材之耐熱性的觀點,宜為鋰鹽或鉀鹽,從提昇對被拉入於模頭時於線材表面易形成均一的被膜之線材的附著性觀點,宜為鎂鹽或鋁鹽。進一步,鋇鹽係可與鈣鹽一起被使用,可謀求對鈣鹽之耐熱性提昇。 The metal salt constituting the saturated fatty acid metal salt may, for example, be a lithium metal salt, a sodium salt, a potassium salt, a calcium salt, a magnesium salt, an aluminum salt, a zinc salt, a phosphonium salt, and/or a composite metal salt thereof. Among them, lithium salt, sodium salt, potassium salt, calcium salt, magnesium salt, aluminum salt and barium salt are preferred. The sodium salt is water-soluble, and the processing conditions of the base material for electroplating which are required to be washed with water in the surface treatment of the base material can be suitably used. Further, the calcium salt is water-insoluble, and it can be suitably used in the processing conditions of the base material which does not require an electroplating treatment or a water washing step. Moreover, from the viewpoint of improving the heat resistance of the lubricating material for the belt-shaped dry wire, it is preferable to use a lithium salt or a potassium salt, and to improve the adhesion of the wire which is easy to form a uniform film on the surface of the wire when being pulled into the die. It should be magnesium or aluminum salt. Further, the onium salt system can be used together with the calcium salt, and the heat resistance of the calcium salt can be improved.
此等之飽和脂肪酸之金屬鹽係可1種單獨使用,亦可併用2種以上而使用。飽和脂肪酸之金屬鹽係於帶狀乾式伸線用潤滑材中含有10~90重量%,宜為50重量%,更宜為30重量%。若飽和脂肪酸之金屬鹽之含量未達10重量%或超過90重量%,有時耐熱性或潤滑性等之效果降低。 These metal salts of the saturated fatty acids may be used alone or in combination of two or more. The metal salt of the saturated fatty acid is contained in the lubricating material for the belt-like dry type yarn in an amount of 10 to 90% by weight, preferably 50% by weight, more preferably 30% by weight. When the content of the metal salt of the saturated fatty acid is less than 10% by weight or more than 90% by weight, the effects such as heat resistance and lubricity may be lowered.
熱塑性樹脂係可舉例如聚乙烯、聚丙烯、聚苯乙烯、丙烯腈/苯乙烯共聚合樹脂、丙烯腈/丁二烯/苯乙烯共聚合樹脂、乙烯/醋酸乙烯酯共聚合樹脂、甲基丙烯酸樹脂、氯乙烯、聚醯胺、聚縮醛、聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、甲基戊烯、聚碳酸酯、聚苯硫醚、聚醚醚酮、聚四氟乙烯、聚醚醯亞胺、聚芳酸酯、聚碸、聚醚碸、聚醯胺醯亞胺。此等之熱塑性樹脂係可1種單獨使用,亦可併用2種以上而使用。其中,宜為熱安定性優之聚醚碸,可提供耐熱性優異之帶狀乾式伸線用潤滑材。 The thermoplastic resin may, for example, be polyethylene, polypropylene, polystyrene, acrylonitrile/styrene copolymer resin, acrylonitrile/butadiene/styrene copolymer resin, ethylene/vinyl acetate copolymer resin, methacrylic acid. Resin, vinyl chloride, polyamine, polyacetal, polyethylene terephthalate, polybutylene terephthalate, methylpentene, polycarbonate, polyphenylene sulfide, polyetheretherketone, Polytetrafluoroethylene, polyether phthalimide, polyarylate, polyfluorene, polyether oxime, polyamidoximine. These thermoplastic resins may be used alone or in combination of two or more. Among them, a polyether oxime which is excellent in heat stability is preferable, and a lubricating material for a belt-shaped dry stretcher which is excellent in heat resistance can be provided.
熱塑性樹脂係於帶狀乾式伸線用潤滑材中含有10~90重量%,宜為30重量%,更宜為50重量%。若熱塑性樹脂之含量未達10重量%或超過90重量%,有時耐熱性或潤濕性及很難形成帶狀等之效果降低。 The thermoplastic resin is contained in the lubricating material for a belt-like dry wire, and is contained in an amount of 10 to 90% by weight, preferably 30% by weight, more preferably 50% by weight. When the content of the thermoplastic resin is less than 10% by weight or more than 90% by weight, the effects of heat resistance, wettability, and difficulty in forming a belt shape or the like may be lowered.
本發明之帶狀乾式伸線用潤滑材係除了飽和脂肪酸之金屬鹽及熱塑性樹脂之外,亦可依需要而含有無機物及/或添加劑。無機物及/或添加劑之含量係無損帶狀乾式伸線用潤滑材之效果的範圍,在帶狀乾式伸線用潤滑材中,為10~40重量%。 In addition to the metal salt of a saturated fatty acid and a thermoplastic resin, the lubricating material for a ribbon-shaped dry wire of the present invention may contain an inorganic substance and/or an additive as needed. The content of the inorganic substance and/or the additive is not limited to the range of the effect of the lubricating material for the dry-type wire drawing, and is 10 to 40% by weight in the lubricating material for the belt-shaped dry wire.
無機物可舉例如硼酸、硼酸鹽、磷酸鹽、硫酸鹽、碳酸鹽、硝酸鹽、消石灰、氧化鈦、滑石、雲母、石墨、二硫化鉬、層狀複氫氧化物、硫。此等之無機物係可1種單獨使用,亦可併用2種以上而使用。 Examples of the inorganic substance include boric acid, borate, phosphate, sulfate, carbonate, nitrate, hydrated lime, titanium oxide, talc, mica, graphite, molybdenum disulfide, layered double hydroxide, and sulfur. These inorganic substances may be used alone or in combination of two or more.
此等之無機物係藉由與含有作為必要成分之飽和脂肪酸之金屬鹽或熱塑性樹脂之組合,俾可提昇帶狀乾式伸線 用潤滑材之功能性。飽和脂肪酸之金屬鹽與無機物之較佳的組合,例如飽和脂肪酸之金屬鹽為飽和脂肪酸之鈉鹽時,宜為含有水溶性無機物的硼酸,飽和脂肪酸之金屬鹽為飽和脂肪酸的鈣鹽時,宜為含有非水溶性無機物之消石灰。 These inorganic substances can be lifted by a combination of a metal salt or a thermoplastic resin containing a saturated fatty acid as an essential component. The functionality of the lubricating material. A preferred combination of a metal salt of a saturated fatty acid and an inorganic substance, for example, a metal salt of a saturated fatty acid is a sodium salt of a saturated fatty acid, preferably a boric acid containing a water-soluble inorganic substance, and a metal salt of a saturated fatty acid is a calcium salt of a saturated fatty acid. It is a slaked lime containing a water-insoluble inorganic substance.
添加劑係可舉例如硼酸、硼酸鹽、磷酸鹽、硫酸鹽、碳酸鹽、硝酸鹽、消石灰、氧化鈦、滑石、雲母、石墨、二硫化鉬、層狀複氫氧化物、硫。此等之添加劑係可1種單獨使用,亦可併用2種以上而使用。 Examples of the additive include boric acid, borate, phosphate, sulfate, carbonate, nitrate, slaked lime, titanium oxide, talc, mica, graphite, molybdenum disulfide, layered double hydroxide, and sulfur. These additives may be used alone or in combination of two or more.
本發明之帶狀乾式伸線用潤滑材係如以下般做法而製造。 The lubricating material for a belt-shaped dry wire according to the present invention is produced as follows.
於加熱熔融之飽和脂肪酸中使具有構成飽和脂肪酸之金屬鹽之金屬的化合物反應而得到的飽和脂肪酸之金屬鹽10~90重量份、與熱塑性樹脂10~90重量份使用加熱混煉機,混合而加熱混煉。使均一地混煉之後所得到的固體,使用輥輪沖壓或加熱式沖壓機而加壓,形成片狀、薄膜狀、或膜狀,通過片切割機,精加工成帶狀,得到帶狀乾式伸線用潤滑材。 10 to 90 parts by weight of a metal salt of a saturated fatty acid obtained by reacting a compound having a metal of a metal salt of a saturated fatty acid in a heated and melted saturated fatty acid, and 10 to 90 parts by weight of a thermoplastic resin, and mixing with a heating kneader Heat mixing. The solid obtained by uniformly kneading is pressed by a roll press or a heated press to form a sheet, a film, or a film, and is finished into a strip shape by a sheet cutter to obtain a strip-like dry type. Lubricating material for the wire.
飽和脂肪酸之金屬鹽係亦可依需要而預先混合無機物或添加物。飽和脂肪酸之金屬鹽係可使用粉末狀、顆粒狀、塊粒狀、或固形狀。 The metal salt of the saturated fatty acid may be preliminarily mixed with an inorganic substance or an additive as needed. The metal salt of the saturated fatty acid may be in the form of a powder, a granule, a granule, or a solid.
所得到之帶狀乾式伸線用潤滑材係在其寬、厚、及長度中,無特別限定而可依母材及伸線加工條件適當選擇者。數10cm~1m左右的片材直接捲捲成薄片輥狀而直接 形成帶狀使用,但亦可適當裁切而形成捲取之膠帶輥輪狀而形成帶狀使用。 The obtained lubricating material for the belt-shaped dry type yarn is not particularly limited as long as it is wide, thick, and long, and can be appropriately selected depending on the base material and the wire drawing processing conditions. The sheet of several 10cm~1m is directly rolled into a roll shape and directly It is used in the form of a belt, but it can also be appropriately cut to form a tape roll that is wound up to form a belt shape.
帶狀乾式伸線用潤滑材之寬係在伸線加工中,可依母材之形狀或徑或長度或材質而適當調整,無特別限定,但為於其母材之表面形成潤滑被膜的寬,宜與母材之徑同等之程度。 The width of the lubricating material for the band-shaped dry wire is appropriately adjusted in the wire drawing process according to the shape, diameter, length or material of the base material, and is not particularly limited, but the width of the lubricating film is formed on the surface of the base material. It should be equal to the diameter of the parent metal.
帶狀乾式伸線用潤滑材之厚係在伸線加工中,可依母材之形狀或徑或長度或材質而適當調整,無特別限定,但為藉模頭半角而最適度的厚度相異者。若帶狀乾式伸線用潤滑材之膜厚太厚,有時未與母材一起被拉入模頭。 The thickness of the lubricating material for the strip-shaped dry wire is appropriately adjusted in the wire drawing process according to the shape, diameter, length or material of the base material, and is not particularly limited, but the optimum thickness varies depending on the half angle of the die head. By. If the film thickness of the lubricating material for the strip-shaped dry wire is too thick, it may not be pulled into the die together with the base material.
所得到之帶狀乾式伸線用潤滑材係如圖1所示般,例如使用模頭箱3內的模頭4而進行伸線加工時,與金屬製之被加工母材的線材2一起拉入於模頭4而使用。其伸線加工的方法係例如為如以下者。帶狀乾式伸線用潤滑材1係與線材2一起對準模頭孔5並設置,與線材2被拉入同時一邊捲繞於線材2一邊拉入於模頭4。從模頭4被拉拔,線材2係被塑性變形並伸線加工,成為所希望的線材2,與線材2一起被拉入於模頭4之帶狀乾式伸線用潤滑材1係藉壓黏、熱黏於線材2之表面形成潤滑被膜6。 The obtained lubricating material for the belt-shaped dry type wire is pulled together with the wire 2 of the metal base material to be processed, for example, when the wire is processed by the die 4 in the die box 3 as shown in Fig. 1 . Used in the die 4. The method of the wire drawing process is, for example, the following. The lubricating material 1 for the tape-like dry wire is aligned with the wire 2 and placed in the die hole 5, and is drawn into the die 4 while being wound around the wire 2 while being pulled. The wire 2 is drawn from the die 4, and the wire 2 is plastically deformed and stretched to form a desired wire 2, and the lubricating material 1 for the band-shaped dry wire which is pulled into the die 4 together with the wire 2 is pressed. The surface of the wire 2 is adhered to the lubricating and heat-bonding film 6 to form a lubricating film 6.
帶狀乾式伸線用潤滑材1係亦可預先於線材2捲繞成螺旋狀而使用,亦可使線材2以上下或左右挾住而使用。因此,帶狀乾式伸線用潤滑材1之形狀係若為帶狀之膜,不限於平面或平滑性,亦可具有起伏、歪扭、扭 轉、翹曲。 The lubricating material 1 for the tape-like dry wire can also be used by winding the wire 2 in a spiral shape in advance, or by using the wire 2 upside down or left and right. Therefore, the shape of the lubricating material 1 for the belt-shaped dry wire is a belt-shaped film, and is not limited to flatness or smoothness, and may have undulations, twists, and twists. Turn, warp.
又,於線材2捲繞帶狀乾式伸線用潤滑材1時,亦可使用捲繞用之輥輪。例如,如圖2所示般,於線材2沿著帶狀乾式伸線用潤滑材1而使其等以左右一對之輥輪7a挾住,扭轉帶狀乾式伸線用潤滑材1,亦可以上下一對之輥輪7b對線材2挾住以使帶狀乾式伸線用潤滑材1捲繞而旋轉。此時,可捲繞、被覆以使線材2以帶狀乾式伸線用潤滑材1包住,亦可直接保持其狀態拉入於模頭4之模頭孔5。左右一對之輥輪7a及上下一對的輥輪7b係分別隨從模頭孔5被拔出,亦可為自動地旋轉,亦可為藉驅動源(未圖示)之動力自己旋轉。 Moreover, when the wire material 2 is wound around the lubricating material 1 for a belt-shaped dry wire, a roller for winding can also be used. For example, as shown in Fig. 2, the wire 2 is slid along the left and right pair of rollers 7a along the belt-shaped dry wire lubricating material 1 to twist the band-shaped dry wire for lubricating material 1 The wire 2 can be caught by the pair of upper and lower rollers 7b so that the band-shaped dry wire lubricating material 1 is wound and rotated. At this time, the wire 2 can be wound and covered so that the wire 2 is wrapped with the lubricating material 1 for the tape-like dry wire, and can be directly pulled into the die hole 5 of the die 4. The pair of right and left rollers 7a and the pair of upper and lower rollers 7b are respectively pulled out from the die hole 5, and may be automatically rotated or rotated by the power of a drive source (not shown).
於線材2捲繞略廣之帶狀乾式伸線用潤滑材1時,如圖3所示般,使線材2與沿著其形狀而包覆般被覆之帶狀乾式伸線用潤滑材1以在胴體之中間凹陷的左右一對輥輪7c挾住,以帶狀乾式伸線用潤滑材1包住線材2,亦可直接保持其狀態拉入於模頭4之模頭孔5。 When the wire 2 is wound around the lubricating material 1 for the tape-like dry wire which is slightly wide, as shown in FIG. 3, the wire 2 is coated with the lubricating material 1 for the tape-like dry wire which is coated and coated along the shape thereof. The pair of left and right rolls 7c recessed in the middle of the body are caught, and the wire 2 is wrapped with the lubricating material 1 for the belt-shaped dry type wire, and can be directly pulled into the die hole 5 of the die 4.
伸線加工條件係無特別限定,而可在與習知之乾式伸線用潤滑劑同樣的條件下使用。 The wire drawing processing conditions are not particularly limited, and can be used under the same conditions as those of the conventional dry wire lubricant.
母材係只要為如鋼鐵之金屬製即可,無特別限定,具體上可舉例如線材、鋼線、管、棒、桿等。 The base material is not particularly limited as long as it is made of a metal such as steel, and specific examples thereof include a wire, a steel wire, a tube, a rod, a rod, and the like.
母材係亦可依需要而實施前處理。前處理具體上可舉例如酸處理、彎曲化、短脈衝噴砂、氣體噴砂等之表面處理。 The base material can also be pretreated as needed. Specific examples of the pretreatment include surface treatment such as acid treatment, bending, short-pulse blasting, and gas blasting.
以下,詳細說明本發明之實施例,但本發明之範圍係不限定於此等之實施例。 Hereinafter, the embodiments of the present invention will be described in detail, but the scope of the present invention is not limited to the embodiments.
試作適用本發明之帶狀乾式伸線用潤滑材的例表示於實施例1,使適用外之粉末狀的乾式伸線用潤滑劑表示於比較例1,適用外之帶狀聚乙烯表示於比較例2。 An example of the lubricating material for a belt-shaped dry wire drawing to which the present invention is applied is shown in Example 1, and a lubricant for dry wire drawing which is applied in powder form is shown in Comparative Example 1, and a banded polyethylene which is applied is shown in comparison. Example 2.
於具備攪拌裝置之反應容器內,一邊攪拌工業用硬脂酸75重量份,一邊加熱熔解後,加入消石灰25重量份。於此混合物持續加熱攪拌至產生黏性。若混合物變硬,停止加熱攪拌,取出而冷卻,以500網目篩粉碎成通過率為60%左右,得到飽和脂肪酸之金屬鹽之鈣系潤滑劑。使所得到之飽和脂肪酸之金屬鹽70重量份、作為熱塑性樹脂之聚乙烯20重量份使用加熱混煉機(商品名:Laboplast mill)而以180℃進行加熱混煉。使所得到之固體以加熱式沖壓機形成膜厚0.5mm以下之片狀後,使用片切割機而切斷成寬為8mm之帶狀,得到帶狀乾式伸線用潤滑材。 After stirring 75 parts by weight of industrial stearic acid in a reaction vessel equipped with a stirring device, the mixture was heated and melted, and then 25 parts by weight of slaked lime was added. The mixture is continuously heated and stirred until viscosity is generated. When the mixture became hard, the heating and stirring were stopped, and the mixture was taken out and cooled, and pulverized into a 500 mesh sieve to have a pass rate of about 60% to obtain a calcium-based lubricant of a metal salt of a saturated fatty acid. 70 parts by weight of the obtained metal salt of the saturated fatty acid and 20 parts by weight of the polyethylene as the thermoplastic resin were heated and kneaded at 180 ° C using a heating kneader (trade name: Laboplast mill). The obtained solid was formed into a sheet having a film thickness of 0.5 mm or less by a hot press, and then cut into a strip having a width of 8 mm using a sheet cutter to obtain a lubricating material for a belt-shaped dry type strand.
於具備攪拌裝置之反應容器內,一邊攪拌工業用硬脂酸75重量份,一邊加熱熔解後,加入消石灰25重量份。於此混合物持續加熱攪拌至產生黏性。若混合物變硬,停 止加熱攪拌,取出而冷卻,以500網目篩粉碎成通過率為60%左右,得到鈣系乾式伸線用潤滑劑。 After stirring 75 parts by weight of industrial stearic acid in a reaction vessel equipped with a stirring device, the mixture was heated and melted, and then 25 parts by weight of slaked lime was added. The mixture is continuously heated and stirred until viscosity is generated. If the mixture hardens, stop The mixture was heated and stirred, taken out and cooled, and pulverized into a 500 mesh sieve to have a pass rate of about 60% to obtain a calcium-based dry type wire lubricant.
使用聚乙烯利用加熱混煉機(商品名:Laboplast mill)而以180℃進行加熱混煉。使所得到之固體以加熱式沖壓機形成膜厚0.5mm以下之片狀後,切斷成帶狀,得到帶狀聚乙烯。 The polyethylene was heated and kneaded at 180 ° C using a heating kneader (trade name: Laboplast mill). The obtained solid was formed into a sheet having a film thickness of 0.5 mm or less by a heating press, and then cut into a strip shape to obtain a belt-shaped polyethylene.
分別使用作為線材之潤滑劑的實施例1之帶狀乾式伸線用潤滑材、比較例1之鈣系乾式伸線用潤滑劑、及比較例2之帶狀聚乙烯,進行藉伸線機伸線加工時之性能評估。 The use of the lubricating material for the band-shaped dry wire drawing of Example 1 as the lubricant of the wire material, the lubricant for the calcium-based dry wire drawing of Comparative Example 1, and the tape-shaped polyethylene of Comparative Example 2, respectively, were carried out by using a stretcher machine. Performance evaluation during line processing.
使母材之線材(碳鋼72A材)藉12重量%鹽酸水溶液,酸洗除去被加工線材表面的氧化垢後,實施水洗數次,為了酸處理之中和及防銹,浸漬於加熱至80℃左右的1重量% Pollux水溶液。使被加工線材從Pollux水溶液拉起,乾燥,於被加工線材上形成Pollux被膜,進行前處理加工。繼而,於模頭箱內投入1g在實施例1所得到之帶狀乾式伸線用潤滑材,依據線速:40m/分、線徑之縮徑:2.8mm →2.5mm →2.25mm →2.00mm 之3階段、伸線量:2kg之條件,進行已實施前處理之被加工線材的伸線。在3階段之伸線加工中,於只1脈衝使用潤滑 材,在2,3脈衝係未使用潤滑材。 The base material wire (carbon steel 72A material) is acid-washed to remove the scale scale on the surface of the wire to be processed by 12% by weight hydrochloric acid aqueous solution, and then washed several times. For acid treatment neutralization and rust prevention, the immersion is heated to 80. A 1% by weight aqueous solution of Pollux around °C. The wire to be processed is pulled up from the aqueous solution of Pollux, dried, and a Pollux film is formed on the wire to be processed, and pretreated. Then, 1 g of the lubricating material for the strip-shaped dry wire obtained in Example 1 was placed in a die box, and the diameter of the wire diameter was 40 m/min, and the diameter of the wire diameter was 2.8 mm. →2.5mm →2.25mm →2.00mm In the third stage, the amount of the wire is 2 kg, and the wire of the processed wire which has been subjected to the pretreatment is carried out. In the three-stage wire drawing process, the lubricating material was used in only one pulse, and the lubricating material was not used in the 2, 3 pulse system.
同樣地,取代潤滑材而使用比較例1之鈣系乾式伸線用潤滑劑300g、比較例2之帶狀聚乙烯1g而分別進行被加工線材之伸線。 In the same manner, 300 g of the calcium-based dry wire drawing lubricant of Comparative Example 1 and 1 g of the band-shaped polyethylene of Comparative Example 2 were used instead of the lubricating material, and the wire of the processed wire was stretched.
使用各潤滑劑而以目視觀察伸線加工之線材的表面之結果表示於表1中。 The results of visually observing the surface of the wire processed by the wire using each of the lubricants are shown in Table 1.
從表1明顯地,即使在任一者之線徑,實施例1之帶狀乾式伸線用潤滑材係於伸線後之線材表面展黏成帶狀乾式伸線用潤滑材為均一之薄膜狀,但比較例1之習知品的粉末狀之鈣系乾式伸線用潤滑劑係第2脈衝以後,藉乾式伸線用潤滑劑之切膜產生一部分金屬光澤。又,比較例2之熱塑性樹脂單獨的帶狀聚乙烯係從第1脈衝對線材未均一地形成潤滑被膜,而產生金屬金澤。第2脈衝係中止。 It is apparent from Table 1 that even in the wire diameter of either one, the lubricating material for the band-shaped dry wire of Example 1 is adhered to the surface of the wire after the wire is stretched to form a uniform film-like material for the dry wire of the tape-like wire. However, the powdery calcium-based dry-type lubricant for the conventional product of Comparative Example 1 is a second pulse, and a part of the metallic luster is produced by the slit film of the dry-type lubricant for stretching. Further, in the polyethylene resin of the thermoplastic resin of Comparative Example 2, the lubricating film was not uniformly formed from the first pulse to the wire, and metal plaque was generated. The second pulse is aborted.
使伸線加工之線材以伸線線材用洗淨劑(共榮社化學股份公司製:Light Clean A-1)洗淨,從洗淨前後之重量 差算出各潤滑劑的附著量,以雷射顯微鏡放大成400倍而觀察洗淨後線材之表面。其結果表示於表2中。 The wire for the processing of the wire is washed with a detergent for the wire and wire (Light Clean A-1, manufactured by Kyoeisha Chemical Co., Ltd.), and the weight before and after washing. The amount of adhesion of each lubricant was calculated by a difference, and the surface of the wire after washing was observed by a magnification of 400 times with a laser microscope. The results are shown in Table 2.
從表2明顯地,可看出使用實施例1之帶狀乾式伸線用潤滑材時,即使在任一者的線徑,帶狀乾式伸線用潤滑材之附著量有多的傾向,藉由模頭與線材之直接接觸而產生的平坦部分之面積比率(平坦率)相較於比較例而為低的傾向。亦即,確認出伸線狀態良好。然而,比較例1係可看出從第2脈衝以後,平坦率大於實施例1之傾向,在第3脈衝伸線後可看出一部分燒傷。亦即,第3脈衝以後係可確認出伸線狀態不良。至比較例2係較第1脈衝看出更多燒傷。亦即,可確認出伸線狀態不良。 As is apparent from Table 2, when the lubricating material for a belt-shaped dry wire drawing of Example 1 is used, the amount of adhesion of the lubricating material for the tape-shaped dry wire tends to be large even in the wire diameter of either one. The area ratio (flatness) of the flat portion which is produced by direct contact between the die and the wire tends to be lower than that of the comparative example. That is, it is confirmed that the wire is in a good condition. However, in Comparative Example 1, it can be seen that the flatness ratio after the second pulse is larger than that of the first embodiment, and a part of the burn can be seen after the third pulse is stretched. That is, after the third pulse, it was confirmed that the state of the wire was poor. To Comparative Example 2, more burns were seen than in the first pulse. That is, it can be confirmed that the state of the wire is poor.
實施例1之帶狀乾式伸線用潤滑材係習知之乾式伸線用潤滑劑與熱塑性樹脂相互作用,潤滑被膜性、展黏性提高,且為帶狀,故可有效率地被拉入於模頭,形成均一的 潤滑被膜。藉其效果,判斷以少於習知之乾式伸線用潤滑劑的使用量可期待效率佳之伸線加工,又,為帶狀,相較於習知之粉粒的乾式伸線用潤滑劑而不易產生因粉塵造成之作業環境的惡化。 The lubricant for dry-type wire for the dry wire of the first embodiment is a conventional lubricant for stretching wire which interacts with a thermoplastic resin to improve the film property and the adhesion, and has a belt shape, so that it can be efficiently pulled in Die, forming a uniform Lubricate the film. By the effect, it is judged that the use amount of the lubricant for the dry type wire which is less than the conventional one can be expected to be excellent in the drawing process, and is also in the form of a belt, which is less prone to be produced than the lubricant for the dry type of the conventional powder. Deterioration of the working environment caused by dust.
本發明之帶狀乾式伸線用潤滑材係可使用於如鋼鐵之金屬製且使粗徑之線材、鋼絲、管、棒、桿等之母材從模頭等的型鋼拉拔,塑形變形成縮徑之線材或桿材等而縮徑之伸線加工時。 The lubricating material for the strip-shaped dry wire of the present invention can be used for metal materials such as steel, and the base material of a wire, a steel wire, a pipe, a rod, a rod, or the like having a large diameter is drawn from a steel such as a die, and is deformed. When reducing the diameter of the wire or rod, etc., the diameter of the wire is processed.
1‧‧‧帶狀乾式伸線用潤滑材 1‧‧‧Landed dry wire lubricants
2‧‧‧線材 2‧‧‧Wire
3‧‧‧模頭箱 3‧‧‧Model box
4‧‧‧模頭 4‧‧‧Mold
5‧‧‧模頭孔 5‧‧‧Mold hole
6‧‧‧潤滑被膜 6‧‧‧Lubricating film
7a‧‧‧輥輪 7a‧‧‧Roller
7b‧‧‧輥輪 7b‧‧‧Roller
圖1係表示適用本發明之帶狀乾式伸線用潤滑材的使用狀態之概要的剖面圖。 Fig. 1 is a cross-sectional view showing an outline of a state of use of a lubricating material for a belt-shaped dry wire drawing to which the present invention is applied.
圖2係表示藉由適用本發明之伸線方法使帶狀乾式伸線用潤滑材捲繞於線材之中途的剖面圖。 Fig. 2 is a cross-sectional view showing a state in which a lubricating material for a belt-shaped dry wire is wound in a wire by applying a wire drawing method of the present invention.
圖3係表示藉由適用本發明之伸線方法使帶狀乾式伸線用潤滑材夾住線材之中途的剖面圖。 Fig. 3 is a cross-sectional view showing the middle of the wire for dry-stretching of the wire by applying the wire drawing method of the present invention.
圖4係表示適用本發明外之乾式伸線用潤滑劑的使用狀態之概要的剖面圖。 Fig. 4 is a cross-sectional view showing an outline of a state of use of a lubricant for dry wire drawing to which the present invention is applied.
Claims (10)
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US (1) | US20140290320A1 (en) |
JP (1) | JP6085559B2 (en) |
KR (1) | KR20140045406A (en) |
CN (1) | CN103649286A (en) |
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JP2014133813A (en) * | 2013-01-10 | 2014-07-24 | Kyoeisha Chem Co Ltd | Lubricant for belt-like dry wire drawing |
CN103952223B (en) * | 2014-03-28 | 2016-03-02 | 安徽为民磁力科技有限公司 | The environment protection water-based wire drawing liquid of a kind of ground fog |
CN103952219B (en) * | 2014-03-28 | 2016-03-23 | 安徽联硕实业有限公司 | A kind of environmental protection wire drawing liquid of high cleaning performance |
KR101582439B1 (en) * | 2015-04-24 | 2016-01-06 | 주식회사 제이엔에프아이티씨 | Magnesium glasses frame and manufacturing process thereof |
CN105296064A (en) * | 2015-10-22 | 2016-02-03 | 无锡市永亿精密铸造有限公司 | Ceramic lubricant for precise casting parts |
CN105969502A (en) * | 2016-05-10 | 2016-09-28 | 安徽九华金润铜业有限公司 | Drawing oil for quick drawing of enameled wire |
CN113409982B (en) * | 2016-10-31 | 2023-02-17 | 住友电气工业株式会社 | Aluminum alloy wire, aluminum alloy stranded wire, coated electric wire, and electric wire with terminal |
KR102361765B1 (en) * | 2016-10-31 | 2022-02-10 | 스미토모 덴키 고교 가부시키가이샤 | Aluminum alloy wire, aluminum alloy stranded wire, sheathed wire, and terminal-mounted wire |
KR102544287B1 (en) * | 2016-10-31 | 2023-06-15 | 스미토모 덴키 고교 가부시키가이샤 | Aluminum alloy wire, aluminum alloy twisted wire, coated electrical wire, and electrical wire with terminal |
JP6112437B1 (en) | 2016-10-31 | 2017-04-12 | 住友電気工業株式会社 | Aluminum alloy wire, aluminum alloy stranded wire, covered wire, and wire with terminal |
KR102612323B1 (en) * | 2018-08-07 | 2023-12-12 | 제이에프이 스틸 가부시키가이샤 | Steel sheet with lubricating film and method of manufacturing the same |
CN112300854A (en) * | 2020-09-24 | 2021-02-02 | 常州市实创润滑剂有限公司 | Metal wire drawing powder and preparation method thereof |
CN118341927A (en) * | 2024-04-22 | 2024-07-16 | 广东韶铸精锻有限公司 | Multistage warm forging line |
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JPS5053768A (en) * | 1973-09-13 | 1975-05-13 | ||
JPS5838797A (en) * | 1981-08-19 | 1983-03-07 | ペンウオルト・コ−ポレ−シヨン | Lubricant agent for normal temperature formation and method therefor |
JP3678938B2 (en) * | 1999-04-02 | 2005-08-03 | 住友金属工業株式会社 | High temperature plastic processing method of metal and resin film used therefor |
JP2007114443A (en) * | 2005-10-20 | 2007-05-10 | Ricoh Co Ltd | Image carrier, lubricant molding, lubricant applicator, image forming apparatus and process cartridge |
US8637427B2 (en) * | 2008-02-29 | 2014-01-28 | Toyo Seikan Kaisha, Ltd. | Adsorptive composition and adsorptive molded article |
JP5204625B2 (en) * | 2008-11-06 | 2013-06-05 | 共栄社化学株式会社 | Borate-free dry wire drawing lubricant |
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- 2012-07-10 WO PCT/JP2012/067540 patent/WO2013008802A1/en active Application Filing
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JP6085559B2 (en) | 2017-02-22 |
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