CN103911205B - The tin plating very thin plate cold rolling oil of environmental protection and application process thereof - Google Patents
The tin plating very thin plate cold rolling oil of environmental protection and application process thereof Download PDFInfo
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- CN103911205B CN103911205B CN201410167937.8A CN201410167937A CN103911205B CN 103911205 B CN103911205 B CN 103911205B CN 201410167937 A CN201410167937 A CN 201410167937A CN 103911205 B CN103911205 B CN 103911205B
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- rolling oil
- thin plate
- cold rolling
- tin plating
- environmental protection
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Abstract
The invention discloses a kind of tin plating very thin plate cold rolling oil of environmental protection, it is characterized in that: in this ROLLING OIL, the mass percent of each component is: 20～the 2 of the OPEO of the tetramethylolmethane of the trihydroxymethylpropanyl ester of 50%, 20～50%, 5～20%, 5～10%, the dialkyl dithiophosphate of 6 ditertbutylparacresols, 1～5%, 1～5% dodecenylsuccinic acid.The present invention also provides for the application process of the tin plating very thin plate cold rolling oil of a kind of above-mentioned environmental protection.The ROLLING OIL of the present invention, without intense stimulus abnormal smells from the patient, health environment-friendly, has good greasy property, easy to maintenance, and stable performance has excellent rust-preventing characteristic, and after rolling, after annealing, detergency is good.
Description
Technical field
The present invention relates to guard technology field, particularly refer to a kind of tin plating very thin plate of environmental protection
Cold rolling oil and application process thereof.
Background technology
The outstanding problem that China's Tinplate Production exists is seriously to lack uncoated tinplate base, from state
Interior built Tin-Plating Production Line is seen, is all single tin plating production in addition to Baosteel, Wuhan Iron and Steel Plant
Line, enterprise self does not produce uncoated tinplate base, and the raw sheet of needs is outer purchases (mainly import)
Solve.Uncoated tinplate base import not only production cost is high, and external uncoated tinplate base resource has
Limit, buying the most more and more difficulty.Tin plating very thin plate is a kind of complex manufacturing, rolling
Technical merit requires the product that the highest, manufacture difficulty is very big and prescription is the strictest,
And ROLLING OIL is the biggest on the impact of tin plating very thin plate cold rolling.
China's packaging industry maintains sustained and rapid growth, and Packaging Industry market scale is more than 5000
Hundred million yuan, and mental package reaches about 50,000,000,000 yuan, according to development and China of packaging industry
GDP growth rate, tin plate demand sustainable growth, drive cold rolling oil demand
Amount sustainable growth, also brings a series of problem of environmental pollution, is degrading the life of the mankind
Deposit and vegeto-animal growing environment.Thus, use and meet the material of environmental requirement, exploitation
Go out the tin plating very thin plate cold rolling oil product of environmental protection and become very urgent and important.
Summary of the invention
For applicable tin plating very thin plate and environmental protection problem, the invention aims to provide ring
Protecting tin plating very thin plate cold rolling oil and application process thereof, this ROLLING OIL belongs to environment-friendly products,
There is good lubricity and rustless property, be suitable for the cold rolling of tin plating very thin plate.
For achieving the above object, the tin plating very thin plate cold rolling of environmental protection provided by the present invention
Oil, it is characterised in that: in this ROLLING OIL, the mass percent of each component is: 20～50%
The octyl phenol polyoxy second of the tetramethylolmethane of trihydroxymethylpropanyl ester, 20～50%, 5～20%
The dialkyl dithiophosphoric acid of the DBPC 2,6 ditertiary butyl p cresol of alkene ether, 5～10%, 1～5%
Ester, 1～5% dodecenylsuccinic acid.
As a kind of preferred version, in this ROLLING OIL, the mass percent of each component is: 30～
The octylphenol polyethylene of the tetramethylolmethane of trihydroxymethylpropanyl ester, 30～40%, 10～15% of 40%
The dialkyl dithio of the DBPC 2,6 ditertiary butyl p cresol of oxygen vinyl Ether, 5～8%, 3～4%
Phosphate ester, 3～5% dodecenylsuccinic acid.The effect that prioritization scheme is made something perfect even more perfect is described.
As another preferred version, in this ROLLING OIL, the mass percent of each component is:
The trihydroxymethylpropanyl ester of 40%, the tetramethylolmethane of 40%, the OPEO of 8%,
The DBPC 2,6 ditertiary butyl p cresol of 7%, the dialkyl dithiophosphate of 4%, 1% laurylene
Base succinic acid.Ibid.
The present invention also provides for the application side of the tin plating very thin plate cold rolling oil of a kind of above-mentioned environmental protection
Method, the method be by described mass percent take trihydroxymethylpropanyl ester, tetramethylolmethane,
OPEO, DBPC 2,6 ditertiary butyl p cresol, dialkyl dithiophosphate,
These raw materials are uniformly mixed, obtain ROLLING OIL by dodecenylsuccinic acid；Then according to
Mass percent take 2～4% ROLLING OIL with 96～98% water be hybridly prepared into working solution,
It is sprayed onto during cold rolling for steel rider seam, working roll or roll surface.
Preferably, take the ROLLING OIL of 3% according to mass percent to mix with the water of 97%
It is configured to working solution, is sprayed onto during cold rolling for steel rider seam, working roll or support
Roller surface.
The effect of the tin plating very thin plate cold rolling oil each component of environmental protection of the present invention is as follows:
Based on trihydroxymethylpropanyl ester, tetramethylolmethane, oil, is to provide greasy property
Main Components, is also the carrier of other additives.
DBPC 2,6 ditertiary butyl p cresol is as antioxidant.Because Organic substance all contains insatiable hunger
And chemical bond, it is possible to there is multiple chemical reaction with other compound, such as oxidation reaction and
Polyreaction, the oxidation reaction of oil makes oil thinning, and acid number increases, and viscosity reduces, oil film
Thinning, occur that the phenomenons such as muddiness cannot use, be unfavorable for transport and long term storage, poly-
Closing reaction causes oils and fats to solidify, and easily makes strip produce mottling.
Dialkyl dithiophosphate is as extreme pressure anti-wear additives.The sheet metal operation of rolling is general
All high temperature, high pressure operating mode under carry out, need add extreme pressure anti-wear additives to improve oil film
Intensity, reduces friction and glutinous roller phenomenon.
Dodecenylsuccinic acid, as rust-inhibiting additive, can be formed the thinnest in metal surface
Cover layer, completely cut off metal and corrosive medium, the anodic dissolution processes making metal can not
Carry out, be effectively prevented thin plate and produce corrosion, reach good rust-proof effect.
Present invention have the advantage that the ROLLING OIL of the present invention without intense stimulus abnormal smells from the patient,
Health environment-friendly, has good greasy property, easy to maintenance, and stable performance has excellent
Good rust-preventing characteristic, after rolling, after annealing, detergency is good.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment one:
Take trihydroxymethylpropanyl ester 20%, tetramethylolmethane 40%, octyl phenol by mass percentage
Polyoxyethylene ether 20%, 2,6 ditertiary butyl p cresol 10%, dialkyl dithiophosphate
5%, dodecenylsuccinic acid 5%, these raw materials are uniformly mixed, then with 98% water
Be mixed into working solution, can withstand up to during cold rolling 1000MPa pressure and
The high temperature action of 200 DEG C, greasy property is good, and very thin plate occurs without corrosion, and very thin plate moves back
After fire, detergency is good.
Embodiment two: take trihydroxymethylpropanyl ester 50%, tetramethylolmethane by mass percentage
20%, octyl phenol polyoxyethylene (10) ether 15%, 2,6 ditertiary butyl p cresol 8%, two
Alkyl dithiophosphoric acid ester 4%, dodecenylsuccinic acid 3%, these raw materials are uniformly mixed,
Then the water with 97% is mixed into working solution, can withstand up to during cold rolling
The pressure of 1000MPa and the high temperature action of 200 DEG C, greasy property is good, and very thin plate does not goes out
Existing corrosion, after the annealing of very thin plate, detergency is good.
Embodiment three: take trihydroxymethylpropanyl ester 30%, tetramethylolmethane by mass percentage
50%, octyl phenol polyoxyethylene (10) ether 5%, 2,6 ditertiary butyl p cresol 8%, two
Alkyl dithiophosphoric acid ester 3%, dodecenylsuccinic acid 4%, these raw materials are uniformly mixed,
Then the water with 97% is mixed into working solution, can withstand up to during cold rolling
The pressure of 1000MPa and the high temperature action of 200 DEG C, greasy property is good, and very thin plate does not goes out
Existing corrosion, after the annealing of very thin plate, detergency is good.
Embodiment four: take trihydroxymethylpropanyl ester 50%, tetramethylolmethane by mass percentage
30%, octyl phenol polyoxyethylene (10) ether 10%, 2,6 ditertiary butyl p cresol 5%, two
Alkyl dithiophosphoric acid ester 1%, dodecenylsuccinic acid 4%, these raw materials are uniformly mixed,
Then the water with 96% is mixed into working solution, can withstand up to during cold rolling
The pressure of 1000MPa and the high temperature action of 200 DEG C, greasy property is good, and very thin plate does not goes out
Existing corrosion, after the annealing of very thin plate, detergency is good.
Embodiment five: take trihydroxymethylpropanyl ester 40%, tetramethylolmethane by mass percentage
40%, octyl phenol polyoxyethylene (10) ether 8%, 2,6 ditertiary butyl p cresol 7%, two
Alkyl dithiophosphoric acid ester 4%, dodecenylsuccinic acid 1%, these raw materials are uniformly mixed,
Then the water with 96% is mixed into working solution, can withstand up to during cold rolling
The pressure of 1000MPa and the high temperature action of 200 DEG C, greasy property is good, and very thin plate does not goes out
Existing corrosion, after the annealing of very thin plate, detergency is good.
Claims (3)
1. the tin plating very thin plate cold rolling oil of environmental protection, it is characterized in that: in this ROLLING OIL, the mass percent of each component is: the trihydroxymethylpropanyl ester of 40%, the tetramethylolmethane of 40%, the OPEO of 8%, the 2,6 ditertiary butyl p cresol of 7%, the dialkyl dithiophosphate of 4%, 1% dodecenylsuccinic acid.
2. the application process of the tin plating very thin plate cold rolling oil of environmental protection described in a claim 1, it is characterized in that: the method be by described mass percent take trihydroxymethylpropanyl ester, tetramethylolmethane, OPEO, 2,6-ditertbutylparacresol, dialkyl dithiophosphate, dodecenylsuccinic acid, these raw materials are uniformly mixed, obtains ROLLING OIL；Then according to mass percent take 2～4% ROLLING OIL with 96～98% water be hybridly prepared into working solution, during cold rolling, be sprayed onto strip steel roll gap, working roll or roll surface.
The application process of the tin plating very thin plate cold rolling oil of environmental protection the most according to claim 2, it is characterized in that: take the ROLLING OIL of 3% according to mass percent and be hybridly prepared into working solution with the water of 97%, during cold rolling, be sprayed onto strip steel roll gap, working roll or roll surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410167937.8A CN103911205B (en) | 2014-04-24 | 2014-04-24 | The tin plating very thin plate cold rolling oil of environmental protection and application process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410167937.8A CN103911205B (en) | 2014-04-24 | 2014-04-24 | The tin plating very thin plate cold rolling oil of environmental protection and application process thereof |
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| Publication Number | Publication Date |
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| CN103911205A CN103911205A (en) | 2014-07-09 |
| CN103911205B true CN103911205B (en) | 2016-08-24 |
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| CN201410167937.8A Expired - Fee Related CN103911205B (en) | 2014-04-24 | 2014-04-24 | The tin plating very thin plate cold rolling oil of environmental protection and application process thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104498149B (en) * | 2014-12-19 | 2017-04-26 | 奎克化学（中国）有限公司 | Environment-friendly tinned sheet rolling oil and preparation method thereof |
| CN108865371B (en) * | 2018-08-01 | 2021-06-15 | 武汉钢铁有限公司 | Environment-friendly rolling oil for secondary cold rolling |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796594A (en) * | 2012-08-24 | 2012-11-28 | 东北大学 | Cold-rolled sheet rolling emulsified oil containing modified nano copper and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003293797A (en) * | 2002-04-08 | 2003-10-15 | Minebea Co Ltd | Bearing for electronic controlled throttle motor |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796594A (en) * | 2012-08-24 | 2012-11-28 | 东北大学 | Cold-rolled sheet rolling emulsified oil containing modified nano copper and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 绿色环保型的铝材轧制润滑添加剂的研制及其性能;周亚军等;《中国有色金属学报》;20030831;第13卷(第4期);1036-1039 * |
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Effective date of registration: 20170721 Address after: 430083, Hubei Wuhan Qingshan District Factory No. 2 Gate joint stock company organs Patentee after: Wuhan iron and Steel Company Limited Address before: 430080 Wuchang, Hubei Friendship Road, No. A, block, floor 999, 15 Patentee before: Wuhan Iron & Steel (Group) Corp. |
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