TW201249340A - Pest control composition and pest control method - Google Patents
Pest control composition and pest control method Download PDFInfo
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- TW201249340A TW201249340A TW101107479A TW101107479A TW201249340A TW 201249340 A TW201249340 A TW 201249340A TW 101107479 A TW101107479 A TW 101107479A TW 101107479 A TW101107479 A TW 101107479A TW 201249340 A TW201249340 A TW 201249340A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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Abstract
Description
201249340 六、發明說明： 【發明所屬之技術領域】 Φ發明係關於有害生物防除組成物及有害生物的防除 方法者。 【先前技術】 傳統上，作爲有害生物防除組成物之有效成份，已知 有許多化合物（例如參考 The Pesticide Manual-15th edition (BCPC 干IJ) ; ISBN 978-1-901396-18-8、及農藥手 冊 2005年版（社團法人 日本植物防疫協會刊）： ISBN4-88926-099-4)。已知 可芬諾（C h r 〇 m a f e η 〇 z i d e )、201249340 VI. Description of the invention: [Technical field to which the invention pertains] The Φ invention is a method for controlling pests and controlling harmful substances. [Prior Art] Conventionally, as an active ingredient of a pest control composition, many compounds are known (for example, refer to The Pesticide Manual-15th edition (BCPC Dry IJ); ISBN 978-1-901396-18-8, and a pesticide) Handbook 2005 edition (published by the Japan Plant Epidemic Prevention Association): ISBN 4-88926-099-4). Known that Cf r 〇 m a f e η 〇 z i d e ,
滅芬諾（Methoxyfenozide)Methoxyfenozide
及得芬諾（Tebufenozide) 0 C(CHa)aAnd Tebufenozide 0 C(CHa)a
【發明內容】 -5- 201249340 本申請書係關於下述[1]〜[5]之發明者。 [1]含有式（I )SUMMARY OF THE INVENTION -5-201249340 This application is related to the inventors of the following [1] to [5]. [1] contains formula (I)
所表不之喹啉化合物及選自（A)組1種以上之hydrazide 化合物及選自（B)組1種以上之害蟲防除化合物之有害 生物防除組成物。 (A)組：可芬諾（Chromafenozide)、滅芬諾（ Methoxyfenozide)及得芬諾（Tebufenozide)所成群。 (B )組：達特南（Dinotefuran )、乙蟲腈（ Ethiprole )、賽速安（T h i a m e t h o x am )、百滅寧（ Permethrin )、可尼丁 （ C 1 othianidin )及烯啶蟲胺（ Nitenpyram)所成群》 [2] [1]記載之有害生物防除組成物中，喹啉化合物與 hydrazide化合物之重量比爲1000: 1〜1: 1000。 [3] [1]或[2]記載之有害生物防除組成物中，喹啉化合 物與害蟲防除化合物之重量比爲5000: 1〜1: 1000。 [4] 使用有效量之[1]〜[3]中任一項記載之有害生物 防除組成物於植物或植物栽培地之有害生物的防除方法。 [5] [4]記載之有害生物的防除方法中，使用於植物或 植物栽培地之步驟係使用於稻米或稻米栽培地之步驟。 用以實施發明之最佳型態 -6- 201249340 本發明之有害生物防除組成物係含有式（I )The quinoline compound and the hydrazide compound selected from the group consisting of (A) and the pest control composition selected from the group consisting of one or more pest control compounds of the group (B). Group (A): Chromafenozide, Methoxyfenozide and Tebufenozide. Group (B): Dinotefuran, Ethiprole, T hiamethox am, Permethrin, C 1 othianidin and Nitenpyram In the pest control composition described in [2] [1], the weight ratio of the quinoline compound to the hydrazide compound is 1000:1 to 1:1000. [3] The pest controlling composition according to [1] or [2], wherein the weight ratio of the quinoline compound to the pest controlling compound is 5000:1 to 1:1000. [4] A pest control method for controlling a pest in a plant or a plant cultivation site by using the pest according to any one of [1] to [3]. [5] The method for controlling a pest according to [4], wherein the step of plant or plant cultivation is used in a step of growing rice or rice. The best form for carrying out the invention -6- 201249340 The pest control composition of the present invention contains the formula (I)
所表示之喹啉化合物（後述有時記爲本喹啉化合物。）及 選自後述（A )組1種以上之hydrazide化合物（後述有時 記爲本hydrazide化合物。）及選自後述（B)組1種以上 之害蟲防除化合物（後述有時記爲本害蟲防除化合物。） 〇 (A )組：可芬諾（Chromafenozide )、滅芬諾（ Methoxyfenozide)及得芬諾（Tebufenozide)所成群》 (B )組：達特南（Dinotefuran )、乙蟲腈（ Ethiprole )、賽速安（Thiamethoxam )、百滅寧（ Permethrin )、可尼丁 （Clothianidin)及稀陡蟲胺（ Nitenpyram )所成群。 本喹啉化合物係已知之化合物，例如可依據國際公開 第2 00 1/09223 1號手冊所記載之方法製造》 可芬諾（Chromafenozide) '滅芬諾（Methoxyfenozide )、得芬諾（Tebufenozide)、乙蟲腈（Ethiprole)、賽 速安（Thiamethoxam )、百滅寧（Permethrin )、可尼丁 (Clothianidin)及稀陡蟲胺（Nitenpyram)中任一種皆爲 已知之化合物，記載於「The Pesticide Manual-15th edition ( BCPC 刊）；I S B N 9 7 8 - 1 - 9 0 1 3 9 6 - 1 8 - 8」之 2 1 1 ' 764、1074、391、443、1112、879、229 及 817 頁等。此 201249340 等化合物可爲市售製劑，亦可爲依據已知方法所製造者。 本發明之有害生物防除組成物中，作爲本hydrazide 化合物係以可芬諾（Chromafenozide)爲宜。作爲本害蟲 防除化合物係以達特南（Dinotefuran )及可尼丁 （ Clothianidin)爲宜。 本發明之有害生物防除組成物中，本喹啉化合物、本 hydrazide化合物及本害蟲防除化合物之含有比率雖非特 別限定者，但相對於1 〇〇重量份之本喹啉化合物，本 hydrazide化合物通常爲 0.1〜100000重量份，以 1〜 1 0000重量份爲宜，本害蟲防除化合物通常爲0.02〜 100000重跫份，以0.2〜10000重量份尤佳。 本發明之有害生物防除組成物中，本嗤啉化合物及本 hydrazide化合物之重量比（=本喹啉化合物：本hydrazide 化合物）通常爲1000: 1〜1: 100，以100: 1〜1: 100或 1 0 00: 1〜1: 1爲宜。本喹啉化合物及本害蟲防除化合物 之重量比通常爲5000: 1〜1: 1000，以500: 1〜1: 100 爲宜，以400:1〜1:1尤佳。 本發明之有害生物防除組成物係可僅混合本喹啉化合 物、本hydrazide化合物及本害蟲防除化合物者，但通常 可使用混合本唼啉化合物、本hydrazide化合物及本害蟲 防除化合物與惰性載體，因應需要，添加界面活性劑或其 他製劑用輔助劑，製劑化成油劑、乳劑、懸浮劑、水合劑 、顆粒水合劑、粉劑、粒劑等者。 另外，前述經製劑化之有害生物防除組成物係可爲本 -8- 201249340 來狀態或添加其他惰性成份使用。 本發明之有害生物防除組成物中，本喹啉化合物、本 hydrazide化合物及本害蟲防除化合物之合計量’通常爲 0.01〜99重量％，以0.1〜90重量％爲宜，以〇.5〜70重量 %更好。 作爲惰性載體，可列舉固體載體、液體載體等。 作爲固體載體，可舉例如高嶺土黏土、潔帕爾阿塔位 粘土、膨潤土、蒙脫石、酸性白土、葉蠟石、滑石、矽藻 土、方解石等之礦物、玉米芯粉、核桃殼粉等之天然有機 物、尿素等之合成有機物、碳酸鈣、硫酸銨等之鹽類、水 合氧化矽等之合成無機物等所成之微粉末或粒狀物等，作 爲液狀載體，可舉例如二甲苯、烷基苯、甲基萘等之芳香 族烴類、異丙醇、乙二醇、丙二醇、乙二醇單乙醚等之醇 類、丙酮、環己酮、異佛爾酮等之酮類、大豆油、棉籽油 等之植物油、石油系脂肪族烴類、酯類、二甲亞碼、乙腈 及水等。 作爲界面活性劑，可舉例如烷基硫酸酯鹽、烷基芳基 磺酸鹽、二烷基磺基琥珀酸鹽、聚氧乙烯烷基芳基醚磷酸 酯鹽、木質素磺酸鹽' 萘磺酸鹽甲醛聚縮合物等之陰離子 界面活性劑及聚氧乙烯烷基芳基醚、聚氧乙烯烷基聚氧丙 烯嵌段共聚物、山梨糖醇酐脂肪酸酯等之非離子界面活性 劑及烷基三甲基銨鹽等之陽離子界面活性劑。 作爲其他製劑用輔助劑，可舉例如聚乙烯醇、聚乙烯 吡咯烷酮等之水溶性高分子、阿拉伯膠、褐藻酸及其鹽、 -9 - 201249340 CMC (羧甲基纖維素）、黃原膠等之多醣類、鋁鎂矽酸鹽 、氧化鋁溶膠等之無機物、防腐劑、著色劑及PAP (酸性 磷酸異丙酯）、BHT (二丁基羥基甲苯）等之安定化劑。 本發明之有害生物防除組成物係可使用於用以保護植 物，以免對植物進行攝食、吸汁等加害之有害生物（例如 有害昆蟲及有害蟎）之加害。 作爲本發明之有害生物防除組成物具有防除效力之有 害生物係可舉例如後述者。 鱗翅目害蟲：斜紋夜蛾（Spodoptera litura)、（ Plutelle xylostella)、紋白蝶（Pieris rapaecrucivora)、 二化螟 （Chilo suppressalis )、黑點銀紋夜蛾（ Autographa nigrisigna )、薛草蛾(Hel icoverpa assulta ) 、黏夜蛾（Pseudaletia separata )、甘藍夜蛾（Mamestra brassicae )、蘋果小角紋捲葉蛾（Adoxophyes orana fasciata)、棉捲葉野螟（Notarcha derogata)、稻縱捲葉 野螺（Cnaphalocrocis medinalis )、馬鈴薯 _ 蛾（ Phthorimaea operculella ) 、 ( Chilo polychrysus )、三化 虫冥（Tryporyza incertulas )、甜菜夜蛾（Spodoptera exigua)、燕菁夜蛾（Agrotis segetum)、切根蟲（ Agrotis ipsilon )、番節夜蛾（Heliothis armigera)、蘇 芽夜蛾（Heliothis virescens)、玉米穗蟲（Heliothis zea )、稻螺鈴（Naranga aenescens )、玉米螺（Ostrinia nubilalis )、亞洲玉米螟（Ostrinia furnacalis)、直紋稻 弄蝶（Parnara guttata)、茶姬捲葉蛾（Adoxophyes sp.) -10- 201249340 、茶細蛾（Caloptilia theivora )、金紋細蛾（ Phyllonorycter ringoneella )、桃駐果蛾（Carposina niponensis)、桃折心蟲（Grapholita molesta)、蘋果 S 蛾(Cydia pomonella)等。 半翅目害蟲：斑飛蟲（Laodelphax striatellus)、褐 飛蟲（Nilaparvata lugens )、白背飛蟲[(Sogatella furcifera )等之飛蝨類、僞黑尾葉蟬（Nephotettix cincticeps )、台灣黑尾葉蟬（Nephotettix virescens )、 電光葉蟬（Recilia dorsalis)、大貫小綠葉禪（Empoasca onukii)等之葉蟬類、棉既（Aphis gossypii)、桃既（ Myzus persicae)、菜讶（Brevicoryne brassicae)、捲葉 挺(Aphis spiraecola)、馬鈴薯網管赔（Macrosiphum euphorbiae)、馬鈴薯讶（Aulacorthum solani)、稻麥既 (Rhopalosiphum padi )、大結呀（Toxoptera citricidus ) 、桃粉赔（Hyalopterus pruni)、蘋果綿呀（Eriosoma lanigerum)等之扮蟲類、草綠椿象（Nezara antennata) 、盲椿（Trigonotylus caelestialium)、黑條紅椿象（ Graphosoma rubrolineatum ) 、二星幢（Eysarcori s lewisi )、點蜂緣椿象（Riptortus clavetus)、中華稻緣椿（ Leptocorisa chinensis)、圓白星椿（Eysarcoris parvus) 、茶翅椿象（Halyomorpha mista)、稻綠捧象（Nezara viridula )、美洲牧草肓幢（Lygus lineolaris)等之棒象 類、溫室粉蟲（Trialeurodes vaporariorum)、煙草粉 1¾ (B e m i s i a t a b a c i )、柑桔裸粉 1¾ ( D i a 1 e u r 〇 d e s c i t r i )、 -11 - 201249340 W 橘刺粉 1¾ (Aleurocanthus spiniferus)等之粉 1¾ 類、赤 圓介殼蟲（Aonidiella aurantii )、梨圓介殼蟲（ Comstockaspis perniciosa)、橘盾介殼蟲（Unaspis citri )、紅蠘介殼蟲（Ceroplastes rubens)、吹綿介殼蟲（ Icerya purchasi)、臀紋粉介殻蟲（Planococcus kraunhiae ) 、 (Pseudococcus longispinis ) 、桑介殼蟲（The quinoline compound (which may be referred to as a quinoline compound described later) and one or more hydrazide compounds (hereinafter referred to as a hydrazide compound as described later) of the group (A) described later are selected from the following (B). One or more pest control compounds (hereinafter sometimes referred to as pest control compounds). Group (A): Chromafenozide, Methoxyfenozide, and Tebufenozide Group (B): Dinotefuran, Ethiprole, Thiamethoxam, Permethrin, Clothianidin, and Nitenpyram . The present quinoline compound is a known compound, for example, it can be produced according to the method described in the International Publication No. 2 00 1/09223 1 "Chromafenozide" Methoxyfenozide, Tebufenozide, Any of Ethiprole, Thiamethoxam, Permethrin, Clothianidin, and Nitenpyram is a known compound and is described in The Pesticide Manual. -15th edition (BCPC); ISBN 9 7 8 - 1 - 9 0 1 3 9 6 - 1 8 - 8" 2 1 1 '764, 1074, 391, 443, 1112, 879, 229 and 817 pages, etc. The compound such as 201249340 may be a commercially available preparation or may be produced according to a known method. In the pest control composition of the present invention, Chromafenozide is preferably used as the hydrazide compound. As the pest control compound, Dinotefuran and Clothianidin are preferred. In the pest control composition of the present invention, the content ratio of the present quinoline compound, the hydrazide compound, and the pest control compound is not particularly limited, but the hydrazide compound is usually used in an amount of 1 part by weight of the present quinoline compound. It is preferably from 0.1 to 100,000 parts by weight, preferably from 1 to 1,000,000 parts by weight, and the pest controlling compound is usually from 0.02 to 100,000 parts by weight, more preferably from 0.2 to 10,000 parts by weight. In the pest control composition of the present invention, the weight ratio of the present porphyrin compound to the hydrazide compound (= the present quinoline compound: the hydrazide compound) is usually 1000:1 to 1:100, to 100:1 to 1:100 Or 1 0 00: 1~1: 1 is appropriate. The weight ratio of the present quinoline compound to the pest control compound is usually 5000:1 to 1:1000, preferably 500:1 to 1:100, and particularly preferably 400:1 to 1:1. The pest control composition of the present invention may be mixed only with the quinoline compound, the hydrazide compound and the pest control compound, but generally, the mixed porphyrin compound, the hydrazide compound, the pest control compound and the inert carrier may be used, and It is necessary to add a surfactant or other auxiliary agent for formulation, and to prepare an oil-forming agent, an emulsion, a suspension, a hydrating agent, a granule hydrating agent, a powder, a granule, and the like. Further, the aforementioned formulated pest control composition may be used in the state of -8-201249340 or other inert ingredients may be added. In the pest control composition of the present invention, the total amount of the present quinoline compound, the hydrazide compound and the pest control compound is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight, preferably 〇.5 to 70. The weight % is better. As an inert carrier, a solid carrier, a liquid carrier, etc. are mentioned. Examples of the solid carrier include minerals such as kaolin clay, jiepal ata clay, bentonite, montmorillonite, acid white clay, pyrophyllite, talc, diatomaceous earth, calcite, corn cob powder, walnut shell powder, and the like. a fine organic powder, a synthetic organic substance such as urea, a salt such as calcium carbonate or ammonium sulfate, or a synthetic inorganic substance such as hydrated cerium oxide, or the like, and a liquid carrier, for example, xylene, An aromatic hydrocarbon such as alkylbenzene or methylnaphthalene, an alcohol such as isopropyl alcohol, ethylene glycol, propylene glycol or ethylene glycol monoethyl ether; a ketone such as acetone, cyclohexanone or isophorone; Vegetable oil such as soybean oil or cottonseed oil, petroleum aliphatic hydrocarbons, esters, dimethyl methacrylate, acetonitrile, water, and the like. As the surfactant, for example, an alkyl sulfate salt, an alkyl aryl sulfonate, a dialkyl sulfosuccinate, a polyoxyethylene alkyl aryl ether phosphate, a lignosulfonate 'naphthalene Anionic surfactant such as sulfonate formaldehyde polycondensate and nonionic surfactant such as polyoxyethylene alkyl aryl ether, polyoxyethylene alkyl polyoxypropylene block copolymer, sorbitan fatty acid ester And a cationic surfactant such as an alkyltrimethylammonium salt. Examples of the auxiliary agent for other preparations include water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone, gum arabic, alginic acid and salts thereof, -9 - 201249340 CMC (carboxymethyl cellulose), xanthan gum, and the like. An antioxidant such as an inorganic substance such as a polysaccharide, an aluminum magnesium silicate or an alumina sol, a preservative, a coloring agent, and a stabilizer such as PAP (isopropyl acid phosphate) or BHT (dibutylhydroxytoluene). The pest control composition of the present invention can be used for the purpose of protecting plants from the harmful effects of harmful substances (e.g., harmful insects and harmful mites) which ingest plants, absorb juice, and the like. The harmful biological system which has the control effect of the pest control composition of the present invention may be, for example, described later. Lepidoptera pests: Spodoptera litura, (Plutelle xylostella), Pieris rapaecrucivora, Chilo suppressalis, Autographa nigrisigna, Hel icoverpa assulta , Pseudaletia separata, Mamestra brassicae, Adoxophyes orana fasciata, Notarcha derogata, Cnaphalocrocis medinalis, potato _ Moth ( Phthorimaea operculella ) , ( Chilo polychrysus ), Tryporyza incertulas, Spodoptera exigua, Agrotis segetum, Agrotis ipsilon, and Spodoptera litura ( Heliothis armigera), Heliothis virescens, Heliothis zea, Naranga aenescens, Ostrinia nubilalis, Ostrinia furnacalis, and straight-leaved rice Parnara guttata), Adoxophyes sp. -10- 201249340, Tea moth (Ca Loptilia theivora ), Phyllonorycter ringoneella, Carposina niponensis, Gramholita molesta, Cydia pomonella, and the like. Hemipteran pests: Laodelphax striatellus, Nilaparvata lugens, white-backed flying insects (Sogatella furcifera, etc., Nephotettix cincticeps, Taiwan black-tailed leaves) Nephotettix virescens, Recilia dorsalis, Empoasca onukii, Aphis gossypii, Myzus persicae, Brevicoryne brassicae, rolls Aphis spiraecola, Macrosiphum euphorbiae, Aulacorthum solani, Rhopalosiphum padi, Toxoptera citricidus, Hyalopterus pruni, Eriosoma Lanigerum), such as Nezara antennata, Trigonotylus caelestialium, Graphosoma rubrolineatum, Eysarcori s lewisi, Riptortus clavetus, Zhonghua rice Leptocorisa chinensis, Eysarcoris parvus, and tea-winged elephant (Halyomorpha mist) a), Nezara viridula, Lygus lineolaris, such as rods, Trialeurodes vaporariorum, tobacco powder 13⁄4 (B emisiatabaci), citrus bare powder 13⁄4 (Dia 1 eur 〇descitri ), -11 - 201249340 W Powder 13⁄4, Aleurocanthus spiniferus, Aonidiella aurantii, Comstockaspis perniciosa, Unaspis citri ), Ceroplastes rubens, Icerya purchasi, Planococcus kraunhiae, (Pseudococcus longispinis), Mulberry scale insect (
Pseudaulacaspis pentagona)等之介殼蟲類、花扁蟲類、 溫帶臭蟲（Cimex lectularius )等之床蟲類、黃木蟲（ Cacopsyllapyricola)等之木蝨類等。 纓翅目：西方花薊馬（Frankliniella occidentalis)、 南黃 Μ 馬（Thrips parmi)、小黃萷馬（Scirtothrips dorsalis)、憩薊馬（Thrips tabaci)、台灣花薊馬（ Frankliniella intonsa)、褐花莉馬（Frankliniella fusea) '洋蔥薊馬（Thrips tabaci)、稻薊馬（Stenchaetothrips biformis)、稻管薊馬（Haplothrips aculeatus)等之薊馬 類等： 前述有害生物中，作爲適合例，可列舉螟蛾類、飛蝨 類、葉蟬類、蚜蟲類、椿象類等。 本發明之有害生物防除組成物亦可於防除植物病害之 目的使用，可防除例如稻米的稻熱病（Magnaporthe grisea ) 及稻米的稻胡麻葉枯病 （Cochliobolus miyabeanus)等之枯穗性病害。 本發明之有害生物防除組成物係藉由使用於植物或植 物栽培地，使用於防除有害生物用。在此，本發明之有害 ⑧ -12- 201249340 生物防除組成物係可使用於植物的莖葉、植物的花、植物 果實、植物種子等之植物的各部位或全部部位。 本發明之有害生物的防除方法係藉由以本發明之有害 生物防除組成物處理植物所進行，但具體上可藉由莖葉散 佈等之對植物莖葉之處理、土壤處理、水面施用等之對植 物栽培地的處理等所進行。 將本發明之有害生物組成物，對植物或植物栽培地進 行處理時，該處理量係可依處理植物的種類、防除對象之 有害生物的種類或發生程度、製劑型態、處理時期、氣象 條件等而改變，但作爲本喹啉化合物、本hydrazide化合 物及本害蟲防除化合物之合計量，每1 000m2之栽培該植 物之地點，通常爲0.5〜3000g，以5〜300g爲宜。 乳化劑、水合劑、懸浮劑等通常可以水稀釋後散佈》 此時’本喹啉化合物、本hydrazide化合物及本害蟲防除 化合物之合計濃度範圍，通常爲〇.〇0〇〇〇1〜1〇重量％，以 0·0000 1〜5重量％爲宜，進而以〇.〇〇〇〇丨〜0.005重量％尤 佳°粉劑、粒劑等通常是不稀釋而可直接處理使用。 本發明之有害生物的防除方法係可使用於旱田、水田 '乾田 '草地 '果樹園等之農耕地或非農耕地用。 農作物：玉黍蜀、稻米、小麥、大麥、黑麥、燕麥、 高梁、棉花、大豆、落花生、蒿麥、甜菜、油菜籽、向曰 葵 '甘蔴、菸草等。 蔬菜：茄科蔬菜（茄子、蕃茄、青椒、辣椒、馬鈴薯 等）、瓜科蔬菜（小黃瓜、南瓜、櫛瓜、西瓜、哈密瓜等 -13- 201249340 )、十字花科蔬菜（油菜、蘿蔔、蕪菁、辣根'大頭菜、 白菜、高麗菜、芥菜、青花菜、花椰菜等）'菊科蔬菜（ 牛蒡、春菊、朝鮮薊、萵巨等）、百合科蔬菜（蔥、洋蔥 、蒜頭、蘆筍等）、繳形花科蔬菜（紅蘿蔔、巴西利、芹 菜、歐防風等）、藜科蔬菜（菠菜、窘蓮菜等）、紫蘇科 蔬菜（紫穌、薄荷、羅勒等）、草舊、蕃薯、山藥、里宇 等。 果樹·仁果類（鎮果、西洋梨、日本梨、木瓜、溫棒 等）、核果類（桃子、李子、油桃、梅子、黃桃、杏桃、 棗子等）、柑橘類（溫州蜜根、柳檀、檸檬.、萊姆、葡萄 柚等）、堅果類（栗子、核桃、榛果、杏仁果、開心果、 腰果、夏威夷火山豆等）、漿果類（藍莓、蔓越莓、黑莓 、覆盆子等）、葡萄、柿子、橄欖、枇杷、香蕉、咖啡、 棗椰子、椰子、油椰子等。 果樹以外的樹木：茶樹、桑樹、花木類（杜鵑花、椿 、繡球花、山茶花、白花八角、櫻花樹、鵝掌楸、紫薇、 桂花樹等）、路樹（日本榉、樺樹、大花四照花、尤加利 樹'銀杏樹、紫丁香、槭樹、櫟樹、白楊木、紫荆、楓樹 、懸鈴木、櫸木、日本香柏、樅樹、鐵杉、杜松、松樹、 雲杉、紅豆杉、榆樹、日本七葉樹等）、珊瑚樹、羅漢松 、杉、檜木、巴豆、日本衛矛、紅芽石楠等。 草地：結縷草類（朝鮮草、馬尼拉草等）、狗牙根草 類（行儀草等）、糠穗草類（小糠穗草、蔓糠穗草、霞糠 穗草等）、蘭草類（原野早熟禾、粗莖早熟禾等）、羊茅 -14- 201249340 類（章狀羊茅、紫羊茅（chewings fescue )、紫羊茅（ creeping red fescue)等）、黑麥草類（多花黑麥草 '黑 麥草等）、鴨茅、梯牧草等。 其他：花卉類（玫瑰、康乃馨、菊、土耳其桔梗、滿 天星、非洲菊、金盞花、鼠尾草、矮牽牛、馬鞭草、鬱金 香、翠菊、龍膽草、百合、三色堇、仙客來 '蘭花、鈴蘭 、薰衣草、紫羅蘭、葉牡丹、報春花、聖誕紅、劍蘭、嘉 德利亞蘭、雛菊、蕙蘭、海棠等）、生質燃料植物（麻瘋 樹、紅花、亞麻薺類、柳枝稷、芒草 '加拿麗鹬草 '蘆竹 、洋麻、木薯、柳等）、觀葉植物等。 前述植物中，作爲適合例，可列舉玉黍蜀、小麥、稻 米等。其中以稻米尤佳。 前述「植物」亦可爲藉由基因重組技術或交配之育種 法而被賦予耐性之植物。 【實施方式】 實施例 以下係以製劑例及實施例更詳細地說明本發明，但本 發明並非局限於後述例者。另外，於以下例中，份係只要 無特別限制，皆表示重量份。 首先表示製劑例。 製劑例1 將15份之本喹啉化合物、8份之可芬諾（ -15- 201249340Pseudaulacaspis pentagona), such as scale insects such as scale insects, genus flatworms, medullary bed bugs (Cimex lectularius), and hibiscus such as Cacopsyllapyricola. Thysanoptera: Frankliniella occidentalis, Thrips parmi, Scirthothrips dorsalis, Thrips tabaci, Frankliniella intonsa, brown flower Frankliniella fusea "Thrips tabaci", Stentchaetothrips biformis, and horses such as Haplothrips aculeatus: Among the above-mentioned pests, examples of suitable pests include 螟Moths, planthoppers, leafhoppers, mites, and mites. The pest control composition of the present invention can also be used for the purpose of controlling plant diseases, and can prevent rice ear diseases such as rice rice fever (Magnaporthe grisea) and rice rice leaf blight (Cochliobolus miyabeanus). The pest control composition of the present invention is used for controlling pests by being used in plants or plant cultivation sites. Here, the harmful 8-12-201249340 biological control composition of the present invention can be used for various parts or all parts of plants such as stems and leaves of plants, flowers of plants, plant fruits, plant seeds and the like. The method for controlling the harmful organism of the present invention is carried out by treating the plant with the pest control composition of the present invention, but specifically, the treatment of plant stems and leaves, soil treatment, water surface application, etc. by stem and leaf dispersion or the like The treatment of the plant cultivation site is carried out. When the pest composition of the present invention is treated on a plant or a plant cultivation site, the treatment amount can be determined according to the type of the plant to be treated, the type or degree of occurrence of the pest, the preparation type, the treatment period, and the meteorological condition. The content of the present quinoline compound, the hydrazide compound, and the pest control compound is usually 0.5 to 3000 g per 5 m 2 of the plant, and preferably 5 to 300 g. Emulsifiers, hydrating agents, suspending agents, etc. can usually be diluted with water and then dispersed. The total concentration range of the present quinoline compound, the hydrazide compound and the pest control compound is usually 〇.〇0〇〇〇1~1〇 The weight % is preferably 0.0000 to 5% by weight, and further preferably 〇.〇〇〇〇丨~0.005 wt%. The powder, granules and the like are usually used without treatment and can be directly treated. The method for controlling pests of the present invention can be used for agricultural fields or non-agricultural fields such as dry fields, paddy fields, 'dry fields', grass trees, orchards. Crops: maize, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, groundnuts, artemisia, beets, rapeseed, stalks, stalks, tobacco, etc. Vegetables: Solanaceae vegetables (eggplant, tomato, green pepper, pepper, potato, etc.), melon vegetables (glybdenum, pumpkin, melon, watermelon, cantaloupe, etc. -13-201249340), cruciferous vegetables (canola, radish, turnip , horseradish 'kohlrabi, cabbage, cabbage, mustard, broccoli, broccoli, etc.) 'Asteraceae vegetables (burdock, chrysanthemum, artichoke, arboreal, etc.), liliaceae vegetables (onions, onions, garlic, asparagus, etc.), Shaped flower vegetables (carrots, Basil, celery, European wind, etc.), leeks (spinach, scallions, etc.), sage vegetables (purple, mint, basil, etc.), grass, sweet potato, Yam, Liyu, etc. Fruit trees, pome fruit (town fruit, western pear, Japanese pear, papaya, warm bar, etc.), stone fruit (peach, plum, nectarine, plum, peach, apricot, date, etc.), citrus (Wenzhou honey root, Willow, lemon, lime, grapefruit, etc., nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, Hawaiian volcanic beans, etc.), berries (blueberries, cranberries, blackberries, covered) Berry, etc.), grapes, persimmons, olives, alfalfa, bananas, coffee, date palm, coconut, oil coconut, etc. Trees other than fruit trees: tea trees, mulberry trees, flowers and trees (azalea, medlar, hydrangea, camellia, white flower octagonal, cherry tree, tulip tree, crape myrtle, osmanthus tree, etc.), road tree (Japanese carp, birch, large flower Four flowers, eucalyptus tree 'ginkgo tree, lilac, maple, eucalyptus, aspen, bauhinia, maple, sycamore, eucalyptus, Japanese cedar, eucalyptus, hemlock, juniper, pine, spruce, Yew, eucalyptus, Japanese horse chestnut, etc.), coral tree, Podocarpus, cedar, eucalyptus, croton, Japanese lance, red bud. Grassland: Zoysia (Korean grass, Manila grass, etc.), Bermudagrass (walking grass, etc.), sorghum grass (small sedge grass, sorghum grass, sorghum grass, etc.), bluegrass ( Wild bluegrass, bluegrass, etc.), Fescue-14-201249340 (chapteris, purple feathers (chewings fescue), purple fescue (creeping red fescue), etc.), ryegrass (multiple black) Wheat straw 'rye grass, etc.), duckgrass, ladder grass and so on. Others: flowers (roses, carnations, chrysanthemums, platycodon grandiflorum, gypsophila, gerbera, calendula, sage, petunia, verbena, tulip, aster, gentian, lily, pansy, cyclamen Come to 'orchid, lily of the valley, lavender, violet, leaf peony, primrose, Christmas red, gladiolus, garland, daisy, cypress, sea bream, etc.), raw fuel plants (jatropha, safflower, linseed, switchgrass) , Miscanthus 'Canada 鹬 ' 'Luzhu, kenaf, cassava, willow, etc.), foliage plants and so on. Among the above plants, examples of suitable examples include maize, wheat, rice, and the like. Among them, rice is especially good. The aforementioned "plant" may also be a plant to which tolerance is imparted by genetic recombination techniques or mating breeding methods. [Embodiment] Hereinafter, the present invention will be described in more detail by way of formulation examples and examples, but the present invention is not limited to the examples described below. Further, in the following examples, the parts are all parts by weight unless otherwise specified. First, the formulation examples are shown. Formulation Example 1 15 parts of the present quinoline compound, 8 parts of cofino ( -15- 201249340)
Chromafenozide )及 15 份之達特南（Dinotefuran)，加 入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣、20 份之水合氧化矽微粉末及36份之矽藻土中，充份攪拌混 合而得水合劑。 製劑例2 將 15份之本喹啉化合物、8份之可芬諾（ Chromafenozide)及 15 份之乙蟲腈（Ethiprole)，加入於 混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣、20份之 水合氧化矽微粉末及36份之矽藻土中，充份攪拌混合而 得水合劑。 製劑例3 將 15份之本唾啉化合物、8份之可芬諾（ Chromafenozide)及 15 份之賽速安（Thiamethoxam)， 加入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣、 20份之水合氧化矽微粉末及36份之矽藻土中，充份攪拌 混合而得水合劑。 製劑例4 將 15份之本喹啉化合物、8份之可芬諾（ Chromafenozide)及 15 份之百滅寧（Permethrin)，加入 於混合4份之月桂基硫酸鈉' 2份之木質素磺酸鈣、20份 之水合氧化矽微粉末及36份之矽藻土中’充份攪拌混合 -16- 201249340 而得水合劑。 製劑例5 將15份之本喹啉化合物、8份之可芬Chromafenozide ) and 15 parts of Dinotefuran, added in 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of hydrated cerium oxide micropowder and 36 parts of diatomaceous earth. The mixture is thoroughly stirred and mixed to obtain a hydrating agent. Formulation Example 2 15 parts of the quinoline compound, 8 parts of Chromafenozide and 15 parts of ethiprole were added to 4 parts of sodium lauryl sulfate and 2 parts of lignosulfonic acid. Calcium, 20 parts of hydrated cerium oxide micropowder and 36 parts of diatomaceous earth were mixed with stirring to obtain a hydrating agent. Formulation Example 3 15 parts of the present porphyrin compound, 8 parts of Chromafenozide and 15 parts of Thiamethoxam were added to 4 parts of sodium lauryl sulfate and 2 parts of lignosulfonic acid. Calcium, 20 parts of hydrated cerium oxide micropowder and 36 parts of diatomaceous earth were mixed with stirring to obtain a hydrating agent. Formulation Example 4 15 parts of the quinoline compound, 8 parts of Chromafenozide and 15 parts of Permethrin were added to mix 4 parts of sodium lauryl sulfate' 2 parts of lignosulfonic acid Calcium, 20 parts of hydrated cerium oxide micropowder and 36 parts of diatomaceous earth 'sufficiently stirred and mixed-16-201249340 to obtain a hydrating agent. Formulation Example 5 15 parts of the quinoline compound, 8 parts of cofen
Chromafenozide)及 15 份之可尼丁（Clothianidin) 入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣 份之水合氧化矽微粉末及36份之矽藻土中’充份攪 合而得水合劑。 製劑例6 將 15份之本喹咐化合物、8份之可芬 Chromafenozide)及 15 份之稀 U定蟲胺（Nitenpyram) 入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣 份之水合氧化矽微粉末及36份之矽藻土中，充份攪 合而得水合劑。 製劑例7 藉由將1份之本喹啉化合物、0.5份之可芬 Chromafenozide )及 2 份之達特南（Dinotefuran)、 份之高嶺土黏土及1 〇份之滑石，充份地粉碎混合， 粉劑。 製劑例8 藉由將1份之本唾啉化合物、0.5份之可芬 諾（ ，加 > 20 拌混 諾（ ，加 、20 拌混 諾（ 86.5 得到 諾（ -17- 201249340Chromafenozide) and 15 parts of Clothianidin in a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate hydrated cerium oxide micropowder and 36 parts of diatomaceous earth Get a hydrating agent. Formulation Example 6 15 parts of the quinacridine compound, 8 parts of Chromafenozide, and 15 parts of Nitenpyram were mixed in 4 parts of sodium lauryl sulfate and 2 parts of calcium lignosulfonate. The hydrated cerium oxide micropowder and 36 parts of diatomaceous earth were thoroughly stirred to obtain a hydrating agent. Formulation Example 7 is thoroughly pulverized and mixed by mixing 1 part of the quinoline compound, 0.5 part of Chromafenozide and 2 parts of Dinotefuran, part of kaolin clay and 1 part of talc. . Formulation Example 8 by adding 1 part of the present porphyrin compound, 0.5 part of cofinol (, plus > 20 mix and mix (, plus, 20 mix and mix (86.5 get promise (-17- 201249340)
Chromafenozide)及 2 份之乙蟲腈（Ethiprole) 、86.5 份 之高嶺土黏土及1 〇份之滑石，充份地粉碎混合，得到粉 劑。 製劑例9 藉由將1份之本喹啉化合物、0.5份之可芬諾（ Chromafenozide)及 2 份之賽速安（Thiamethoxam)、 8 6.5份之高嶺土黏土及10份之滑石，充份地粉碎混合， 得到粉劑。 製劑例1 0 藉由將1份之本喹啉化合物、0.5份之可芬諾（ Chromafenozide)及 2 份之百滅寧（Permethrin) 、86.5 份之高嶺土黏土及1 0份之滑石，充份地粉碎混合，得到 粉劑。 製劑例1 1 藉由將1份之本喹啉化合物、0.5份之可芬諾（ Chromafenozide)及 1.5 份之可尼丁（Clothianidin) 、87 份之高嶺土黏土及1 〇份之滑石，充份地粉碎混合，得到 粉劑。 製劑例1 2 藉由將1份之本唾啉化合物、0.5份之可芬諾（ -18- 201249340Chromafenozide) and 2 parts of Ethiprole, 86.5 parts of kaolin clay and 1 part of talc are thoroughly pulverized and mixed to obtain a powder. Formulation Example 9 was thoroughly pulverized by using 1 part of the quinoline compound, 0.5 part of Chromafenozide, and 2 parts of Thiamethoxam, 8 6.5 parts of kaolin clay, and 10 parts of talc. Mix to get a powder. Formulation Example 10 is fully provided by using 1 part of the quinoline compound, 0.5 part of Chromafenozide, 2 parts of Permethrin, 86.5 parts of kaolin clay, and 10 parts of talc. The mixture was pulverized to obtain a powder. Formulation Example 1 1 satisfactorily by using 1 part of the quinoline compound, 0.5 part of Chromafenozide, 1.5 parts of Clothianidin, 87 parts of kaolin clay, and 1 part of talc. The mixture was pulverized to obtain a powder. Formulation Example 1 2 by using 1 part of the present porphyrin compound, 0.5 part of cofinol (-18-201249340)
Chromafenozide)及 1.5 份之稀淀蟲胺（Nitenpyram)、 87份之高嶺土黏土及10份之滑石，充份地粉碎混合，得 到粉劑。 製劑例13 將 1〇份之本喹啉化合物、4份之可芬諾（ Chromafenozide) 、6 份之達特南（Dinotefuran) 、30 份 之聚氧乙烯烷基醚硫酸銨鹽與白碳黑之混合物（重量比爲 5 0 : 5 0 )及5 0份的水混合，藉由以濕式粉碎法進行微粉 碎，得到懸浮劑。 製劑例14 將 1〇份之本喹啉化合物、4份之可芬諾（ Chromafenozide) 、6 份之乙蟲腈（Ethiprole) 、30 份之 聚氧乙烯烷基醚硫酸銨鹽與白碳黑之混合物（重量比爲50 :50)及50份的水混合，藉由以濕式粉碎法進行微粉碎 ，得到懸浮劑。 製劑例15 將 10份之本喹啉化合物、4份之可芬諾（ Chromafenozide ) 、6 份之賽速安（Thiamethoxam) 、30 份之聚氧乙烯烷基醚硫酸銨鹽與白碳黑之混合物（重量比 爲50 : 50 )及50份的水混合，藉由以濕式粉碎法進行微 粉碎，得到懸浮劑。 -19- 201249340 製劑例1 6 將10份之本喹啉化合物、4份之可芬諾（ Chromafenozide ) 、6 份之百滅寧（Permethrin) 、30 份 之聚氧乙烯烷基醚硫酸銨鹽與白碳黑之混合物（重量比爲 5 0 : 5 0 )及5 0份的水混合，藉由以濕式粉碎法進行微粉 碎，得到懸浮劑。 製劑例17 將 10份之本喹啉化合物、4份之可芬諾（ Chromafenozide) 、6 份之可尼丁（Clothianidin) '30 份 之聚氧乙烯烷基醚硫酸銨鹽與白碳黑之混合物（重量比爲 5 〇 : 5 0 )及5 0份的水混合，藉由以濕式粉碎法進行微粉 碎，得到懸浮劑。 製劑例1 8 將 10份之本喹啉化合物、4份之可芬諾（ Chromafenozide) 、6 份之烯啶蟲胺（Nit enpyram ) 、3 0 份之聚氧乙烯烷基醚硫酸銨鹽與白碳黑之混合物（重量比 爲50: 50)及50份的水混合，藉由以濕式粉碎法進行微 粉碎，得到懸浮劑。 接著，以試驗例表示本發明之效果。 試驗例1 ⑧ -20- 201249340 將各 10mg 之本喹啉化合物、可芬諾（ Chromafenozide )、達特南（Dinotefuran )、乙蟲腈（ Ethiprole )、賽速安（Thiamethoxam )、可尼丁 （ Clothianidin)及稀陡蟲胺（Nitenpyram)，分別溶解於 lml之含Sorgen TW-2 0 (第一工業製藥製）之丙酮（和光 純藥工業製）後，以含有0.02容量％之展著劑（商品名： Dain (註冊商標），住化武田園藝製）的水稀釋成規定濃 度。混合本喹啉化合物水稀釋液與可芬諾（ Chromafenozide)水稀釋液及達特南（Dinotefuran)、乙 蟲腈（Ethiprole)、賽速安（Thiamethoxam)、可尼丁（ Clothianidin)或嫌u定蟲胺（Nitenpyram)的水稀釋液，調 製試驗用藥液。 播種於放入培養土之塑膠製栽培缽，育苗15天程度 ，對3片本葉完全展開的稻米（Oryza sativa，品種：七 星），使用噴霧槍將前述試驗用藥劑液，對每一缽進行散 布處理10ml。風乾後，與稻熱病發病的稻米一同放入25 °C的濕室（濕度爲9 5 -1 0 0 % )內，靜置2 4小時。之後， 分離前述稻熱病發病的稻米後，於前述濕室內栽培5天， 測定病班面積率（爲處理區的病斑面積率。）。另外，重 複進行此試驗2次。 除了未散佈試驗用藥液以外，與前述同樣地栽培稻米 ，測定病班面積率（爲無處理區的病斑面積率。）。依據 後述式1 )算出防除價。Chromafenozide) and 1.5 parts of Nitenpyram, 87 parts of kaolin clay and 10 parts of talc are thoroughly comminuted and mixed to obtain a powder. Formulation Example 13 One part of the present quinoline compound, 4 parts of Chromafenozide, 6 parts of Dinotefuran, 30 parts of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon black The mixture (weight ratio of 50:50) and 50 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a suspension. Formulation Example 14 One part of the present quinoline compound, 4 parts of Chromafenozide, 6 parts of ethiprole, 30 parts of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon black The mixture (weight ratio of 50:50) and 50 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a suspension. Formulation Example 15 A mixture of 10 parts of the quinoline compound, 4 parts of Chromafenozide, 6 parts of Thiamethoxam, 30 parts of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon black (50:50 by weight) and 50 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a suspension. -19- 201249340 Formulation Example 1 6 10 parts of the quinoline compound, 4 parts of Chromafenozide, 6 parts of Permethrin, 30 parts of polyoxyethylene alkyl ether ammonium sulfate and A mixture of white carbon black (weight ratio of 50:50) and 50 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a suspension. Formulation Example 17 A mixture of 10 parts of the quinoline compound, 4 parts of Chromafenozide, 6 parts of Clothianidin '30 parts of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon black (Weight ratio: 5 〇: 50) and 50 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a suspension. Formulation Example 1 8 10 parts of the quinoline compound, 4 parts of Chromafenozide, 6 parts of Niten enpyram, 30 parts of polyoxyethylene alkyl ether sulfate ammonium salt and white A mixture of carbon black (weight ratio of 50:50) and 50 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a suspension. Next, the effects of the present invention are shown by test examples. Test Example 1 8 -20- 201249340 Each 10 mg of the quinoline compound, Chromafenozide, Dinotefuran, Ethiprole, Thiamethoxam, and Clothianidin And a solution of 0.02% by volume of a spreading agent (product) after dissolving in 1 ml of acetone containing Sorgen TW-2 0 (manufactured by Wako Pure Chemical Industries, Ltd.). Name: The water of Dain (registered trademark), Sumitomo Takeda Gardening) is diluted to the specified concentration. Mixing the aqueous dilution of the quinoline compound with Chromafenozide water dilution and Dinotefuran, Ethiprole, Thiamethoxam, Clothianidin or susceptibility An aqueous dilution of Nitenpyram was prepared to prepare a test solution. The seedlings are placed in a plastic cultivating cultivating soil in a culture soil, and the seedlings are fully sown for 15 days. Three rice leaves (Oryza sativa, variety: seven stars) are completely spread, and the test chemical liquid is applied to each cockroach using a spray gun. Spread 10ml. After air drying, it is placed in a wet room (humidity of 9.5-100%) at 25 °C in the same place as rice with rice fever, and allowed to stand for 24 hours. Thereafter, after the rice having the onset of rice fever was isolated, it was cultivated in the wet chamber for 5 days, and the disease area ratio (the lesion area ratio of the treatment area) was measured. In addition, this test was repeated twice. Rice was cultivated in the same manner as described above except that the test drug solution was not dispersed, and the disease area ratio (the lesion area ratio in the non-treated area) was measured. The price control is calculated according to the following formula 1).
式 1 ):防除價=100x ( A — B ) /A -21 - 201249340 A :無處理區之病斑面積率 B:處理區之病斑面積率 該平均値如表1所示。 ⑧ 表1 試驗化合物 處理濃度(ppm) 防除價 本喹啉化合物 20 + + 9.1 可芬諾 0.1 本唾啉化合物 20 + + 可芬諾 0.1 63.6 + + 達特南 0.05 本喹啉化合物 20 + + 可芬諾 0.1 40.9 + + 乙蟲腈 0.25 本喹啉化合物 20 + + 可芬諾 0.1 54.5 + + 賽速安 0.05 本喹啉化合物 20 + + 可芬諾 0.1 40.9 + + 可尼丁 0.05 本喹啉化合物 20 + + 可芬諾 0.1 40.9 + + 嫌D定蟲月女 0.05 -22- 201249340 試驗例2 將各10mg之本唾琳化合物、可芬諾（Chromafenozide) 、達特南（Dinotefuran)、乙蟲腈（Ethiprole)、賽速安 (Thiamethoxam )、百滅寧（Permethrin )、可尼丁 （ Clothianidin )及烯啶蟲胺（Nitenpyram )，分別溶解於 lml之含Sorgen TW-20(第一工業製藥製）之丙酮（和光 純藥工業製）後，以含有0.02容量％之展著劑（商品名： DaU (註冊商標），住化武田園藝製）的水稀釋成規定濃 度。混合本喹啉化合物水稀釋液與可芬諾（ Chromafenozide)水稀釋液及達特南（Dinotefuran)、乙 蟲腈（Ethiprole)、賽速安（Thiamethoxam)、百滅寧（ Permethrin )、可尼丁 （Clothianidin)或稀 D定蟲胺（ Nitenpyram)的水稀釋液，調製試驗用藥液》 播種於放入培養土之塑膠製栽培缽，育苗15天程度 ，對3片本葉完全展開的稻米（Oryza sativa，品種：七 星），使用噴霧槍將前述試驗用藥劑液，對每一缽進行散 布處理10ml。風乾後，與稻熱病發病的稻米一同放入25 °C的濕室（濕度爲95 - 1 00% )內，靜置24小時。之後， 分離前述稻熱病發病的稻米後，於前述濕室內栽培5天， 測定病班面積率（爲處理區的病斑面積率。）。另外，重 複進行此試驗2次》 除了未散佈試驗用藥液以外，與前述同樣地栽培稻米 ，測定病班面積率（爲無處理區的病斑面積率。）。依據 -23- 201249340 後述式1 )算出防除價。 式 1 ):防除價=100x ( A— B ) /A Α:無處理區之病斑面積率 B:處理區之病斑面積率 該平均値如表2所示。 表2 試驗化合物 處理濃度(ppm) 防除價 本喹啉化合物 33 + + 94.0 可芬諾 33 本嗤啉化合物 33 + + 可芬諾 33 100 + + 達特南 33 本喹啉化合物 33 + + 可芬諾 33 98.0 + + 乙蟲腈 33 本喹啉化合物 33 + + 可芬諾 33 99.0 + + 賽速安 33 本喹啉化合物 33 + + 可芬諾 33 99.0 + + 百滅寧 33 201249340 表2後續 試驗化合物 處理濃度(ppm) 防除價 本喹啉化合物 33 + + 可芬諾 33 99.0 + + 可尼丁 33 本喹啉化合物 33 + + 可芬諾 33 100 + + 嫌陡蟲fee 33 試驗例3 將各1 Omg之本喹啉化合物、可芬諾（Chromafenozide) 、可尼丁（Clothianidin)及嫌淀蟲胺（Nitenpyram) ’ 分 別溶解於1ml之含Sorgen TW-20 (第一工業製藥製）之丙 酮（和光純藥工業製）後，以含有〇·〇2容量％之展著劑（ 商品名：Dain (註冊商標），住化武田園藝製）的水稀釋 成規定濃度。混合本喹啉化合物水稀釋液與可芬諾（Formula 1): Control price = 100x ( A - B ) / A - 21 - 201249340 A : Area of the lesion area without treatment area B: Area of the lesion area of the treatment area The average value is shown in Table 1. 8 Table 1 Test compound treatment concentration (ppm) Detergent quinoline compound 20 + + 9.1 Coventino 0.1 This porphyrin compound 20 + + Coventino 0.1 63.6 + + Dartnam 0.05 This quinoline compound 20 + + Fenno 0.1 40.9 + + ethiprole 0.25 quinoline compound 20 + + cofinol 0.1 54.5 + + cyanohydrin 0.05 quinoline compound 20 + + fenfenol 0.1 40.9 + + nicidine 0.05 quinolin compound 20 + + Cofinol 0.1 40.9 + + D-disease female 0.05 -22- 201249340 Test Example 2 Each 10 mg of the salivary compound, Chromafenozide, Dinotefuran, Ethromidin (Ethiprole), Thiamethoxam, Permethrin, Clothianidin, and Nitenpyram, respectively, dissolved in 1 ml of Sorgen TW-20 (manufactured by Daiichi Kogyo Co., Ltd.) Acetone (manufactured by Wako Pure Chemical Industries, Ltd.) was diluted to a predetermined concentration with water containing 0.02% by volume of a spreading agent (trade name: DaU (registered trademark), Sumitomo Takeda Gardening Co., Ltd.). Mixing water dilution of quinoline compound with Chromafenozide water dilution and Dinotefuran, Ethiprole, Thiamethoxam, Permethrin, and Cotinidine (Clothianidin) or a diluted water solution of Nitenpyram, which is prepared by culturing a plastic cultivating sputum in a culture soil, and growing the seedlings for 15 days. Sativa, variety: seven stars), the test solution was sprayed with a spray gun to 10 ml of each mash. After air drying, it was placed in a wet room (humidity of 95 - 1 00%) at 25 °C with rice with rice fever, and allowed to stand for 24 hours. Thereafter, after the rice having the onset of rice fever was isolated, it was cultivated in the wet chamber for 5 days, and the disease area ratio (the lesion area ratio of the treatment area) was measured. In addition, the test was repeated twice. The rice was cultivated in the same manner as described above except that the test liquid was not dispersed, and the area ratio of the disease was measured (the area ratio of the lesions in the non-treated area). According to -23- 201249340, the following formula 1) is used to calculate the price. Formula 1): Control price = 100x ( A - B ) / A Α: area of lesion area without treatment area B: area ratio of lesion area of treatment area The average value is shown in Table 2. Table 2 Test compound treatment concentration (ppm) Detergent quinoline compound 33 + + 94.0 Coventino 33 Benzoline compound 33 + + Coventino 33 100 + + Dartnam 33 Quinoline compound 33 + + Cofen Connaught 33 98.0 + + Ethanilonitrile 33 Quinoline Compound 33 + + Coventino 33 99.0 + + Sai Suan 33 Quinoline Compound 33 + + Coventino 33 99.0 + + Baifening 33 201249340 Table 2 Follow-up Test Compound treatment concentration (ppm) Detergent quinoline compound 33 + + Coventino 33 99.0 + + Cotinine 33 Benquinoline compound 33 + + Coventino 33 100 + + Dwarf fee 33 Test Example 3 Each 1 Omg of the quinoline compound, Chromafenozide, Clothianidin and Nitenpyram ' dissolved in 1 ml of acetone containing Sorgen TW-20 (manufactured by Daiichi Kogyo Co., Ltd.) It is diluted to a predetermined concentration with water containing a sputum (product name: Dain (registered trademark), Sumitomo Takeda Gardening Co., Ltd.). Mixing the aqueous quinoline compound with fentanol
Chromafenozide)、可尼丁（Clothianidin)或稀症蟲胺（Chromafenozide), Clothianidin or diltiazem (
Nitenpyram)的水稀釋液，調製試驗用藥液。 對2.5葉期之紙缽種植稻米（Oryza sativa，品種：七 星）幼苗，每一缽散佈l〇ml之前述試驗用藥液。將此稻 米幼苗風乾後，放入放有4.8ml水的玻璃製試管（直徑爲 30mm，高度爲200mm)。於此試管中，各放入飼養10隻 褐飛蝨（Nilaparvata lugens)的3齡幼蟲，放置於室內（ 2 5 °C，濕度爲60% ) »4天後，觀察試驗幼蟲的生死。由 -25- 201249340 該觀察結果，依式2)算出死蟲率、依式3)算出修正死 蟲率。另外，重複進行試驗2次。該平均値如表3所示。 式2):死蟲率（％)=處理區死蟲數/試驗蟲數χΐ〇〇 式3):修正死蟲率（％)={(處理區死蟲率-無處理 區死蟲率）/(100·無處理區死蟲率）}χ100 表3 試驗化合物 處理濃度(ppm) 修正殺蟲率(％) 本喹啉化合物 20 + + 可芬諾 0.1 40.0 + + 可尼丁 0.05 本喹啉化合物 20 + + 可芬諾 0.1 75.0 + + 嫌π定蟲胺 0.05 本喹啉化合物 20 + + 30.0 可芬諾 0.1 可芬諾 0.1 30.0 可尼丁 0.05 25.0 烯啶蟲胺 0.05 65.0 試驗例4 將各10mg之本喹啉化合物、可芬諾（Chromafenozide) 及百滅寧（Permethrin) ’分別溶解於1ml之含Sorgen TW-2 0 (第一工業製藥製）之丙酮（和光純藥工業製）後 ，以含有0.02容量％之展著劑（商品名：Dain (註冊商標 ⑧ -26- 201249340 )*住化武田園藝製）的水稀釋成規定濃度。混合本喹啉 化合物水稀釋液、可芬諾（Chromafenozide)水稀釋液及 百滅寧（Permethrin)水稀釋液，調製試驗用藥液。 對2.5葉期之紙缽種植稻米（Oryza sativa，品種：七 星）幼苗，每一缽散佈l〇ml之前述試驗用藥液。將此稻 米幼苗風乾後，放入放有水的塑膠杯（直徑爲90mm，高 度爲30mm)。於其中，各放入飼養10隻稻縱捲葉野螟（ Cnaphalocrocis medinalis)的 1 齡幼蟲，放置於室內（25 °C，濕度爲60%) 。4天後，觀察試驗幼蟲的生死。由該 觀察結果，依試驗例3記載之式2 )算出死蟲率、依式3 )算出修正死蟲率。另外，重複進行試驗2次。 該平均値如表4所示。 表4 試驗化合物 處理濃度(ppm) 修正殺蟲率(％) 本喹啉化合物 20 + + 可芬諾 0.1 88.2 + + 百滅寧 10 本喹啉化合物 20 + + 0.0 可芬諾 0.1 可芬諾 0.1 0.0 百滅寧 10 80.0 試驗例5 將各10mg之本喹啉化合物、可芬諾（Chromafenozide) 、達特南（Dinotefuran )及可尼丁（ Clothianidin )，分 -27- 201249340 別溶解於lm丨之含Sorgen TW-20(第一工業製藥製）之丙 酮（和光純藥工業製）後，以含有0.02容量％之展箸劑（ 商品名：Dain (註冊商標），住化武田園藝製）的水稀釋 成規定濃度。混合本喹啉化合物水稀釋液、可芬諾（ Chromafenozide)水稀釋液及達特南（Dinotefuran)或可 尼丁（ Clothianidin)水稀釋液，調製試驗用藥液。 對2.5葉期之紙缽種植稻米（Oryza sativa，品種：七 星）幼苗，每一缽散佈10m丨之前述試驗用藥液。將此稻 米幼苗風乾後，放入放有水的塑膠杯（直徑爲90mm，高 度爲30mm)。於其中，各放入飼養1〇隻稻縱捲葉野螟（ Cnaphalocrocis medinalis)的 1 齡幼蟲，放置於室內（25 °C，濕度爲60% ) 。3天後，觀察試驗幼蟲的生死。由該 觀察結果，依試驗例3記載之式2)算出死蟲率、依式3 )算出修正死蟲率。另外，重複進行試驗2次。 該平均値如表5所示。 -28- 201249340 表5 試驗化合物 處理濃度(ppm) 修正殺蟲率(％) 本喹啉化合物 100 + + 可芬諾 0.1 73.7 + + 達特南 100 本喹啉化合物 100 + + 可芬諾 0.1 100 + + 可尼丁 100 本喹啉化合物 100 + + 21.1 可芬諾 0.1 可芬諾 0.1 15.8 達特南 100 57.9 可尼丁 100 95.0 產業上利用性 藉由本發明可防除有害生物。 -29-A water dilution of Nitenpyram) was used to prepare a test solution. Seedlings of rice (Oryza sativa, variety: seven stars) were planted on a paper leaf of 2.5 leaf stage, and each of the above test solutions was dispensed with l〇ml. After the rice seedlings were air-dried, a glass test tube (having a diameter of 30 mm and a height of 200 mm) containing 4.8 ml of water was placed. In this test tube, 10 larvae of 10 brown planthoppers (Nilaparvata lugens) were placed in the chamber and placed indoors (25 ° C, humidity 60%). After 4 days, the life and death of the test larvae were observed. From -25- 201249340, the observation results were calculated according to Equation 2), and the corrected mortality rate was calculated according to Equation 3). In addition, the test was repeated twice. The average is shown in Table 3. Formula 2): Dead insect rate (%) = number of dead insects in the treatment area / number of test insects χΐ〇〇 3): corrected mortality rate (%) = {(treatment area dead insect rate - no treatment area dead insect rate) /(100·No treatment area dead insect rate)}χ100 Table 3 Test compound treatment concentration (ppm) Modified insecticidal rate (%) Benquinoline compound 20 + + Coventino 0.1 40.0 + + Nicotine 0.05 This quinoline Compound 20 + + Coffenesol 0.1 75.0 + + π octopamine 0.05 quinolin compound 20 + + 30.0 fenfenol 0.1 fenfenol 0.1 30.0 cotinine 0.05 25.0 nitenpyram 0.05 65.0 test case 4 10 mg of the quinoline compound, Chromafenozide, and Permethrin were dissolved in 1 ml of acetone containing Sorgen TW-2 0 (manufactured by Kokusai Kogyo Co., Ltd.). It is diluted to a predetermined concentration with water containing 0.02% by volume of a spreading agent (trade name: Dain (registered trademark 8 -26-201249340)* Sumitomo Takeda Horticulture). The test solution was prepared by mixing the aqueous dilution of the quinoline compound, the Chromafenozide water dilution, and the Permethrin water dilution. Seedlings of rice (Oryza sativa, variety: seven stars) were planted on a paper leaf of 2.5 leaf stage, and each of the above test solutions was dispensed with l〇ml. After the rice seedlings were air-dried, they were placed in a plastic cup with water (90 mm in diameter and 30 mm in height). Among them, 10 first-instar larvae of 10 Cnaphalocrocis medinalis were placed in a room (25 ° C, humidity 60%). After 4 days, the life and death of the test larvae were observed. From the observation results, the mortality rate was calculated according to the formula 2) described in Test Example 3, and the corrected mortality rate was calculated according to the formula 3). In addition, the test was repeated twice. The average is shown in Table 4. Table 4 Test compound treatment concentration (ppm) Modified insecticidal rate (%) Benquinoline compound 20 + + Coffenesol 0.1 88.2 + + Benfenin 10 Benquinoline compound 20 + + 0.0 Coventino 0.1 Coventino 0.1 0.0 百灭宁10 80.0 Test Example 5 Each 10 mg of the quinoline compound, Chromafenozide, Dinotefuran and Clothianidin, -27-201249340 were dissolved in lm丨Water containing Sorgen TW-20 (manufactured by Wako Pure Chemical Industries, Ltd.), which contains 0.02% by volume of a sputum agent (trade name: Dain (registered trademark), Sumitomo Takeda Gardening) Dilute to the specified concentration. The test drug solution was prepared by mixing the aqueous dilution of the quinoline compound, the Chromafenozide water dilution, and the Dinotefuran or Clothianidin water dilution. Seedlings of rice (Oryza sativa, variety: seven stars) were planted in the paper leaf of 2.5 leaf stage, and the above test liquid was spread for 10 m each. After the rice seedlings were air-dried, they were placed in a plastic cup with water (90 mm in diameter and 30 mm in height). Among them, one-instar larvae of one Cnaphalocrocis medinalis were placed in a room (25 ° C, humidity 60%). After 3 days, the life and death of the test larvae were observed. From the observation results, the mortality rate was calculated according to the formula 2) described in Test Example 3, and the corrected mortality rate was calculated according to the formula 3). In addition, the test was repeated twice. The average is shown in Table 5. -28- 201249340 Table 5 Test compound treatment concentration (ppm) Modified insecticidal rate (%) Benquinoline compound 100 + + Coventino 0.1 73.7 + + Dartnan 100 Quinoline compound 100 + + Coventino 0.1 100 + + konidine 100 quinolin compound 100 + + 21.1 fenfen 0.1 fenfen 0.1 15.8 tonnan 100 57.9 konidine 100 95.0 Industrial Applicability The present invention can prevent pests. -29-
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