JP2013107860A - Noxious arthropod control composition and noxious arthropod control method - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a noxious arthropod control composition and a noxious arthropod control method which possess excellent control effect against noxious arthropods.SOLUTION: The noxious arthropod control composition contains a compound represented by formula (1), one or more compounds selected from a group (A), and one or more compounds selected from a group (B), and has excellent control effect against noxious arthropods, wherein the group (A) is composed of chromafenozide, methoxyfenozide, tebufenozide, cartap, silafluofen, clothianidin, nitenpyram, and spinetoram, and the group (B) is composed of isothianil, ferimzone, fthalide, tricyclazole, validamycin A, furametpyr, diclocymet, azoxystrobin, flutolanil, pencycuron, N-[2-(1,3-dimethylbutyl)phenyl]-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide, and kasugamycin hydrochloride.

Description

  The present invention relates to a harmful arthropod control composition and a method for controlling harmful arthropods.

  Conventionally, many compounds are known as an active ingredient of the harmful arthropod control composition (for example, refer nonpatent literature 1).

The Pesticide Manual-15th edition (BCPC); ISBN 978-1-901396-18-8

  An object of the present invention is to provide a harmful arthropod control composition having an excellent control effect on harmful arthropods and a method for controlling harmful arthropods.

で示される化合物と、群（Ａ）より選ばれる１種以上の化合物と、群（Ｂ）より選ばれる１種以上の化合物とを含有する有害節足動物防除組成物。
群（Ａ）：クロマフェノジド、メトキシフェノジド、テブフェノジド、カルタップ、スピネトラム、シラフルオフェン、クロチアニジン及びニテンピラムからなる群。
群（Ｂ）：イソチアニル、フェリムゾン、フサライド、トリシクラゾール、バリダマイシンＡ、フラメトピル、ジクロシメット、アゾキシストロビン、フルトラニル、ペンシクロン、Ｎ−［２−（１，３−ジメチルブチル）フェニル］−１，３−ジメチル−５−フルオロ−１Ｈ−ピラゾール−４−カルボキサミド及びカスガマイシン塩酸塩からなる群。
［２］ 式（１）で示される化合物と、群（Ａ）より選ばれる１種以上の化合物との重量比が、１００：１〜１：１００である［１］記載の有害節足動物防除組成物。
［３］ 式（１）で示される化合物と、群（Ｂ）より選ばれる１種以上の化合物との重量比が、１００：１〜１：１００である［１］又は［２］記載の有害節足動物防除組成物。
［４］ ［１］〜［３］いずれか一項記載の有害節足動物防除組成物の有効量を、植物又は植物の栽培地に施用する工程を含む有害節足動物の防除方法。
［５］ 植物又は植物の栽培地に施用する工程が、イネ又はイネの栽培地に施用する工程である［４］記載の有害節足動物の防除方法。 As a result of studying to find a harmful arthropod control composition having an excellent control effect on harmful arthropods, the present inventors have selected from the compound represented by the following formula (1) and the following group (A): It has been found that a composition containing at least one compound selected from the group (B) below has an excellent controlling effect on harmful arthropods.
That is, the present invention is as follows.
[1] Formula (1)

A harmful arthropod control composition comprising a compound represented by formula (1), one or more compounds selected from the group (A), and one or more compounds selected from the group (B).
Group (A): A group consisting of chromafenozide, methoxyphenozide, tebufenozide, cartap, spinetoram, silafluophene, clothianidin and nitenpyram.
Group (B): Isothianyl, ferrimzone, fusalide, tricyclazole, validamycin A, furamethpyr, diclocimet, azoxystrobin, flutolanil, pencyclon, N- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl A group consisting of -5-fluoro-1H-pyrazole-4-carboxamide and kasugamycin hydrochloride.
[2] The harmful arthropod control according to [1], wherein the weight ratio of the compound represented by the formula (1) to one or more compounds selected from the group (A) is 100: 1 to 1: 100. Composition.
[3] The harmfulness according to [1] or [2], wherein the weight ratio of the compound represented by the formula (1) to one or more compounds selected from the group (B) is 100: 1 to 1: 100 Arthropod control composition.
[4] A method for controlling harmful arthropods, comprising a step of applying an effective amount of the composition for controlling harmful arthropods according to any one of [1] to [3] to a plant or a planting site of the plant.
[5] The method for controlling harmful arthropods according to [4], wherein the step of applying to a plant or a plant cultivation area is a step of applying to rice or a rice cultivation site.

  According to the present invention, harmful arthropods can be controlled.

The harmful arthropod control composition of the present invention is a compound represented by the formula (1) (hereinafter sometimes referred to as the present cyanamide compound) and one or more compounds selected from the group (A) (hereinafter referred to as “the cyanamide compound”). And a pest control compound in some cases) and one or more compounds selected from the group (B) (hereinafter may be referred to as the present plant disease control compound).
Group (A): A group consisting of chromafenozide, methoxyphenozide, tebufenozide, cartap, spinetoram, silafluophene, clothianidin and nitenpyram.
Group (B): Isothianyl, ferrimzone, fusalide, tricyclazole, validamycin A, furamethpyr, diclocimet, azoxystrobin, flutolanil, pencyclon, N- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl A group consisting of -5-fluoro-1H-pyrazole-4-carboxamide (hereinafter sometimes referred to as compound (I)) and kasugamycin hydrochloride.

  The cyanamide compound used in the present invention is a known compound and can be produced, for example, by the method described in International Publication No. 2007/095229.

  Also, the chromafenozide, methoxyphenozide, tebufenozide, cartap, silafluophene, clothianidin, nitenpyram, ferimzone, fusaride, tricyclazole, validamycin A, flametopil, diclosimet, azoxystrobin, flutolanil, pencyclon and kasugamycin hydrochloride used in the present invention are all known. For example, 211, 764, 1074, 168, 1029, 229, 817, 497, 904, 1163 of “The Pesticide Manual-15th edition (BCPC); ISBN 978-1-901396-18-8”. 1187, 580, 340, 62, 559, 871, and 685 pages. These compounds are obtained from commercially available preparations or can be obtained by producing them by known methods.

  Isotianil used in the present invention is a known compound and can be produced, for example, by the method described in WO99 / 024413.

  The spinetoram used in the present invention is a known compound and can be produced, for example, by the method described in WO 97/00265.

  Compound (I) used in the present invention is a known compound, and is described in, for example, International Publication No. 2003/010149 pamphlet. This compound can be obtained by producing by the method described in the publication.

  The content ratio of the present cyanamide compound, the present pest control compound, and the present plant disease control compound in the harmful arthropod control composition of the present invention is not particularly limited, but the present pest control is performed with respect to 100 parts by weight of the present cyanamide compound. The compound is usually 0.1 to 100,000 parts by weight, preferably 1 to 10,000 parts by weight, and the plant disease control compound is usually 1 to 100,000 parts by weight, preferably 10 to 10,000 parts by weight.

The harmful arthropod control composition of the present invention may be a mixture of the present cyanamide compound, the present pest control compound and the present plant disease control compound, but usually the present cyanamide compound, the present pest control compound and the present plant. A disease control compound and an inert carrier such as a solid carrier and a liquid carrier are mixed, and if necessary, a surfactant and other formulation adjuvants are added, and then an oil, emulsion, flowable, wettable powder, granule Those formulated into wettable powders, powders, granules and the like are used.
Moreover, the above-mentioned formulated harmful arthropod control composition can be used as a harmful arthropod control agent as it is or by adding other inactive ingredients.
The total amount of the present cyanamide compound, the present pest control compound and the present plant disease control compound in the harmful arthropod control composition of the present invention is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight. The range is more preferably 0.5 to 70% by weight.

Examples of solid carriers used in formulation include kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, corn cob flour, walnut shell powder, etc. Natural organic materials, synthetic organic materials such as urea, salts such as calcium carbonate and ammonium sulfate, fine powders or granular materials made of synthetic inorganic materials such as synthetic silicon hydroxide, etc., and liquid carriers include, for example, xylene, alkylbenzene, methyl Aromatic hydrocarbons such as naphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether, ketones such as acetone, cyclohexanone and isophorone, vegetable oils such as soybean oil and cottonseed oil, petroleum fats Group hydrocarbon , Esters, dimethyl sulfoxide, acetonitrile and water.
Examples of surfactants include anionic interfaces such as alkyl sulfate esters, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkylaryl ether phosphate esters, lignin sulfonates, naphthalene sulfonate formaldehyde polycondensates, and the like. Nonionic surfactants such as activators and polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers, sorbitan fatty acid esters, and cationic surfactants such as alkyltrimethylammonium salts.
Examples of other adjuvants for preparation include water-soluble polymers such as polyvinyl alcohol and polyvinyl pyrrolidone, gum arabic, alginic acid and salts thereof, polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum, aluminum magnesium silicate, alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.

  The harmful arthropod control composition of the present invention can be used to protect plants from harm by harmful arthropods (for example, harmful insects) that feed plants, suck and so on.

  Examples of the harmful arthropods having the control effect of the harmful arthropod control composition of the present invention include the following harmful arthropods.

Hemiptera: small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), planthoppers such as Sejirounka (Sogatella furcifera), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), tea Roh green leafhopper (Empoasca onukii) such as Leafhoppers, cotton aphids (Aphis gossypii), peach aphids (Myzus persicae), radish aphids (Brevicorine brassicae), snowy aphids (Aphis spiraecola), tulip beetle aphids iphum euphorbiae), potato beetle aphid (Aulacorthum solani), wheat aphidia (Rhopalosiphum padi), citrus green aphid (Nezara antennata), Trichotylus calestiariaum, Akasushi turtle (Graphosoma rubrolineatum), Otogeshiraboshikameshi (Eysarcoris reesei) avetus), spider helicopter (Leptocorisa chinensis), thornbill beetle (Eysarcoris parvus), stag beetle (Haryomorpha mistula), Nemara vitora (Nezara virul) white flies such as vaporiarum, tobacco whiteflies (Bemisia tabaci), mandarin whites (Dialeurodes citri), Aleurocanthus spiniferus (Aonurocanthus spiraferus), Comstockaspis perniciosa), citrus snow scale (Unaspis citri), Rubiroumushi (Ceroplastes rubens), Ise rear scale insects (Icerya purchasi), mealybug (Planococcus kraunhiae), mulberry mealybugs (Pseudococcus longispinis), white peach scale (Pseudaulacaspis pentagona), etc. Larvae such as scale insects, bedbugs, bedbugs such as bedbugs (Chimex electrarius), bedworms such as pair silla (Capposylla pyricola), and the like.
Lepidoptera: rice stem borer (Chilo suppressalis), Sankameiga (Tryporyza incertulas), leaf roller (Cnaphalocrocis medinalis), Watanomeiga (Notarcha derogata), Indian meal moth (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), high Madara Roh moth (Hellula undalis), Japanese medusa such as Shibata toga (Pediasia teterrellus), Spodoptera litura, Spodoptera exigua, Ayuyotoga (Pseudaletia sepata), Atoga assicae), Agrotis ipsilon, Tamanaginawaba (Plusia nigrisigna), Iragosainawaba (Trichoplusia ni), Trichopulsia, Heliotis, Helicobelpa, etc. Nashihimeshinsukui (Graphophrita molesta), Leguminivora glycinivolorella, Azoxaaphia moth (Matsumuraes azukihachacha), Adonoxaphya scallop magnanima), yellow-tailed spiders (Archips fuscocupreanus), codling moths (Cydia pomonella) etc. Anopheles, Limantria, Euproctinis, etc., Suga, such as Plutella xylostella, Peptinophora gossypiella, Phythromea operphylla H ntria cunea) Arctiidae such as, clothes moth (Tinea translucens), Hirozukoga such as webbing clothes moth (Tineola bisselliella), Tuta absolute diluter (Tuta absoluta) and the like.
Thysanoptera: western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips parmi), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), tobacco thrips (Frankliniella fusca), onion thrips Thrips such as (Thrips tabaci), rice thrips (Stenchaethotrips biformis), and rice thrips (Haplotrips acculeatus), etc .;
Diptera: onion maggot (Hylemya antiqua), seedcorn maggot (Hylemya platura), rice leafminer (Agromyza oryzae), rice Hime leafminer (Hydrellia griseola), Inekimoguribae (Chlorops oryzae), leafminer such as beans leafminer (Liriomyza trifolii), melon fly (Dacus cucurbitae), fruit fly (Ceratitis capitata) and the like;
Coleoptera: beetle, Epilachna vigintioctopunctata (Epilachna vigintioctopunctata), cucurbit leaf beetle (Aulacophora femoralis), Kisujinomihamushi (Phyllotreta striolata), Inedorooimushi (Oulema oryzae), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), boll weevil (Anthonomus grandis), Azuki beetle (Callosobruchus chinensis), Shibahorusu weevil (Sphenophorus venatus), Japanese beetle (Popilia japonica), Douganebububu (Anomala cupre) ..), Corn rootworm fellow (Diabrotica spp), Colorado potato beetle (Leptinotarsa decemlineata), fellow of click beetles (Agriotes spp), cigarette beetle (Lasioderma serricorne) and the like;
Pterodoptera: Kelly (Grylotalpa africana), Oxya yezoensis, Oxya japonica, etc.

  Among the harmful arthropods, preferred examples include planthoppers, green moths, leafhoppers, aphids, stink bugs, rice weevil, rice beetles and the like.

  The harmful arthropod control composition of the present invention may be used for the purpose of controlling plant diseases. For example, rice blast (Magnaporthe grisea), blight (Rhizotonia solani), pseudo-blight (brown fungus nucleus) Rhizoctonia oryzae-sativae, Rhizotonia zeae, Rhizotonia oryzae leaf, Rhizoctonia oryzae leaf, Rhizotonia oryzae leaf, Rhizotonia oryzae leaf Blight diseases such as blight (Cochliobolus Miyabeanus), rice wilt disease (Claviceps virens), bacterial blast blight (Burkholderia glumae), internal browning (Erwinia ananas), white leaf blight (Xanthomonas oryzae), stem blight (Cercospora oryzae), discolored rice (Curvularia sp., Epicoccum sp.), Alternaria sp. Can be controlled.

  The harmful arthropod control composition of the present invention can control harmful arthropods by being applied to plants or plant cultivation areas. Examples of plants include plant foliage, plant flowers, plant nuts, plant seeds, and the like.

  The method for controlling harmful arthropods of the present invention is carried out by applying the composition for controlling harmful arthropods of the present invention to plants or plant cultivation areas. Application to the cultivation area of plants, such as treatment to foliage, soil treatment, water surface application, etc. are mentioned.

When the harmful arthropod composition of the present invention is applied to a plant or a plant cultivation site, the application amount is the type of plant to be applied, the type and occurrence of harmful arthropods to be controlled, the formulation form, Although it can be changed according to the application time, weather conditions, etc., the total amount of the present cyanamide compound, the present pest control compound and the present plant disease control compound is usually 0.05 to 3000 g per 1000 m ² where the plant is cultivated, preferably 0.5 to 300 g.
Emulsions, wettable powders, flowables and the like are usually treated by diluting with water and spraying. In this case, the total concentration of the present cyanamide compound, the present pest control compound and the present plant disease control compound is usually in the range of 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight. Powders, granules, etc. are usually processed without dilution.

Specifically, the treatment of plant foliage such as foliage spraying according to the present invention is, for example, a human sprayer, a power sprayer, a boom sprayer, a punkrsprayer, a human power duster (mini duster) or a power duster ( Examples thereof include a method of treating the surface of a plant to be cultivated by ground spraying using a pipe duster or the like, airborne control using an unmanned helicopter, etc.

  Specific examples of the treatment to the plant cultivation area such as soil treatment and water surface application in the present invention include, for example, planting hole treatment, plant root treatment, grooving treatment, rowing treatment, rowing at the time of sowing, and the entire surface. Treatment, lateral strip treatment, water surface treatment, buttock surface spraying, inter-strain spraying, soil irrigation, seedling irrigation, chemical injection, chemical drip irrigation, chemigation, seedling box treatment (nursery box spraying, seedling box irrigation, seedling box Chemical drenched water), nursery treatment (seedbed spraying, nursery bed irrigation, water seedling surrogate seedling spraying, seedling immersion), bed soil admixing treatment (floor soil admixing, bed soaking before sowing, sowing before sowing, sowing after sowing, Addition of soil cover), soil mixing, paste fertilizer mixing, preferably seedling box treatment (nursing box spraying, seedling box irrigation, seedling box chemical solution flooding), nursery treatment (seed bed spraying, nursery bed irrigation, water seedling surrogate seedling spraying, seedling Soaking), floor soil mixing treatment (floor soil mixing, before sowing) Soil mixing, time of sowing soil cover before spraying, seeding when cover soil after spraying, cover soil mixing), soil mixing, paste fertilizer mixing include submerged spraying.

  The method for controlling harmful arthropods of the present invention can be used in farmland such as fields, paddy fields, dry fields, lawns, orchards, or non-farm fields.

  The harmful arthropod control composition of the present invention can be used for controlling harmful arthropods of plants included in the following “crop”. However, these plants are examples and are not limited to these.

"produce":
Agricultural crops: corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, etc.
Vegetables: Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelons, melons, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage) , Mustard, broccoli, cauliflower, rape, etc.), asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), liliaceae vegetables (eg, leek, onion, garlic, asparagus), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint, basil etc.), strawberry, sweet potato, yam, taro etc.
Fruit trees: berries (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
Trees other than fruit trees: tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi, sakura, yurinoki, crape myrtle, snapdragon, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak) , Poplar, redwood, fu, sycamore, zelkova, blackfish, Japanese amberjack, moths, pine, pine, spruce, yew, elm, Japanese cypress, etc.), coral jug, dogwood, cedar, cypress, croton, masaki, kanamochi, etc.
Lawn: Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Neurodonidae, etc.), Bentgrass (Oleoptera, Hykonukagusa, Odonoptera, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Oonishi nokegusa, Drosophila, etc.) , Grass, etc.), ryegrass (rat, wheat, etc.), anemonefish, blue whale, etc.
Other: Flowers (Rose, Carnation, Chrysanthemum, Eustoma, Gypsophila, Gerbera, Marigold, Salvia, Petunia, Verbena, Tulip, Aster, Gentian, Lily, Pansy, Cyclamen, Orchid, Lily of the valley, Lavender, Stock, Habutton, Primula, Poinsettia, gladiolus, cattleya, daisy, symbidium, begonia, etc.), biofuel plants (Jatropha, safflower, Amanas, switchgrass, miscanthus, kusayoshi, dangiku, kenaf, cassava, willow, etc.), houseplants, etc.

  Among the plants, corn, wheat, rice and the like can be mentioned as preferable examples. Of these, rice is particularly preferable.

  The plant may be a plant to which resistance is imparted by a genetic recombination technique or a breeding method by crossing.

  When the method for controlling harmful arthropods according to the present invention is used in rice or rice cultivated land, for example, it can be applied before sowing, during sowing, after sowing, before transplanting, at the time of transplanting or after transplanting of rice. it can. The period of application may vary depending on the growth state of rice, the occurrence of pests and pests, weather conditions, etc., but it can usually be mentioned from 30 days before sowing to 20 days after transplanting, based on the day of sowing or transplanting rice. Preferably, from the time of sowing to before transplantation, more preferably from 3 days before transplantation to before transplantation.

  The application amount when applied to a seedling box for paddy rice seedlings is usually 0 per nursery box (about 60 cm wide, about 30 cm long) as the total amount of the cyanamide compound, the pest control compound and the plant disease control compound. 0.1 to 35 g, preferably 0.2 to 20 g.

  Hereinafter, the present invention will be described in more detail with reference to formulation examples and test examples, but the present invention is not limited to the following examples. In the following examples, parts represent parts by weight unless otherwise specified.

  First, formulation examples are shown.

Formulation Example 1
2 parts of the present cyanamide compound, 1.5 parts of chromafenozide, 1.5 parts of clothianidin, 5 parts of ferrimzone, 5 parts of fusaride, 1.5 parts of furametopyl, 1 part of synthetic hydrous silicon oxide, 2 parts of calcium lignin sulfonate, 30 parts of bentonite Further, the kaolin clay is thoroughly pulverized and mixed in the remaining proportion, water is added and kneaded well, and then granulated and dried to obtain 100 parts of granules.

Formulation Examples 2-6
Instead of 1.5 parts of Chromafenozide in Formulation Example 1, the same operation as in Formulation Example 1 was carried out except that the respective compounds and amounts used in Table 1 were applied to obtain 100 parts of each granule.

Formulation Examples 7-12
Instead of 1.5 parts of clothianidin in Preparation Examples 1 to 6, the same operation as in Preparation Examples 1 to 6 is performed except that 4 parts of Nitenpyram is applied to obtain 100 parts of each granule.

Formulation Examples 13-24
It replaces with 5 parts of fusalides of formulation examples 1-12, and except having applied tricyclazole 4 parts, operation similar to formulation examples 1-12 is performed, and 100 parts of each granule is obtained.

Formulation Examples 25-36
It replaces with 5 parts of fusalides of the formulation examples 1-12, and except having applied 3 parts of diclocimet, operation similar to the formulation examples 1-12 is performed, and 100 parts of each granule is obtained.

Formulation Examples 37-48
Instead of 5 parts of fusalide in Formulation Examples 1 to 12, the same operation as in Formulation Examples 1 to 12 is performed except that 3 parts of isotianil is applied to obtain 100 parts of each granule.

Formulation Examples 49-96
The same operation as in Formulation Examples 1 to 48 was performed except that 5 parts of validamycin A was applied instead of 1.5 parts of Frametopil in Formulation Examples 1 to 48 to obtain 100 parts of each granule.

Formulation Examples 97-144
The same operation as in Formulation Examples 1 to 48 was carried out except that 7 parts of flutolanil was applied instead of 1.5 parts of Frametopil in Formulation Examples 1 to 48 to obtain 100 parts of each granule.

Formulation Examples 145 to 192
Instead of 1.5 parts of Frametopil in Formulation Examples 1 to 48, the same operation as in Formulation Examples 1 to 48 is performed except that 1.5 parts of pencyclone is applied to obtain 100 parts of each granule.

Formulation Examples 193 to 240
The same operation as in Formulation Examples 1 to 48 was performed except that 2 parts of Compound (I) was applied instead of 1.5 parts of Frametopil in Formulation Examples 1 to 48 to obtain 100 parts of each granule.

Formulation Examples 241 to 264
Instead of 5 parts of ferrimzone in Formulation Examples 1 to 24, the same operation as in Formulation Examples 1 to 24 is performed except that 2.3 parts of kasugamycin hydrochloride is applied to obtain 100 parts of each granule.

Formulation Examples 265 to 288
The same operation as in Formulation Examples 241 to 264 is carried out except that 5 parts of validamycin A is applied instead of 1.5 parts of Frametopil in Formulation Examples 241 to 264 to obtain 100 parts of each granule.

Formulation Examples 289-312
The same operation as in Formulation Examples 241 to 264 is performed except that 7 parts of flutolanil is applied instead of 1.5 parts of Frametopil in Formulation Examples 241 to 264 to obtain 100 parts of each granule.

Formulation Examples 313 to 336
The same operation as in Formulation Examples 241 to 264 is carried out except that 1.5 parts of Penciclone is applied instead of 1.5 parts of Frametopil in Formulation Examples 241 to 264, and 100 parts of each granule is obtained.

Formulation Examples 337-360
The same operation as in Formulation Examples 241 to 264 is performed except that 2 parts of Compound (I) is applied instead of 1.5 parts of Frametopil in Formulation Examples 241 to 264 to obtain 100 parts of each granule.

Formulation Example 361
5 parts of the present cyanamide compound, 5 parts of chromafenozide, 5 parts of clothianidin, 15 parts of ferrimzone and 15 parts of furametopil were mixed with 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 15 parts of synthetic hydrous hydroxide powder and the remainder of diatomaceous earth. Add to the mixture and mix well with stirring to obtain 100 parts of wettable powder.

Formulation Examples 362-366
Instead of 5 parts of Chromafenozide in Formulation Example 361, the same operation as in Formulation Example 361 was performed except that the respective compounds and amounts used in Table 2 were applied to obtain 100 parts of each wettable powder.

Formulation Examples 367-372
Instead of 5 parts of clothianidin in Formulation Examples 361 to 366, the same operation as in Formulation Examples 361 to 366 was performed except that 10 parts of Nitenpyram was applied to obtain 100 parts of each wettable powder.

Formulation Examples 373-384
Instead of 15 parts of ferrimzone in Formulation Examples 361 to 372, the same operation as in Formulation Examples 361 to 372 is performed except that 15 parts of fusaride is applied to obtain 100 parts of each wettable powder.

Formulation Examples 385-396
Instead of 15 parts of ferrimzone in Formulation Examples 361 to 372, the same operation as in Formulation Examples 361 to 372 is performed except that 10 parts of tricyclazole is applied to obtain 100 parts of each wettable powder.

Formulation Examples 397-408
Instead of 15 parts of ferrimzone in Formulation Examples 361 to 372, the same operation as in Formulation Examples 361 to 372 was performed except that 10 parts of diclocimet was applied to obtain 100 parts of each wettable powder.

Formulation Examples 409-420
Instead of 15 parts of ferrimzone in Formulation Examples 361 to 372, the same operation as in Formulation Examples 361 to 372 is performed except that 1.4 parts of kasugamycin hydrochloride is applied to obtain 100 parts of each wettable powder.

Formulation Examples 421 to 480
The same operation as in Formulation Examples 361 to 420 was performed except that 5 parts of validamycin A was applied instead of 15 parts of Frametopil in Formulation Examples 361 to 420 to obtain 100 parts of each wettable powder.

Formulation Examples 481-540
The same operation as in Formulation Examples 361 to 420 was performed except that 20 parts of flutolanil was applied instead of 15 parts of Frametopil in Formulation examples 361 to 420 to obtain 100 parts of each wettable powder.

Formulation Examples 541-600
Instead of 15 parts of Frametopil in Formulation Examples 361 to 420, operations similar to those in Formulation Examples 361 to 420 are performed except that 20 parts of Pencyclon are applied to obtain 100 parts of each wettable powder.

Formulation Examples 601-660
The same operation as in Formulation Examples 361 to 420 was carried out except that 5 parts of Compound (I) was applied instead of 15 parts of Frametopil in Formulation Examples 361 to 420 to obtain 100 parts of each wettable powder.

Formulation Example 661
Wet milling 100 parts of a mixture of 5 parts of the present cyanamide compound, 5 parts of chromafenozide, 15 parts of ferrimzone, 15 parts of fusaride, 10 parts of furametopil, 50 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of water A flowable agent is obtained by pulverizing by the method.

Formulation Examples 662-668
Instead of 5 parts of Chromafenozide in Formulation Example 661, the same operation as in Formulation Example 661 was carried out except that the respective compounds and amounts used in Table 3 were applied to obtain 100 parts of each flowable agent.

Formulation Examples 669 to 676
It replaces with 15 parts of fusalides of the formulation examples 661-668, and except having applied 8 parts of tricyclazole, operation similar to the formulation examples 661-668 is performed, and 100 parts of each flowable agent is obtained.

Formulation Examples 677-684
It replaces with 15 parts of fusalides of the formulation examples 661-668, and except having applied 3.5 parts of diclocimet, operation similar to the formulation examples 661-668 is performed, and 100 parts of each flowable agent is obtained.

Formulation Examples 685-692
It replaces with 15 parts of fusalides of the formulation examples 661-668, and except having applied 10 parts of isotianil, operation similar to the formulation examples 661-668 is performed, and 100 parts of each flowable agent is obtained.

Formulation Examples 693-724
In place of 10 parts of Frametopil in Formulation Examples 661 to 692, the same operation as in Formulation Examples 661 to 692 is performed except that 5 parts of validamycin A is applied to obtain 100 parts of each flowable.

Formulation Examples 725-756
Instead of 10 parts of Frametopil in Formulation Examples 661 to 692, the same operation as in Formulation Examples 661 to 692 is performed except that 20 parts of flutolanil is applied to obtain 100 parts of each flowable.

Formulation Examples 757-788
In place of 10 parts of Frametopil in Formulation Examples 661 to 692, the same operation as in Formulation Examples 661 to 692 is carried out except that 20 parts of pencyclone is applied to obtain 100 parts of each flowable.

Formulation Examples 789-820
The same operation as in Formulation Examples 661 to 692 is performed except that 5 parts of Compound (I) is applied instead of 10 parts of Frametopil in Formulation Examples 661 to 692 to obtain 100 parts of each flowable.

Formulation Examples 821 to 836
Instead of 15 parts of ferrimzone in Formulation Examples 661 to 676, the same operation as in Formulation Examples 661 to 676 is performed except that 1.4 parts of kasugamycin hydrochloride is applied to obtain 100 parts of each flowable.

Formulation Examples 837 to 852
The same operation as in Formulation Examples 821 to 836 was performed except that 5 parts of validamycin A was applied instead of 10 parts of Frametopil in Formulation Examples 821 to 836 to obtain 100 parts of each flowable.

Formulation Examples 853-868
Instead of 10 parts of Frametopil in Formulation Examples 821 to 836, the same operation as in Formulation Examples 821 to 836 is performed except that 20 parts of flutolanil is applied to obtain 100 parts of each flowable.

Formulation Examples 869-884
In place of 10 parts of Frametopil in Formulation Examples 821 to 836, the same operation as in Formulation Examples 821 to 836 is performed except that 20 parts of pencyclone is applied to obtain 100 parts of each flowable.

Formulation Examples 885 to 900
The same operation as in Formulation Examples 821 to 836 was performed except that 5 parts of Compound (I) was applied instead of 10 parts of Frametopil in Formulation Examples 821 to 836 to obtain 100 parts of each flowable.

Formulation Example 901
By thoroughly pulverizing and mixing 0.5 part of the present cyanamide compound, 0.3 part of chromafenozide, 0.15 part of clothianidin, 0.5 part of furametopil, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.

Formulation Examples 902 to 906
Instead of 0.3 part of Chromafenozide in Formulation Example 901, the same operation as in Formulation Example 901 was carried out except that the respective compounds and amounts used in Table 4 were applied to obtain 100 parts of each powder.

Formulation Examples 907 to 912
Instead of 0.15 part of clothianidin in Preparation Examples 901 to 906, the same operation as in Preparation Examples 901 to 906 is carried out except that 0.25 part of Nitenpyram is applied to obtain 100 parts of each powder.

Formulation Examples 913 to 924
The same operation as in Formulation Examples 901 to 912 is performed except that 0.3 part of validamycin A is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 925 to 936
The same operation as in Formulation Examples 901 to 912 is performed except that 1.5 parts of flutolanil is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 937-948
The same operation as in Formulation Examples 901 to 912 is carried out except that 2 parts of pencyclon is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 949-960
The same operation as in Formulation Examples 901 to 912 was carried out except that 2 parts of Compound (I) was applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 961-972
In place of 0.5 part of Frametopil in Formulation Examples 901 to 912, the same operation as in Formulation Examples 901 to 912 is performed except that 2 parts of ferrimzone is applied to obtain 100 parts of each powder.

Formulation Examples 973-984
The same operation as in Formulation Examples 901 to 912 is carried out except that 2.5 parts of fusaride is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 985 to 996
The same operation as in Formulation Examples 901 to 912 was performed except that 2 parts of tricyclazole was applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 997-1008
The same operation as in Formulation Examples 901 to 912 is performed except that 0.5 part of diclosimet is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 1009-1020
Instead of 0.5 part of Frametopil in Formulation Examples 901 to 912, the same operation as in Formulation Examples 901 to 912 is performed except that 2 parts of isotianil is applied to obtain 100 parts of each powder.

Formulation Examples 1021-1032
The same operation as in Formulation Examples 901 to 912 is performed except that 0.6 part of azoxystrobin is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Examples 1033-1044
The same operation as in Formulation Examples 901 to 912 is performed except that 0.11 part of Kasugamycin hydrochloride is applied instead of 0.5 part of Frametopil in Formulation Examples 901 to 912 to obtain 100 parts of each powder.

Formulation Example 1045
By thoroughly pulverizing and mixing 0.5 parts of the present cyanamide compound, 0.3 parts of chromafenozide, 2 parts of ferrimzone, 0.5 part of furametopill, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.

Formulation Examples 1046-1052
Instead of 0.3 part of Chromafenozide in Formulation Example 1045, the same operation as in Formulation Example 1045 was performed except that the respective compounds and amounts used in Table 5 were applied to obtain 100 parts of each powder.

Formulation Examples 1053 to 1060
The same operation as in Formulation Examples 1045 to 1052 is performed except that 2.5 parts of fusaride is applied instead of 2 parts of ferrimzone in Formulation Examples 1045 to 1052, and 100 parts of each powder is obtained.

Formulation Examples 1061-1068
Instead of 2 parts of ferrimzone in Formulation Examples 1045 to 1052, the same operation as in Formulation Examples 1045 to 1052 is performed except that 2 parts of tricyclazole is applied to obtain 100 parts of each powder.

Formulation Examples 1069-1076
Instead of 2 parts of ferrimzone in Formulation Examples 1045 to 1052, the same operation as in Formulation Examples 1045 to 1052 is performed except that 0.5 part of diclocimet is applied to obtain 100 parts of each powder.

Formulation Examples 1077-1084
Instead of 2 parts of ferrimzone in Formulation Examples 1045 to 1052, the same operation as in Formulation Examples 1045 to 1052 is performed except that 0.5 part of isothianyl is applied to obtain 100 parts of each powder.

Formulation Examples 1085-1092
Instead of 2 parts of ferrimzone in Formulation Examples 1045 to 1052, the same operation as in Formulation Examples 1045 to 1052 is carried out except that 0.11 part of Kasugamycin hydrochloride is applied to obtain 100 parts of each powder.

Formulation Examples 1093 to 1140
The same operation as in Formulation Examples 1045 to 1092 is performed except that 0.3 part of validamycin A is applied instead of 0.5 part of Frametopil in Formulation Examples 1045 to 1092 to obtain 100 parts of each powder.

Formulation Examples 1041-1188
The same operation as in Formulation Examples 1045 to 1092 is performed except that 2 parts of flutolanil is applied instead of 0.5 part of Frametopil in Formulation Examples 1045 to 1092 to obtain 100 parts of each powder.

Formulation Examples 1189 to 1236
The same operation as in Formulation Examples 1045 to 1092 is carried out except that 2 parts of penciclone is used in place of 0.5 part of Frametopil in Formulation Examples 1045 to 1092 to obtain 100 parts of each powder.

Formulation examples 1237 to 1284
The same operation as in Formulation Examples 1045 to 1092 is performed except that 2 parts of Compound (I) is applied instead of 0.5 part of Frametopil in Formulation Examples 1045 to 1092 to obtain 100 parts of each powder.

Formulation Example 1285
By thoroughly pulverizing and mixing 0.5 part of the present cyanamide compound, 0.3 part of chromafenozide, 2 parts of ferrimzone, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.

Formulation examples 1286 to 1292
Instead of 0.3 part of Chromafenozide in Formulation Example 1285, the same operation as in Formulation Example 1285 was performed except that the respective compounds and amounts used in Table 6 were applied to obtain 100 parts of each powder.

Formulation Examples 1293-1300
Instead of 2 parts of ferrimzone in Formulation Examples 1285 to 1292, the same operation as in Formulation Examples 1285 to 1292 is performed except that 2.5 parts of fusaride is applied to obtain 100 parts of each powder.

Formulation Examples 1301-1308
Instead of 2 parts of ferrimzone in Formulation Examples 1285 to 1292, operations similar to those in Formulation Examples 1285 to 1292 are performed except that 2 parts of tricyclazole are applied to obtain 100 parts of each powder.

Formulation Examples 1309 to 1316
Instead of 2 parts of ferrimzone in Formulation Examples 1285 to 1292, the same operation as in Formulation Examples 1285 to 1292 is performed except that 0.5 part of diclocimet is applied to obtain 100 parts of each powder.

Formulation Examples 1317-1324
Instead of 2 parts of ferrimzone in Formulation Examples 1285 to 1292, the same operation as in Formulation Examples 1285 to 1292 is performed except that 0.5 part of isothianyl is applied to obtain 100 parts of each powder.

Formulation Examples 1325-1332
Instead of 2 parts of ferrimzone in Formulation Examples 1285 to 1292, operations similar to those in Formulation Examples 1285 to 1292 are performed except that 0.6 part of azoxystrobin is applied to obtain 100 parts of each powder.

Formulation Examples 1333 to 1340
In place of 2 parts of ferrimzone in Formulation Examples 1285 to 1292, the same operation as in Formulation Examples 1285 to 1292 is performed except that 0.11 part of Kasugamycin hydrochloride is applied to obtain 100 parts of each powder.

Formulation Example 1341
By thoroughly pulverizing and mixing 0.5 part of the present cyanamide compound, 0.15 part of clothianidin, 0.3 part of validamycin A, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.

Formulation Examples 1342 to 1345
Instead of 0.3 part of validamycin A in Formulation Example 1341, the same operation as in Formulation Example 1341 was applied except that the respective compounds and amounts used in Table 7 were applied to obtain 100 parts of each powder.

Formulation Examples 1346 to 1350
Instead of 0.15 part of clothianidin in Formulation Examples 1341-1345, the same operation as in Formulation Examples 1341-1345 is performed except that 0.25 part of Nitenpyram is applied to obtain 100 parts of each powder.

  Next, the effect of the present invention will be shown by test examples.

Test example 1
This cyanamide compound, chromafenozide, methoxyphenozide, tebufenozide, cartap, spinetoram, silafluophene, clothianidin, nitenpyram, isotianil, ferimzone, fusaride, tricyclazole, azoxystrobin, framethopir, validamycin A, diclocimet, pentoclone, compound The hydrochloride is dissolved in acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing a surfactant (polyoxyethylene sorbitan monococoate, trade name: Sorgen TW-20, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.), and then reaches a predetermined concentration. So as to dilute with 0.02% by volume of water (trade name: Dyne (registered trademark), manufactured by Sumitomo Chemical Horticulture).
Diluted water of this cyanamide compound, chromafenozide, methoxyphenozide, tebufenozide, cartap, silafluophene, clothianidin, nitenpyram or spinetoram in water diluted with isothianyl, ferrimzone, fusaride, tricyclazole, azoxystrobin, flametopyr, validamycin A, diclocimet A test drug solution having a predetermined concentration (concentrations are shown in Tables 8 to 35) is prepared by mixing with water-diluted solution of flutolanil, pencyclon, compound (I) or kasugamycin hydrochloride.
2.5 ml of paper pot planted rice (Oryza sativa, variety: Nanatsuboshi) seedlings are sprayed with 10 ml of the test chemical per strain. The rice seedlings are air-dried and then put into a glass test tube (diameter 30 mm, height 200 mm) containing 4.8 ml of water. Ten third instar larvae of the brown planthopper are released into the test tube and placed indoors (25 ° C., humidity 60%). These are treated zones.
On the other hand, water containing 0.02% by volume of a spreading agent (trade name: Dyne (registered trademark), manufactured by Sumitomo Chemical Horticulture) was prepared, and a 2.5-leaf paper pot planted rice (Oryza sativa, variety: N Natsuboshi) Spread 10 ml of the spreading agent-containing water per strain on young seedlings. The rice seedlings are air-dried and then put into a glass test tube (diameter 30 mm, height 200 mm) containing 4.8 ml of water. Ten third instar larvae of the brown planthopper are released into the test tube and placed indoors (25 ° C., humidity 60%). These are designated as untreated areas.
After 4 days, the treated larvae are observed for life and death in each of the treated group and the untreated group. From the observation results, the mortality rate is calculated by Equation 1), and the corrected mortality rate is calculated by Equation 2).
As a result, it can be confirmed that the planthopper is controlled in the treatment area.

  Formula 1); death rate (%) = number of treated area dead insects / number of test insects × 100

  Formula 2); corrected mortality rate (%) = {(treatment area mortality rate−untreated area mortality ratio) / (100−untreated area mortality ratio)} × 100

Claims (5)

Formula (1)

A harmful arthropod control composition comprising a compound represented by formula (1), one or more compounds selected from the group (A), and one or more compounds selected from the group (B).
Group (A): A group consisting of chromafenozide, methoxyphenozide, tebufenozide, cartap, spinetoram, silafluophene, clothianidin and nitenpyram.
Group (B): Isothianyl, ferrimzone, fusalide, tricyclazole, validamycin A, furamethpyr, diclocimet, azoxystrobin, flutolanil, pencyclon, N- [2- (1,3-dimethylbutyl) phenyl] -1,3-dimethyl A group consisting of -5-fluoro-1H-pyrazole-4-carboxamide and kasugamycin hydrochloride.   The harmful arthropod control composition according to claim 1, wherein the weight ratio of the compound represented by the formula (1) to one or more compounds selected from the group (A) is 100: 1 to 1: 100.   The harmful arthropod according to claim 1 or 2, wherein the weight ratio of the compound represented by the formula (1) to one or more compounds selected from the group (B) is 100: 1 to 1: 100. Control composition.   A method for controlling harmful arthropods, comprising a step of applying an effective amount of the harmful arthropod control composition according to any one of claims 1 to 3 to a plant or a plant cultivation site.   5. The method for controlling harmful arthropods according to claim 4, wherein the step of applying the plant or the plant cultivation site is a step of applying the plant to the rice or the rice cultivation site.