WO2012090911A1 - Harmful arthropod control composition and method for controlling harmful arthropods - Google Patents

Harmful arthropod control composition and method for controlling harmful arthropods Download PDF

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Publication number
WO2012090911A1
WO2012090911A1 PCT/JP2011/080021 JP2011080021W WO2012090911A1 WO 2012090911 A1 WO2012090911 A1 WO 2012090911A1 JP 2011080021 W JP2011080021 W JP 2011080021W WO 2012090911 A1 WO2012090911 A1 WO 2012090911A1
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Prior art keywords
compound
parts
present
control composition
group
Prior art date
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PCT/JP2011/080021
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French (fr)
Japanese (ja)
Inventor
えみ子 坂本
法久 坂元
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住友化学株式会社
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Priority to CN2011800630941A priority Critical patent/CN103260414A/en
Priority to KR1020137019814A priority patent/KR20140018864A/en
Publication of WO2012090911A1 publication Critical patent/WO2012090911A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

Definitions

  • the present invention relates to a harmful arthropod control composition and a method for controlling harmful arthropods.
  • Non-Patent Document 1 discloses many compounds as active ingredients of harmful arthropod control compositions.
  • An object of the present invention is to provide a harmful arthropod control composition having an excellent control effect on harmful arthropods.
  • a cyanamide compound represented by formula (2) [Wherein, the combination of R 1 and R 2 represents a combination in which R 1 is a methyl group and R 2 is a chlorine atom, or a combination in which R 1 is a methyl group and R 2 is a cyano group.
  • a harmful arthropod control composition comprising an anthranilamido compound represented by the formula (1) and one or more blast control compounds selected from the group (A).
  • the harmful arthropod control composition according to [2], wherein the weight ratio of the cyanamide compound and the blast control compound is 50: 1 to 1: 100.
  • a method for controlling harmful arthropods comprising a step of applying an effective amount of the composition for controlling harmful arthropods according to any one of [1] to [3] to a plant or a planting site.
  • harmful arthropods can be controlled.
  • the harmful arthropod control composition of the present invention includes a cyanamide compound represented by the following formula (1) (hereinafter sometimes referred to as the present cyanamide compound) and an anthranilamide compound represented by the following formula (2) ( Hereinafter, it may be referred to as the present anthranilamido compound) and one or more blast control compounds selected from the following group (A) (hereinafter may be referred to as the present blast control compound).
  • the combination of R 1 and R 2 represents a combination in which R 1 is a methyl group and R 2 is a chlorine atom, or a combination in which R 1 is a methyl group and R 2 is a cyano group.
  • the cyanamide compound used in the present invention is a known compound and can be produced, for example, by the method described in International Publication No. 2007/095229.
  • anthranilamide compound (1) a compound in which R 1 is a methyl group and R 2 is a chlorine atom in the formula (2) (hereinafter referred to as the present anthranilamide compound (1)) is, for example, “The Pesticide Manual. -15th edition (published by BCPC); ISBN 978-1-901396-18-8 ”, page 175, and the compound can be obtained from a commercially available formulation or produced by a known method.
  • anthranilamide compound (2) a compound in which R 1 is a methyl group and R2 is a cyano group in the formula (2) (hereinafter referred to as the present anthranilamide compound (2)) is, for example, “The Pesticide Manual- 15th edition (published by BCPC); ISBN 978-1-901396-18-8 ”, page 251, and the compound can be produced by the method described in International Publication No. 2004/067528.
  • probenazole, thiazinyl, tricyclazole, oryastrobine and pyroxylone used in the present invention are all known compounds, for example, “The Pesticide Manual-15th edition (BCPC); ISBN 978-1-901396-18-8” 927, 1134, 1163, 840, and 999 pages. These compounds can be obtained from commercially available preparations or produced by known methods. Isotianil used in the present invention is a known compound and can be produced, for example, by the method described in WO99 / 024413.
  • the content ratio of the cyanamide compound, the anthranilamide compound, and the rice blast control compound in the harmful arthropod control composition of the present invention is not particularly limited, but is 100 parts by weight of the cyanamide compound.
  • the anthranilamide compound is usually 0.1 to 50000 parts by weight, preferably 1 to 5000 parts by weight, and the blast control compound is usually 0.2 to 100,000 parts by weight, preferably 2 to 10000 parts by weight. is there.
  • the harmful arthropod control composition of the present invention may be a mixture of the cyanamide compound, the anthranilamide compound and the rice blast control compound, but usually the cyanamide compound, the anthranilamide compound and the rice blast.
  • Mix disease control compound and inert carrier add surfactants and other formulation adjuvants as needed, oil, emulsion, flowable, wettable powder, wettable powder, powder, granule What was formulated into an agent or the like is used.
  • the above-mentioned formulated harmful arthropod control composition can be used as a harmful arthropod control agent as it is or by adding other inactive ingredients.
  • the total amount of the present cyanamide compound, the present anthranilamido compound and the present blast control compound in the harmful arthropod control composition of the present invention is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight.
  • the range is more preferably 0.5 to 70% by weight.
  • solid carriers used in formulation include kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, corn cob flour, walnut shell powder, etc.
  • Natural organic materials synthetic organic materials such as urea, salts such as calcium carbonate and ammonium sulfate, fine powders or granular materials made of synthetic inorganic materials such as synthetic silicon hydroxide, etc.
  • liquid carriers include, for example, xylene, alkylbenzene, methyl Aromatic hydrocarbons such as naphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether, ketones such as acetone, cyclohexanone and isophorone, vegetable oils such as soybean oil and cottonseed oil, petroleum fats Group hydrocarbon , Esters, dimethyl sulfoxide, acetonitrile and water.
  • surfactants include anionic interfaces such as alkyl sulfate esters, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkylaryl ether phosphate esters, lignin sulfonates, naphthalene sulfonate formaldehyde polycondensates, and the like.
  • Nonionic surfactants such as activators and polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers, sorbitan fatty acid esters, and cationic surfactants such as alkyltrimethylammonium salts.
  • formulation adjuvants include, for example, water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone, gum arabic, alginic acid and its salts, polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum, aluminum magnesium silicate, alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.
  • water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone
  • gum arabic alginic acid and its salts
  • polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum
  • aluminum magnesium silicate such as aluminum magnesium silicate
  • alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.
  • PAP isopropyl acid phosphate
  • the harmful arthropod control composition of the present invention can be used to protect plants from harm by harmful arthropods that feed plants, suck juice, and the like.
  • Examples of the harmful arthropods having the control effect of the harmful arthropod control composition of the present invention include the following.
  • Hemiptera small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), planthopper such Sejirounka (Sogatella furcifera), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Inazuma leafhopper (Recilia dorsalis), Chanomidorihime Leafhoppers such as leafhoppers (Epoasca onukii), cotton aphids (Aphis gossypi), peach aphids (Myzus persicae), radish aphids (Brevicorine brassicae), Yukina gear aphids spiraecola), tulip aphid (Macrosiphum euphorbiae), potato aphid (Aulacorthum solani), oat constricted aphid (Rhopalosip
  • Lami Aonidiella aurantii, San Jose scale Aphid (Comstockcaspis perniciosa), Citrus snow scale (Unaspis citrus), Ruby loam beetle (Ceroplastes ruba), Iceria cochla Scale insects such as scale insects (Pseudococcus longispinis) and scale insects (Pseudaulacapaspis pentagona), bed bugs such as bedbugs (Cimex lectularius), pair larva ps yricola) psyllid such as such.
  • Lepidoptera rice stem borer (Chilo suppressalis), Sankameiga (Tryporyza incertulas), leaf roller (Cnaphalocrocis medinalis), Watanomeiga (Notarcha derogata), Indian meal moth (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), high Madara Roh moth (Hellula undalis), Japanese medusa such as Shibatatsuga (Pediasia teterrellus), Lotus moth (Spodoptera litura), Spodoptera exigua, Ayuyoto (Pseudaletia sepata), Itoyoto esamia inferens, moths (Mamestra brassicae), agrotis ipsilon, stag beetle (Plasia nigrisigna), ceramus moths, genus Trichoplusia, White butterflies, genus Adoxofies, Nashihimes
  • Thysanoptera western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips peri), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), tobacco thrips (Frankliniella fusca), rice thrips (Thenchaetotrips biformis), thrips such as Hecklotrips acculeatus, etc .; Diptera: onion maggot (Hylemya antiqua), seedcorn maggot (Hylemya platura), rice leafminer (Agromyza oryzae), rice Hime leafminer (Hydrellia griseola), Inekimoguribae (Chlorops oryzae), leafminer such as beans leafminer (Liriomyza trifolii), melon fly (Dacus cucurbitae), fruit fly (Ceratitis capita
  • preferred examples include planthoppers, leafhoppers, aphids, stink bugs, rice weevil, rice beetles, moths, and moths.
  • the harmful arthropod control composition of the present invention may be used for the purpose of controlling plant diseases, and can control, for example, rice blast (Magnaporthe grisea).
  • the harmful arthropod control composition of the present invention can be used in agricultural fields such as fields, paddy fields, dry fields, lawns, orchards, or non-cultivated areas.
  • the harmful arthropod control composition of the present invention can be used for controlling pests on the farmland in farmlands where "plants" are cultivated.
  • plants for which the harmful arthropod control composition of the present invention can be used include the following.
  • Agricultural crops corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, etc.
  • Vegetables Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelons, melons, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage) , Mustard, broccoli, cauliflower, rape, etc.), asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), liliaceae vegetables (eg, leek, onion, garlic, asparagus), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint
  • Fruit trees berries (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
  • Trees other than fruit trees tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi, sakura, yurinoki, crape myrtle, snapdragon, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak) , Poplar, redwood, fu, sycamore, zelkova, blackfish, Japanese amberjack, moths, pine, pine, spruce, yew, elm, Japanese cypress, etc.), coral jug, dogwood, cedar, cypress, croton, masaki, kanamochi, etc.
  • Lawn Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Neurodonidae, etc.), Bentgrass (Oleoptera, Hykonukagusa, Odonoptera, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Oonishi nokegusa, Drosophila, etc.) , Grass, etc.), ryegrass (rat, wheat, etc.), anemonefish, blue whale, etc.
  • corn, wheat, rice and the like can be mentioned as preferable examples. Of these, rice is particularly preferable.
  • the “plant” may be a plant to which resistance is imparted by a genetic recombination technique or a breeding method by crossing.
  • the harmful arthropod control composition of the present invention is used to control harmful arthropods by being applied to plants or planting areas.
  • plants include plant foliage, plant flowers, plant nuts, plant seeds, and the like.
  • the method for controlling harmful arthropods of the present invention is carried out by treating the composition for controlling harmful arthropods of the present invention. Specifically, for example, treatment of plant foliage such as foliage spraying, Treatment of seeds, soil treatment, water surface application, etc. to plant cultivation areas. Further, in the method for controlling harmful arthropods of the present invention, the present cyanamide compound, the present anthranilamido compound and the present blast control compound are applied separately or successively to a plant or a plant cultivation site. Is also included.
  • the treatment of the foliage of plants such as foliage spraying in the present invention includes, for example, ground spraying using a human sprayer, power sprayer, boom sprayer or cruckle sprayer, air control or unmanned helicopter A method of treating the surface of a plant being cultivated, for example, by aerial spraying performed using
  • Specific examples of the treatment of plant seeds in the present invention include immersion treatment, spraying treatment, smearing treatment, film coating treatment, and pellet coating treatment.
  • planting hole treatment specifically, for example, planting hole treatment, stock source treatment, grooving treatment, rowing treatment, full surface treatment, side stripe treatment
  • planting hole treatment specifically, for example, planting hole treatment, stock source treatment, grooving treatment, rowing treatment, full surface treatment, side stripe treatment
  • Examples include seedling box treatment, seedbed treatment, soil mixing, bed soil mixing, paste fertilizer mixing, water surface treatment, flooding spraying and the like, and preferably a seedling box treatment.
  • the amount of treatment is the type of plant to be treated, the type and occurrence of harmful arthropods to be controlled, the formulation form,
  • the total amount of the cyanamide compound, the anthranilamide compound, and the rice blast control compound is usually 0.05 to 10,000 g per 1000 m 2 where the plant is cultivated, preferably 0.5 to 1000 g.
  • the treatment amount is 1 box (horizontal) as the total amount of the cyanamide compound, the anthranilamide compound and the rice blast control compound. (About 60 cm, length about 30 cm) is usually 0.1 to 35 g, preferably 0.2 to 20 g.
  • the treatment amount is The total amount of the cyanamide compound, the present anthranilamide compound, and the present blast control compound is usually 2 to 700 g, preferably 4 to 400 g, per 1000 m 2 of the place where rice is cultivated after transplanting.
  • the amount of treatment is the type of plant to be treated, the type and degree of occurrence of harmful arthropods to be controlled, the formulation form, the treatment time,
  • the total amount of the cyanamide compound, the anthranilamide compound, and the rice blast control compound is usually 0.001 to 100 g, preferably 0.05 to 50 g, per 1 kg of seeds.
  • the harmful arthropod control composition of the present invention is treated by spraying emulsions, wettable powders, flowables, etc., usually diluted with water.
  • the total concentration of the present cyanamide compound, the present anthranilamido compound and the present blast control compound is usually in the range of 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight.
  • Powders, granules, etc. are usually processed as they are without dilution.
  • the method for controlling harmful arthropods according to the present invention when used in rice or rice cultivated land, for example, it can be applied before sowing, during sowing, after sowing, before transplanting, at the time of transplanting or after transplanting of rice. it can.
  • the timing of application may vary depending on the growth state of rice, the occurrence of pests and pests, weather conditions, etc., but it can usually be mentioned from 30 days before sowing to 20 days after transplanting, based on the day of sowing or transplanting rice.
  • from the time of sowing to before transplantation more preferably from 3 days before transplantation to before transplantation.
  • Formulation Example 1 2 parts of the present cyanamide compound, 0.75 part of the present anthranilamide compound (1), 2 parts of isotianil, 1 part of synthetic hydrous silicon oxide, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and 100 parts of kaolin clay balance After pulverizing and mixing, adding water and kneading well, granulation and drying are performed to obtain granules.
  • Formulation Examples 2-7 instead of 2 parts of isotianil, the same operation as in Formulation Example 1 is carried out except that the respective compounds and amounts used in [Table 1] are applied to obtain respective granules.
  • Formulation Example 8 2 parts of the cyanamide compound, 0.75 part of the anthranilamide compound (2), 2 parts of isothianyl, 1 part of synthetic hydrous silicon oxide, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and 100 parts of kaolin clay balance After pulverizing and mixing, adding water and kneading well, granulation and drying are performed to obtain granules.
  • Formulation Example 15 While mixing 2 parts of the present cyanamide compound, 10 parts of the present anthranilamide compound (1) and 4 parts of isothianyl, 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic hydrous silicon oxide fine powder and the remainder of diatomaceous earth were mixed. In addition, well mixed with stirring to obtain 100 parts of wettable powder.
  • Formulation Examples 16-20 It replaces with 4 parts of isotianil, and except having applied each compound and usage-amount of [Table 3], operation similar to the formulation example 15 is performed, and 100 parts of each wettable powder is obtained.
  • Formulation Example 21 While mixing 2 parts of the present cyanamide compound, 10 parts of the present anthranilamide compound (2) and 4 parts of isotianil, 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic hydrous silicon oxide fine powder and the remainder of diatomaceous earth were mixed. In addition, well mixed with stirring to obtain 100 parts of wettable powder.
  • Formulation Examples 22 to 26 It replaces with 4 parts of isotianil, and except having applied each compound and usage-amount of the [Table 4] description, operation similar to the formulation example 21 is performed, and 100 parts of each wettable powder is obtained.
  • Formulation Example 27 A powder is obtained by thoroughly pulverizing and mixing 3 parts of the present cyanamide compound, 1.5 parts of the present anthranilamide compound (1), 0.6 part of isotianil, 84.9 parts of kaolin clay and 10 parts of talc.
  • Formulation Examples 28-32 The powders are obtained in the same manner as in Formulation Example 27 except that the respective compounds and amounts used in [Table 5] are used instead of 0.6 parts of isotianil.
  • Formulation Example 33 A powder is obtained by thoroughly pulverizing and mixing 3 parts of the present cyanamide compound, 1.5 parts of the anthranilamide compound (2), 0.6 part of isothianyl, 84.9 parts of kaolin clay and 10 parts of talc.
  • Formulation Examples 34 to 38 The powders are obtained in the same manner as in Formulation Example 33, except that the respective compounds and amounts used in [Table 6] are used instead of 0.6 parts of isotianil.
  • Formulation Example 39 100 parts of a mixture obtained by mixing 10 parts of the cyanamide compound, 2 parts of the anthranilamide compound (1), 4 parts of isotianil, 50 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of the water by a wet grinding method A flowable agent is obtained by pulverizing.
  • Formulation Example 45 100 parts of a mixture prepared by mixing 10 parts of the cyanamide compound, 2 parts of the anthranilamide compound (2), 4 parts of isotianil, 50 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of the water by a wet pulverization method A flowable agent is obtained by pulverizing.
  • Formulation Examples 46-50 instead of 4 parts of isotianil, the same operation as in Formulation Example 45 is carried out except that the respective compounds and amounts used in [Table 8] are applied to obtain respective flowable agents.
  • a test chemical solution was prepared. 2.5 ml of paper pot planted rice (Oryza sativa, cultivar: Hoshino Yume) 1 ml of seedling was applied with 0.6 ml of the chemical solution for the test. After leaving still for 2 hours, it transplanted to the flooded soil of a 1 / 10000a Wagner pot, and set

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

This harmful arthropod control composition, which contains the cyanamide compound indicated by formula (1), the anthranilamide compound indicated by formula (2) (in the formula, the combination of R1 and R2 represents the combination of R1 being a methyl group and R2 being a chlorine atom, or the combination of R1 being a methyl group and R2 being a cyano group), and at least one blast disease control composition selected from group (A), has superior control efficacy. Group (A) is the group comprising: isotianil, probenazole, tiadinil, tricyclazole, orysastrobin, and pyroquilon.

Description

有害節足動物防除組成物及び有害節足動物の防除方法Harmful arthropod control composition and harmful arthropod control method
　本特許出願は、日本国特許出願第２０１０－２８９６１３号について優先権を主張するものであり、ここに参照することによって、その全体が本明細書中へ組み込まれるものとする。
　本発明は、有害節足動物防除組成物及び有害節足動物の防除方法に関するものである。 This patent application claims priority with respect to Japanese Patent Application No. 2010-289613, which is hereby incorporated by reference in its entirety.
The present invention relates to a harmful arthropod control composition and a method for controlling harmful arthropods.
　従来、有害節足動物防除組成物の有効成分として、多くの化合物が知られている（例えば、非特許文献１参照）。 Conventionally, many compounds are known as active ingredients of harmful arthropod control compositions (see, for example, Non-Patent Document 1).
　本発明は、有害節足動物に対する優れた防除効力を有する有害節足動物防除組成物を提供することを課題とする。 An object of the present invention is to provide a harmful arthropod control composition having an excellent control effect on harmful arthropods.
　本発明者等は、有害節足動物に対する優れた防除効力を有する有害節足動物防除組成物を見出すべく検討した結果、下記式（１）で示されるシアナミド化合物と、下記式（２）で示されるアントラニルアミド化合物と、下記群（Ａ）より選ばれる１種以上のいもち病防除化合物とを含有する組成物が、有害節足動物に対する優れた防除効力を有することを見出し、本発明に到った。
　すなわち、本発明とは以下の［１］～［５］のものである。
［１］　式（１）
Figure JPOXMLDOC01-appb-I000003
で示されるシアナミド化合物と、式（２）
Figure JPOXMLDOC01-appb-I000004
〔式中、Ｒ１及びＲ２の組合せは、Ｒ１がメチル基かつＲ２が塩素原子である組合せ、又は、Ｒ１がメチル基かつＲ２がシアノ基である組合せを表す。〕
で示されるアントラニルアミド化合物と、群（Ａ）より選ばれる１種以上のいもち病防除化合物とを含有する有害節足動物防除組成物。
群（Ａ）：イソチアニル、プロベナゾール、チアジニル、トリシクラゾール、オリサストロビン及びピロキロンからなる群。
［２］　シアナミド化合物と、アントラニルアミド化合物との重量比が、１００：１～１：５０である［１］記載の有害節足動物防除組成物。
［３］　シアナミド化合物と、いもち病防除化合物との重量比が、５０：１～１：１００である［２］記載の有害節足動物防除組成物。
［４］　［１］～［３］いずれか一項記載の有害節足動物防除組成物の有効量を、植物又は植物の栽培地に施用する工程を含む有害節足動物の防除方法。
［５］　植物又は植物の栽培地が、イネ又はイネの栽培地である［４］記載の有害節足動物の防除方法。 As a result of studies to find a harmful arthropod control composition having an excellent control effect on harmful arthropods, the present inventors have shown that a cyanamide compound represented by the following formula (1) and the following formula (2) And a composition containing at least one blast disease control compound selected from the following group (A) has an excellent control effect against harmful arthropods. It was.
That is, the present invention includes the following [1] to [5].
[1] Formula (1)
Figure JPOXMLDOC01-appb-I000003
A cyanamide compound represented by formula (2):
Figure JPOXMLDOC01-appb-I000004
[Wherein, the combination of R 1 and R 2 represents a combination in which R 1 is a methyl group and R 2 is a chlorine atom, or a combination in which R 1 is a methyl group and R 2 is a cyano group. ]
A harmful arthropod control composition comprising an anthranilamido compound represented by the formula (1) and one or more blast control compounds selected from the group (A).
Group (A): A group consisting of isothianyl, probenazole, thiazinyl, tricyclazole, orisatrobin and pyroxylone.
[2] The harmful arthropod control composition according to [1], wherein the weight ratio of the cyanamide compound to the anthranilamide compound is 100: 1 to 1:50.
[3] The harmful arthropod control composition according to [2], wherein the weight ratio of the cyanamide compound and the blast control compound is 50: 1 to 1: 100.
[4] A method for controlling harmful arthropods, comprising a step of applying an effective amount of the composition for controlling harmful arthropods according to any one of [1] to [3] to a plant or a planting site.
[5] The method for controlling harmful arthropods according to [4], wherein the plant or the plant cultivation site is rice or a rice cultivation site.
　本発明により、有害節足動物を防除することができる。 According to the present invention, harmful arthropods can be controlled.
　本発明の有害節足動物防除組成物とは、下記式（１）で示されるシアナミド化合物（以下、本シアナミド化合物と記す場合がある。）と、下記式（２）で示されるアントラニルアミド化合物（以下、本アントラニルアミド化合物と記す場合がある。）と、下記群（Ａ）より選ばれる１種以上のいもち病防除化合物（以下、本いもち病防除化合物と記す場合がある。）とを含有するものである。
Figure JPOXMLDOC01-appb-I000005
Figure JPOXMLDOC01-appb-I000006
〔式中、Ｒ１及びＲ２の組合せは、Ｒ１がメチル基かつＲ２が塩素原子である組合せ、又は、Ｒ１がメチル基かつＲ２がシアノ基である組合せを表す。〕
群（Ａ）：イソチアニル、プロベナゾール、チアジニル、トリシクラゾール、オリサストロビン及びピロキロンからなる群。 The harmful arthropod control composition of the present invention includes a cyanamide compound represented by the following formula (1) (hereinafter sometimes referred to as the present cyanamide compound) and an anthranilamide compound represented by the following formula (2) ( Hereinafter, it may be referred to as the present anthranilamido compound) and one or more blast control compounds selected from the following group (A) (hereinafter may be referred to as the present blast control compound). Is.
Figure JPOXMLDOC01-appb-I000005
Figure JPOXMLDOC01-appb-I000006
[Wherein, the combination of R 1 and R 2 represents a combination in which R 1 is a methyl group and R 2 is a chlorine atom, or a combination in which R 1 is a methyl group and R 2 is a cyano group. ]
Group (A): A group consisting of isothianyl, probenazole, thiazinyl, tricyclazole, orisatrobin and pyroxylone.
　本発明に用いられるシアナミド化合物は公知の化合物であり、たとえば国際公開第２００７／０９５２２９号パンフレットに記載された方法で製造することができる。 The cyanamide compound used in the present invention is a known compound and can be produced, for example, by the method described in International Publication No. 2007/095229.
　本アントラニルアミド化合物のうち、式（２）において、Ｒ１がメチル基であり、Ｒ２が塩素原子である化合物（以下、本アントラニルアミド化合物（１）と記す。）は、例えば「Ｔｈｅ　Ｐｅｓｔｉｃｉｄｅ　Ｍａｎｕａｌ－１５ｔｈ　ｅｄｉｔｉｏｎ（ＢＣＰＣ刊）；ＩＳＢＮ　９７８－１－９０１３９６－１８－８」の１７５ページに記載されており、該化合物は市販の製剤から得るか、公知の方法により製造することにより得られる。
　本アントラニルアミド化合物のうち、式（２）において、Ｒ１がメチル基であり、Ｒ２がシアノ基である化合物（以下、本アントラニルアミド化合物（２）と記す。）は、例えば「Ｔｈｅ　Ｐｅｓｔｉｃｉｄｅ　Ｍａｎｕａｌ－１５ｔｈ　ｅｄｉｔｉｏｎ（ＢＣＰＣ刊）；ＩＳＢＮ　９７８－１－９０１３９６－１８－８」の２５１ページに記載されており、該化合物は国際公開第２００４／０６７５２８号パンフレットに記載された方法で製造することができる。 Among the anthranilamide compounds, a compound in which R 1 is a methyl group and R 2 is a chlorine atom in the formula (2) (hereinafter referred to as the present anthranilamide compound (1)) is, for example, “The Pesticide Manual. -15th edition (published by BCPC); ISBN 978-1-901396-18-8 ”, page 175, and the compound can be obtained from a commercially available formulation or produced by a known method.
Among the anthranilamide compounds, a compound in which R 1 is a methyl group and R2 is a cyano group in the formula (2) (hereinafter referred to as the present anthranilamide compound (2)) is, for example, “The Pesticide Manual- 15th edition (published by BCPC); ISBN 978-1-901396-18-8 ”, page 251, and the compound can be produced by the method described in International Publication No. 2004/067528.
　また、本発明に用いられるプロベナゾール、チアジニル、トリシクラゾール、オリサストロビン及びピロキロンはいずれも公知の化合物であり、例えば「 Ｔｈｅ　Ｐｅｓｔｉｃｉｄｅ　Ｍａｎｕａｌ－１５ｔｈ　ｅｄｉｔｉｏｎ（ＢＣＰＣ刊）；ＩＳＢＮ　９７８－１－９０１３９６－１８－８ 」の９２７、１１３４、１１６３、８４０及び９９９ページ等に記載されている。これらの化合物は市販の製剤から得るか、公知の方法により製造することにより得られる。
　本発明に用いられるイソチアニルは公知の化合物であり、例えば国際公開第９９／０２４４１３号パンフレットに記載された方法で製造することができる。 In addition, probenazole, thiazinyl, tricyclazole, oryastrobine and pyroxylone used in the present invention are all known compounds, for example, “The Pesticide Manual-15th edition (BCPC); ISBN 978-1-901396-18-8” 927, 1134, 1163, 840, and 999 pages. These compounds can be obtained from commercially available preparations or produced by known methods.
Isotianil used in the present invention is a known compound and can be produced, for example, by the method described in WO99 / 024413.
　本発明の有害節足動物防除組成物における、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物との含有割合は、特に限定されるものではないが、本シアナミド化合物１００重量部に対して、本アントラニルアミド化合物が、通常０．１～５００００重量部、好ましくは１～５０００重量部であり、本いもち病防除化合物が、通常０．２～１０００００重量部、好ましくは２～１００００重量部である。 The content ratio of the cyanamide compound, the anthranilamide compound, and the rice blast control compound in the harmful arthropod control composition of the present invention is not particularly limited, but is 100 parts by weight of the cyanamide compound. The anthranilamide compound is usually 0.1 to 50000 parts by weight, preferably 1 to 5000 parts by weight, and the blast control compound is usually 0.2 to 100,000 parts by weight, preferably 2 to 10000 parts by weight. is there.
　本発明の有害節足動物防除組成物は、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物とを単に混合したものでもよいが、通常は、本シアナミド化合物、本アントラニルアミド化合物及び本いもち病防除化合物と不活性担体とを混合し、必要に応じて界面活性剤やその他の製剤用補助剤を添加して、油剤、乳剤、フロアブル剤、水和剤、顆粒水和剤、粉剤、粒剤等に製剤化されたものが用いられる。
　また、前記の製剤化された有害節足動物防除組成物は、そのまま又はその他の不活性成分を添加して有害節足動物防除剤として使用することができる。
　本発明の有害節足動物防除組成物における、本シアナミド化合物、本アントラニルアミド化合物及び本いもち病防除化合物の合計量は、通常０．０１～９９重量％、好ましくは０．１～９０重量％の範囲、さらに好ましくは０．５～７０重量％の範囲である。 The harmful arthropod control composition of the present invention may be a mixture of the cyanamide compound, the anthranilamide compound and the rice blast control compound, but usually the cyanamide compound, the anthranilamide compound and the rice blast. Mix disease control compound and inert carrier, add surfactants and other formulation adjuvants as needed, oil, emulsion, flowable, wettable powder, wettable powder, powder, granule What was formulated into an agent or the like is used.
Moreover, the above-mentioned formulated harmful arthropod control composition can be used as a harmful arthropod control agent as it is or by adding other inactive ingredients.
The total amount of the present cyanamide compound, the present anthranilamido compound and the present blast control compound in the harmful arthropod control composition of the present invention is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight. The range is more preferably 0.5 to 70% by weight.
　製剤化の際に用いられる固体担体としては、例えばカオリンクレー、アッタパルジャイトクレー、ベントナイト、モンモリロナイト、酸性白土、パイロフィライト、タルク、珪藻土、方解石等の鉱物、トウモロコシ穂軸粉、クルミ殻粉等の天然有機物、尿素等の合成有機物、炭酸カルシウム、硫酸アンモニウム等の塩類、合成含水酸化珪素等の合成無機物等からなる微粉末あるいは粒状物等が挙げられ、液体担体としては、例えばキシレン、アルキルベンゼン、メチルナフタレン等の芳香族炭化水素類、２－プロパノール、エチレングリコール、プロピレングリコール、エチレングリコールモノエチルエーテル等のアルコール類、アセトン、シクロヘキサノン、イソホロン等のケトン類、ダイズ油、綿実油等の植物油、石油系脂肪族炭化水素類、エステル類、ジメチルスルホキシド、アセトニトリル及び水が挙げられる。
　界面活性剤としては、例えばアルキル硫酸エステル塩、アルキルアリールスルホン酸塩、ジアルキルスルホコハク酸塩、ポリオキシエチレンアルキルアリールエーテルリン酸エステル塩、リグニンスルホン酸塩、ナフタレンスルホネートホルムアルデヒド重縮合物等の陰イオン界面活性剤及びポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンアルキルポリオキシプロピレンブロックコポリマー、ソルビタン脂肪酸エステル等の非イオン界面活性剤、及びアルキルトリメチルアンモニウム塩等の陽イオン界面活性剤が挙げられる。
　その他の製剤用補助剤としては、例えばポリビニルアルコール、ポリビニルピロリドン等の水溶性高分子、アラビアガム、アルギン酸及びその塩、ＣＭＣ（カルボキシメチルセルロ－ス）、ザンサンガム等の多糖類、アルミニウムマグネシウムシリケート、アルミナゾル等の無機物、防腐剤、着色剤及びＰＡＰ（酸性リン酸イソプロピル）、ＢＨＴ等の安定化剤が挙げられる。 Examples of solid carriers used in formulation include kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, corn cob flour, walnut shell powder, etc. Natural organic materials, synthetic organic materials such as urea, salts such as calcium carbonate and ammonium sulfate, fine powders or granular materials made of synthetic inorganic materials such as synthetic silicon hydroxide, etc., and liquid carriers include, for example, xylene, alkylbenzene, methyl Aromatic hydrocarbons such as naphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether, ketones such as acetone, cyclohexanone and isophorone, vegetable oils such as soybean oil and cottonseed oil, petroleum fats Group hydrocarbon , Esters, dimethyl sulfoxide, acetonitrile and water.
Examples of surfactants include anionic interfaces such as alkyl sulfate esters, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkylaryl ether phosphate esters, lignin sulfonates, naphthalene sulfonate formaldehyde polycondensates, and the like. Nonionic surfactants such as activators and polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers, sorbitan fatty acid esters, and cationic surfactants such as alkyltrimethylammonium salts.
Other formulation adjuvants include, for example, water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone, gum arabic, alginic acid and its salts, polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum, aluminum magnesium silicate, alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.
　本発明の有害節足動物防除組成物は、植物に対して摂食、吸汁等の加害を行う有害節足動物による加害から植物を保護するために用いることができる。 The harmful arthropod control composition of the present invention can be used to protect plants from harm by harmful arthropods that feed plants, suck juice, and the like.
　本発明の有害節足動物防除組成物が防除効力を有する有害節足動物としては、例えば次のものが挙げられる。 Examples of the harmful arthropods having the control effect of the harmful arthropod control composition of the present invention include the following.
　半翅目害虫：ヒメトビウンカ（Ｌａｏｄｅｌｐｈａｘ　ｓｔｒｉａｔｅｌｌｕｓ）、トビイロウンカ（Ｎｉｌａｐａｒｖａｔａ　ｌｕｇｅｎｓ）、セジロウンカ（Ｓｏｇａｔｅｌｌａ　ｆｕｒｃｉｆｅｒａ）等のウンカ類、ツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ　ｃｉｎｃｔｉｃｅｐｓ）、タイワンツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ　ｖｉｒｅｓｃｅｎｓ）、イナズマヨコバイ（Ｒｅｃｉｌｉａ　ｄｏｒｓａｌｉｓ）、チャノミドリヒメヨコバイ（Ｅｍｐｏａｓｃａ　ｏｎｕｋｉｉ）等のヨコバイ類、ワタアブラムシ（Ａｐｈｉｓ　ｇｏｓｓｙｐｉｉ）、モモアカアブラムシ（Ｍｙｚｕｓ　ｐｅｒｓｉｃａｅ）、ダイコンアブラムシ（Ｂｒｅｖｉｃｏｒｙｎｅ　ｂｒａｓｓｉｃａｅ）、ユキヤナギアブラムシ（Ａｐｈｉｓ　ｓｐｉｒａｅｃｏｌａ）、チューリップヒゲナガアブラムシ（Ｍａｃｒｏｓｉｐｈｕｍ　ｅｕｐｈｏｒｂｉａｅ）、ジャガイモヒゲナガアブラムシ（Ａｕｌａｃｏｒｔｈｕｍ　ｓｏｌａｎｉ）、ムギクビレアブラムシ（Ｒｈｏｐａｌｏｓｉｐｈｕｍ　ｐａｄｉ）、ミカンクロアブラムシ（Ｔｏｘｏｐｔｅｒａ　ｃｉｔｒｉｃｉｄｕｓ）、モモコフキアブラムシ（Ｈｙａｌｏｐｔｅｒｕｓ　ｐｒｕｎｉ）、リンゴワタムシ（Ｅｒｉｏｓｏｍａ　ｌａｎｉｇｅｒｕｍ）等のアブラムシ類、アオクサカメムシ（Ｎｅｚａｒａ　ａｎｔｅｎｎａｔａ）、アカヒゲホソミドリカスミカメ（Ｔｒｉｇｏｎｏｔｙｌｕｓ　ｃａｅｌｅｓｔｉａｌｉｕｍ）、アカスジカメムシ（Ｇｒａｐｈｏｓｏｍａ　ｒｕｂｒｏｌｉｎｅａｔｕｍ）、オオトゲシラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ　ｌｅｗｉｓｉ）、ホソハリカメムシ（Ｒｉｐｔｏｒｔｕｓ　ｃｌａｖｅｔｕｓ）、クモヘリカメムシ（Ｌｅｐｔｏｃｏｒｉｓａ　ｃｈｉｎｅｎｓｉｓ）、トゲシラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ　ｐａｒｖｕｓ）、クサギカメムシ（Ｈａｌｙｏｍｏｒｐｈａ　ｍｉｓｔａ）、ミナミアオカメムシ（Ｎｅｚａｒａ　ｖｉｒｉｄｕｌａ）、ターニシュトプラントバグ（Lｙｇuｓ　ｌｉｎｅｏｌａｒｉｓ）等のカメムシ類、オンシツコナジラミ（Ｔｒｉａｌｅｕｒｏｄｅｓ　ｖａｐｏｒａｒｉｏｒｕｍ）、タバココナジラミ（Ｂｅｍｉｓｉａ　ｔａｂａｃｉ）、ミカンコナジラミ（Ｄｉａｌｅｕｒｏｄｅｓ　ｃｉｔｒｉ）、ミカントゲコナジラミ（Ａｌｅｕｒｏｃａｎｔｈｕｓ　ｓｐｉｎｉｆｅｒｕｓ）等のコナジラミ類、アカマルカイガラムシ（Ａｏｎｉｄｉｅｌｌａ　ａｕｒａｎｔｉｉ）、サンホーゼカイガラムシ（Ｃｏｍｓｔｏｃｋａｓｐｉｓ　ｐｅｒｎｉｃｉｏｓａ）、シトラススノースケール（Ｕｎａｓｐｉｓ　ｃｉｔｒｉ）、ルビーロウムシ（Ｃｅｒｏｐｌａｓｔｅｓ　ｒｕｂｅｎｓ）、イセリヤカイガラムシ（Ｉｃｅｒｙａ　ｐｕｒｃｈａｓｉ）、フジコナカイガラムシ（Ｐｌａｎｏｃｏｃｃｕｓ　ｋｒａｕｎｈｉａｅ）、クワコナカイガラムシ（Ｐｓｅｕｄｏｃｏｃｃｕｓ　ｌｏｎｇｉｓｐｉｎｉｓ）、クワシロカイガラムシ（Ｐｓｅｕｄａｕｌａｃａｓｐｉｓ　ｐｅｎｔａｇｏｎａ）等のカイガラムシ類、グンバイムシ類、トコジラミ（Ｃｉｍｅｘ　ｌｅｃｔｕｌａｒｉｕｓ）等のトコジラミ類、ペアシラ（Ｃａｃｏｐｓｙｌｌａ　ｐｙｒｉｃｏｌａ）等のキジラミ類等。 Hemiptera: small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), planthopper such Sejirounka (Sogatella furcifera), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Inazuma leafhopper (Recilia dorsalis), Chanomidorihime Leafhoppers such as leafhoppers (Epoasca onukii), cotton aphids (Aphis gossypi), peach aphids (Myzus persicae), radish aphids (Brevicorine brassicae), Yukina gear aphids spiraecola), tulip aphid (Macrosiphum euphorbiae), potato aphid (Aulacorthum solani), oat constricted aphid (Rhopalosiphum padi), oranges aphid (Toxoptera citricidus), Momoko butterbur aphid (Hyalopterus pruni), woolly apple aphid (Eriosoma lanigerum), etc. Aphids, Nezara antenata, Trichotylus calestialium, Grafosoma rubrolineatum, Otogeshirahoshika Eysarcoris lewisi, Ripetortus clavetus, Spider Heliter (Leptocorisa chinensis), Togeshirahoshimushi (Eysarcoris parvus), Kusagimemushimushi, Hemi-giemushi Stink bugs such as Lygus lineolaris, Trichouredos vapariorum, Tobacco whiteflies (Bemisia tabaci), Citrus whiteflies (Dialeurodes citrus), Citrus aurora sp. Lami, Aonidiella aurantii, San Jose scale Aphid (Comstockcaspis perniciosa), Citrus snow scale (Unaspis citrus), Ruby loam beetle (Ceroplastes ruba), Iceria cochla Scale insects such as scale insects (Pseudococcus longispinis) and scale insects (Pseudaulacapaspis pentagona), bed bugs such as bedbugs (Cimex lectularius), pair larva ps yricola) psyllid such as such.
　鱗翅目害虫：ニカメイガ（Ｃｈｉｌｏ　ｓｕｐｐｒｅｓｓａｌｉｓ）、サンカメイガ（Ｔｒｙｐｏｒｙｚａ　ｉｎｃｅｒｔｕｌａｓ）、コブノメイガ（Ｃｎａｐｈａｌｏｃｒｏｃｉｓ　ｍｅｄｉｎａｌｉｓ）、ワタノメイガ（Ｎｏｔａｒｃｈａ　ｄｅｒｏｇａｔａ）、ノシメマダラメイガ（Ｐｌｏｄｉａ　ｉｎｔｅｒｐｕｎｃｔｅｌｌａ）、アワノメイガ（Ｏｓｔｒｉｎｉａ　ｆｕｒｎａｃａｌｉｓ）、ハイマダラノメイガ（Ｈｅｌｌｕｌａ　ｕｎｄａｌｉｓ）、シバツトガ（Ｐｅｄｉａｓｉａ　ｔｅｔｅｒｒｅｌｌｕｓ）等のメイガ類、ハスモンヨトウ（Ｓｐｏｄｏｐｔｅｒａ　ｌｉｔｕｒａ）、シロイチモジヨトウ（Ｓｐｏｄｏｐｔｅｒａ　ｅｘｉｇｕａ）、アワヨトウ（Ｐｓｅｕｄａｌｅｔｉａ　ｓｅｐａｒａｔａ）、イネヨトウ（Ｓｅｓａｍｉａ　ｉｎｆｅｒｅｎｓ）、ヨトウガ（Ｍａｍｅｓｔｒａ　　ｂｒａｓｓｉｃａｅ）、タマナヤガ（Ａｇｒｏｔｉｓ　ｉｐｓｉｌｏｎ），タマナギンウワバ（Ｐｌｕｓｉａ　ｎｉｇｒｉｓｉｇｎａ）、イラクサギンウワバ（Ｔｒｉｃｈｏｐｌｕｓｉａ　ｎi）、トリコプルシア属、ヘリオティス属、ヘリコベルパ属等のヤガ類、モンシロチョウ（Ｐｉｅｒｉｓ　ｒａｐａｅ）等のシロチョウ類、アドキソフィエス属、ナシヒメシンクイ（Ｇｒａｐｈｏｌｉｔａ　ｍｏｌｅｓｔａ）、マメシンクイガ（Ｌｅｇｕｍｉｎｉｖｏｒａ　ｇｌｙｃｉｎｉｖｏｒｅｌｌａ），アズキサヤムシガ（Ｍａｔｓｕｍｕｒａｅｓｅｓ　ａｚｕｋｉｖｏｒａ）、リンゴコカクモンハマキ（Ａｄｏｘｏｐｈｙｅｓ　ｏｒａｎａ　ｆａｓｃｉａｔａ）、チャノコカクモンハマキ（Ａｄｏｘｏｐｈｙｅｓ　ｈｏｎｍａｉ．）、チャハマキ（Ｈｏｍｏｎａ　ｍａｇｎａｎｉｍａ）、ミダレカクモンハマキ（Ａｒｃｈｉｐｓ　ｆｕｓｃｏｃｕｐｒｅａｎｕｓ）、コドリンガ（Ｃｙｄｉａ　ｐｏｍｏｎｅｌｌａ）等のハマキガ類、チャノホソガ（Ｃａｌｏｐｔｉｌｉａ　ｔｈｅｉｖｏｒａ）、キンモンホソガ（Ｐｈｙｌｌｏｎｏｒｙｃｔｅｒ　ｒｉｎｇｏｎｅｅｌｌａ）のホソガ類、モモシンクイガ（Ｃａｒｐｏｓｉｎａ　ｎｉｐｏｎｅｎｓｉｓ）等のシンクイガ類、リオネティア属等のハモグリガ類、リマントリア属、ユープロクティス属等のドクガ類、コナガ（Ｐｌｕｔｅｌｌａ　ｘｙｌｏｓｔｅｌｌａ）等のスガ類、ワタアカミムシ（Ｐｅｃｔｉｎｏｐｈｏｒａ　ｇｏｓｓｙｐｉｅｌｌａ）ジャガイモガ（Ｐｈｔｈｏｒｉｍａｅａ　ｏｐｅｒｃｕｌｅｌｌａ）等のキバガ類、アメリカシロヒトリ（Ｈｙｐｈａｎｔｒｉａ　ｃｕｎｅａ）等のヒトリガ類、イガ（Ｔｉｎｅａ　ｔｒａｎｓｌｕｃｅｎｓ）、コイガ（Ｔｉｎｅｏｌａ　ｂｉｓｓｅｌｌｉｅｌｌａ）等のヒロズコガ類、トゥタアブソリュータ（Ｔｕｔａ　ａｂｓｏｌｕｔａ）等。 Lepidoptera: rice stem borer (Chilo suppressalis), Sankameiga (Tryporyza incertulas), leaf roller (Cnaphalocrocis medinalis), Watanomeiga (Notarcha derogata), Indian meal moth (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), high Madara Roh moth (Hellula undalis), Japanese medusa such as Shibatatsuga (Pediasia teterrellus), Lotus moth (Spodoptera litura), Spodoptera exigua, Ayuyoto (Pseudaletia sepata), Itoyoto esamia inferens, moths (Mamestra brassicae), agrotis ipsilon, stag beetle (Plasia nigrisigna), ceramus moths, genus Trichoplusia, White butterflies, genus Adoxofies, Nashihimeshinsukoi (Graphivita molesta), bean shinnigaiga (Leguminivora glycinnivorella), Azusayamasushiga (Matsumuraes azukivivora), apple coconut ax Kakumonhamaki (Adoxophyes honmai.), Chahamaki (Homona magnanima), Mi someone summer fruit moth (Archips fuscocupreanus), Tortricidae such as codling moth (Cydia pomonella), Chanohosoga (Caloptilia theivora), subfraction such apple leaf miner (Phyllonorycter ringoneella), peach fruit moth (Carposina niponensis, etc., mosquito moths such as Rionetia genus, Limantria genus, Euprocutis genus moths, Suga such as Plutella xylostella, cotton potato sipepiella potato (Phthorimaea operculella) Kibaga such as, Tiger Moth such as the United States White Arctiidae (Hyphantria cunea), clothes moth (Tinea translucens), Hirozukoga such as webbing clothes moth (Tineola bisselliella), Tuta absolute diluter (Tuta absoluta) and the like.
　アザミウマ目害虫：ミカンキイロアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ　ｏｃｃｉｄｅｎｔａｌｉｓ）、ミナミキイロアザミウマ（Ｔｈｒｉｐｓ　ｐａｒｍｉ）、チャノキイロアザミウマ（Ｓｃｉｒｔｏｔｈｒｉｐｓ　ｄｏｒｓａｌｉｓ）、ネギアザミウマ（Ｔｈｒｉｐｓ　ｔａｂａｃｉ）、ヒラズハナアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ　ｉｎｔｏｎｓａ）、タバコアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ　ｆｕｓｃａ）、イネアザミウマ（Ｓｔｅｎｃｈａｅｔｏｔｈｒｉｐｓ　ｂｉｆｏｒｍｉｓ）、イネクダアザミウマ（Ｈａｐｌｏｔｈｒｉｐｓ　ａｃｕｌｅａｔｕｓ）等のアザミウマ類等；
　双翅目害虫：タマネギバエ（Ｈｙｌｅｍｙａ　ａｎｔｉｑｕａ）、タネバエ（Ｈｙｌｅｍｙａ　ｐｌａｔｕｒａ）、イネハモグリバエ（Ａｇｒｏｍｙｚａ　ｏｒｙｚａｅ）、イネヒメハモグリバエ（Ｈｙｄｒｅｌｌｉａ　ｇｒｉｓｅｏｌａ）、イネキモグリバエ（Ｃｈｌｏｒｏｐｓ　ｏｒｙｚａｅ）、マメハモグリバエ（Ｌｉｒｉｏｍｙｚａ　ｔｒｉｆｏｌｉｉ）等のハモグリバエ類、ウリミバエ（Ｄａｃｕｓ　ｃｕｃｕｒｂｉｔａｅ）、チチュウカイミバエ（Ｃｅｒａｔｉｔｉｓ　ｃａｐｉｔａｔａ）等；
　甲虫目害虫：ニジュウヤホシテントウ（Ｅｐｉｌａｃｈｎａ　ｖｉｇｉｎｔｉｏｃｔｏｐｕｎｃｔａｔａ）、ウリハムシ（Ａｕｌａｃｏｐｈｏｒａ　ｆｅｍｏｒａｌｉｓ）、キスジノミハムシ（Ｐｈｙｌｌｏｔｒｅｔａ　ｓｔｒｉｏｌａｔａ）、イネドロオイムシ（Ｏｕｌｅｍａ　ｏｒｙｚａｅ）、イネゾウムシ（Ｅｃｈｉｎｏｃｎｅｍｕｓ　ｓｑｕａｍｅｕｓ）、イネミズゾウムシ（Ｌｉｓｓｏｒｈｏｐｔｒｕｓ　ｏｒｙｚｏｐｈｉｌｕｓ）、ワタミゾウムシ（Ａｎｔｈｏｎｏｍｕｓ　ｇｒａｎｄｉｓ）、アズキゾウムシ（Ｃａｌｌｏｓｏｂｒｕｃｈｕｓ　ｃｈｉｎｅｎｓｉｓ）、シバオサゾウムシ（Ｓｐｈｅｎｏｐｈｏｒｕｓ　ｖｅｎａｔｕｓ）、マメコガネ（Ｐｏｐｉｌｌｉａ　ｊａｐｏｎｉｃａ）、ドウガネブイブイ（Ａｎｏｍａｌａ　ｃｕｐｒｅａ）、コーンルートワームの仲間（Ｄｉａｂｒｏｔｉｃａ　ｓｐｐ.）、コロラドハムシ（Ｌｅｐｔｉｎｏｔａｒｓａ　ｄｅｃｅｍｌｉｎｅａｔａ）、コメツキムシの仲間（Ａｇｒｉｏｔｅｓ　ｓｐｐ.）、タバコシバンムシ（Ｌａｓｉｏｄｅｒｍａ　ｓｅｒｒｉｃｏｒｎｅ）等；
　直翅目害虫：ケラ（Ｇｒｙｌｌｏｔａｌｐａ　ａｆｒｉｃａｎａ）、コバネイナゴ（Ｏｘｙａ　ｙｅｚｏｅｎｓｉｓ）、ハネナガイナゴ（Ｏｘｙａ　ｊａｐｏｎｉｃａ）等。 Thysanoptera: western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips parmi), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), tobacco thrips (Frankliniella fusca), rice thrips (Thenchaetotrips biformis), thrips such as Hecklotrips acculeatus, etc .;
Diptera: onion maggot (Hylemya antiqua), seedcorn maggot (Hylemya platura), rice leafminer (Agromyza oryzae), rice Hime leafminer (Hydrellia griseola), Inekimoguribae (Chlorops oryzae), leafminer such as beans leafminer (Liriomyza trifolii), melon fly (Dacus cucurbitae), fruit fly (Ceratitis capitata) and the like;
Coleoptera: beetle, Epilachna vigintioctopunctata (Epilachna vigintioctopunctata), cucurbit leaf beetle (Aulacophora femoralis), Kisujinomihamushi (Phyllotreta striolata), Inedorooimushi (Oulema oryzae), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), boll weevil (Anthonomus grandis), Azuki beetle (Callosobruchus chinensis), Shibahorusu weevil (Sphenophorus venatus), Japanese beetle (Popilia japonica), Douganebububu (Anomala cupre) ..), Corn rootworm fellow (Diabrotica spp), Colorado potato beetle (Leptinotarsa decemlineata), fellow of click beetles (Agriotes spp), cigarette beetle (Lasioderma serricorne) and the like;
Pterodoptera: Kelly (Grylotalpa africana), Oxya yezoensis, Oxya japonica, etc.
　前記有害節足動物の中でも、好ましい例として、ウンカ類、ヨコバイ類、アブラムシ類、カメムシ類、イネミズゾウムシ、イネドロオイムシ、メイガ類、ヤガ類等を挙げることができる。 Among the harmful arthropods, preferred examples include planthoppers, leafhoppers, aphids, stink bugs, rice weevil, rice beetles, moths, and moths.
　本発明の有害節足動物防除組成物は植物病害を防除する目的で用いてもよく、例えばイネのいもち病（Ｍａｇｎａｐｏｒｔｈｅ　ｇｒｉｓｅａ）などを防除することができる。 The harmful arthropod control composition of the present invention may be used for the purpose of controlling plant diseases, and can control, for example, rice blast (Magnaporthe grisea).
　本発明の有害節足動物防除組成物は、畑、水田、乾田、芝生、果樹園等の農耕地又は非農耕地用にて用いることができる。また、本発明の有害節足動物防除組成物は、「植物」等を栽培する農耕地等において、当該農耕地の有害生物を防除するために使用することができる。 The harmful arthropod control composition of the present invention can be used in agricultural fields such as fields, paddy fields, dry fields, lawns, orchards, or non-cultivated areas. In addition, the harmful arthropod control composition of the present invention can be used for controlling pests on the farmland in farmlands where "plants" are cultivated.
　本発明の有害節足動物防除組成物を用いることができる植物としては、例えば次のものが挙げられる。 Examples of plants for which the harmful arthropod control composition of the present invention can be used include the following.
　農作物：トウモロコシ、イネ、コムギ、オオムギ、ライムギ、エンバク、ソルガム、ワタ、ダイズ、ピーナッツ、ソバ、テンサイ、ナタネ、ヒマワリ、サトウキビ、タバコ等。
　野菜；ナス科野菜（ナス、トマト、ピーマン、トウガラシ、ジャガイモ等）、ウリ科野菜（キュウリ、カボチャ、ズッキーニ、スイカ、メロン等）、アブラナ科野菜（ダイコン、カブ、セイヨウワサビ、コールラビ、ハクサイ、キャベツ、カラシナ、ブロッコリー、カリフラワー、アブラナ等）、キク科野菜（ゴボウ、シュンギク、アーティチョーク、レタス等）、ユリ科野菜（ネギ、タマネギ、ニンニク、アスパラガス等）、セリ科野菜（ニンジン、パセリ、セロリ、アメリカボウフウ等）、アカザ科野菜（ホウレンソウ、フダンソウ等）、シソ科野菜（シソ、ミント、バジル等）、イチゴ、サツマイモ、ヤマノイモ、サトイモ等。
　果樹：仁果類（リンゴ、セイヨウナシ、ニホンナシ、カリン、マルメロ等）、核果類（モモ、スモモ、ネクタリン、ウメ、オウトウ、アンズ、プルーン等）、カンキツ類（ウンシュウミカン、オレンジ、レモン、ライム、グレープフルーツ等）、堅果類（クリ、クルミ、ハシバミ、アーモンド、ピスタチオ、カシューナッツ、マカダミアナッツ等）、液果類（ブルーベリー、クランベリー、ブラックベリー、ラズベリー等）、ブドウ、カキ、オリーブ、ビワ、バナナ、コーヒー、ナツメヤシ、ココヤシ、アブラヤシ等。
　果樹以外の樹木：チャ、クワ、花木類（サツキ、ツバキ、アジサイ、サザンカ、シキミ、サクラ、ユリノキ、サルスベリ、キンモクセイ等）、街路樹（トネリコ、カバノキ、ハナミズキ、ユーカリ、イチョウ、ライラック、カエデ、カシ、ポプラ、ハナズオウ、フウ、プラタナス、ケヤキ、クロベ、モミノキ、ツガ、ネズ、マツ、トウヒ、イチイ、ニレ、トチノキ等）、サンゴジュ、イヌマキ、スギ、ヒノキ、クロトン、マサキ、カナメモチ、等。
　芝生：シバ類（ノシバ、コウライシバ等）、バミューダグラス類（ギョウギシバ等）、ベントグラス類（コヌカグサ、ハイコヌカグサ、イトコヌカグサ等）、ブルーグラス類（ナガハグサ、オオスズメノカタビラ等）、フェスク類（オニウシノケグサ、イトウシノケグサ、ハイウシノケグサ等）、ライグラス類（ネズミムギ、ホソムギ等）、カモガヤ、オオアワガエリ等。
その他：花卉類（バラ、カーネーション、キク、トルコギキョウ、カスミソウ、ガーベラ、マリーゴールド、サルビア、ペチュニア、バーベナ、チューリップ、アスター、リンドウ、ユリ、パンジー、シクラメン、ラン、スズラン、ラベンダー、ストック、ハボタン、プリムラ、ポインセチア、グラジオラス、カトレア、デージー、シンビジューム、ベゴニア等）、バイオ燃料植物（ヤトロファ、ベニバナ、アマナズナ類、スイッチグラス、ミスカンサス、クサヨシ、ダンチク、ケナフ、キャッサバ、ヤナギ等）、観葉植物等。 Agricultural crops: corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, etc.
Vegetables: Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelons, melons, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage) , Mustard, broccoli, cauliflower, rape, etc.), asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), liliaceae vegetables (eg, leek, onion, garlic, asparagus), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint, basil etc.), strawberry, sweet potato, yam, taro etc.
Fruit trees: berries (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
Trees other than fruit trees: tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi, sakura, yurinoki, crape myrtle, snapdragon, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak) , Poplar, redwood, fu, sycamore, zelkova, blackfish, Japanese amberjack, moths, pine, pine, spruce, yew, elm, Japanese cypress, etc.), coral jug, dogwood, cedar, cypress, croton, masaki, kanamochi, etc.
Lawn: Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Neurodonidae, etc.), Bentgrass (Oleoptera, Hykonukagusa, Odonoptera, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Oonishi nokegusa, Drosophila, etc.) , Grass, etc.), ryegrass (rat, wheat, etc.), anemonefish, blue whale, etc.
Other: Flowers (Rose, Carnation, Chrysanthemum, Eustoma, Gypsophila, Gerbera, Marigold, Salvia, Petunia, Verbena, Tulip, Aster, Gentian, Lily, Pansy, Cyclamen, Orchid, Lily of the valley, Lavender, Stock, Habutton, Primula, Poinsettia, gladiolus, cattleya, daisy, symbidium, begonia, etc.), biofuel plants (Jatropha, safflower, Amanas, switchgrass, miscanthus, kusayoshi, dangiku, kenaf, cassava, willow, etc.), houseplants, etc.
　前記植物の中でも、好ましい例として、トウモロコシ、コムギ、イネ等を挙げることができる。その中でも、特にイネが好ましい。 Among the plants, corn, wheat, rice and the like can be mentioned as preferable examples. Of these, rice is particularly preferable.
　上記「植物」は、遺伝子組換え技術や交配による育種法により耐性を付与された植物であってもよい。 The “plant” may be a plant to which resistance is imparted by a genetic recombination technique or a breeding method by crossing.
　本発明の有害節足動物防除組成物は、植物又は植物の栽培地に施用することにより、有害節足動物を防除するために用いられる。ここで植物としては、植物の茎葉、植物の花、植物の実、植物の種子等が挙げられる。 The harmful arthropod control composition of the present invention is used to control harmful arthropods by being applied to plants or planting areas. Examples of plants include plant foliage, plant flowers, plant nuts, plant seeds, and the like.
　本発明の有害節足動物の防除方法は、本発明の有害節足動物防除組成物を処理することにより行われるが、具体的には、例えば、茎葉散布などの植物の茎葉への処理、植物の種子への処理、土壌処理、水面施用などの植物の栽培地への処理等が挙げられる。また、本発明の有害節足動物の防除方法には、本シアナミド化合物、本アントラニルアミド化合物および本いもち病防除化合物とを、別々に、又は連続して、植物又は植物の栽培地に施用する態様も含まれる。 The method for controlling harmful arthropods of the present invention is carried out by treating the composition for controlling harmful arthropods of the present invention. Specifically, for example, treatment of plant foliage such as foliage spraying, Treatment of seeds, soil treatment, water surface application, etc. to plant cultivation areas. Further, in the method for controlling harmful arthropods of the present invention, the present cyanamide compound, the present anthranilamido compound and the present blast control compound are applied separately or successively to a plant or a plant cultivation site. Is also included.
　本発明における茎葉散布などの植物の茎葉への処理としては、具体的には、例えば、人力噴霧機、動力噴霧機、ブームスプレーヤ若しくはパンクルスプレーヤを用いて行う地上散布や、航空防除若しくは無人ヘリコプターを用いて行う空中散布等により、栽培されている植物の表面に処理する方法が挙げられる。 Specifically, the treatment of the foliage of plants such as foliage spraying in the present invention includes, for example, ground spraying using a human sprayer, power sprayer, boom sprayer or cruckle sprayer, air control or unmanned helicopter A method of treating the surface of a plant being cultivated, for example, by aerial spraying performed using
　本発明における植物の種子への処理としては、具体的には、例えば、浸漬処理、吹きつけ処理、塗沫処理、フィルムコート処理及びペレットコート処理等が挙げられる。 Specific examples of the treatment of plant seeds in the present invention include immersion treatment, spraying treatment, smearing treatment, film coating treatment, and pellet coating treatment.
　本発明における土壌処理や水面施用などの植物の栽培地への処理としては、具体的には、例えば、植穴処理、株元処理、植溝処理、作条処理、全面処理、側条処理、育苗箱処理、苗床処理、培土混和、床土混和、ペースト肥料混和、水面処理、湛水散布等が挙げられ、好ましくは育苗箱処理が挙げられる。 As the treatment to the planting area of the plant such as soil treatment and water surface application in the present invention, specifically, for example, planting hole treatment, stock source treatment, grooving treatment, rowing treatment, full surface treatment, side stripe treatment, Examples include seedling box treatment, seedbed treatment, soil mixing, bed soil mixing, paste fertilizer mixing, water surface treatment, flooding spraying and the like, and preferably a seedling box treatment.
　本発明の有害節足動物組成物を、植物又は植物の栽培地に処理する場合、その処理量は、処理する植物の種類、防除対象である有害節足動物の種類や発生程度、製剤形態、処理時期、気象条件等によって変化させ得るが、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物との合計量として、当該植物を栽培する場所１０００ｍ2あたり通常０．０５～１００００ｇ、好ましくは０．５～１０００ｇである。 When the harmful arthropod composition of the present invention is treated in a plant or a plant cultivation area, the amount of treatment is the type of plant to be treated, the type and occurrence of harmful arthropods to be controlled, the formulation form, The total amount of the cyanamide compound, the anthranilamide compound, and the rice blast control compound is usually 0.05 to 10,000 g per 1000 m 2 where the plant is cultivated, preferably 0.5 to 1000 g.
　本発明の有害節足動物組成物を、イネの育苗箱に施用する場合、その処理量は、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物との合計量として育苗箱１箱（横 約６０ｃｍ、縦 約３０ｃｍ）あたり通常０．１～３５ｇ、好ましくは０．２～２０ｇであり、移植後のイネを栽培する場所１０００ｍ2あたり育苗箱２０箱を用いる場合、その処理量は、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物との合計量として、移植後のイネを栽培する場所１０００ｍ2あたり通常２～７００ｇ、好ましくは４～４００ｇである。 When the harmful arthropod composition of the present invention is applied to a rice seedling box, the treatment amount is 1 box (horizontal) as the total amount of the cyanamide compound, the anthranilamide compound and the rice blast control compound. (About 60 cm, length about 30 cm) is usually 0.1 to 35 g, preferably 0.2 to 20 g. When using 20 seedling boxes per 1000 m 2 where the rice is to be cultivated after transplanting, the treatment amount is The total amount of the cyanamide compound, the present anthranilamide compound, and the present blast control compound is usually 2 to 700 g, preferably 4 to 400 g, per 1000 m 2 of the place where rice is cultivated after transplanting.
　本発明の有害節足動物組成物を、植物の種子に処理する場合、その処理量は、処理する植物の種類、防除対象である有害節足動物の種類や発生程度、製剤形態、処理時期、気象条件等によって変化させ得るが、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物との合計量として、種子１ｋｇあたり通常０．００１～１００ｇ、好ましくは０．０５～５０ｇである。 When the harmful arthropod composition of the present invention is treated on plant seeds, the amount of treatment is the type of plant to be treated, the type and degree of occurrence of harmful arthropods to be controlled, the formulation form, the treatment time, The total amount of the cyanamide compound, the anthranilamide compound, and the rice blast control compound is usually 0.001 to 100 g, preferably 0.05 to 50 g, per 1 kg of seeds.
　本発明の有害節足動物防除組成物は、乳剤、水和剤、フロアブル剤等は通常水で希釈して散布することにより処理する。この場合、本シアナミド化合物と本アントラニルアミド化合物と本いもち病防除化合物との合計での濃度は、通常０．００００１～１０重量％、好ましくは０．０００１～５重量％の範囲である。粉剤、粒剤等は通常希釈することなくそのまま処理する。 The harmful arthropod control composition of the present invention is treated by spraying emulsions, wettable powders, flowables, etc., usually diluted with water. In this case, the total concentration of the present cyanamide compound, the present anthranilamido compound and the present blast control compound is usually in the range of 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight. Powders, granules, etc. are usually processed as they are without dilution.
　本発明の有害節足動物の防除方法を、イネ又はイネの栽培地にて使用する際は、例えば、イネの播種前、播種時、播種後、移植前、移植時若しくは移植後に施用することができる。施用する時期は、イネの生育状態、病虫害雑草の発生状況、気象条件等によって変わりうるが、通常、イネの播種あるいは移植の日を基準として、播種３０日前から移植２０日後までを挙げることができ、好ましくは、播種時から移植前であり、更に好ましくは、移植３日前から移植前である。 When the method for controlling harmful arthropods according to the present invention is used in rice or rice cultivated land, for example, it can be applied before sowing, during sowing, after sowing, before transplanting, at the time of transplanting or after transplanting of rice. it can. The timing of application may vary depending on the growth state of rice, the occurrence of pests and pests, weather conditions, etc., but it can usually be mentioned from 30 days before sowing to 20 days after transplanting, based on the day of sowing or transplanting rice. Preferably, from the time of sowing to before transplantation, more preferably from 3 days before transplantation to before transplantation.
　以下、本発明を製剤例及び試験例にてさらに詳しく説明するが、本発明は以下の例のみに限定されるものではない。なお、以下の例において、部は特にことわりの無い限り重量部を表す。 Hereinafter, the present invention will be described in more detail with formulation examples and test examples, but the present invention is not limited to the following examples. In the following examples, parts represent parts by weight unless otherwise specified.
　まず、製剤例を示す。 First, formulation examples are shown.
製剤例１
　本シアナミド化合物２部、本アントラニルアミド化合物（１）０．７５部、イソチアニル２部、合成含水酸化珪素１部、リグニンスルホン酸カルシウム２部、ベントナイトを３０部及びカオリンクレー残部の混合物１００部をよく粉砕混合し、水を加えてよく練り合せた後、造粒乾燥することにより粒剤を得る。 Formulation Example 1
2 parts of the present cyanamide compound, 0.75 part of the present anthranilamide compound (1), 2 parts of isotianil, 1 part of synthetic hydrous silicon oxide, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and 100 parts of kaolin clay balance After pulverizing and mixing, adding water and kneading well, granulation and drying are performed to obtain granules.
製剤例２～７
　イソチアニル２部に代えて、［表１］記載のそれぞれの化合物及び使用量を適用した以外は製剤例１と同様の操作を行い、それぞれの粒剤を得る。 Formulation Examples 2-7
Instead of 2 parts of isotianil, the same operation as in Formulation Example 1 is carried out except that the respective compounds and amounts used in [Table 1] are applied to obtain respective granules.
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
製剤例８
　本シアナミド化合物２部、本アントラニルアミド化合物（２）０．７５部、イソチアニル２部、合成含水酸化珪素１部、リグニンスルホン酸カルシウム２部、ベントナイトを３０部及びカオリンクレー残部の混合物１００部をよく粉砕混合し、水を加えてよく練り合せた後、造粒乾燥することにより粒剤を得る。 Formulation Example 8
2 parts of the cyanamide compound, 0.75 part of the anthranilamide compound (2), 2 parts of isothianyl, 1 part of synthetic hydrous silicon oxide, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and 100 parts of kaolin clay balance After pulverizing and mixing, adding water and kneading well, granulation and drying are performed to obtain granules.
製剤例９～１４
　イソチアニル２部に代えて、［表２］記載のそれぞれの化合物及び使用量を適用した以外は製剤例８と同様の操作を行い、それぞれの粒剤を得る。 Formulation Examples 9-14
Instead of 2 parts of isotianil, the same operation as in Formulation Example 8 is carried out except that the respective compounds and amounts used in [Table 2] are applied to obtain respective granules.
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
製剤例１５
　本シアナミド化合物２部、本アントラニルアミド化合物（１）１０部及びイソチアニル４部を、ラウリル硫酸ナトリウム４部、リグニンスルホン酸カルシウム２部、合成含水酸化珪素微粉末２０部及び珪藻土残部を混合した中に加え、よく攪拌混合して水和剤１００部を得る。 Formulation Example 15
While mixing 2 parts of the present cyanamide compound, 10 parts of the present anthranilamide compound (1) and 4 parts of isothianyl, 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic hydrous silicon oxide fine powder and the remainder of diatomaceous earth were mixed. In addition, well mixed with stirring to obtain 100 parts of wettable powder.
製剤例１６～２０
　イソチアニル４部に代えて、［表３］記載のそれぞれの化合物及び使用量を適用した以外は製剤例１５と同様の操作を行い、それぞれの水和剤１００部を得る。 Formulation Examples 16-20
It replaces with 4 parts of isotianil, and except having applied each compound and usage-amount of [Table 3], operation similar to the formulation example 15 is performed, and 100 parts of each wettable powder is obtained.
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
製剤例２１
　本シアナミド化合物２部、本アントラニルアミド化合物（２）１０部及びイソチアニル４部を、ラウリル硫酸ナトリウム４部、リグニンスルホン酸カルシウム２部、合成含水酸化珪素微粉末２０部及び珪藻土残部を混合した中に加え、よく攪拌混合して水和剤１００部を得る。 Formulation Example 21
While mixing 2 parts of the present cyanamide compound, 10 parts of the present anthranilamide compound (2) and 4 parts of isotianil, 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic hydrous silicon oxide fine powder and the remainder of diatomaceous earth were mixed. In addition, well mixed with stirring to obtain 100 parts of wettable powder.
製剤例２２～２６
　イソチアニル４部に代えて、［表４］記載のそれぞれの化合物及び使用量を適用した以外は製剤例２１と同様の操作を行い、それぞれの水和剤１００部を得る。 Formulation Examples 22 to 26
It replaces with 4 parts of isotianil, and except having applied each compound and usage-amount of the [Table 4] description, operation similar to the formulation example 21 is performed, and 100 parts of each wettable powder is obtained.
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
製剤例２７
　本シアナミド化合物３部、本アントラニルアミド化合物（１）１．５部、イソチアニル０．６部、カオリンクレー８４．９部及びタルク１０部をよく粉砕混合することにより粉剤を得る。 Formulation Example 27
A powder is obtained by thoroughly pulverizing and mixing 3 parts of the present cyanamide compound, 1.5 parts of the present anthranilamide compound (1), 0.6 part of isotianil, 84.9 parts of kaolin clay and 10 parts of talc.
製剤例２８～３２
　イソチアニル０．６部に代えて、［表５］記載のそれぞれの化合物及び使用量を適用した以外は製剤例２７と同様の操作を行い、それぞれの粉剤を得る。 Formulation Examples 28-32
The powders are obtained in the same manner as in Formulation Example 27 except that the respective compounds and amounts used in [Table 5] are used instead of 0.6 parts of isotianil.
Figure JPOXMLDOC01-appb-T000011
Figure JPOXMLDOC01-appb-T000011
製剤例３３
　本シアナミド化合物３部、本アントラニルアミド化合物（２）１．５部、イソチアニル０．６部、カオリンクレー８４．９部及びタルク１０部をよく粉砕混合することにより粉剤を得る。 Formulation Example 33
A powder is obtained by thoroughly pulverizing and mixing 3 parts of the present cyanamide compound, 1.5 parts of the anthranilamide compound (2), 0.6 part of isothianyl, 84.9 parts of kaolin clay and 10 parts of talc.
製剤例３４～３８
　イソチアニル０．６部に代えて、［表６］記載のそれぞれの化合物及び使用量を適用した以外は製剤例３３と同様の操作を行い、それぞれの粉剤を得る。 Formulation Examples 34 to 38
The powders are obtained in the same manner as in Formulation Example 33, except that the respective compounds and amounts used in [Table 6] are used instead of 0.6 parts of isotianil.
Figure JPOXMLDOC01-appb-T000012
Figure JPOXMLDOC01-appb-T000012
製剤例３９
　本シアナミド化合物１０部、本アントラニルアミド化合物（１）２部、イソチアニル４部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩５０部を含むホワイトカーボン３０部及び水残部を混合した混合物１００部を湿式粉砕法で微粉砕することにより、フロアブル剤を得る。 Formulation Example 39
100 parts of a mixture obtained by mixing 10 parts of the cyanamide compound, 2 parts of the anthranilamide compound (1), 4 parts of isotianil, 50 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of the water by a wet grinding method A flowable agent is obtained by pulverizing.
製剤例４０～４４
　イソチアニル４部に代えて、［表７］記載のそれぞれの化合物及び使用量を適用した以外は製剤例３９と同様の操作を行い、それぞれのフロアブル剤を得る。 Formulation Examples 40-44
Each flowable agent is obtained in the same manner as in Formulation Example 39 except that the respective compounds and amounts used in [Table 7] are applied instead of 4 parts of isotianil.
Figure JPOXMLDOC01-appb-T000013
Figure JPOXMLDOC01-appb-T000013
製剤例４５
　本シアナミド化合物１０部、本アントラニルアミド化合物（２）２部、イソチアニル４部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩５０部を含むホワイトカーボン３０部及び水残部を混合した混合物１００部を湿式粉砕法で微粉砕することにより、フロアブル剤を得る。 Formulation Example 45
100 parts of a mixture prepared by mixing 10 parts of the cyanamide compound, 2 parts of the anthranilamide compound (2), 4 parts of isotianil, 50 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of the water by a wet pulverization method A flowable agent is obtained by pulverizing.
製剤例４６～５０
　イソチアニル４部に代えて、［表８］記載のそれぞれの化合物及び使用量を適用した以外は製剤例４５と同様の操作を行い、それぞれのフロアブル剤を得る。 Formulation Examples 46-50
Instead of 4 parts of isotianil, the same operation as in Formulation Example 45 is carried out except that the respective compounds and amounts used in [Table 8] are applied to obtain respective flowable agents.
Figure JPOXMLDOC01-appb-T000014
Figure JPOXMLDOC01-appb-T000014
　次に、本発明の効果を試験例にて示す。 Next, the effect of the present invention will be shown by test examples.
試験例１
　本シアナミド化合物、本アントラニルアミド化合物（１）、本アントラニルアミド化合物（２）、イソチアニル、プロベナゾール、チアジニル、トリシクラゾール、オリサストロビン及びピロキロンそれぞれ１０ｍｇを、ソルゲンＴＷ－２０（第一工業製薬製）を５％（ｗ／ｖ）含むアセトン（和光純薬工業製）０．２ｍｌにそれぞれ溶解した後、所定濃度になるように水で希釈した。
　本シアナミド化合物の水希釈液と、本アントラニルアミド化合物（１）又は本アントラニルアミド化合物（２）の水希釈液と、イソチアニル、プロベナゾール、チアジニル、トリシクラゾール、オリサストロビン又はピロキロンの水希釈液とを混合し、試験用薬液を調製した。
　２．５葉期のペーパーポット植えイネ（Ｏｒｙｚａ ｓａｔｉｖａ、品種：ほしのゆめ）稚苗１株の株元土壌に前記試験用の薬液０．６ｍｌを施用した。２時間静置した後、１／１００００ａワグネルポットの湛水した土壌に移植し、温室（２３℃）に置いた。処理１日後、イネの株元をプラスチック製カップで覆い、トビイロウンカの３齢幼虫を１０頭ずつ放飼した。これを処理区と呼ぶ。
　一方、前記試験用の薬液で処理しなかったイネ稚苗を、処理区と同様に、移植し、温室に置き、幼虫を放飼した。これを無処理区と呼ぶ。
　放飼６日後に供試した幼虫の生死を観察した。その観察結果から、式１）によって死虫率、式２）によって補正死虫率を算出した。なお、試験は２反復で行った。その平均値を表９及び表１０に示す。 Test example 1
10 mg each of the cyanamide compound, the anthranilamide compound (1), the anthranilamide compound (2), isothianyl, probenazole, thiazinyl, tricyclazole, orisatrobin and pyroxylone, and 5% of Sorgen TW-20 (Daiichi Kogyo Seiyaku) Each was dissolved in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing w / v) and then diluted with water to a predetermined concentration.
A water dilution of the cyanamide compound, a water dilution of the anthranilamide compound (1) or the anthranilamide compound (2), and a water dilution of isothianyl, probenazole, thiazinyl, tricyclazole, orisatrobin or pyroxylone, A test chemical solution was prepared.
2.5 ml of paper pot planted rice (Oryza sativa, cultivar: Hoshino Yume) 1 ml of seedling was applied with 0.6 ml of the chemical solution for the test. After leaving still for 2 hours, it transplanted to the flooded soil of a 1 / 10000a Wagner pot, and set | placed in the greenhouse (23 degreeC). One day after the treatment, the rice stock was covered with a plastic cup, and 10 third instar larvae of the brown planthopper were released. This is called a processing zone.
On the other hand, rice seedlings that were not treated with the test chemical were transplanted, placed in a greenhouse, and larvae were released in the same manner as in the treatment group. This is called an untreated section.
The life and death of the larvae tested 6 days after release were observed. From the observation results, the mortality rate was calculated by Equation 1) and the corrected mortality rate was calculated by Equation 2). The test was repeated twice. The average values are shown in Tables 9 and 10.
　式１）；死虫率（％）＝（供試虫数－生存虫数）／供試虫数×１００ Formula 1): Death rate (%) = (number of test insects−number of surviving insects) / number of test insects × 100
　式２）；補正死虫率（％）＝｛（処理区死虫率－無処理区死虫率）／（１００－無処理区死虫率）｝×１００  Formula 2): Corrected mortality rate (%) = {(treated area mortality rate−untreated area mortality ratio) / (100−untreated area mortality ratio)} × 100
Figure JPOXMLDOC01-appb-T000015
Figure JPOXMLDOC01-appb-T000015
Figure JPOXMLDOC01-appb-T000016
Figure JPOXMLDOC01-appb-T000016

Claims (5)

  1. 　式（１）
    Figure JPOXMLDOC01-appb-I000001
    で示されるシアナミド化合物と、式（２）
    Figure JPOXMLDOC01-appb-I000002
    〔式中、Ｒ１及びＲ２の組合せは、Ｒ１がメチル基かつＲ２が塩素原子である組合せ、又は、Ｒ１がメチル基かつＲ２がシアノ基である組合せを表す。〕
    で示されるアントラニルアミド化合物と、群（Ａ）より選ばれる１種以上のいもち病防除化合物とを含有する有害節足動物防除組成物。
    群（Ａ）：イソチアニル、プロベナゾール、チアジニル、トリシクラゾール、オリサストロビン及びピロキロンからなる群。     Formula (1)
    Figure JPOXMLDOC01-appb-I000001
    A cyanamide compound represented by formula (2):
    Figure JPOXMLDOC01-appb-I000002
    [Wherein, the combination of R 1 and R 2 represents a combination in which R 1 is a methyl group and R 2 is a chlorine atom, or a combination in which R 1 is a methyl group and R 2 is a cyano group. ]
    A harmful arthropod control composition comprising an anthranilamido compound represented by the formula (1) and one or more blast control compounds selected from the group (A).
    Group (A): A group consisting of isothianyl, probenazole, thiazinyl, tricyclazole, orisatrobin and pyroxylone.
  2. 　シアナミド化合物と、アントラニルアミド化合物との重量比が、１００：１～１：５０である請求項１記載の有害節足動物防除組成物。 2. The harmful arthropod control composition according to claim 1, wherein the weight ratio of the cyanamide compound to the anthranilamide compound is 100: 1 to 1:50.
  3. 　シアナミド化合物と、いもち病防除化合物との重量比が、５０：１～１：１００である請求項２記載の有害節足動物防除組成物。 3. The harmful arthropod control composition according to claim 2, wherein the weight ratio of the cyanamide compound and the blast control compound is 50: 1 to 1: 100.
  4. 　請求項１～３いずれか一項記載の有害節足動物防除組成物の有効量を、植物又は植物の栽培地に施用する工程を含む有害節足動物の防除方法。 A method for controlling harmful arthropods, comprising a step of applying an effective amount of the harmful arthropod control composition according to any one of claims 1 to 3 to a plant or a plant cultivation site.
  5. 　植物又は植物の栽培地が、イネ又はイネの栽培地である請求項４記載の有害節足動物の防除方法。 5. The method for controlling harmful arthropods according to claim 4, wherein the plant or the plant cultivation area is rice or rice cultivation.
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WO2013191114A1 (en) * 2012-06-21 2013-12-27 住友化学株式会社 Arthropod pest control composition and arthropod pest control method

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EP2661176A1 (en) * 2010-12-27 2013-11-13 Sumitomo Chemical Company Limited Arthropod pest control composition and method for controlling arthropod pests
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