TWI524847B - Harmful organism-controlling composition and control method of harmful organisms - Google Patents

Harmful organism-controlling composition and control method of harmful organisms Download PDF

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TWI524847B
TWI524847B TW101111812A TW101111812A TWI524847B TW I524847 B TWI524847 B TW I524847B TW 101111812 A TW101111812 A TW 101111812A TW 101111812 A TW101111812 A TW 101111812A TW I524847 B TWI524847 B TW I524847B
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harmful
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harmful arthropod
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TW201244630A (en
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坂本惠美子
坂元法久
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住友化學股份有限公司
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/26Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-nitrogen bonds, e.g. azides, diazo-amino compounds, diazonium compounds, hydrazine derivatives
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

有害生物防治組成物及有害生物之防治方法 Pest control composition and pest control method

本發明係有關有害節肢動物防治組成物及有害節肢動物之防治方法。 The invention relates to a method for controlling harmful arthropod control components and harmful arthropods.

有害節肢動物防治組成物之有效成分已知有多種化合物(請參照例如The Pesticide Manual-15th edition(BCPC刊):ISBN 978-1-901396-18-8)。有害節肢動物防治組成物之有效成分係已知有:可芬諾(chromafenozide) 滅芬諾(methoxyfenozide) 及得芬諾(tebufenozide) An active ingredient of noxious arthropods controlling composition of a variety of compounds are known (see e.g. The Pesticide Manual-15 th edition ( BCPC published): ISBN 978-1-901396-18-8). The active ingredients of harmful arthropod control compositions are known to be: chromafenozide Methoxyfenozide And tefeno (tebufenozide)

本發明為以下之[1]至[6]。 The present invention is the following [1] to [6].

[1]一種有害節肢動物防治組成物,其含有:式(1)表示之氰胺化合物 1種以上之選自群(A)之昆蟲成長控制化合物、及1種以上之選自群(B)之紋枯病防治化合物。 [1] A harmful arthropod control composition comprising: a cyanamide compound represented by the formula (1) One or more insect growth control compounds selected from the group (A), and one or more kinds of sheath blight control compounds selected from the group (B).

群(A):由滅芬諾、可芬諾及得芬諾所成之群組。 Group (A): A group consisting of fentanyl, cofino and defenofol.

群(B):由福多寧(flutolanil)、賓克隆(pencycuron)、N-[2-(1,3-二甲基丁基)苯基]-5-氟-1,3-二甲基-1H-吡唑-4-甲醯胺、福拉比(furametpyr)及維利黴素(Validamycin A)所成之群組。 Group (B): by flutolanil, pencycuron, N-[2-(1,3-dimethylbutyl)phenyl]-5-fluoro-1,3-dimethyl a group of -1H-pyrazole-4-carbamamine, furametpyr and validinomycin (Validamycin A).

[2]如[1]記載之有害節肢動物防治組成物,其中,氰胺化合物與昆蟲成長控制化合物之重量比為50:1至1:50。 [2] The harmful arthropod control composition according to [1], wherein the weight ratio of the cyanamide compound to the insect growth controlling compound is from 50:1 to 1:50.

[3]如[1]或[2]記載之有害節肢動物防治組成物,其中,氰胺化合物與紋枯病防治化合物之重量比為50:1至1:100。 [3] The harmful arthropod control composition according to [1] or [2], wherein the weight ratio of the cyanamide compound to the sheath blight control compound is from 50:1 to 1:100.

[4]如[1]至[3]中任一項記載之有害節肢動物防治組成物,其中,紋枯病防治化合物為福多寧、賓克隆或N-[2-(1,3-二甲基丁基)苯基]-5-氟-1,3-二甲基-1H-吡唑-4-甲醯胺。 [4] The harmful arthropod control composition according to any one of [1] to [3] wherein the sheath blight control compound is fondolin, bin clone or N-[2-(1,3-di) Methylbutyl)phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide.

[5]一種有害節肢動物之防治方法,其包含下述步驟:將有 效量之如[1]至[4]中任一項記載之有害節肢動物防治組成物施用於植物或植物之栽培地的步驟。 [5] A method for controlling harmful arthropods, comprising the steps of: having The step of applying the harmful arthropod control composition according to any one of [1] to [4] to a cultivation site of a plant or a plant.

[6]如[5]記載之有害節肢動物之防治方法,其中,施用於植物或植物之栽培地的步驟,係施用於稻或稻之栽培地的步驟。 [6] The method for controlling a harmful arthropod according to [5], wherein the step of applying to a cultivation site of a plant or a plant is a step of applying to a cultivation site of rice or rice.

本發明之有害節肢動物防治組成物為含有下述式(1)表示之氰胺化合物(以下,亦稱為本氰胺化合物)、1種以上之選自下述群(A)之昆蟲成長控制化合物(以下,亦稱為本昆蟲成長控制化合物)及1種以上之選自下述群(B)之紋枯病防治化合物(以下,亦稱為本紋枯病防治化合物)者。 The harmful arthropod control composition of the present invention is an insect growth control system comprising a cyanamide compound represented by the following formula (1) (hereinafter also referred to as a cyanamide compound) and one or more selected from the group (A) below. The compound (hereinafter also referred to as the present insect growth controlling compound) and one or more kinds of sheath blight control compounds (hereinafter also referred to as the present sheath blight control compound) selected from the group (B) below.

群(A):由滅芬諾、可芬諾及得芬諾所成之群組。 Group (A): A group consisting of fentanyl, cofino and defenofol.

群(B):由福多寧、賓克隆、N-[2-(1,3-二甲基丁基)苯基]-5-氟-1,3-二甲基-1H-吡唑-4-甲醯胺、福拉比及維利黴素所成之群組。 Group (B): by fotonine, binrel, N-[2-(1,3-dimethylbutyl)phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole- A group of 4-carbendazim, foraby, and vesicomycin.

本氰胺化合物為公知之化合物,可依據例如國際公開第2007/095229號說明書中記載之方法製造。 The present cyanamide compound is a known compound and can be produced, for example, according to the method described in the specification of International Publication No. 2007/095229.

滅芬諾、可芬諾、得芬諾、福多寧、賓克隆、福拉比及維利黴素均為公知之化合物,記載於例如「The Pesticide Manual-15th edition(BCPC刊):ISBN 978-1-901396-18-8」之第764頁、211頁、1074頁、559頁、871頁、580頁及1187頁等。該等化合物可由市售之製劑獲得,或以公知之方法製造而獲得。 Diphenoxylate off, diphenoxylate can give diphenoxylate, Fu Duoning, Binke Long, furametpyr and Willy of rapamycin are known compounds, described for example in "The Pesticide th edition (BCPC published) 15 Manual-: ISBN 978-1-901396-18-8" pages 764, 211, 1074, 559, 871, 580, and 1187. Such compounds can be obtained from commercially available formulations or can be obtained by known methods.

N-[2-(1,3-二甲基丁基)苯基]-5-氟-1,3-二甲基-1H-吡唑-4-甲醯胺(以下,亦稱為本活性化合物(I))為公知之化合物,可依據例如國際公開第2003/010149號說明書中記載之方法製造。 N-[2-(1,3-dimethylbutyl)phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (hereinafter also referred to as the active activity) The compound (I)) is a known compound and can be produced, for example, according to the method described in the specification of International Publication No. 2003/010149.

上述紋枯病防治化合物較佳為福多寧、賓克隆及本活性化合物(I)。 The above-mentioned sheath blight control compound is preferably fudanine, a clone and the active compound (I).

於本發明之有害節肢動物防治組成物中,本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合物之含有比率並無特別限制,相對於本氰胺化合物100重量份,本昆蟲成長控制化合物通常為0.2至50000重量份,較佳為2至5000重量份,更佳為5至2000重量份,本紋枯病防治化合物通常為0.2至100000重量份,較佳為2至10000重量份,更佳為5至5000重量份。 In the harmful arthropod control composition of the present invention, the content ratio of the present cyanamide compound, the insect growth control compound, and the sheath blight control compound is not particularly limited, and the insect grows relative to 100 parts by weight of the cyanamide compound. The control compound is usually from 0.2 to 50,000 parts by weight, preferably from 2 to 5,000 parts by weight, more preferably from 5 to 2,000 parts by weight, and the stalk control compound is usually from 0.2 to 100,000 parts by weight, preferably from 2 to 10,000 parts by weight. More preferably, it is 5 to 5000 parts by weight.

於本發明之有害節肢動物防治組成物中,本氰胺化合物與本昆蟲成長控制化合物之重量比(本氰胺化合物:本昆蟲成長控制化合物)通常為500:1至1:500,較佳為50:1至1:50,更佳為20:1至1:20。 In the harmful arthropod control composition of the present invention, the weight ratio of the cyanamide compound to the insect growth controlling compound (the present cyanamide compound: the insect growth controlling compound) is usually from 500:1 to 1:500, preferably 50:1 to 1:50, more preferably 20:1 to 1:20.

於本發明之有害節肢動物防治組成物中,本氰胺化合物與本紋枯病防治化合物之重量比(本氰胺化合物:本紋枯病防治化合物)通常為500:1至1:1000,較佳為50:1至1:100,更佳為20:1至1:50。 In the harmful arthropod control composition of the present invention, the weight ratio of the cyanamide compound to the sheath blight control compound (the present cyanamide compound: the sheath blight control compound) is usually 500:1 to 1:1000, The ratio is 50:1 to 1:100, more preferably 20:1 to 1:50.

於本發明之有害節肢動物防治組成物中,本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合物可為單純混合者,惟通常係使用將本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合物與惰性載體混合,並根據需要添加界面活性劑或其他之製劑用補助劑,而予以製劑化成油劑、乳劑、水懸劑(flowable)、水和劑、顆粒水和劑、粉劑、粒劑等者。 In the harmful arthropod control composition of the present invention, the present cyanamide compound, the insect growth control compound, and the sheath blight control compound may be a simple mixture, but the present cyanamide compound and the insect growth control compound are usually used. And the sheath blight prevention compound is mixed with an inert carrier, and if necessary, a surfactant or other formulation auxiliary agent is added, and the formulation is converted into an oil agent, an emulsion, a flowable, a water and a granule, and a granule water and Agents, powders, granules, etc.

經製劑化之有害節肢動物防治組成物可直接使用或再添加其他惰性成分(水、砂、植物油等)使用。 The formulated harmful arthropod control composition can be used directly or in addition to other inert ingredients (water, sand, vegetable oil, etc.).

於本發明之有害節肢動物防治組成物中,本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合物之合計量通常為0.01至99重量%,較佳為0.1至90重量%,更佳為0.5至70重量%。 In the harmful arthropod control composition of the present invention, the total amount of the cyanamide compound, the insect growth control compound and the present sheath blight control compound is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight, more Preferably it is from 0.5 to 70% by weight.

惰性載體可列舉固體載體、液體載體。 The inert carrier may, for example, be a solid carrier or a liquid carrier.

固體載體可列舉例如由高嶺土黏土(kaolin clay)、綠坡縷石黏土(attapulgite clay)、膨潤土(bentonite)、蒙脫石、酸性白土、葉蠟石、滑石、矽藻土、方解石等礦物、玉米穗軸粉、核桃殼粉等天然有機物、尿素等合成有機物、碳酸鈣、硫酸銨等鹽類、合成之含水之氧化矽等合成無機物等所構成之微粉末或粒狀物等。 Examples of the solid carrier include minerals such as kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, and corn. A fine powder or a granular material composed of a natural organic substance such as cob powder, walnut shell powder, a synthetic organic substance such as urea, a salt such as calcium carbonate or ammonium sulfate, a synthetic inorganic substance such as a synthetic cerium oxide or the like.

液體載體可列舉例如二甲苯、烷基苯、甲基萘等芳族烴類、2-丙醇、乙二醇、丙二醇、乙二醇一乙醚等醇類、丙酮、環己酮、異佛爾酮等酮類、大豆油、棉籽油等植物油、石油系脂肪族烴類、酯類、二甲基亞碸、乙腈及水等。 Examples of the liquid carrier include aromatic hydrocarbons such as xylene, alkylbenzene, and methylnaphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol, and ethylene glycol monoethyl ether, acetone, cyclohexanone, and isophor. Vegetable oils such as ketones such as ketones, soybean oil, cottonseed oil, petroleum-based aliphatic hydrocarbons, esters, dimethyl hydrazine, acetonitrile, water, and the like.

界面活性劑可列舉例如烷基硫酸酯鹽、烷基芳基磺酸鹽、二烷基磺基琥珀酸鹽、聚氧伸乙基烷基芳基醚磷酸酯鹽、木質磺酸鹽、萘磺酸鹽甲醛縮聚物等陰離子界面活性劑,及聚氧伸乙基烷基芳基醚、聚氧伸乙基烷基聚氧伸丙基嵌段共聚物、山梨醇酐脂肪酸酯等非離子界面活性劑,及烷基三甲基銨鹽等陽離子界面活性劑。 The surfactant may, for example, be an alkyl sulfate salt, an alkyl aryl sulfonate, a dialkyl sulfosuccinate, a polyoxyethylidene aryl ether phosphate, a lignosulfonate or a naphthalene sulfonate. Anionic surfactant such as acid ester polycondensate, and nonionic interface such as polyoxyalkylene aryl ether, polyoxyethylene ethyl polyoxyalkylene block copolymer, sorbitan fatty acid ester An active agent, and a cationic surfactant such as an alkyltrimethylammonium salt.

其他之製劑用補助劑可列舉例如聚乙烯醇、聚乙烯吡咯啶酮等水溶性高分子化合物、阿拉伯樹膠、褐藻酸及其鹽、CMC(羧甲基纖維素)、黃原膠(xanthan gum)等多糖類、矽酸鎂鋁、氧化鋁溶膠等無機物、防腐劑、著色劑及PAP(酸性磷酸異丙酯)、BHT(二丁基羥基甲苯)等安定化劑。 Other auxiliary agents for preparation include water-soluble polymer compounds such as polyvinyl alcohol and polyvinylpyrrolidone, gum arabic, alginic acid and salts thereof, CMC (carboxymethyl cellulose), and xanthan gum. An antioxidant such as an inorganic substance such as a polysaccharide, magnesium aluminum silicate or an alumina sol, a preservative, a coloring agent, and a stabilizer such as PAP (isopropyl acid phosphate) or BHT (dibutylhydroxytoluene).

本發明之有害節肢動物防治組成物可用於保護植物,使其不受會對植物進行攝食、吸汁等加害之有害節肢動物所加害。 The harmful arthropod control composition of the present invention can be used to protect plants from harmful arthropods that ingest plants, absorb juice, and the like.

關於本發明之有害節肢動物防治組成物具有防治效力之有害節肢動物,可列舉例如下述者。 The harmful arthropod having the control effect of the harmful arthropod control composition of the present invention may, for example, be as follows.

半翅目害蟲:斑飛蝨(Laodelphax striatellus)、褐飛蝨(Nilaparvata lugens)、白背飛蝨(Sogatella furcifera)等飛蝨類、偽黑尾葉蟬(Nephotettix cincticeps)、台灣黑尾葉蟬(Nephotettix virescens)、電光葉蟬(Recilia dorsalis)、茶小綠葉蟬(Empoasca onukii)等葉蟬類、棉蚜(Aphis gossypii)、桃蚜(Myzus persicae)、菜蚜(Brevicoryne brassicae)、捲葉蚜(Aphis spiraecola)、馬鈴薯長管蚜(Macrosiphum euphorbiae)、 馬鈴薯蚜(Aulacorthum solani)、稻麥蚜(Rhopalosiphum padi)、大桔蚜(Toxoptera citricidus)、桃粉蚜(Hyalopterus pruni)、蘋果綿蚜(Eriosoma lanigerum)等蚜蟲類、東方稻綠椿(Nezara antennata)、赤須盲蝽(Trigonotylus caelestialium)、黑條紅椿象(Graphosoma rubrolineatum)、二星蝽(Eysarcoris lewisi)、點蜂緣椿象(Riptortus clavetus)、中華稻緣蝽(Leptocorisa chinensis)、白星蝽(Eysarcoris parvus)、茶翅椿象(Halyomorpha mista)、稻綠椿(Nezara viridula)、美國牧草盲蝽(Lygus Lineolaris)等椿象類、温室粉蝨(Trialeurodes vaporariorum)、煙草粉蝨(Bemisia tabaci)、柑橘裸粉蝨(Dialeurodes citri)、柑橘刺粉蝨(Aleurocanthus spiniferus)等粉蝨類、赤圓介殼蟲(Aonidiella aurantii)、梨圓介殼蟲(Comstockaspis perniciosa)、桔矢尖介殼蟲(Unaspis citri)、紅蠟介殼蟲(Ceroplastes rubens)、吹綿介殼蟲(Icerya purchasi)、臀紋粉介殼蟲(Planococcus kraunhiae)、長尾粉介殼蟲(Pseudococcus longispinis)、桑介殼蟲(Pseudaulacaspis pentagona)等介殼蟲類、軍配蟲類(Tingidae)、溫帶臭蟲(Cimex lectularius)等臭蟲類、梨木蝨(Cacopsylla pyricola)等木蝨類等。 Hemiptera pests: Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, Nephotettix cincticeps, Nephotettix virescens ), Recilia dorsalis, Empoasca onukii, Aphis gossypii, Myzus persicae, Brevicoryne brassicae, Aphis spiraecola ), potato long tube (Macrosiphum euphorbiae), Aulacorthum solani, Rhopalosiphum padi, Toxoptera citricidus, Hyalopterus pruni, Eriosoma lanigerum, etc., Nezara antennata , Trigonotylus caelestialium, Graphosoma rubrolineatum, Eysarcoris lewisi, Riptortus clavetus, Leptocorisa chinensis, Eysarcoris parvus, Halomorpha mista, Nezara viridula, Lygus Lineolaris, Trialeurodes vaporariorum, Bemisia tabaci, Dialeurodes Citri), Aleurocanthus spiniferus, Aonidiella aurantii, Comstockaspis perniciosa, Unaspis citri, Ceroplastes Rubens), Icerya purchasi, Planococcus kraunhiae, Pseudococcus longispin Is), such as scale insects such as Pseudaulacaspis pentagona, Tingidae, Cimex lectularius, and cockroaches such as Cacopsylla pyricola.

鱗翅目害蟲:二化螟(Chilo suppressalis)、三化螟(Tryporyza incertulas)、瘤野螟(Cnaphalocrocis medinalis)、棉捲葉野螟(Notarcha derogata)、印度谷螟 (Plodia interpunctella)、亞洲玉米螟(Ostrinia furnacalis)、菜心野螟(Hellula undalis)、大草皮卷螟(Pediasia teterrellus)等螟蛾類、斜紋夜蛾(Spodoptera litura)、甜菜夜蛾(Spodoptera exigua)、黏夜蛾(Pseudaletia separate)、稻蛀莖夜蛾(Sesamia inferens)、甘藍夜蛾(Mamestra brassicae)、球菜夜蛾(Agrotis ipsilon)、黑點銀紋夜蛾(Plusia nigrisigna)、粉斑夜蛾(Trichoplusia ni)、金翅夜蛾屬(Trichoplusia)、實夜蛾屬(Heliothis)、鈴夜蛾屬(Helicoverpa)等夜蛾類、紋白蝶(Pieris rapae)等白蝶類、捲葉蛾(Adoxophyes)屬、桃折心蟲(Grapholita molesta)、大豆食心蟲(Leguminivora glycinivorella)、豆小捲葉蛾(Matsumuraeses azukivora)、棉褐帶卷葉蛾(Adoxophyes orana fasciata)、茶小捲葉蛾(Adoxophyes honmai)、茶捲葉蛾(Homona magnanima)、杏黃捲蛾(Archips fuscocupreanus)、蘋果蠹蛾(Cydia pomonella)等捲蛾類、茶細蛾(Caloptilia theivora)、金紋細蛾(Phyllonorycter ringoniella)等細蛾類、桃蛀果蛾(Carposina niponensis)等蛀果蛾類、潛蛾屬(Lyonetia)之葉潛蛾類、毒蛾屬(Lymantria)、黃毒蛾屬(Euproctis)等毒蛾類、小菜蛾(Plutella xylostella)等菜蛾類、紅鈴蟲(Pectinophora gossypiella)、馬鈴薯塊莖蛾(Phthorimaea operculella)等旋蛾類(Gelechiidae)、美國白蛾(Hyphantria cunea)等燈蛾類、衣蛾(Tinea translucens)、幕衣蛾(Tineola bisselliella)等衣蛾類、番茄斑潛蠅(Tuta absoluta)等。 Lepidoptera pests: Chilo suppressalis, Tryporyza incertulas, Cnaphalocrocis medinalis, Notarcha derogata, Indian glutinous rice (Plodia interpunctella), Asian corn borer (Ostrinia furnacalis), Hellula undalis, Pediasia teterrellus, Spodoptera litura, Spodoptera exigua , Pseudaletia separate, Sesamia inferens, Mamestra brassicae, Agrotis ipsilon, Plusia nigrisigna, pink spot night White butterfly, Adoxophyes, etc., such as the genus Trichoplusia ni, Trichoplusia, Heliothis, Helicoverpa, and the genus Pieris rapae. , Grapholita molesta, Leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata, Adoxophyes honmai, and Homona magnanima ), moths such as Archips fuscocupreanus, Cydia pomonella, Caloptilia theivora, Phyllonycter ringoniella, etc. , such as the fruit moth (Carposina niponensis), the genus Moth, the genus Lyyotria, the Lymantria, the Euproctis, the genus Moth, the Plutella xylostella, etc. Plutella xylostella, Pectinophora gossypiella, potato tuber moth (Phthorimaea operculella), etc. (Gelechiidae), Hyphantria cunea, etc., Moth, Moth (Tinea Translucens), Tineola bisselliella, and other species, Tuta absoluta.

薊馬目害蟲:西方花薊馬(Frankliniella occidentalis)、南黃薊馬(Thrips parmi)、茶黃薊馬(Scirtothrips dorsalis)、蔥薊馬(Thrips tabaci)、花薊馬(Frankliniella intonsa)、烟褐花薊馬(Frankliniella fusca)、蔥薊馬(Thrips tabaci)、稻薊馬(Stenchaetothrips biformis)、稻管薊馬(Haplothrips aculeatus)等薊馬類等;雙翅目害蟲:蔥種蠅(Hylemya antiqua)、玉米種蠅(Hylemya platura)、稻潛葉蠅(Agromyza oryzae)、水稻潛葉蠅(Hydrellia griseola)、稻稈蠅(Chlorops oryzae)、非洲菊斑潛蠅(Liriomyza trifolii)等潛葉蠅類、瓜實蠅(Dacus cucurbitae)、地中海果實蠅(Ceratitis capitata)等;鞘翅目害蟲:茄二十八星瓢蟲(Epilachna vigintioctopunctata)、黃守瓜(Aulacophora femoralis)、黃條葉蚤(Phyllotreta striolata)、稻負泥蟲(Oulema oryzae)、稻象鼻蟲(Echinocnemus squameus)、水稻水象鼻蟲(Lissorhoptrus oryzophilus)、棉蛉象鼻蟲(Anthonomus grandis)、綠豆象(Callosobruchuschinensis)、椰象鼻蟲(Sphenophorus venatus)、日本豆金龜(Popillia japonica)、金銅金龜(Anomala cuprea)、玉米根蟲之同類(Diabrotica spp.)、科羅拉多金花蟲 (Leptinotarsa decemlineata)、叩頭蟲之同類(Agriotes spp.)、煙甲蟲(Lasioderma serricorne)等。 蓟马目虫虫: Frankliniella occidentalis, Thrips parmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, smoky brown Frankliniella fusca, Thrips tabaci, Stenchaethrips biformis, Haplothrips aculeatus, etc.; Diptera pest: Hylemya antiqua , leafy flies such as Hylemya platura, Agromyza oryzae, Hydrellia griseola, Chlorops oryzae, Liriomyza trifolii, Dacus cucurbitae, Ceratitis capitata, etc.; Coleoptera pests: Epilachna vigintioctopunctata, Aulacophora femoralis, Phyllotreta striolata, Oulema oryzae, Echinocnemus squameus, Lisorhoptrus oryzophilus, Anthonomus grandis, Callosobruchuschinensis, coconut Nasal worm (Sphenophorus venatus), Japan bean beetles (Popillia japonica), bronze beetle (Anomala cuprea), the same kind of corn rootworm (Diabrotica spp.), Colorado potato beetle (Leptinotarsa decemlineata), Agottoes spp., Lasioderma serricorne, etc.

直翅目害蟲:非洲螻蛄(Gryllotalpa africana)、小翅稻蝗(Oxya yezoensis)、日本稻蝗(Oxya japonica)等。 Orthoptera pests: Growlalpa africana, Oxya yezoensis, Oxya japonica, etc.

上述有害節肢動物中,較佳之例可列舉飛蝨類、葉蟬類、蚜蟲類、椿象類、水稻水象鼻蟲、稻負泥蟲、螟蛾類、夜蛾類。 Among the above-mentioned harmful arthropods, preferred examples include planthoppers, spider mites, mites, mites, rice water weevil, rice worms, hawk moths, and night moths.

本發明之有害節肢動物防治組成物可防治水稻之紋枯病(Rhizoctonia solani)等植物病害。 The harmful arthropod control composition of the present invention can prevent plant diseases such as rice sheath blight (Rhizoctonia solani).

本發明之有害節肢動物防治組成物可用於旱田、水田、乾田、草坪、果樹園等農耕地或非農耕地。又,可在栽培「植物」等之農耕地等,為了防治該農耕地之有害生物而使用本發明之有害節肢動物防治組成物。 The harmful arthropod control composition of the invention can be used for agricultural fields or non-agricultural fields such as dry fields, paddy fields, dry fields, lawns, orchards. In addition, the harmful arthropod control composition of the present invention can be used for controlling the pests of the agricultural land, such as cultivation of "plants" and the like.

可使用本發明有害節肢動物防治組成物之植物可列舉例如下述者。 As the plant which can use the harmful arthropod control composition of this invention, the following are mentioned, for example.

農作物:玉米、水稻、小麥、大麥、黑麥、燕麥、高粱、棉、大豆、花生、蕎麥、甜菜、油菜籽、向日葵、甘蔗、煙草等。 Crops: corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, peanuts, buckwheat, sugar beets, rapeseed, sunflower, sugar cane, tobacco, etc.

蔬菜:茄科蔬菜(茄子、蕃茄、青椒、辣椒、馬鈴薯等)、葫蘆科蔬菜(黃瓜、南瓜、櫛瓜(zucchini)、西瓜、哈密瓜(melon)等)、十字花科蔬菜(蘿蔔、蕪菁(turnip)、辣根(horseradish)、甘藍(kohlrabi)、白菜、高麗菜、芥菜、青花菜、花椰菜、油菜等)、菊科蔬菜(牛蒡、茼蒿菜、朝鮮薊、萵苣等)、百合科蔬菜(葱、洋葱、大蒜、蘆筍等)、 傘形科蔬菜(胡蘿蔔、荷蘭芹(parsley)、芹菜、歐洲防風草(parsnip)等)、藜科蔬菜(菠菜、莙薘菜等)、紫蘇科蔬菜(紫蘇、薄荷、羅勒(九層塔)等)、草莓、地瓜、山芋、芋頭等。 Vegetables: Solanaceae vegetables (eggplant, tomato, green pepper, pepper, potato, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, etc.), cruciferous vegetables (radish, turnip ( Turnip), horseradish, kohlrabi, cabbage, cabbage, mustard, broccoli, broccoli, rape, etc., compositae (burdock, wormwood, artichoke, lettuce, etc.), liliaceae ( Onions, onions, garlic, asparagus, etc.) Umbelliferous vegetables (carrots, parsley, celery, parsnips, etc.), leeks (spinach, leeks, etc.), perilla vegetables (perilla, mint, basil (nine-story tower), etc.) , strawberries, sweet potatoes, hawthorn, taro, etc.

果樹:仁果類(蘋果、西洋梨、日本梨、花梨、榅桲等)、核果類(桃子、李子、油桃、梅子、櫻桃、杏、黑棗(prune)等)、柑橘類(溫州蜜柑、柳橙、檸檬、萊姆、葡萄柚等)、堅果類(粟子、胡桃、榛、杏仁、開心果、腰果、夏威夷豆(Macadamia nut)等)、液果類(藍莓、蔓越莓、黑莓、覆盆子等)、葡萄、柿子、橄欖、琵琶、香蕉、咖啡、海棗、椰子、油椰子等。 Fruit trees: pome fruit (apple, pear, Japanese pear, rosewood, medlar, etc.), stone fruit (peach, plum, nectarine, plum, cherry, apricot, prune, etc.), citrus (Wenzhou mandarin, willow) Orange, lemon, lime, grapefruit, etc., nuts (corn, walnut, alfalfa, almond, pistachio, cashew, macadamia nut, etc.), liquid fruit (blueberry, cranberry, blackberry, covered) Pots, etc.), grapes, persimmons, olives, alfalfa, bananas, coffee, dates, coconuts, oil coconuts, etc.

果樹以外之樹木:茶樹、桑樹、花木類(皋月杜鵑(Rhododendron indicum)、山茶、繡球花、茶梅(sasanqua)、日本芥草(Illicium anisatum)、櫻花、美國鵝掌楸(Liriodendron tulipifera)、紫薇、桂花等)、街路樹(梣樹、樺樹、花水木(Benthamidia florida)、尤加利、銀杏、紫丁香、楓樹、樫(oak)、白楊、紫荊、楓香樹(Liquidambar formosana)、懸鈴木、櫸樹、黑檜、日本冷杉、日本鐵杉、杜松、松、魚鱗雲杉、紫杉、榆樹、七葉樹等)、日本珊瑚樹、羅漢松、杉、日本扁柏、巴豆、日本衛矛、紅芽石楠等。 Trees other than fruit trees: tea trees, mulberry trees, flower trees (Rhododendron indicum, camellia, hydrangea, sasanqua, Illicium anisatum, cherry blossom, Liriodendron tulipifera, Lagerstroemia, Osmanthus fragrans, etc., street trees (Benthamidia florida, eucalyptus, ginkgo, lilac, maple, oak, poplar, bauhinia, Liquidambar formosana, Platanus, eucalyptus, black scorpion, Japanese fir, Japanese hemlock, juniper, pine, fish scale spruce, yew, eucalyptus, horse chestnut, etc.), Japanese coral tree, Podocarpus, Chinese fir, Japanese cypress, Croton, Japanese medicinal Spear, red bud, heather, etc.

草坪:結縷草類(結縷草、馬尼拉草等)、百慕達草類(百慕達草等)、糠穗草類(玉山糠穗草穎、匍匐糠穗草穎、霞糠穗草等)、藍草類(草地早熟禾、粗莖早熟禾等)、羊茅類 (葦狀羊茅、紫羊茅、麗江羊茅等)、黑麥草類(多花黑麥草(Lolium multiflorum Lam)、多年生黑麥草(Lolium perenne)等)、鴨茅、梯牧草等。 Lawn: Zoysia (Caocao, Manila grass, etc.), Bermuda grass (Bermuda grass, etc.), 糠草草(玉山糠穗草颖, 匍匐糠穗草颖, Xia 糠草草Etc.), bluegrass (bluegrass, bluegrass, etc.), fescue (Taro fescue, purple fescue, Lijiang fescue, etc.), ryegrass (Lolium multiflorum Lam, perennial ryegrass (Lolium perenne), etc.), Dactylis glabra, Timothy grass, etc.

其他:花卉類(薔薇、康乃馨、菊、洋桔梗、滿天星、非洲菊、金盞花、西洋紅、矮牽牛、馬鞭草、鬱金香、翠菊(Callistephus chinensis)、龍膽、百合、三色堇、仙客來、蘭花、鈴蘭、薰衣草、紫蘿蘭、葉牡丹、報春花、聖誕紅、唐菖蒲、嘉德利亞蘭、雛菊、鳳蘭(cymbidium)、秋海棠等)、生質燃料植物(油桐樹、紅花、亞麻薺類、柳枝稷、芒草、鷸草、蘆竹、洋麻(kenaf)、樹薯、柳等)、觀葉植物等。 Other: flowers (rose, carnation, chrysanthemum, eustoma, gypsophila, gerbera, calendula, western red, petunia, verbena, tulip, aster (Callistephus chinensis), gentian, lily, pansy, Cyclamen, orchid, lily of the valley, lavender, violet, leaf peony, primrose, christmas red, gladiolus, garland, daisy, cymbidium, begonia, etc., biofuel plant (tung tree) , safflower, linseed, switchgrass, miscanthus, valerian, arundo, kenaf, cassava, willow, etc., foliage plants, etc.

上述植物中,較佳例可列舉玉米、小麥、稻等。其中,又以稻為較佳。 Among the above plants, preferred examples include corn, wheat, rice, and the like. Among them, rice is preferred.

上述「植物」亦可為經由基因重組技術或交配之育種法而賦予耐性之植物。 The above "plant" may also be a plant which confers tolerance by a genetic recombination technique or a breeding method of mating.

本發明之有害節肢動物防治組成物可經由施用於植物或植物之栽培地等而防治有害節肢動物。此處,就植物而言,可施用於植物之莖葉、植物之花、植物之果實、植物之種子等。 The harmful arthropod control composition of the present invention can control harmful arthropods by applying to plants or plant cultivation sites and the like. Here, as far as the plant is concerned, it can be applied to the stems and leaves of plants, the flowers of plants, the fruits of plants, the seeds of plants, and the like.

本發明之有害節肢動物之防治方法包含:將上述有害節肢動物防治組成物之有效量施用於植物或植物之栽培地的步驟。 The method for controlling a harmful arthropod of the present invention comprises the step of applying an effective amount of the above-mentioned harmful arthropod controlling composition to a cultivation site of a plant or a plant.

本發明之有害節肢動物之防治方法係藉由施用本發明之有害節肢動物防治組成物而進行。具體之施用方法可列 舉:莖葉散布等對植物莖葉之處理、對植物種子之處理、土壤處理、水面施用等對植物之栽培地之處理等。 The method for controlling harmful arthropods of the present invention is carried out by applying the harmful arthropod controlling composition of the present invention. Specific application methods can be listed For the treatment of plant stems and leaves, such as the treatment of plant stems and leaves, treatment of plant seeds, soil treatment, water surface application, etc.

對植物莖葉之處理,可列舉:經由使用人力噴霧機、動力噴霧機、桿式噴藥機(boom sprayer)、畔庫魯噴藥機進行地上散布,或使用航空防治或無人駕駛直升機進行空中散布等,而對所栽培之植物表面進行處理之方法。 For the treatment of plant stems and leaves, it can be enumerated by using a human sprayer, a power sprayer, a boom sprayer, a Bakulu sprayer, or using aerial control or unmanned helicopters. Dispersing, etc., the method of treating the surface of the cultivated plant.

對植物種子之處理,可列舉:浸漬處理、吹附處理、塗沬處理、薄膜塗佈處理及粒子塗佈處理等。 Examples of the treatment of the plant seeds include an immersion treatment, a blowing treatment, a coating treatment, a film coating treatment, and a particle coating treatment.

對植物栽培地之處理,可列舉:植穴處理、根株處理、植溝處理、作條處理、全面處理、側條處理、育苗箱處理、苗床處理、培土混合、床土混合、糊狀肥料混合、水面處理、湛水散布等。 For the treatment of plant cultivation sites, there may be mentioned acupuncture treatment, root treatment, planting treatment, strip processing, comprehensive treatment, side strip treatment, seedling box treatment, seedbed treatment, soil mixing, bed soil mixing, paste fertilizer mixing. , water surface treatment, Zhan water distribution.

將本發明之有害節肢動物防治組成物施用於植物或植物之栽培地時,其施用量可根據植物之種類、防治對象之有害節肢動物之種類或發生程度、製劑形態、處理時期、氣象條件等變化,惟,本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合物之合計量,在栽培該植物之場所,每1000m2通常為0.5至3000g,較佳為5至300g。 When the harmful arthropod control composition of the present invention is applied to a cultivation site of a plant or a plant, the application amount thereof may be according to the kind of the plant, the type or degree of occurrence of the harmful arthropod of the control object, the form of the preparation, the treatment period, the weather condition, and the like. The total amount of the cyanamide compound, the insect growth control compound, and the present blight control compound is usually 0.5 to 3000 g, preferably 5 to 300 g per 1000 m 2 in the place where the plant is cultivated.

於本說明書中,有效量係指本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合物之合計施用量,意指用於防治有害節肢動物所必需之施用量。 In the present specification, the effective amount means the total application amount of the present cyanamide compound, the insect growth control compound, and the present sheath blight control compound, and means the application amount necessary for controlling harmful arthropods.

本發明之有害節肢動物防治組成物為乳劑、水和劑、水懸劑等時,通常經由用水稀釋並散布而施用。此時,本氰胺化合物、本昆蟲成長控制化合物及本紋枯病防治化合 物之合計濃度通常為0.00001至10重量%,較佳為0.0001至5重量%。本發明之有害節肢動物防治組成物為粉劑、粒劑時,通常不經稀釋,以原狀施用。 When the harmful arthropod controlling composition of the present invention is an emulsion, a water and a liquid, an aqueous suspension or the like, it is usually applied by diluting and spreading with water. At this time, the present cyanamide compound, the insect growth control compound, and the sheath blight control combination The total concentration of the substances is usually from 0.00001 to 10% by weight, preferably from 0.0001 to 5% by weight. When the harmful arthropod control composition of the present invention is a powder or a granule, it is usually applied as it is without being diluted.

[實施例] [Examples]

以下,以製劑例及試驗例對本發明作更詳細的說明,惟,本發明不只限於以下之例。又,於以下之例中,”份”若無特別說明,則表示重量份。 Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples, but the present invention is not limited to the following examples. In the following examples, "parts" means parts by weight unless otherwise specified.

首先,顯示製劑例。 First, a formulation example is shown.

製劑例1 Formulation Example 1

將本氰胺化合物5份、滅芬諾20份及福多寧2份,加入混合有月桂基硫酸鈉4份、木質磺酸鈣2份、合成之含水之氧化矽微粉末20份及殘量之矽藻土的混合物中,充分攪拌混合,獲得水和劑100份。 5 parts of the cyanamide compound, 20 parts of mefenac and 2 parts of futonine, and added with 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic cerium oxide micro-powder and residual amount The mixture of the diatomaceous earth was thoroughly stirred and mixed to obtain 100 parts of water and a solvent.

製劑例2至5 Formulation Examples 2 to 5

除了使用[表1]記載之各化合物及使用量替代福多寧2份以外,其餘進行與製劑例1相同之操作,獲得各水和劑100份。 The same operation as in Formulation Example 1 was carried out except that each of the compounds described in [Table 1] and the amount used were used instead of the two parts of the formulation, and 100 parts of each water and the agent were obtained.

製劑例6 Formulation Example 6

將本氰胺化合物5份、可芬諾20份及福多寧2份,加入混合有月桂基硫酸鈉4份、木質磺酸鈣2份、合成之含水之氧化矽微粉末20份及殘量之矽藻土的混合物中,充分攪拌混合,獲得水和劑100份。 5 parts of the cyanamide compound, 20 parts of coffeine and 2 parts of futonine were added to mix 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic cerium oxide micro-powder and residual The mixture of the diatomaceous earth was thoroughly stirred and mixed to obtain 100 parts of water and a solvent.

製劑例7至10 Formulation Examples 7 to 10

除了使用[表2]記載之各化合物及使用量替代福多寧2份以外,其餘進行與製劑例6相同之操作,獲得各水和劑100份。 The same operation as in Preparation Example 6 was carried out except that each compound described in [Table 2] and the amount used were used instead of the two parts of the formulation, and 100 parts of each water and the agent were obtained.

製劑例11 Formulation Example 11

將本氰胺化合物5份、得芬諾20份及福多寧2份,加入混合有月桂基硫酸鈉4份、木質磺酸鈣2份、合成之含水之氧化矽微粉末20份及殘量之矽藻土的混合物中,充分攪拌混合,獲得水和劑100份。 5 parts of the cyanamide compound, 20 parts of fenfenol and 2 parts of pentandin were added to mix 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic cerium oxide micro-powder and residual The mixture of the diatomaceous earth was thoroughly stirred and mixed to obtain 100 parts of water and a solvent.

製劑例12至15 Formulation Examples 12 to 15

除了使用[表3]記載之各化合物及使用量替代福多寧2份以外,其餘進行與製劑例11相同之操作,獲得各水和 劑100份。 The same operation as in Preparation Example 11 was carried out except that each compound described in [Table 3] and the amount used were used instead of the two parts of Formonine to obtain each water and 100 parts.

製劑例16 Formulation Example 16

將本氰胺化合物0.35份、滅芬諾0.5份、福多寧2份、滑石10份及殘量之高嶺土黏土充分粉碎混合,獲得粉劑100份。 0.35 parts of the cyanamide compound, 0.5 part of fentanyl, 2 parts of pentandin, 10 parts of talc, and kaolin clay of the residual amount were sufficiently pulverized and mixed to obtain 100 parts of a powder.

製劑例17至20 Formulation Examples 17 to 20

除了使用[表4]記載之各化合物及使用量替代福多寧2份以外,其餘進行與製劑例16相同之操作,獲得各粉劑100份。 The same operation as in Preparation Example 16 was carried out except that each of the compounds described in [Table 4] and the amount used were used instead of the two parts of the formulation, and 100 parts of each powder was obtained.

製劑例21 Formulation Example 21

將本氰胺化合物0.35份、可芬諾0.5份、福多寧2份、滑石10份及殘量之高嶺土黏土充分粉碎混合,獲得粉劑100份。 0.35 parts of the cyanamide compound, 0.5 part of fentanyl, 2 parts of pentandin, 10 parts of talc, and kaolin clay of the residual amount were sufficiently pulverized and mixed to obtain 100 parts of a powder.

製劑例22至25 Formulation Examples 22 to 25

除了使用[表5]記載之各化合物及使用量替代福多寧2份以外,其餘進行與製劑例21相同之操作,獲得各粉劑100份。 The same operation as in Preparation Example 21 was carried out except that each compound described in [Table 5] and the amount used were used instead of the two parts of the formulation, and 100 parts of each powder was obtained.

製劑例26 Formulation Example 26

將本氰胺化合物0.35份、得芬諾0.75份、福多寧2份、滑石10份及殘量之高嶺土黏土充分粉碎混合,獲得粉劑100份。 0.35 parts of the cyanamide compound, 0.75 parts of fentanol, 2 parts of pentandin, 10 parts of talc, and kaolin clay of the residual amount were sufficiently pulverized and mixed to obtain 100 parts of a powder.

製劑例27至30 Formulation Examples 27 to 30

除了使用[表6]記載之各化合物及使用量替代福多寧2份以外,其餘進行與製劑例26相同之操作,獲得各粉劑100份。 The same operation as in Preparation Example 26 was carried out except that each of the compounds described in [Table 6] and the amount used were used instead of the two parts of the formulation, and 100 parts of each powder was obtained.

製劑例31 Formulation Example 31

將混合有本氰胺化合物2份、滅芬諾4份、福多寧16份、含有聚氧伸乙基烷基醚硫酸銨鹽50份之白碳(white carbon)30份、及殘量之水的混合物100份用濕式粉碎法進行微粉碎,獲得水懸劑。 2 parts of the present cyanamide compound, 4 parts of mefenfen, 16 parts of futonine, 30 parts of white carbon containing 50 parts of polyoxyethylene ethyl ether sulfate ammonium salt, and the residual amount 100 parts of the water mixture was finely pulverized by a wet pulverization method to obtain an aqueous suspension.

於本說明書中,含有聚氧伸乙基烷基醚硫酸銨鹽50份之白碳,係指聚氧伸乙基烷基醚硫酸銨鹽與白碳之重量比為1:1之混合物。 In the present specification, white carbon containing 50 parts of polyoxyethylene ethyl ether sulfate ammonium salt means a mixture of polyoxyethylene ethyl ether sulfate ammonium salt and white carbon in a weight ratio of 1:1.

製劑例32至35 Formulation Examples 32 to 35

除了使用[表7]記載之各化合物及使用量替代福多寧16份以外,其餘進行與製劑例31相同之操作,獲得各水懸劑100份。 The same operation as in Preparation Example 31 was carried out except that each of the compounds described in [Table 7] and the amount used were used instead of 16 parts of Formonine, and 100 parts of each aqueous suspension was obtained.

製劑例36 Formulation Example 36

將混合有本氰胺化合物2份、可芬諾4份、福多寧16份、含有聚氧伸乙基烷基醚硫酸銨鹽50份之白碳30份、及殘量之水的混合物100份用濕式粉碎法進行微粉碎,獲得水懸劑。 Mixing 100 parts of the present cyanamide compound, 4 parts of coffenes, 16 parts of futonine, 30 parts of white carbon containing 50 parts of polyoxyethylene ethyl ether sulfate ammonium salt, and a mixture of residual water 100 The fraction was finely pulverized by a wet pulverization method to obtain an aqueous suspension.

製劑例37至40 Formulation Examples 37 to 40

除了使用[表8]記載之各化合物及使用量替代福多寧16份以外,其餘進行與製劑例36相同之操作,獲得各水懸劑100份。 The same operation as in Preparation Example 36 was carried out except that each of the compounds described in [Table 8] and the amount used were used instead of 16 parts of Formonine, and 100 parts of each aqueous suspension was obtained.

製劑例41 Formulation Example 41

將混合有本氰胺化合物2份、得芬諾8份、福多寧16份、含有聚氧伸乙基烷基醚硫酸銨鹽50份之白碳30份、及殘量之水的混合物100份用濕式粉碎法進行微粉碎,獲得水懸劑。 Mixing 100 parts of the present cyanamide compound, 8 parts of fentanol, 16 parts of futonine, 30 parts of white carbon containing 50 parts of polyoxyethylene ethyl ether sulfate ammonium salt, and residual water 100 The fraction was finely pulverized by a wet pulverization method to obtain an aqueous suspension.

製劑例42至45 Formulation Examples 42 to 45

除了使用[表9]記載之各化合物及使用量替代福多寧16份以外,其餘進行與製劑例41相同之操作,獲得各水 懸劑100份。 The same operation as in Preparation Example 41 was carried out except that each compound described in [Table 9] and the amount used were used instead of 16 parts of Formonine to obtain each water. Suspension 100 parts.

接著,以試驗例顯示本發明之效果。 Next, the effects of the present invention are shown by test examples.

試驗例1 Test example 1

將本氰胺化合物6mg分別溶解於含有SORGEN TW-20(第一工業製藥公司製造)之丙酮(和光純藥工業公司製造)0.2mL後,用含有展著劑(商品名:答茵(音譯)(註冊商標),住化武田園藝製造)0.02容量%之水稀釋,使其成為預定濃度。將滅芬諾、可芬諾、得芬諾、福多寧、賓克隆及本活性化合物(I)3mg分別溶解於含有SORGEN TW-20(第一工業製藥公司製造)之丙酮(和光純藥工業公司製造)0.2mL後,用含有展著劑(商品名:答茵(註冊商標),住化武田園藝製造)0.02容量%之水稀釋,使其成為預定濃度。 6 mg of the cyanamide compound was dissolved in 0.2 mL of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing SORGEN TW-20 (manufactured by Daiichi Kogyo Co., Ltd.), and the exhibiting agent was used (trade name: A. (registered trademark), Shouhua Takeda Horticulture Manufacturing) 0.02% by volume of water is diluted to make it a predetermined concentration. Dissolving 3 mg of fentanol, cofino, fenfenolone, formin, pennazole and the active compound (I) in acetone containing SORGEN TW-20 (manufactured by Daiichi Kogyo Co., Ltd.) 0.2 mL of the product was diluted with water containing 0.02% by volume of a spreading agent (trade name: A. (registered trademark), Shouhua Takeda Horticulture) to make it a predetermined concentration.

將本氰胺化合物之水稀釋液,與滅芬諾、可芬諾或得芬諾之水稀釋液,及福多寧、賓克隆或本活性化合物(I)之水稀釋液混合,而調製試驗用藥液。 Mixing the aqueous dilution of the cyanamide compound with a water dilution of fentanyl, cofino or fenfenol, and a water dilution of budolyn, penzyl or the active compound (I), and preparing the test Use liquid medicine.

對2.5葉期之紙盒種植水稻(栽培稻(Oryza sativa), 品種:星之夢)幼苗,每株散布上述試驗用藥液10mL。將該水稻幼苗風乾後,放入已裝有水4.8mL之玻璃製試驗管(直徑30mm,高200mm)。在該試驗管中各飼養10隻褐飛蝨之3歲幼蟲,放置在室內(25℃,濕度55%),作為處理區。 Planting rice (Oryza sativa) in a 2.5-leaf carton, Variety: Star Dream) Seedlings, each plant spreading 10 mL of the above test solution. After the rice seedlings were air-dried, a glass test tube (diameter 30 mm, height 200 mm) containing 4.8 mL of water was placed. Ten 3-year-old larvae of the brown planthopper, each of which was housed in the test tube, were placed indoors (25 ° C, humidity 55%) as a treatment zone.

在放入未散布上述試驗用藥液之2.5葉期之紙盒種植水稻(栽培稻(Oryza sativa),品種:星之夢)幼苗及水4.8mL之玻璃製試驗管(直徑30mm,高200mm)中,與處理區相同地飼養褐飛蝨之3歲幼蟲,放置在室內,作為無處理區。 In a rice plant (cultivated rice (Oryza sativa), variety: star dream) seedlings and water 4.8 mL of a glass test tube (diameter 30 mm, height 200 mm), which was placed in a 2.5-leaf stage carton in which the above test solution was not dispersed, The 3-year-old larva of the brown planthopper, which was raised in the same manner as the treatment zone, was placed indoors as a no-treatment zone.

對於處理區、無處理區皆觀察開始飼養5日後供以試驗之幼蟲之生死。從該等觀察結果,根據式1)算出死蟲率,根據式2)算出補正死蟲率。又,反覆進行試驗2次。表10表示其平均值。 For the treatment area and the non-treatment area, the life and death of the experimental larvae after 5 days of feeding were observed. From these observation results, the mortality rate was calculated according to Formula 1), and the corrected mortality rate was calculated according to Formula 2). Again, the test was repeated twice. Table 10 shows the average value thereof.

式1)死蟲率(%)=(供試驗蟲數-生存蟲數)/供試驗蟲數×100 Formula 1) Dead insect rate (%) = (number of test insects - number of living insects) / number of test insects × 100

式2)補正死蟲率(%)={(處理區死蟲率-無處理區死蟲率)/(100-無處理區死蟲率)}×100 Formula 2) Correction of dead insect rate (%) = {(treatment area dead insect rate - no treatment area dead insect rate) / (100 - no treatment area dead insect rate)} × 100

[產業上之可利用性] [Industrial availability]

根據本發明,可防治有害節肢動物。 According to the present invention, harmful arthropods can be controlled.

Claims (5)

一種有害節肢動物防治組成物,其含有:式(I)表示之氰胺化合物 滅芬諾、及賓克隆。 A harmful arthropod control composition comprising: a cyanamide compound represented by formula (I) Defenfen, and Binclones. 如申請專利範圍第1項所述之有害節肢動物防治組成物,其中,氰胺化合物與滅芬諾之重量比為50:1至1:50。 The harmful arthropod control composition according to claim 1, wherein the weight ratio of the cyanamide compound to the mefenolone is from 50:1 to 1:50. 如申請專利範圍第1項或第2項所述之有害節肢動物防治組成物,其中,氰胺化合物與賓克隆之重量比為50:1至1:100。 The harmful arthropod control composition according to claim 1 or 2, wherein the weight ratio of the cyanamide compound to the bin clone is from 50:1 to 1:100. 一種有害節肢動物之防治方法,其包含下述步驟:將有效量之如申請專利範圍第1項至第3項中任一項所述之有害節肢動物防治組成物施用於植物或植物之栽培地的步驟。 A method for controlling harmful arthropods, comprising the steps of: applying an effective amount of a harmful arthropod control composition according to any one of claims 1 to 3 to a cultivation site of a plant or a plant A step of. 如申請專利範圍第4項所述之有害節肢動物之防治方法,其中,施用於植物或植物之栽培地的步驟,係施用於稻或稻之栽培地的步驟。 The method for controlling a harmful arthropod according to the invention of claim 4, wherein the step of applying to the cultivation site of the plant or the plant is the step of applying to the cultivation site of rice or rice.
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