TW201320895A - Arthropod pest control composition, and arthropod pest control method - Google Patents

Arthropod pest control composition, and arthropod pest control method Download PDF

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TW201320895A
TW201320895A TW101130653A TW101130653A TW201320895A TW 201320895 A TW201320895 A TW 201320895A TW 101130653 A TW101130653 A TW 101130653A TW 101130653 A TW101130653 A TW 101130653A TW 201320895 A TW201320895 A TW 201320895A
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Norihisa Sakamoto
Emiko Sakamoto
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Sumitomo Chemical Co
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

An arthropod pest control composition according to the present invention comprises an amide compound represented by formula (1), at least one insect growth regulator compound selected from group (A) and at least one planthopper control compound selected from group (B), and has an excellent controlling effect on arthropod pests. Group (A): a group consisting of methoxyfenozide, chromafenozide and tebufenozide. Group (B): a group consisting of clothianidin, nitenpyram, buprofezin and ethiprole.

Description

有害節肢動物防除組成物及有害節肢動物之防除方法 Harmful arthropod control composition and harmful arthropod control method

本專利申請書係對於日本專利申請第2011-183396號,主張具有優先權者,在此藉由參考,包含其全體於本說明書中者。 The present patent application is hereby incorporated by reference in its entirety in its entirety in the entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire all all all all all all all all all all each

本發明係關於有害節肢動物防除組成物及有害節肢動物之防除方法者。 The present invention relates to a method for controlling harmful arthropod control compositions and harmful arthropods.

傳統上,作為有害節肢動物防除組成物之有效成份,已知許多的化合物(例如參考非專利文獻1)。已知作為有害節肢動物防除組成物之有效成份如後述等。 Conventionally, many compounds have been known as effective components of a harmful arthropod control composition (for example, refer to Non-Patent Document 1). It is known as an effective component of a harmful arthropod control composition as described later.

滅芬諾(Methoxyfenozide) 可芬諾(Chromafenozide) 得芬諾(Tebufenozide) Methoxyfenozide Chromafenozide Tebufenozide

[先前技術文獻] [Previous Technical Literature] [非專利文獻] [Non-patent literature]

[非專利文獻1]The Pesticide Manual-15th edition(BCPC刊);ISBN 978-1-901396-18-8 [Non-Patent Document 1] The Pesticide Manual-15th edition (BCPC); ISBN 978-1-901396-18-8

本發明係以提供對有害節肢動物具有優異的防除效力之有害節肢動物防除組成物為課題。 The present invention is directed to providing a harmful arthropod control composition having excellent control effects against harmful arthropods.

本發明者等為發現對有害節肢動物具有優異的防除效力之有害節肢動物防除組成物,進行檢討的結果,發現含有後述式(1)所表示之醯胺化合物、以及選自後述組(A)中至少1種昆蟲成長控制化合物、以及選自後述組(B)中至少1種稻蝨類防除化合物之組成物,對有害節肢動物具有優異的防除效力,完成本發明。 The inventors of the present invention conducted a review to find a harmful arthropod control composition having an excellent control effect against harmful arthropods, and found that the indoleamine compound represented by the following formula (1) and the group (A) selected from the group (A) described later were found. At least one insect growth controlling compound and a composition selected from at least one rice blast control compound in the group (B) described below have excellent control effects against harmful arthropods, and the present invention has been completed.

亦即,所謂本發明係後述[1]~[6]者。 That is, the present invention is described later in [1] to [6].

[1]含有式(1)所表示之醯胺化合物、以及選自組(A)中至少1種昆蟲成長控制化合物、以及選自組(B)中至少1種稻蝨類防除化合物之有害節肢動物防除組成物。 [1] The guanamine compound represented by the formula (1), and at least one insect growth control compound selected from the group (A), and the harmful arthropod selected from at least one rice blast control compound in the group (B) Animal control composition.

組(A):滅芬諾(Methoxyfenozide)、可芬諾(Chromafenozide)及得芬諾(Tebufenozide)所成群。 Group (A): Methoxyfenozide, Chromafenozide and Tebufenozide.

組(B):可尼丁(Clothianidin)、烯啶蟲胺(Nitenpyram)、布芬淨(Buprofezin)及乙蟲清(Ethiprole)所成群。 Group (B): a group of Clothianidin, Nitenpyram, Buprofezin, and Ethiprole.

[2][1]記載之有害節肢動物防除組成物,其中醯胺化合物與昆蟲成長控制化合物之重量比為50:1~1:50。 [2] The harmful arthropod control composition described in [1], wherein the weight ratio of the indoleamine compound to the insect growth controlling compound is 50:1 to 1:50.

[3][1]或[2]記載之有害節肢動物防除組成物,其中醯胺化合物與稻蝨類防除化合物之重量比為50:1~1:50。 [3] The harmful arthropod control composition described in [1] or [2], wherein the weight ratio of the guanamine compound to the rice blast control compound is 50:1 to 1:50.

[4][1]~[3]中任一項記載之有害節肢動物防除組成物,其中稻蝨類防除化合物係布芬淨(Buprofezin)或乙蟲清(Ethiprole)。 [4] The harmful arthropod control composition according to any one of [1] to [3], wherein the rice blast control compound is Buprofezin or Ethiprole.

[5]包含施用有效量的[1]~[4]中任一項記載之有害節肢動物防除組成物於植物或植物栽培地之步驟之有害節肢動物之防除方法。 [5] A method for controlling harmful arthropods comprising the step of administering an effective amount of the harmful arthropod controlling composition according to any one of [1] to [4] in a plant or plant cultivation site.

[6]施用於植物或植物栽培地之步驟係施用於稻子或稻子栽培地之步驟之[5]記載之有害節肢動物之防除方法。 [6] The step of applying to a plant or a plant cultivation site is a method for controlling harmful arthropods as described in [5] of the step of applying rice or rice cultivation.

藉由本發明可防除有害節肢動物。 By the invention, harmful arthropods can be prevented.

用以實施發明之最佳型態 The best form for implementing the invention

所謂本發明之有害節肢動物防除組成物係含有後述式(1)所表示之醯胺化合物(後述記為本醯胺化合物。)、選自後述組(A)中至少1種昆蟲成長控制化合物(後述記為本昆蟲成長控制化合物。)以及選自後述組(B)中至少1種稻蝨類防除化合物(後述記為本稻蝨類防除化合物。)者。 The harmful arthropod control composition of the present invention contains at least one insect growth controlling compound selected from the group (A) described below by a guanamine compound (hereinafter referred to as a guanamine compound) represented by the following formula (1). The insect growth control compound (hereinafter referred to as "insect growth control compound") and at least one rice blast control compound (hereinafter referred to as rice blast control compound) selected from the group (B) described later.

組(A):滅芬諾(Methoxyfenozide)、可芬諾(Chromafenozide)及得芬諾(Tebufenozide)所成群。 Group (A): Methoxyfenozide, Chromafenozide and Tebufenozide.

組(B):可尼丁(Clothianidin)、烯啶蟲胺(Nitenpyram)、布芬淨(Buprofezin)及乙蟲清(Ethiprole)所成群。 Group (B): a group of Clothianidin, Nitenpyram, Buprofezin, and Ethiprole.

本醯胺化合物係已知的化合物,例如可以國際公開第2003/010149號手冊所記載之方法製造。 The known compound of the present indoleamine compound can be produced, for example, by the method described in the handbook of International Publication No. 2003/010149.

另外,本發明所使用之滅芬諾(Methoxyfenozide)、可芬諾(Chromafenozide)、得芬諾(Tebufenozide)、可尼丁(Clothianidin)、烯啶蟲胺(Nitenpyram)、布芬淨(Buprofezin)及乙蟲清(Ethiprole)係任一項皆為已知之化合物,例如「The Pesticide Manual-15th edition(BCPC刊);ISBN 978-1-901396-18-8」之764、211、1074、229、817、138及443頁等所記載。此等化合物係可 由市售製劑取得,或以已知之方法製造取得。 In addition, Methoxyfenozide, Chromafenozide, Tebufenozide, Clothianidin, Nitenpyram, Buprofezin and the like used in the present invention Ethiprole is a compound known to all, such as "The Pesticide Manual-15th edition (BCPC); ISBN 978-1-901396-18-8" 764, 211, 1074, 229, 817 , pages 138 and 443, etc. These compounds are available Obtained from commercially available formulations or obtained by known methods.

本發明之有害節肢動物防除組成物中,本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物之含有比率雖非特別限定者,但相對於100重量份之本醯胺化合物,本昆蟲成長控制化合物通常為0.2~50000重量份,以2~5000重量份為宜,以5~2000重量份尤佳,本稻蝨類防除化合物通常為0.2~50000重量份,以2~5000重量份為宜,以5~2000重量份尤佳。 In the harmful arthropod controlling composition of the present invention, the content ratio of the present indoleamine compound, the insect growth controlling compound, and the present rice bran controlling compound is not particularly limited, but is based on 100 parts by weight of the present indoleamine compound. The insect growth control compound is usually 0.2 to 50,000 parts by weight, preferably 2 to 5000 parts by weight, more preferably 5 to 2000 parts by weight, and the rice blast control compound is usually 0.2 to 50,000 parts by weight, and 2 to 5000 parts by weight. Preferably, it is preferably 5 to 2000 parts by weight.

本發明之有害節肢動物防除組成物中,本醯胺化合物與本昆蟲成長控制化合物之重量比(本醯胺化合物:本昆蟲成長控制化合物)通常為500:1~1:500,以50:1~1:50為宜,以20:1~1:20尤佳。 In the harmful arthropod controlling composition of the present invention, the weight ratio of the present indoleamine compound to the insect growth controlling compound (the present indoleamine compound: the insect growth controlling compound) is usually 500:1 to 1:500 to 50:1. ~1:50 is appropriate, especially 20:1~1:20.

本發明之有害節肢動物防除組成物中,本醯胺化合物與本稻蝨類防除化合物之重量比(本醯胺化合物:本稻蝨類防除化合物)通常為500:1~1:500,以50:1~1:50為宜,以20:1~1:20尤佳。 In the harmful arthropod control composition of the present invention, the weight ratio of the present indoleamine compound to the present rice bran control compound (the present indoleamine compound: the rice blast control compound) is usually from 500:1 to 1:500 to 50. : 1~1:50 is appropriate, especially 20:1~1:20.

本發明之有害節肢動物防除組成物係可僅混合本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物者,但通常可使用混合本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物與惰性載體,因應需要而添加界面活性劑或其他製劑用輔助劑,製劑化成油劑、乳劑、懸浮劑、水合劑、顆粒水合劑、粉劑、粒劑等者。 The harmful arthropod control composition of the present invention may be mixed only with the present indoleamine compound, the insect growth control compound and the rice blast control compound, but generally, the mixed guanamine compound, the insect growth control compound and the rice can be used. The anthraquinone control compound and the inert carrier are added with a surfactant or other preparation auxiliary agent as needed, and are formulated into an oil-forming agent, an emulsion, a suspension agent, a hydrating agent, a granule hydrating agent, a powder, a granule, and the like.

另外,前述經製劑化之有害節肢動物防除組成物係可以原本狀態或添加其他惰性成份,作為有害節肢動物防除 組成物使用。 In addition, the above-mentioned formulated harmful arthropod control composition can be used as a harmful arthropod in the original state or by adding other inert ingredients. The composition is used.

本發明之有害節肢動物防除組成物中,本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物之合計量通常為0.01~99重量%,以0.1~90重量%之範圍為宜,以0.5~70重量%之範圍尤佳。 In the harmful arthropod controlling composition of the present invention, the total amount of the present indoleamine compound, the insect growth controlling compound and the present rice bran controlling compound is usually 0.01 to 99% by weight, preferably in the range of 0.1 to 90% by weight. It is particularly preferably in the range of 0.5 to 70% by weight.

作為惰性載體,可列舉固體載體、液體載體等。 As an inert carrier, a solid carrier, a liquid carrier, etc. are mentioned.

作為固體載體,可舉例如高嶺土黏土、凹凸棒黏土(Attapulgite Clay)、膨潤土、蒙脫石、酸性白土、葉蠟石、滑石、矽藻土、方解石等之礦物、玉米芯粉、核桃殼粉等之天然有機物、尿素等之合成有機物、碳酸鈣、硫酸銨等之鹽類、水合氧化矽等之合成無機物等所成之微粉末或粒狀物等,作為液狀載體,可舉例如二甲苯、烷基苯、甲基萘等之芳香族烴類、2-丙醇、乙二醇、丙二醇、乙二醇單乙醚等之醇類、丙酮、環己酮、異佛爾酮等之酮類、大豆油、棉籽油等之植物油、石油系脂肪族烴類、酯類、二甲亞碼、乙腈及水等。 Examples of the solid carrier include kaolin clay, Attapulgite Clay, bentonite, montmorillonite, acid white clay, pyrophyllite, talc, diatomaceous earth, calcite, minerals, corncob powder, walnut shell powder, and the like. a fine organic powder, a synthetic organic substance such as urea, a salt such as calcium carbonate or ammonium sulfate, or a synthetic inorganic substance such as hydrated cerium oxide, or the like, and a liquid carrier, for example, xylene, An aromatic hydrocarbon such as an alkylbenzene or a methylnaphthalene; an alcohol such as 2-propanol, ethylene glycol, propylene glycol or ethylene glycol monoethyl ether; a ketone such as acetone, cyclohexanone or isophorone; Vegetable oil such as soybean oil or cottonseed oil, petroleum aliphatic hydrocarbons, esters, dimethyl methacrylate, acetonitrile, water, and the like.

作為界面活性劑,可舉例如烷基硫酸酯鹽、烷基芳基磺酸鹽、二烷基磺基琥珀酸鹽、聚氧乙烯烷基芳基醚磷酸酯鹽、木質素磺酸鹽、萘磺酸鹽甲醛聚縮合物等之陰離子界面活性劑及聚氧乙烯烷基芳基醚、聚氧乙烯烷基聚氧丙烯嵌段共聚物、山梨糖醇酐脂肪酸酯等之非離子界面活性劑及烷基三甲基銨鹽等之陽離子界面活性劑。 The surfactant may, for example, be an alkyl sulfate salt, an alkyl aryl sulfonate, a dialkyl sulfosuccinate, a polyoxyethylene alkyl aryl ether phosphate, a lignosulfonate or a naphthalene. Anionic surfactant such as sulfonate formaldehyde polycondensate and nonionic surfactant such as polyoxyethylene alkyl aryl ether, polyoxyethylene alkyl polyoxypropylene block copolymer, sorbitan fatty acid ester And a cationic surfactant such as an alkyltrimethylammonium salt.

作為其他製劑用輔助劑,可舉例如聚乙烯醇、聚乙烯吡咯烷酮等之水溶性高分子、阿拉伯膠、褐藻酸及其鹽、 羧甲基纖維素(CMC)、黃原膠等之多醣類、鋁鎂矽酸鹽、氧化鋁溶膠等之無機物、防腐劑、著色劑及酸性磷酸異丙酯(PAP)、二丁基羥基甲苯(BHT)等之安定化劑。 Examples of the auxiliary agent for other preparations include water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone, gum arabic, alginic acid, and salts thereof. Inorganic substances such as carboxymethyl cellulose (CMC), xanthan gum, etc., aluminum magnesium silicate, alumina sol, etc., preservatives, colorants, and acidic isopropyl phosphate (PAP), dibutyl hydroxy A stabilizer for toluene (BHT) or the like.

本發明之有害節肢動物防除組成物係可使用於用以保護植物,以免於對植物進行攝食、吸汁等加害之有害節肢動物之加害。 The harmful arthropod control composition of the present invention can be used for protecting plants from the harmful arthropods which ingest the plants, suck the juice and the like.

作為本發明之有害節肢動物防除組成物係具有防除效力之有害節肢動物,可舉例如後述者。 As a harmful arthropod having a control effect of the harmful arthropod control composition of the present invention, for example, it will be described later.

半翅目害蟲:斑飛蝨(Laodelphax striatellus)、褐飛蝨(Nilaparvata lugens)、白背飛蝨(Sogatella furcifera)等之稻蝨類、偽黑尾葉蟬(Nephotettix cincticeps)、台灣黑尾葉蟬(Nephotettix virescens)、電光葉蟬(Recilia dorsalis)、大貫小綠葉蟬(Empoasca onukii)等之葉蟬類、棉蚜(Aphis gossypii)、桃蚜(Myzus persicae)、菜蚜(Brevicoryne brassicae)、捲葉蚜(Aphis spiraecola)、馬鈴薯網管蚜(Macrosiphum euphorbiae)、馬鈴薯蚜(Aulacorthum solani)、稻麥蚜(Rhopalosiphum padi)、大桔蚜(Toxoptera citricidus)、桃粉蚜(Hyalopterus pruni)、蘋果綿蚜(Eriosoma lanigerum)等之蚜蟲類、草綠椿象(Nezara antennata)、盲椿(Trigonotylus caelestialium)、黑條紅椿象(Graphosoma rubrolineatum)、二星蝽(Eysarcoris lewisi)、點蜂緣椿象(Riptortus clavetus)、中華稻緣椿(Leptocorisa chinensis)、圓白星椿(Eysarcoris parvus)、茶翅椿象(Halyomorpha mista)、稻綠椿象(Nezara viridula)、美洲牧草盲蝽(Lygus lineolaris)等之椿象類、溫室粉蝨(Trialeurodes vaporariorum)、煙草粉蝨(Bemisia tabaci)、柑桔裸粉蝨(Dialeurodes citri)、柑橘刺粉蝨(Aleurocanthus spiniferus)等之粉蝨類、赤圓介殼蟲(Aonidiella aurantii)、梨圓介殼蟲(Comstockaspis perniciosa)、橘盾介殼蟲(Unaspis citri)、紅蠟介殼蟲(Ceroplastes rubens)、吹綿介殼蟲(Icerya purchasi)、臀紋粉介殼蟲(Planococcus kraunhiae)、(Pseudococcus longispinis)、桑介殼蟲(Pseudaulacaspis pentagona)等之介殼蟲類、花扁蟲類、溫帶臭蟲(Cimex lectularius)等之床蝨類、黃木蝨(Cacopsylla pyricola)等之木蝨類等。 Hemipteran pests: Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, rice mites, Nephotettix cincticeps, Nephotettix Verescens), Recilia dorsalis, Empoasca onukii, Aphis gossypii, Myzus persicae, Brevicoryne brassicae, leafhopper Aphis spiraecola),Macrosiphum euphorbiae,Aulacorthum solani,Rhopalosiphum padi,Toxoptera citricidus,Hyalopterus pruni,Eriosoma lanigerum Such as aphids, Nezara antennata, Trigonotylus caelestialium, Graphosoma rubrolineatum, Eysarcoris lewisi, Riptortus Clavetus), Leptocorisa chinensis, Eysarcoris parvus, Halyomorpha mista, Nezara viridula, Lygus lineolaris, etc. Trialeurodes vaporariorum, Bemisia tabaci, Dialeurodes citri, Aleurocanthus spiniferus, Aonidiella aurantii, Pear round Comstockaspis perniciosa, Unaspis citri, Ceroplastes rubens, Icerya purchasi, Planococcus kraunhiae, Pseudococcus longispinis, mulberry A scale insect such as a scale insect such as Pseudaulacaspis pentagona, a flat worm, a Cimex lectularius, or a hibiscus such as Cacopsylla pyricola.

鱗翅目害蟲:二化螟(Chilo suppressalis)、三化螟(Tryporyza incertulas)、稻縱捲葉野螟(Cnaphalocrocis medinalis)、棉捲葉野螟(Notarcha derogata)、印度穀蛾(Plodia interpunctella)、亞洲玉米螟(Ostrinia furnacalis)、菜心野螟(Hellula undalis)、草螟(Pediasia teterrellus)等之螟蛾類、斜紋夜蛾(Spodoptera litura)、甜菜夜蛾(Spodoptera exigua)、黏夜蛾(Pseudaletia separata)、稻蛀莖夜蛾(Sesamia inferens)、甘藍夜蛾(Mamestra brassicae)、切根蟲(Agrotis ipsilon)、黑點銀紋夜蛾(Plusia nigrisigna)、粉斑夜蛾(Trichoplusia ni)、Trichoplusia spp.、Heliothis spp.、Helicoverpa spp.等之夜蛾類、紋白蝶(Pieris rapae)等之粉蝶類、茶姬捲葉蛾屬、桃折心蟲(Grapholita molesta)、大豆食心蟲(Leguminivora glycinivorella)、Matsumuraeses azukivora、蘋果小角紋捲葉蛾(Adoxophyes orana fasciata)、茶小角紋捲葉蛾(Adoxophyes honmai)、茶捲葉蛾(Homona magnanima)、Archips fuscocupreanus、蘋果蠹蛾(Cydia pomonella)等之捲葉蛾類、茶細蛾(Caloptilia theivora)、金紋細蛾(Phyllonorycter ringoneella)等之細蛾類、桃蛀果蛾(Carposina niponensis)等之蛀果蛾類、Lyonetia屬之葉潛蛾類、Lymantria spp.、黃毒蛾屬(Euproctis spp.)等之毒蛾類、小菜蛾(Plutella xylostella)等之巢蛾類、紅鈴麥蛾(Pectinophora gossypiella)、馬鈴薯蠹蛾(Phthorimaea operculella)等之旋蛾類、美國白蛾(Hyphantria cunea)等之燈蛾類、衣蛾(Tinea translucens)、小衣蛾(Tineola bisselliella)等之蕈蛾類、斑潛蠅(Tuta absoluta)等。 Lepidopteran pests: Chilo suppressalis, Tryporyza incertulas, Cnaphalocrocis medinalis, Notarcha derogata, Plodia interpunctella, Asia Corn borer (Ostrinia furnacalis), Hellula undalis, Pediasia teterrellus, Spodoptera litura, Spodoptera exigua, Pseudaletia separata ), Sesamia inferens, Cabbageworm (Mamestra) Brassicae, Agrotis ipsilon, Plusia nigrisigna, Trichoplusia ni, Trichoplusia spp., Heliothis spp., Helicoverpa spp., etc. Pieris rapae), such as the pink butterfly, the genus Gypsophila, the genus of the genus of the genus, the genus of the genus of the genus, the genus of the genus of the genus, the genus of the genus of the genus, the genus of the genus of the genus, the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus , Mohonna magnanima, Archips fuscocupreanus, Cydia pomonella, etc., Moth, Moth, Moth, Moth, and other, Mothna magnan, Calyptilia theivora, Phyllolycter ringoneella Nihonensis), such as the fruit moth, the leaf moth of the Lyonetica genus, the Lymantria spp., the Euphtis spp., the moth, the Plutella xylostella, the red moth, the red moth (Pectinophora gossypiella), potato moth (Phthorimaea operculella), etc., Moth, Hyphantria cunea, etc. Tinea translucens), Tineola bisselliella, etc., Moth, Tuta absoluta, and the like.

纓翅目害蟲:西方花薊馬(Frankliniella occidentalis)、南黃薊馬(Thrips parmi)、小黃薊馬(Scirtothrip dorsalis)、蔥薊馬(Thrips tabaci)、台灣花薊馬(Frankliniella intonsa)、褐花薊馬 (Frankliniella fusca)、稻薊馬(Stenchaetothrips biformis)、稻管薊馬(Haplothrips aculeatus)等之薊馬類等; 雙翅目害蟲:蔥種蠅(Hylemya antiqua)、玉米種蠅(Hylemya platura)、稻潛(葉)蠅(Agromyza oryzae)、水稻稻潛葉蠅(Hydrellia griseola)、稻桿蠅(Chlorops oryzae)、非洲菊斑潛蠅(Liriomyza trifolii)等之潛蠅類、瓜實蠅(Dacus cucurbitae)、地中海果實蠅(Ceratitis capitata)等;甲蟲目害蟲:茄二十八星瓢蟲(Epilachna vigintioctopunctata)、黃守瓜(Aulacophora femoralis)、黃條葉蚤(Phyllotreta striolata)、負泥蟲(Oulema oryzae)、稻象鼻蟲(Echinocnemus squameus)、水稻水象鼻蟲(Lissorhoptrus oryzophilus)、棉蛉象鼻蟲(Anthonomus grandis)、綠豆象(Callosobruchus chinensis)、椰象鼻蟲(Sphenophorus venatus)、日本金龜子(Popillia japonica)、金銅金龜(Anomala cuprea)、玉米根蟲近親(Diabrotica spp.)、科羅拉多金花蟲(Leptinotarsa decemlineata)、叩頭蟲近親(Agriotes spp.)、煙甲蟲(Lasioderma serricorne)等;直翅目害蟲:非洲螻蛄(Gryllotalpa africana)、小翅稻蝗(Oxya yezoensis)、日本稻蝗(Oxya japonica)等。 Thysanoptera pests: Frankliniella occidentalis, Thrips parmi, Scirthothrip dorsalis, Thrips tabaci, Frankliniella intonsa, brown Flower horse (Frankliniella fusca), Stendchaetothrips biformis, and horses such as Haplothrips aculeatus; Diptera pests: Hylemya antiqua, Hylemya platura, Agromyza oryzae, Hydrellia griseola, Chlorops oryzae, Liriomyza trifolii, such as the larvae, Dacus cucurbitae, Ceratitis capitata, etc.; beetle pests: Epilachna vigintioctopunctata, Huang Shou Aulacophora femoralis, Phyllotreta striolata, Oulema oryzae, Echinocnemus squameus, Lisorhoptrus oryzophilus, Cotton aphid (Anthonomus grandis) ), mung bean (Callosobruchus chinensis), sphenophorus venatus, Popillia japonica, Anomala cuprea, Diabrotica spp., Leptinotarsa decemlineata Agriotes spp., Lasioderma serricorne, etc.; Orthoptera pests: Gryllotalpa africana, Oxya yezoensis, This rice grasshopper (Oxya japonica) and the like.

前述之有害節肢動物中,可列舉稻蝨類及葉蟬類等之半翅目害蟲、螟蛾類及夜蛾類等之鱗翅目害蟲作為適合例。 Among the above-mentioned harmful arthropods, lepidopteran pests such as rice mites and spider mites, lepidopteran moths, and noctuidae are suitable examples.

本發明之有害節肢動物防除組成物亦可防除稻米紋枯病(Rhizoctonia solani)等之植物病害。 The harmful arthropod control composition of the present invention can also prevent plant diseases such as Rhizoctonia solani.

本發明之有害節肢動物防除組成物係可使用於旱田、水田、乾田、草地、果樹園等之農耕地或非農耕地用。另外,本發明之有害節肢動物防除組成物係於栽培「植物」等之農耕地等,可使用於用以防除該農耕地之有害生物。 The harmful arthropod control composition of the present invention can be used for agricultural land or non-agricultural land in dry fields, paddy fields, dry fields, grasslands, orchards, and the like. Further, the harmful arthropod control composition of the present invention can be used for controlling pests of the agricultural land, such as cultivation of "plants" and the like.

作為可使用本發明之有害節肢動物防除組成物之植物,可列舉如後述者。 As a plant which can use the harmful arthropod control composition of this invention, it is mentioned later.

農作物:玉黍蜀、稻米、小麥、大麥、黑麥、燕麥、高梁、棉花、大豆、落花生、蕎麥、甜菜、油菜籽、向日葵、甘蔗、菸草等。 Crops: maize, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, groundnuts, buckwheat, sugar beets, rapeseed, sunflower, sugar cane, tobacco, etc.

蔬菜:茄科蔬菜(茄子、蕃茄、青椒、辣椒、馬鈴薯等)、瓜科蔬菜(小黃瓜、南瓜、櫛瓜、西瓜、哈密瓜等)、十字花科蔬菜(蘿蔔、蕪菁、辣根、大頭菜、白菜、高麗菜、芥菜、青花菜、花椰菜、油菜等)、菊科蔬菜(牛蒡、春菊、朝鮮薊、萵苣等)、百合科蔬菜(蔥、洋蔥、蒜頭、蘆筍等)、繖形花科蔬菜(紅蘿蔔、巴西利、芹菜、歐防風等)、藜科蔬菜(菠菜、莙薘菜等)、紫蘇科蔬菜(紫蘇、薄荷、羅勒等)、草莓、蕃薯、山藥、里芋等。 Vegetables: Solanaceae vegetables (eggplant, tomato, green pepper, pepper, potato, etc.), melon vegetables (glybdenum, pumpkin, melon, watermelon, cantaloupe, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Cabbage, cabbage, mustard, broccoli, broccoli, rape, etc.), Compositae (burdock, chrysanthemum, artichoke, lettuce, etc.), lily vegetables (onions, onions, garlic, asparagus, etc.), umbelliferous vegetables (carrots, Basil, celery, European windproof, etc.), leeks (spinach, leeks, etc.), sage vegetables (perilla, mint, basil, etc.), strawberries, sweet potatoes, yam, lee, etc.

果樹:仁果類(蘋果、西洋梨、日本梨、木瓜、榲桲 等)、核果類(桃子、李子、油桃、梅子、黃桃、杏桃、棗子等)、柑橘類(溫州蜜柑、柳橙、檸檬、萊姆、葡萄柚等)、堅果類(栗子、核桃、榛果、杏仁果、開心果、腰果、夏威夷火山豆等)、漿果類(藍莓、蔓越莓、黑莓、覆盆子等)、葡萄、柿子、橄欖、枇杷、香蕉、咖啡、棗椰子、椰子、油椰子等。 Fruit trees: Pome fruit (apple, pear, Japanese pear, papaya, medlar Etc.), stone fruit (peach, plum, nectarine, plum, peach, apricot, date, etc.), citrus (Wenzhou mandarin orange, orange, lemon, lime, grapefruit, etc.), nuts (chestnuts, walnuts, Hazelnuts, almonds, pistachios, cashews, Hawaiian volcanic beans, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, olives, alfalfa, bananas, coffee, date palms, coconuts, Oil coconut and so on.

果樹以外的樹木:茶樹、桑樹、花木類(杜鵑花、椿、繡球花、山茶花、白花八角、櫻花樹、鵝掌楸、紫薇、桂花樹等)、路樹(日本梣、樺樹、大花四照花、尤加利樹、銀杏樹、紫丁香、槭樹、櫟樹、白楊木、紫荊、楓樹、懸鈴木、櫸木、日本香柏、樅樹、鐵杉、杜松、松樹、雲杉、紅豆杉、榆樹、日本七葉樹等)、珊瑚樹、羅漢松、杉、檜木、巴豆、日本衛矛、紅芽石楠等。 Trees other than fruit trees: tea trees, mulberry trees, flowers and trees (azalea, medlar, hydrangea, camellia, white flower octagonal, cherry tree, tulip tree, crape myrtle, osmanthus tree, etc.), road tree (Japanese carp, birch, large flower Four flowers, eucalyptus, ginkgo, lilac, maple, eucalyptus, aspen, bauhinia, maple, sycamore, eucalyptus, Japanese cedar, eucalyptus, hemlock, juniper, pine, spruce, Yew, eucalyptus, Japanese horse chestnut, etc.), coral tree, Podocarpus, cedar, eucalyptus, croton, Japanese lance, red bud.

草地:結縷草類(朝鮮草、馬尼拉草等)、狗牙根草類(行儀草等)、糠穗草類(小糠穗草、蔓糠穗草、霞糠穗草等)、蘭草類(原野早熟禾、粗莖早熟禾等)、羊茅類(葦狀羊茅、紫羊茅(chewings fescue)、紫羊茅(creeping red fescue)等)、黑麥草類(多花黑麥草、黑麥草等)、鴨茅、梯牧草等。 Grassland: Zoysia (Korean grass, Manila grass, etc.), Bermudagrass (walking grass, etc.), sorghum grass (small sedge grass, sorghum grass, sorghum grass, etc.), bluegrass ( Wild bluegrass, bluegrass, etc., fescue (chewing fescue, creeping red fescue, etc.), ryegrass (multi-flowered ryegrass, ryegrass) Etc.), duckgrass, ladder grass and so on.

其他:花卉類(玫瑰、康乃馨、菊、土耳其桔梗、滿天星、非洲菊、金盞花、鼠尾草、矮牽牛、馬鞭草、鬱金香、翠菊、龍膽草、百合、三色堇、仙客來、蘭花、鈴蘭、薰衣草、紫羅蘭、葉牡丹、報春花、聖誕紅、劍蘭、嘉德利亞蘭、雛菊、蕙蘭、海棠等)、生質燃料植物(麻 瘋樹、紅花、亞麻薺類、柳枝稷、芒草、加拿麗鷸草、蘆竹、洋麻、木薯、柳等)、觀葉植物等。 Others: flowers (roses, carnations, chrysanthemums, platycodon grandiflorum, gypsophila, gerbera, calendula, sage, petunia, verbena, tulip, aster, gentian, lily, pansy, cyclamen Come, orchid, lily of the valley, lavender, violet, leaf peony, primrose, Christmas red, gladioli, garland, daisy, cypress, sea bream, etc.), biomass fuel plant (hemp) Mad tree, safflower, flaxseed, switchgrass, miscanthus, canadensis, sorrel, kenaf, cassava, willow, etc.), foliage plants, etc.

前述植物中,作為適合例,可列舉玉黍蜀、小麥、稻米等。其中以稻米尤佳。 Among the above plants, examples of suitable examples include maize, wheat, rice, and the like. Among them, rice is especially good.

前述「植物」亦可為藉由基因重組技術或交配之育種法而被賦予耐性之植物。 The aforementioned "plant" may also be a plant to which tolerance is imparted by genetic recombination techniques or breeding methods of mating.

本發明之有害節肢動物防除組成物係藉由施用於植物或植物栽培地等,可防除有害節肢動物。在此,作為植物係可列舉植物的莖葉、植物的花、植物果實、植物種子等。本發明之有害節肢動物之防除方法係包含施用有效量的前述有害節肢動物防除組成物於植物或植物栽培地之步驟。 The harmful arthropod control composition of the present invention can prevent harmful arthropods by being applied to plants or plant cultivation sites and the like. Here, examples of the plant system include stems and leaves of plants, flowers of plants, plant fruits, plant seeds, and the like. The method for controlling a harmful arthropod of the present invention comprises the step of applying an effective amount of the aforementioned harmful arthropod controlling composition to a plant or plant cultivation site.

本發明之有害節肢動物之防除方法係藉由施用有效量的本發明之有害節肢動物防除組成物於植物或植物栽培地所進行,但作為具體的施用方法,可列舉莖葉散佈等之對植物莖葉之處理、對植物種子之處理、土壤處理、水面施用等之對植物栽培地的處理。所謂本發明之有害節肢動物防除組成物之有效量係指對有害節肢動物,可發揮防除效果之本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物之合計施用量。 The method for controlling harmful arthropods of the present invention is carried out by applying an effective amount of the harmful arthropod control composition of the present invention to a plant or a plant cultivation site, but as a specific application method, a plant for stem and leaf dispersion or the like can be cited. Treatment of plant cultivation sites such as treatment of stems and leaves, treatment of plant seeds, soil treatment, and surface application. The effective amount of the harmful arthropod control composition of the present invention refers to a total application amount of the present indoleamine compound, the insect growth control compound, and the present rice bran control compound which can exert a control effect against harmful arthropods.

作為對植物莖葉之處理,可列舉藉由使用人力噴霧機、動力噴霧機、長管噴霧機(boom sprayer)或PANCRU-Sprayer進行之地面散佈、或使用航空防除或無人直升機進行之空中散佈等,對所栽培之植物表面進行處 理之方法。 As the treatment of the stems and leaves of the plant, ground spreading by using a human sprayer, a power sprayer, a boom sprayer or a PANCRU-Sprayer, or an airborne use of an air defense or an unmanned helicopter may be mentioned. , on the surface of the cultivated plant The method of rationality.

作為對植物種子之處理,可列舉浸漬處理、吹附處理、塗抹處理、薄膜被覆處理及小球被覆處理等。 Examples of the treatment of the plant seed include an immersion treatment, a blowing treatment, a smear treatment, a film coating treatment, and a pellet coating treatment.

作為對植物栽培地的處理,可列舉植穴處理、根部周圍處理、植溝處理、作畦處理、全面處理、側畦處理、育苗箱處理、苗床處理、培養土混合、床土混合、糊狀肥料混合、水面處理、湛水散佈等。 As the treatment of plant cultivation sites, planting point treatment, root treatment, planting treatment, sputum treatment, comprehensive treatment, side treatment, seedling box treatment, seed bed treatment, culture soil mixing, bed soil mixing, paste Fertilizer mixing, surface treatment, and water spreading.

將本發明之有害節肢動物防除組成物,施用於植物或植物的栽培地時,其施用量雖依植物的種類、防除對象之有害節肢動物的種類或發生程度、製劑型態、施用時期、氣象條件等而可改變,但作為本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物之合計施用量,每1000m2之該栽培植物場所,通常為0.5~3000g,以5~300g為宜。 When the harmful arthropod control composition of the present invention is applied to a cultivation site of a plant or a plant, the application amount thereof depends on the type of the plant, the type or degree of occurrence of the harmful arthropod, the preparation type, the application period, and the weather. The conditions may be changed, but the total application amount of the present guanamine compound, the insect growth control compound, and the rice blast control compound is usually 0.5 to 3000 g per 1000 m 2 of the cultivated plant site, and 5 to 300 g is used. should.

本發明之有害節肢動物防除組成物係乳劑、水合劑、懸浮劑等時,通常以水稀釋,藉由散佈所施用。此時,本醯胺化合物、本昆蟲成長控制化合物與本稻蝨類防除化合物之合計濃度,通常為0.00001~10重量%,以0.0001~5重量%為宜。本發明之有害節肢動物防除組成物係粉劑、粒劑等時,通常不稀釋而以原本型態施用。 When the harmful arthropod control composition of the present invention is an emulsion, a hydrating agent, a suspending agent or the like, it is usually diluted with water and applied by dispersion. In this case, the total concentration of the present indoleamine compound, the insect growth controlling compound, and the rice blast control compound is usually 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight. When the harmful arthropod control composition of the present invention is a powder, a granule or the like, it is usually applied in an original form without dilution.

實施例 Example

以下係以製劑例及試驗例更詳細地說明本發明,但本 發明並非局限於後述例者。另外,於後述例中,份係只要無特別限制,皆表示重量份。 Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples, but The invention is not limited to the latter examples. In the following examples, the parts are all parts by weight unless otherwise specified.

首先表示製劑例。 First, the formulation examples are shown.

製劑例1 Formulation Example 1

將20份之本醯胺化合物、5份之滅芬諾及6.6份之可尼丁,加入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣、20份之水合氧化矽微粉末及剩餘量之矽藻土中,充份攪拌混合而得100份之水合劑。 20 parts of the decylamine compound, 5 parts of fenfluster and 6.6 parts of konidine were added to mix 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of hydrated cerium oxide micro The powder and the remaining amount of the diatomaceous earth were mixed with stirring to obtain 100 parts of a hydrating agent.

製劑例2~4 Formulation Example 2~4

除了取代6.6份之可尼丁,改使用[表1]記載之各化合物及使用量以外,進行與製劑例1相同的操作,得到各100份之水合劑。 The same procedure as in Preparation Example 1 was carried out except that each of the compounds described in [Table 1] and the amount used were replaced with 6.6 parts of the cotinine, and 100 parts of each hydrating agent was obtained.

製劑例5 Formulation Example 5

將20份之本醯胺化合物、5份之可芬諾及6.6份之可尼丁,加入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣、20份之水合氧化矽微粉末及剩餘量之矽藻土中,充份 攪拌混合而得100份之水合劑。 20 parts of the decylamine compound, 5 parts of cofinol and 6.6 parts of cotinine were added to mix 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of hydrated cerium oxide micro Powder and residual amount of diatomaceous earth The mixture was stirred to obtain 100 parts of a hydrating agent.

製劑例6~8 Formulation examples 6~8

除了取代6.6份之可尼丁,改使用[表2]記載之各化合物及使用量以外,進行與製劑例5相同的操作,得到各100份之水合劑。 The same operation as in the preparation example 5 was carried out except that each of the compounds described in [Table 2] and the amount used were replaced with 6.6 parts of the cotinine, and 100 parts of each hydrating agent was obtained.

製劑例9 Formulation Example 9

將20份之本醯胺化合物、7.5份之得芬諾及6.6份之可尼丁,加入於混合4份之月桂基硫酸鈉、2份之木質素磺酸鈣、20份之水合氧化矽微粉末及剩餘量之矽藻土中,充份攪拌混合而得100份之水合劑。 20 parts of the decylamine compound, 7.5 parts of fenfluolol and 6.6 parts of konidine were added to mix 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of hydrated cerium oxide micro The powder and the remaining amount of the diatomaceous earth were mixed with stirring to obtain 100 parts of a hydrating agent.

製劑例10~12 Formulation examples 10~12

除了取代6.6份之可尼丁,改使用[表3]記載之各化合物及使用量以外,進行與製劑例9相同的操作,得到各100份之水合劑。 The same operation as in Preparation Example 9 was carried out except that each of the compounds described in [Table 3] and the amount used were replaced with 6.6 parts of the cotinine, and 100 parts of each hydrating agent was obtained.

製劑例13 Formulation Example 13

將0.75份之本醯胺化合物、0.5份之滅芬諾、0.15份之可尼丁、10份之滑石及剩餘量之高嶺土黏土,藉由充份粉碎混合而得100份之粉劑。 0.75 parts of the present indoleamine compound, 0.5 part of fentanyl, 0.15 part of cotinine, 10 parts of talc and the remaining amount of kaolin clay were mixed by pulverization to obtain 100 parts of a powder.

製劑例14~17 Formulation Example 14~17

除了取代0.15份之可尼丁,改使用[表4]記載之各化合物及使用量以外,進行與製劑例13相同的操作,得到各100份之粉劑。 The same operation as in Preparation Example 13 was carried out except that 0.15 parts of the cotinine was used instead of the compound of [Table 4], and 100 parts of each powder was obtained.

製劑例18 Formulation Example 18

將0.75份之本醯胺化合物、0.5份之可芬諾、0.15份之可尼丁、10份之滑石及剩餘量之高嶺土黏土,藉由充份粉碎混合而得100份之粉劑。 0.75 parts of the present indoleamine compound, 0.5 part of cofinol, 0.15 part of cotinine, 10 parts of talc and the remaining amount of kaolin clay were mixed by pulverization to obtain 100 parts of a powder.

製劑例19~22 Formulation Examples 19~22

除了取代0.15份之可尼丁,改使用[表5]記載之各化合物及使用量以外,進行與製劑例18相同的操作,得到各100份之粉劑。 The same operation as in Preparation Example 18 was carried out, except that 0.15 parts of the cotinine was used instead of the compound described in [Table 5], and 100 parts of each powder was obtained.

製劑例23 Formulation Example 23

將0.75份之本醯胺化合物、0.75份之得芬諾、0.15份之可尼丁、10份之滑石及剩餘量之高嶺土黏土,藉由充份粉碎混合而得100份之粉劑。 0.75 parts of the decylamine compound, 0.75 parts of fenflurene, 0.15 parts of nicotitin, 10 parts of talc, and the remaining amount of kaolin clay were mixed and pulverized to obtain 100 parts of the powder.

製劑例24~27 Formulation Example 24~27

除了取代0.15份之可尼丁,改使用[表6]記載之各化合物及使用量以外,進行與製劑例23相同的操作,得到各100份之粉劑。 The same operation as in Preparation Example 23 was carried out except that each of the compounds described in [Table 6] and the amount used were replaced with 0.15 parts of the cotinine, and 100 parts of each powder was obtained.

製劑例28 Formulation Example 28

藉由將100份之混合2份之本醯胺化合物、10份之滅芬諾、4份之可尼丁、30份之含50份之聚氧乙烯烷基醚硫酸銨鹽之白煙以及剩餘量之水之混合物,以濕式粉碎法進行微粉碎,得到懸浮劑。本說明書中,所謂含50份之聚氧乙烯烷基醚硫酸銨鹽之白煙係指聚氧乙烯烷基醚硫酸銨鹽與白煙之重量比為1:1之混合物。 By mixing 100 parts of 2 parts of the present guanamine compound, 10 parts of fenfluno, 4 parts of nicidine, 30 parts of 50 parts of white oxyethylene alkyl ether sulfate, and the remaining The mixture of water in an amount is finely pulverized by a wet pulverization method to obtain a suspension. In the present specification, the white smoke containing 50 parts of the polyoxyethylene alkyl ether sulfate ammonium salt means a mixture of a polyoxyethylene alkyl ether sulfate ammonium salt and a white smoke in a weight ratio of 1:1.

製劑例29~31 Formulation Examples 29~31

除了取代4份之可尼丁,改使用[表7]記載之各化合物及使用量以外,進行與製劑例28相同的操作,得到各100份之懸浮劑。 The same operation as in Preparation Example 28 was carried out except that each of the compounds described in [Table 7] and the amount used were replaced with 4 parts of the cotinine to obtain 100 parts of each suspension.

製劑例32 Formulation Example 32

藉由將100份之混合2份之本醯胺化合物、10份之可芬諾、4份之可尼丁、30份之含50份之聚氧乙烯烷基醚硫酸銨鹽之白煙以及剩餘量之水之混合物,以濕式粉碎法進行微粉碎,得到懸浮劑。 By mixing 100 parts of 2 parts of the present indoleamine compound, 10 parts of coffeine, 4 parts of cotinine, 30 parts of white smoke containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder The mixture of water in an amount is finely pulverized by a wet pulverization method to obtain a suspension.

製劑例33~35 Formulation Example 33~35

除了取代4份之可尼丁,改使用[表8]記載之各化合物及使用量以外,進行與製劑例32相同的操作,得到各100份之懸浮劑。 The same procedure as in Preparation Example 32 was carried out except that each of the compounds described in [Table 8] and the amount used were replaced with 4 parts of the cotinine to obtain 100 parts of each suspension.

製劑例36 Formulation Example 36

藉由將100份之混合2份之本醯胺化合物、16份之得芬諾、4份之可尼丁、30份之含50份之聚氧乙烯烷基醚硫酸銨鹽之白煙以及剩餘量之水之混合物,以濕式粉碎法進行微粉碎,得到懸浮劑。 By mixing 100 parts of 2 parts of the present guanamine compound, 16 parts of fenofol, 4 parts of nicidine, 30 parts of 50 parts of white oxyalkyl ether ether sulfate, and the remaining The mixture of water in an amount is finely pulverized by a wet pulverization method to obtain a suspension.

製劑例37~39 Formulation Examples 37~39

除了取代4份之可尼丁,改使用[表9]記載之各化合物及使用量以外,進行與製劑例36相同的操作,得到各100 份之懸浮劑。 The same operation as in the preparation example 36 was carried out except that each of the compounds described in [Table 9] and the amount used were used instead of the four parts of the cotinine. A portion of the suspension.

接著,以試驗例表示本發明之效果。 Next, the effects of the present invention are shown by test examples.

試驗例1 Test example 1

將3mg之本醯胺化合物,溶解於0.2ml之含Sorgen TW-20(第一工業製藥製)之丙酮(和光純藥工業製)後,以含有0.02容量%之展著劑(商品名:Dain(註冊商標),住化武田園藝製)的水稀釋成規定濃度。將3mg之滅芬諾、可芬諾及得芬諾,分別溶解於0.2ml之含Sorgen TW-20(第一工業製藥製)之丙酮(和光純藥工業製)後,以含有0.02容量%之展著劑(商品名:Dain(註冊商標),住化武田園藝製)的水稀釋成規定濃度。將布芬淨(商品名:Applaud Flowable,日本農藥製)及乙蟲腈(商品名:KIRAPPU Flowable,北興化學製)之市售製劑,以含有0.02容量%之展著劑(商品名:Dain(註冊商標),住化武田園藝製)的水稀釋成規定濃度。 3 mg of the decylamine compound was dissolved in 0.2 ml of acetone containing Sorgen TW-20 (manufactured by Wako Pure Chemical Industries, Ltd.) to contain 0.02% by volume of a spreading agent (trade name: Dain). The water of (registered trademark), Sumitomo Takeda Gardening) is diluted to the specified concentration. 3 mg of fenfluno, cofenfen and defenofol were dissolved in 0.2 ml of acetone containing Sorgen TW-20 (manufactured by Wako Pure Chemical Industries, Ltd.) to contain 0.02% by volume. The water of the spreading agent (trade name: Dain (registered trademark), Sumitomo Takeda Gardening) is diluted to a predetermined concentration. A commercially available preparation of Buchfen (product name: Applaud Flowable, manufactured by Nippon Pesticide) and acetonitrile (trade name: KIRAPPU Flowable, manufactured by Kitacing Chemical Co., Ltd.) containing 0.02% by volume of a spreading agent (trade name: Dain (trade name: Dain) The water of the registered trademark), Sumitomo Takeda Gardening) is diluted to the specified concentration.

混合本醯胺化合物的水稀釋液、及滅芬諾、可芬諾或得芬諾的水稀釋液、與布芬淨、或乙蟲清的水稀釋液,調 製試驗用藥液。 Mix a water dilution of the indoleamine compound, and a water dilution of the fentanol, cofinon or defenofol, with a water dilution of buffing, or acetaminophen, Preparation of test liquid.

對2.5葉期之種植於紙缽之稻(Oryza sativa,品種:星夢)幼苗,每株散佈10ml之前述試驗用藥液。將此稻米幼苗風乾後,放入已加入4.8ml的水之玻璃製試管(直徑為30mm,高度為200mm)。於該試管中,各放入飼養10隻褐飛蝨的3齡幼蟲,放置於室內(25℃,濕度為55%)。稱此為處理區。 For the 2.5-leaf stage rice seedlings (Oryza sativa, variety: Xingmeng) seedlings, 10 ml of the aforementioned test drug solution was distributed per plant. The rice seedlings were air-dried, and placed in a glass test tube (having a diameter of 30 mm and a height of 200 mm) to which 4.8 ml of water had been added. In the test tube, 10 instar larvae of 10 brown planthoppers were placed and placed indoors (25 ° C, humidity 55%). Call this the processing area.

另一方面,將未以前述試驗用藥液處理之稻米幼苗,與處理區同樣地放入試管,放入飼養幼蟲,放置於室內。稱此為無處理區。 On the other hand, rice seedlings which were not treated with the above-mentioned test drug solution were placed in a test tube in the same manner as the treatment zone, and placed in a larva, and placed in a room. Call this a no-treatment zone.

處理區與無處理區皆於放入飼養5天後,觀察試驗幼蟲的生死。由此等觀察結果,依式1)算出死蟲率,依式2)算出修正死蟲率。另外,重複進行試驗2次。該平均值如表10所示。 Both the treated area and the untreated area were placed in the rear for 5 days, and the life and death of the test larvae were observed. From the observation results, the mortality rate is calculated according to the formula 1), and the corrected mortality rate is calculated according to the formula 2). In addition, the test was repeated twice. The average value is shown in Table 10.

式1);死蟲率(%)=(試驗蟲數-存活蟲數)/試驗蟲數×100 Formula 1); mortality rate (%) = (number of test insects - number of living insects) / number of test insects × 100

式2);修正死蟲率(%)={(處理區死蟲率-無處理區死蟲率)/(100-無處理區死蟲率)}×100 Formula 2); corrected mortality rate (%) = {(treatment area dead insect rate - no treatment area dead insect rate) / (100 - no treatment area dead insect rate)} × 100

Claims (6)

一種有害節肢動物防除組成物,其特徵係含有式(1)所表示之醯胺化合物、以及選自組(A)中至少1種昆蟲成長控制化合物、以及選自組(B)中至少1種稻蝨類防除化合物, 組(A):滅芬諾(Methoxyfenozide)、可芬諾(Chromafenozide)及得芬諾(Tebufenozide)所成群組(B):可尼丁(Clothianidin)、烯啶蟲胺(Nitenpyram)、布芬淨(Buprofezin)及乙蟲清(Ethiprole)所成群。 A harmful arthropod control composition characterized by comprising a guanamine compound represented by the formula (1), and at least one insect growth controlling compound selected from the group (A), and at least one selected from the group (B) Rice blast control compounds, Group (A): Groups of Methoxyfenozide, Chromafenozide and Tebufenozide (B): Clothianidin, Nitenpyram, Buffen Buprofezin and Ethiprole are clustered. 如申請專利範圍第1項之有害節肢動物防除組成物,其中醯胺化合物與昆蟲成長控制化合物之重量比為50:1~1:50。 For example, in the harmful arthropod control composition of claim 1, the weight ratio of the guanamine compound to the insect growth controlling compound is 50:1 to 1:50. 如申請專利範圍第1項或第2項之有害節肢動物防除組成物,其中醯胺化合物與稻蝨類防除化合物之重量比為50:1~1:50。 For example, in the harmful arthropod control composition of claim 1 or 2, the weight ratio of the guanamine compound to the rice blast control compound is 50:1 to 1:50. 如申請專利範圍第1項至第3項中任一項之有害節肢動物防除組成物,其中稻蝨類防除化合物係布芬淨(Buprofezin)或乙蟲清(Ethiprole)。 The harmful arthropod control composition according to any one of claims 1 to 3, wherein the rice blast control compound is Buprofezin or Ethiprole. 一種有害節肢動物之防除方法,其特徵係包含施用有效量的如申請專利範圍第1項至第4項中任一項之有害節 肢動物防除組成物於植物或植物栽培地之步驟。 A method for controlling harmful arthropods, characterized by administering an effective amount of a harmful section as in any one of items 1 to 4 of the patent application scope The step of controlling the composition of the limbs in a plant or plant cultivation site. 如申請專利範圍第5項之有害節肢動物之防除方法,其中施用於植物或植物栽培地之步驟係施用於稻子或稻子栽培地之步驟。 A method for controlling harmful arthropods according to claim 5, wherein the step of applying to the plant or plant cultivation site is the step of applying to the rice or rice cultivation site.
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JP2013043866A (en) 2013-03-04

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