KR101947210B1 - Arthropod pest control composition, and arthropod pest control method - Google Patents
Arthropod pest control composition, and arthropod pest control method Download PDFInfo
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- KR101947210B1 KR101947210B1 KR1020147007172A KR20147007172A KR101947210B1 KR 101947210 B1 KR101947210 B1 KR 101947210B1 KR 1020147007172 A KR1020147007172 A KR 1020147007172A KR 20147007172 A KR20147007172 A KR 20147007172A KR 101947210 B1 KR101947210 B1 KR 101947210B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The arthropod pest controlling composition according to the present invention comprises an amide compound represented by the following formula (1):
At least one insect growth regulator compound selected from the following group (A) and at least one plant hopper control compound selected from the following group (B), and has an excellent control effect against arthropod pests. Group (A): a group consisting of methoxyphenozide, chromaphanoid, and tebufenozide. Group (B): a group consisting of chlothianidine, niphene pyram, bupropene, and etiprol.
Description
The present application is based on and claims the priority of Japanese Patent Application No. 2011-183396, the entire contents of which are incorporated herein by reference.
The present invention relates to an arthropod pest control composition and a method of controlling arthropod pests.
Heretofore, various compounds as active ingredients of arthropod pest control composition are known (see, for example, Non-Patent Document 1). As the active ingredient in the arthropod pest control composition, the following are known.
Methoxyphenozide
Chroma phenoid
Tebupenojid
Citation List
Non-patent literature
Non-Patent Document 1: The Pesticide Manual-15 edition (published by BCPC); ISBN 978-1-901396-18-8
It is an object of the present invention to provide an arthropod pest controlling composition having an excellent controlling effect against arthropod pests.
The present inventors have earnestly studied to provide an arthropod pest controlling composition having an excellent controlling effect against arthropod pests, and finally found that an amide compound represented by the formula (1) as described below, a group selected from the group Compositions comprising at least one insect growth regulator compound and at least one plant hopper control compound selected from group (B) as described below have excellent control effects against arthropod pests, Respectively.
The present invention includes the following [1] to [6]:
[1] An amide compound represented by the following formula (1):
At least one insect growth regulator compound selected from the following group (A) and at least one plant hopper control compound selected from the following group (B):
Group (A): a group consisting of methoxyphenozide, chromaphanoid and tebufenozide,
Group (B): a group consisting of chlothianidine, niphene pyram, bupropene, and etiprol.
[2] The arthropod pest controlling composition according to [1] above, wherein the weight ratio of the amide compound to the insect growth regulator compound is 50: 1 to 1:50.
[3] The arthropod pest controlling composition according to [1] or [2], wherein the weight ratio of the amide compound to the plant hopper controlling compound is 50: 1 to 1:50.
[4] The arthropod pest controlling composition according to any one of [1] to [3] above, wherein the plant hopper controlling compound is bupropene or etiprol.
[5] A method for controlling arthropod pests comprising the step of applying an effective amount of an arthropod pest control composition according to any one of [1] to [4] to a plant or plant growth area.
[6] The method for controlling arthropod pests according to [5] above, wherein the step of applying to a plant or a plant growth region is applied to a region where rice or rice grows.
According to the present invention, arthropod pests can be controlled.
The arthropod pest controlling composition of the present invention comprises an amide compound represented by the following formula (1):
(Hereinafter referred to as " present amide growth regulator compound ") selected from the following group (A) and the following group (B) One or more plant hopper control compounds (hereinafter referred to as "the present plant hopper control compounds"):
Group (A): a group consisting of methoxyphenozide, chromaphanoid and tebufenozide,
Group (B): a group consisting of chlothianidine, niphene pyram, bupropene, and etiprol.
The amide compounds are known compounds and can be obtained, for example, by the method described in WO 2003/010149.
Both methoxyphenozide, chromaphenozide, tebufenozide, chlothianidine, niphene pyram, bupropezin and etioprol, which are used in the present invention, are known compounds and are described, for example, in "The Pesticide Manual- 15, < / RTI > edition (BCPC publication); ISBN 978-1-901396-18-8, pages 764, 211, 1074, 229, 817, 138 and 443. These compounds can be obtained from commercial sources or can be prepared by known methods.
In the arthropod pest controlling composition of the present invention, the ratio of the present amide compound, the present insect growth regulating compound and the plant hopper controlling compound is not particularly limited. The insect growth regulator compound is generally used in an amount of 0.2 to 50,000 parts by weight, preferably 2 to 5,000 parts by weight, more preferably 5 to 2,000 parts by weight based on 100 parts by weight of the present amide compound. 0.2 to 50,000 parts by weight, preferably 2 to 5,000 parts by weight, more preferably 5 to 2,000 parts by weight based on 100 parts by weight of the amide compound.
In the arthropod pest controlling composition of the present invention, the weight ratio of the present amide compound to the present insect growth regulator compound (= main amide compound: present insect growth regulator compound) is generally 500: 1 to 1: 500, preferably 50: To 1:50, more preferably from 20: 1 to 1:20.
In the arthropod pest controlling composition of the present invention, the weight ratio of the present amide compound to the present plant hopper controlling compound (= main amide compound: the present plant hopper controlling compound) is generally 500: 1 to 1: 500, preferably 50: To 1:50, more preferably from 20: 1 to 1:20.
The arthropod pest controlling composition of the present invention can be prepared by simply mixing the present amide compound, the present insect growth regulator compound and the plant hopper controlling compound, or by simply mixing the present amide compound, the present insect growth regulating compound and the plant hopper controlling compound and the inert carrier and If necessary, formulating the mixture into a formulation such as an oil solution, an emulsifiable concentrate, a suspension concentrate, a wettable powder, an aqueous dispersible granule, a powder or granules, after mixing the surfactant and / or other formulation additives Can be manufactured.
The arthropod pest control composition thus formulated can be used as such or an arthropod pest control agent added to an arthropod pest control composition formulated with other inert ingredients can be used.
In the arthropod pest controlling composition of the present invention, the total amount of the present amide compound, present insect growth regulating compound and plant hopper controlling compound is generally 0.01 to 99% by weight, preferably 0.1 to 90% by weight, more preferably 0.5 to 10% 70% by weight.
Examples of inert carriers include solid carriers and liquid carriers.
Examples of solid carriers include minerals (e.g., kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth and calcite); Natural organic materials (eg corn versus powder and walnut shell powder); Synthetic organic materials (e.g., urea); Salts (e.g., calcium carbonate and ammonium sulfate); And synthetic powders (e.g., synthetic hydrated silicon oxides). Examples of liquid carriers are aromatic hydrocarbons (e.g., xylene, alkylbenzene and methylnaphthalene); Alcohols (e.g., 2-propanol, ethylene glycol, propylene glycol, and ethylene glycol monoethyl ether); Ketones (e.g., acetone, cyclohexanone, and isophorone); Vegetable oils (e.g., soybean oil and cottonseed oil); Petroleum-based aliphatic hydrocarbons; ester; Dimethyl sulfoxide; Acetonitrile; And water.
Examples of surfactants include anionic surfactants such as alkyl sulfate ester salts, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkyl aryl ether phosphate ester salts, lignin sulfonates, and naphthalene sulfonate formaldehyde pearlescent Mixture); Nonionic surfactants (e.g., polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers and sorbitan fatty acid esters); And cationic surfactants (e.g., alkyltrimethylammonium salts).
Examples of other formulation additives include water soluble polymers (e.g., polyvinyl alcohol and polyvinylpyrrolidone); Polysaccharides [e.g., gum arabic, alginic acid and its salts, CMC (carboxymethylcellulose) and xanthan gum]; Minerals (e.g., aluminum magnesium silicate and alumina-sol); Preservatives; coloring agent; And stabilizers such as isopropyl acid phosphate (PAP) and dibutylhydroxytoluene (BHT).
The arthropod pest controlling composition of the present invention can be used to protect plants from damage caused by feeding or suckling by arthropod pests.
Examples of arthropod pests having an arthropod pest control composition of the present invention having a controlling effect are included as follows:
Hemiptera: Delphacidae such as Laodelphax striatellus, Nilaparvata lugens and Sogatella furcifera; Deltocephalidae such as Nephotettix cincticeps, Nephotettix virescens, Recilia dorsalis and Empoasca itakii; Aphididae such as Aphis gossypii, Myzus persicae, Brevicoryne brassicae, Aphis spiraecola, Macrosiphum euphorbiae, Aulacorthum aphididae, solani, Rhopalosiphum padi, Toxoptera citricidus, Hyalopterus pruni and Eriosoma lanigerum; (Nezara antennata), Trigonotylus caelestialium, Graphosoma rubrolineatum, Eysarcoris lewisi, Riptortus clavetus, Hip-waist (lower back), Pentatomidae such as Nezara antennata, Leptocorisa chinensis, Eysarcoris parvus, Halyomorpha mista, Nezara viridula, and Lygus lineolaris; Aleyrodidae such as Trialeurodes vaporariorum, Bemisia tabaci, Dialeurodes citri and Aleurocanthus spiniferus; Coccoidea, such as Aonidiella aurantii, Comstockaspis perniciosa, Unaspis citri, Ceroplastes rubens, Icerya purchasi, ), Planococcus kraunhiae, Pseudococcus longispinis and Pseudaulacaspis pentagona; Shing worm (Tingidae); Cimicidea, such as Cimex lectularius; Psyllidae, such as Cacopsylla pyricola; Etc.
Lepidoptera: Pyralidae, such as Chilo suppressalis, Tryporyza incertulas, Cnaphalocrocis medinalis, Notarcha derogata, Plodia interpunctella, Ostrinia furnacalis, Hellula undalis and Pediasia teterrellus; Noctuidae, for example Spodoptera litura, Spodoptera exigua, Pseudaletia separata, Sesamia inferens, Mamestra brassicae, Agrotis ipsilon, Trichoplusia ni, Thorichoplusia spp., Heliothis spp., And Helicoverpa spp.), And the like; Pieridae, such as Pieris rapae; Such as Tortricidae such as Adoxophyes spp., Grapholita molesta, Leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes, Orana fasciata, Adoxophyes honmai., Homona magnanima, Archips fuscocupreanus, and Cydia pomonella; Gracillariidae such as Caloptilia theivora and Phyllonorycter ringoneella; Carposinidae, such as Carposina niponensis; Lyonetiidae such as Lyonetia spp .; Lymantriidae such as Lymantria spp. And Euproctis spp .; Yponomeutidae, such as Plutella xylostella; Gelechiidae such as Pectinophora gossypiella and Phthorimaea operculella; Arctiidae such as the American white caterpillar (Hyphantria cunea); Tineidae, such as Tinea translucens and Tineola bisselliella; Tomato moth (Tuta absoluta); Etc.
Thysanoptera: Thripidae such as Frankliniella occidentalis, Thrips parmi, Scirtothrips dorsalis, Thrips tabaci, Taiwan Thrips worms, Frankliniella intonsa, Frankliniella fusca, Stenchaetothrips biformis and Haplothrips aculeatus; Etc.
Diptera: Agromyzidae, such as Hylemya antiqua, Hylemya platura, Agromyza oryzae, Hydrellia griseola, Chlorops oryzae, And American leafy dragonfly (Liriomyza trifolii); Dacus cucurbitae, Ceratitis capitata; Etc.
Coleoptera: Epilachna vigintioctopunctata, Aulacophora femoralis, Phyllotreta striolata, Oulema oryzae, Echinocnemus squameus, Lissorhoptrus oryzophilus, , Anthonomus grandis, Callosobruchus chinensis, Sphenophorus venatus, Popillia japonica, Anomala cuprea, Diabrotica spp., And the like. Leptinotarsa decemlineata, Agriotes spp. And Lasioderma serricorne; Etc.
Orthoptera: Gryllotalpa africana, Oxya yezoensis, Oxya japonica; Etc.
Of the arthropod pests, Bacineae such as Anthracnidae and Mycobacterium; And the like are preferred.
The arthropod pest controlling composition of the present invention can prevent plant diseases such as rice sheath blight caused by Rhizoctonia solani.
The arthropod pest controlling composition of the present invention can be used in agricultural or non-agricultural lands such as fields, paddies, fields, lawns and orchards. The arthropod pest controlling composition of the present invention can also be used for pest control in agricultural lands such as "plants"
Examples of plants to which the arthropod pest controlling composition of the present invention may be applied include as follows:
Crops: corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco;
Vegetables: vegetables and vegetables (eggplant, tomato, bell pepper, red pepper, potato), pak and vegetables (cucumber, zucchini, watermelon and melon), flat vegetables and vegetables (radish, turnip, horseradish, kohlrabi), cabbage, cabbage, shredded cabbage, broccoli, cauliflower, flatland, etc.), chrysanthemum vegetables (burdock, artichoke, lettuce, etc.), lilies and vegetables (eg, onion, garlic, and asparagus) (Such as carrots, parsley, celery, parsnip, etc.), honeybees and vegetables (spinach, modern), lentils and vegetables (Japanese basil, mint, basil, etc.), strawberries, sweet potatoes, Etc;
Fruit trees: Citrus fruits (apple, pear, Japanese pear, quince and queen), nuclear fruits (peach, plum, peach, Japanese plum, cherry, apricot, prune) (Such as Satsuma mandarin, orange, lemon, lime and grapefruit), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia nuts, etc.), enteric foods (such as blueberries, cranberries, blackberries, raspberries, , Grapes, persimmons, olives, loquats, bananas, coffee, jujubes, coconuts, oil palm trees and the like;
Trees other than fruit trees; (Such as rhododendron, camellia, hydrangea, rhododendron, rhododendron, cherry, tulip tree, acacia, orange osmanthus, etc.), aster family tree (ash tree, birch tree, eucalyptus, ginkgo tree Japanese lilac, maple, oak, poplar, bamboo tree, Chinese sweet gum, sycamore, zelkova, Japanese arborvitae, fir, Japanese hemlock, juniper, pine, spruce Corn tree, podocarpus, cedar, cypress, persimmon, Euonymus japonicus, photinia glabra, etc.), and the like. ;
Grass: Zoysia (Korean zoysiagrass, Zoysia matrella, etc.), Bermuda grass (Cynodon dactylon, etc.), bent grass (Agrostis alba, creeping bent grass, hiland bent, etc.), bluegrass (meadow grass, bird grass, etc.), fescue (toll skew tall fescue, chewings fescue, creeping red fescue, etc.), ryegrass (darnel, rye grass, etc.), orchard grass, , Timothy grass, etc .;
Other: Flowers (roses, carnations, chrysanthemums, prairie gentian, pomegranate, gerbera, marigold, sage, petunia, verbena, tulip, lotus flower, lily, lily, pansy, cyclamen, orchid, ), Biofuel plants (such as jatropha, safflower, camelina, switchgrass, weed, reed canary grass, etc.), ornamental cabbage, primula, poinsettia, gladiolus, cattleya, daisy, symbium, grass, yams, sheep, cassava, willow, etc.), ornamental plants.
Among the above-mentioned plants, preferred are maize, wheat, rice, etc., and particularly rice.
As used herein, "plant" may be those which are resistant by genetic modification techniques or breeding methods by crossing breeding.
The arthropod pest controlling composition of the present invention can be applied to the plant or plant growth area, for example, for controlling its arthropod pests. Plants include the stem and leaves of plants, flowers of plants, fruit of plants, seeds of plants. The method of controlling arthropod pests of the present invention comprises the step of applying an effective amount of the arthropod pest controlling composition of the present invention to a plant or plant growth area.
In the method for controlling arthropod pests of the present invention, an effective amount of the arthropod pest controlling composition of the present invention is applied to a plant or plant growth area. Examples of application methods include application to plant stems and leaves, such as foliage application; Application to plant seeds; And application to plant growth areas such as soil application and submerged application. An "effective amount" of the arthropod pest control composition of the present invention means the total application amount of the present amide compound, the present insect growth regulator compound and the present plant hopper control compound, and the application amount capable of exhibiting the controlling effect against arthropod pests.
Specific examples of application to the stem and leaf of a plant include surface spraying using a manual sprayer, power sprayer, boom sprayer or pencil sprayer, application to the surface of cultivated plants such as aerosol spraying or spraying using a radio control helicopter .
Specific examples of application to seeds of plants include immersion treatment, spray treatment, spray coating treatment, film coating treatment and pellet coating treatment.
Specific examples of applications to the plant growth area include, but are not limited to, blood vessel treatment, plant foot treatment, cored bone treatment, breakfast treatment, frontal spreading, side row treatment, Incorporation of cultivation soil, incorporation of seedling photos, incorporation of paste fertilizer, water treatment, application of fresh water and the like.
When the arthropod pest controlling composition of the present invention is applied to a plant or plant growth area, the application amount varies depending on the type of plant, the species or the group size of the arthropod pests to be controlled, the form, , The total amount of the present amide compound, present insect growth regulator compound and plant hopper controlling compound is generally in the range of 0.5 to 3,000 g, preferably 5 to 300 g per 1,000 m 2 of the plant growth area.
The arthropod pest controlling composition of the present invention in the form of an emulsifiable concentrate, wettable powder or suspension concentrate is generally applied after dilution with water. In this case, the total concentration of the present amide compound, present insect growth regulating compound and plant hopper controlling compound is generally 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight. The arthropod pest controlling composition of the present invention in powder or granule form is generally applied as such, without dilution.
Example
Hereinafter, the present invention will be described in more detail with reference to Formulation Examples and Test Examples, but the present invention is not limited thereto. In the examples, the term "part (s) " means part (s) unless otherwise specified.
First, a formulation example will be presented below.
Formulation Example 1
20 parts of the main amide compound, 5 parts of methoxyphenozide and 6.6 parts of chlorothianidine was added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic hydrated silicon oxide fine powder and the remaining diatomaceous earth After the addition, 100 parts of wettable powder is obtained by sufficiently mixing under stirring.
Formulation Examples 2 to 4
The same procedure as described in Formulation 1 was repeated, except that each compound of each usage as shown in Table 1 was applied instead of 6.6 parts of clotidine, to obtain 100 parts of each of the target wettable powders.
Formulation Example 5
20 parts of the main amide compound, 5 parts of chromaphanoid and 6.6 parts of chlorothianidine were added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic hydrated silicon oxide fine powder and the remaining diatomaceous earth Then, 100 parts of a wettable powder is obtained by sufficiently mixing under stirring.
Formulation Examples 6 to 8
The same procedure as described in Formulation Example 5 was repeated, except that each compound of each usage as shown in Table 2 was applied instead of 6.6 parts of clotidine, to obtain 100 parts of each of the target wettable powders.
Formulation Example 9
20 parts of the main amide compound, 7.5 parts of tebufenozide and 6.6 parts of chlorothianidine were added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic hydrated silicon oxide fine powder and the remaining diatomaceous earth Then, 100 parts of a wettable powder is obtained by sufficiently mixing under stirring.
Formulation Examples 10 to 12
The same procedure as described in Formulation Example 9 was repeated to obtain 100 parts of each of the target wettable powders, except that each compound of each usage as shown in Table 3 was applied instead of 6.6 parts of clotidine.
Formulation Example 13
0.75 part of the main amide compound, 0.5 part of methoxyphenozide, 0.15 part of chlorothianidine, 10 parts of talc and the rest of kaolin clay are thoroughly pulverized and mixed to obtain 100 parts by mass.
Formulation Examples 14 to 17
The same procedure as described in Formulation 13 was repeated, except that each compound of each usage as shown in Table 4 was applied instead of 0.15 part of clotheyanidine to obtain 100 parts of each target powder.
Formulation Example 18
0.75 part of the present amide compound, 0.5 part of chromaphanoid, 0.15 part of chlothianidine, 10 parts of talc and the remaining kaolin clay are thoroughly pulverized and mixed to obtain 100 parts by mass.
Formulation Examples 19 to 22
The same procedure as described in Formulation Example 18 was repeated, except that each compound of each amount as shown in Table 5 was applied instead of 0.15 part of clotidine, to obtain 100 parts of each target powder.
Formulation Example 23
0.75 part of the present amide compound, 0.75 part of tebufenozide, 0.15 part of clothenianidine, 10 parts of talc and the remaining kaolin clay are thoroughly pulverized and mixed to obtain 100 parts by mass.
Formulation Examples 24 to 27
The same procedure as described in Formulation Example 23 was repeated, except that each compound of each usage as shown in Table 6 was applied instead of 0.15 part of clotheyanidine to obtain 100 parts of each target powder.
Formulation Example 28
30 parts of white carbon containing 2 parts of the amide compound, 10 parts of methoxyphenozide, 4 parts of chlorothianidine, 50 parts of ammonium polyoxyethylene alkyl ether sulfate and a mixture of 100 parts of the remaining water was subjected to wet milling Trituration affords a suspension concentrate. Here, "white carbon containing 50 parts of ammonium polyoxyethylene alkyl ether sulfate" means a mixture of ammonium polyoxyethylene alkyl ether sulfate and white carbon (1: 1 by weight).
Formulation Examples 29 to 31
The same procedure as described in Formulation Example 28 was repeated, except that each compound of each dose as shown in Table 7 was applied instead of 4 parts of clotidine, to obtain 100 parts of each of the target suspending concentrates.
Formulation Example 32
30 parts of white carbon containing 50 parts of ammonium polyoxyethylene alkyl ether sulfate and 100 parts of the remaining water was pulverized by wet pulverization to obtain a mixture of 2 parts of the main amide compound, 10 parts of chromaphanoid, 4 parts of chlorothianidine, 50 parts of ammonium polyoxyethylene alkyl ether sulfate, To obtain a suspended concentrate.
Formulation Examples 33 to 35
The same procedure as described in Formulation 32 was repeated, except that each compound of each usage as shown in Table 8 was applied instead of 4 parts of clotidine, to obtain 100 parts of each of the target suspending concentrates.
Formulation Example 36
30 parts of white carbon containing 2 parts of the amide compound, 16 parts of tebufenozide, 4 parts of chlorothianidine, 50 parts of ammonium polyoxyethylene alkyl ether sulfate, and 100 parts of the remainder water was pulverized by wet grinding To obtain a suspended concentrate.
Formulation Examples 37 to 39
The same procedure as described in Formulation Example 36 is repeated, except that each compound of each dosage as shown in Table 9 is applied instead of 4 parts of clotidine, to obtain 100 parts of each of the target suspending concentrates.
Next, the effects of the present invention will be described below with reference to a test example.
Test Example 1
3 mg of the present amide compound was dissolved in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing SORGEN TW-20 (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) And diluted with water containing 0.02% by volume of a dispersing agent (trade name: Dain (registered trademark), manufacturer Sumitomo chemical garden products inc.). Each of 3 mg of methoxyphenozide, chromaphanoid and tebufenozide was dissolved in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing SORGEN TW-20 (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) , Ltd.) and then diluted with water containing 0.02% by volume of a dispersing agent (product name: Dain (registered trademark), manufactured by Sumitomo Chemical garden products inc.) So as to have a predetermined concentration. Each of the commercial products of propylene (product name: Applaud Flowable, manufactured by Nihon Nohyaku Co. Ltd.) and ethiprole (product name: KIRAPPU Flowable, manufactured by Hokko Chemical Industry Co., Ltd.) was mixed with 0.02% Manufactured by Sumitomo Chemical Co., Ltd., manufacturer Sumitomo chemical garden products inc.).
A test solution was prepared by mixing a water dilution of the present amide compound and a water dilution of methoxyphenozide, chromaphanoid or tebufenozide, and a water dilution of bupropagen or etiprol.
Each test solution was sprayed to a rice seedling (Oryza sativa, breed: Hoshinoyume) of 2.5 leaf stage, which was grown in paper in an amount of 10 ml per seedling. The rice seedlings were air-dried and placed in a glass test tube (diameter: 30 mm, height: 200 mm) containing 4.8 ml of water. The test tubes were placed in a room (temperature: 25 ° C, humidity: 55%) after releasing 10 larvae of 3-instar larvae in a test tube. This is called the processed-section.
In the same manner as in the treated-section, rice seedlings that were not arbitrarily treated with the test solution were placed in a test tube, the insects were released to the test tube, and the test tube was placed in the room. This is called the unprocessed - section.
After 5 days of test larvae release, insects were observed for mortality in both sections.
From the observation results, the mortality rate was calculated by the following equation (1), and the corrected mortality rate was calculated by the following equation (2). For each treatment, two replicates were made. The average values are shown in Table 10.
Equation 1); Mortality (%) = (number of tested insects - number of surviving insects) / number of tested insects x 100
Equation 2); Corrected mortality (%) = {(mortality of treated section - mortality of untreated section) / (100 - mortality of untreated section)} x 100
Claims (6)
Methoxyphenozide, and ethiprole. ≪ RTI ID = 0.0 > 5. < / RTI >
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| JP2011183396A JP5810748B2 (en) | 2011-08-25 | 2011-08-25 | Harmful arthropod control composition and harmful arthropod control method |
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| PCT/JP2012/071459 WO2013027829A1 (en) | 2011-08-25 | 2012-08-24 | Arthropod pest control composition, and arthropod pest control method |
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| CN106689149A (en) * | 2015-07-20 | 2017-05-24 | 江苏龙灯化学有限公司 | Insecticide composition |
| CN105875600A (en) * | 2016-04-13 | 2016-08-24 | 南通清安健无水印染研究所（普通合伙） | Preparation method of trunk-injecting microcapsule pesticide for controlling longhorn beetles on poplars |
| CN111226973B (en) * | 2020-03-20 | 2021-08-17 | 漯河市农业科学院 | Pesticide synergistic composition for preventing and controlling armyworm |
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| AU2005298940A1 (en) * | 2004-10-22 | 2006-05-04 | Basf Aktiengesellschaft | Pesticidal mixtures |
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| CN101911943B (en) * | 2010-06-28 | 2013-04-17 | 陕西上格之路生物科学有限公司 | Methoxyfenozide-containing insecticidal composition |
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