KR101946667B1 - Harmful arthropod control composition, and harmful arthropod control method - Google Patents
Harmful arthropod control composition, and harmful arthropod control method Download PDFInfo
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- KR101946667B1 KR101946667B1 KR1020147007171A KR20147007171A KR101946667B1 KR 101946667 B1 KR101946667 B1 KR 101946667B1 KR 1020147007171 A KR1020147007171 A KR 1020147007171A KR 20147007171 A KR20147007171 A KR 20147007171A KR 101946667 B1 KR101946667 B1 KR 101946667B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The harmful arthropod controlling composition according to the present invention comprises an amide compound represented by the following formula (1):
Tricyclazole and at least one plant hopper control compound selected from the following group (A), and has an excellent control effect against harmful arthropods: Group (A): Clothianidine, Nitinaflam, Dinotefuran, Ethioprol, Silaflophene, and Ethopenprox.
Description
This application is a continuation-in-part of Japanese Patent Application No. 2011-183397, which is incorporated herein by reference in its entirety.
The present invention relates to an arthropod pest control composition and a method of controlling arthropod pests.
Heretofore, various compounds as active ingredients of arthropod pest control composition are known (see, for example, Non-Patent Document 1).
Citation List
Non-patent literature
Non-Patent Document 1: The Pesticide Manual-15 edition (published by BCPC); ISBN 978-1-901396-18-8
It is an object of the present invention to provide an arthropod pest controlling composition having an excellent controlling effect against arthropod pests.
The present inventors have earnestly studied to provide an arthropod pest controlling composition having an excellent controlling effect against arthropod pests, and have finally found that the amide compound represented by the formula (1) as described below, the tricyclazole and the group A ) Has been found to have an excellent control effect on arthropod pests, thereby achieving the present invention. ≪ Desc / Clms Page number 2 >
The present invention includes the following [1] to [6]:
[1] An amide compound represented by the following formula (1):
Tricyclazole and at least one plant hopper controlling compound selected from the following group (A):
Group (A): a group consisting of chlothianidine, niphene pyram, dinotefuran, etioprol, silafluophene and ethopenprox.
[2] The arthropod pest controlling composition according to [1] above, wherein the weight ratio of amide compound to tricyclazole is 50: 1 to 1:50.
[3] The arthropod pest controlling composition according to [1] or [2], wherein the weight ratio of the amide compound to the plant hopper controlling compound is 50: 1 to 1:50.
[4] The arthropod pest controlling composition according to any one of [1] to [3] above, wherein the plant hopper controlling compound is dinotefuran, etiprole, silafluofen or ethopenprox.
[5] A method for controlling arthropod pests comprising the step of applying an effective amount of an arthropod pest control composition according to any one of [1] to [4] to a plant or plant growth area.
[6] The method for controlling arthropod pests according to [5] above, wherein the step of applying to a plant or a plant growth region is applied to a region where rice or rice grows.
According to the present invention, arthropod pests can be controlled.
The arthropod pest controlling composition of the present invention comprises an amide compound represented by the following formula (1):
(Hereinafter sometimes referred to as " the present plant amide compound "), tricyclazole and at least one plant hopper controlling compound selected from the following group (A)
Group (A): a group consisting of chlothianidine, niphene pyram, dinotefuran, etioprol, silafluophene and ethopenprox.
The present amide compounds used in the present invention are known compounds and can be obtained, for example, by the method described in WO 2003/010149.
Both tricyclazole, chlothianidine, niphene pyram, dinotefuran, etioprol, silafluophen and ethopenprox used in the present invention are known compounds and are described, for example, in "The Pesticide Manual - 15th Edition (BCPC Quot; ISBN 978-1-901396-18-8 ", 1163, 229, 817, 391, 443, 1029 and 454. These compounds can be obtained from commercial sources or can be prepared by known methods.
In the arthropod pest controlling composition of the present invention, the ratio of the main amide compound, tricyclazole, and plant hopper controlling compound is not particularly limited. The tricyclazole is generally used in an amount of 0.2 to 50,000 parts by weight, preferably 2 to 5,000 parts by weight, more preferably 10 to 2,000 parts by weight based on 100 parts by weight of the present amide compound. The present plant hopper- 0.2 to 50,000 parts by weight, preferably 2 to 5,000 parts by weight, more preferably 5 to 2,000 parts by weight, based on 100 parts by weight of the compound.
In the arthropod pest controlling composition of the present invention, the weight ratio of the main amide compound to the tricyclazol (= the main amide compound: tricyclazole) is generally from 500: 1 to 1: 500, preferably from 50: 1 to 1:50 , More preferably from 10: 1 to 1:20.
In the arthropod pest controlling composition of the present invention, the weight ratio of the present amide compound to the present plant hopper controlling compound (= main amide compound: the present plant hopper controlling compound) is generally 500: 1 to 1: 500, preferably 50: To 1:50, more preferably from 20: 1 to 1:20.
The arthropod pest controlling composition of the present invention can be prepared by simply mixing the present amide compound, tricyclazole and plant hopper control compound or by simply mixing the present amide compound, tricyclazole and plant hopper control compound and inert carrier and, if necessary, And / or other formulation additives, and then formulating the mixture into a formulation such as an oil solution, an emulsifiable concentrate, a suspension concentrate, a wettable powder, an aqueous dispersible granule, a powder or granules .
The arthropod pest control composition thus formulated can be used as such or an arthropod pest control agent added to an arthropod pest control composition formulated with other inert ingredients can be used.
In the arthropod pest controlling composition of the present invention, the total amount of the main amide compound, tricyclazol and plant hopper controlling compound is generally 0.01 to 99% by weight, preferably 0.1 to 90% by weight, more preferably 0.5 to 70% % to be.
Examples of inert carriers include solid carriers and liquid carriers.
Examples of solid carriers include minerals (e.g., kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth and calcite); Natural organic materials (eg corn versus powder and walnut shell powder); Synthetic organic materials (e.g., urea); Salts (e.g., calcium carbonate and ammonium sulfate); And synthetic powders (e.g., synthetic hydrated silicon oxides). Examples of liquid carriers are aromatic hydrocarbons (e.g., xylene, alkylbenzene and methylnaphthalene); Alcohols (e.g., 2-propanol, ethylene glycol, propylene glycol, and ethylene glycol monoethyl ether); Ketones (e.g., acetone, cyclohexanone, and isophorone); Vegetable oils (e.g., soybean oil and cottonseed oil); Petroleum-based aliphatic hydrocarbons; ester; Dimethyl sulfoxide; Acetonitrile; And water.
Examples of surfactants include anionic surfactants such as alkyl sulfate ester salts, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkyl aryl ether phosphate ester salts, lignin sulfonates, and naphthalene sulfonate formaldehyde pearlescent Mixture); Nonionic surfactants (e.g., polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers and sorbitan fatty acid esters); And cationic surfactants (e.g., alkyltrimethylammonium salts).
Examples of other formulation additives include water soluble polymers (e.g., polyvinyl alcohol and polyvinylpyrrolidone); Polysaccharides [e.g., gum arabic, alginic acid and its salts, CMC (carboxymethylcellulose) and xanthan gum]; Minerals (e.g., aluminum magnesium silicate and alumina-sol); Preservatives; coloring agent; And stabilizers such as isopropyl acid phosphate (PAP) and dibutylhydroxytoluene (BHT).
The arthropod pest controlling composition of the present invention can be used to protect plants from damage caused by feeding or suckling by arthropod pests.
Examples of arthropod pests having an arthropod pest control composition of the present invention having a controlling effect are included as follows:
Hemiptera: Delphacidae such as Laodelphax striatellus, Nilaparvata lugens and Sogatella furcifera; Deltocephalidae such as Nephotettix cincticeps, Nephotettix virescens, Recilia dorsalis and Empoasca itakii; Aphididae such as Aphis gossypii, Myzus persicae, Brevicoryne brassicae, Aphis spiraecola, Macrosiphum euphorbiae, Aulacorthum aphididae, solani, Rhopalosiphum padi, Toxoptera citricidus, Hyalopterus pruni and Eriosoma lanigerum; (Nezara antennata), Trigonotylus caelestialium, Graphosoma rubrolineatum, Eysarcoris lewisi, Riptortus clavetus, Hip-waist (lower back), Pentatomidae such as Nezara antennata, Leptocorisa chinensis, Eysarcoris parvus, Halyomorpha mista, Nezara viridula, and Lygus lineolaris; Aleyrodidae such as Trialeurodes vaporariorum, Bemisia tabaci, Dialeurodes citri and Aleurocanthus spiniferus; Coccoidea, such as Aonidiella aurantii, Comstockaspis perniciosa, Unaspis citri, Ceroplastes rubens, Icerya purchasi, ), Planococcus kraunhiae, Pseudococcus longispinis and Pseudaulacaspis pentagona; Shing worm (Tingidae); Cimicidea, such as Cimex lectularius; Psyllidae, such as Cacopsylla pyricola; Etc.
Thysanoptera: Thripidae such as Frankliniella occidentalis, Thrips parmi, Scirtothrips dorsalis, Thrips tabaci, Taiwan Thrips worms, Frankliniella intonsa, Frankliniella fusca, Stenchaetothrips biformis and Haplothrips aculeatus; Etc.
Diptera: Agromyzidae, such as Hylemya antiqua, Hylemya platura, Agromyza oryzae, Hydrellia griseola, Chlorops oryzae, And American leafy dragonfly (Liriomyza trifolii); Dacus cucurbitae, Ceratitis capitata; Etc.
Coleoptera: Epilachna vigintioctopunctata, Aulacophora femoralis, Phyllotreta striolata, Oulema oryzae, Echinocnemus squameus, Lissorhoptrus oryzophilus, , Anthonomus grandis, Callosobruchus chinensis, Sphenophorus venatus, Popillia japonica, Anomala cuprea, Diabrotica spp., And the like. Leptinotarsa decemlineata, Agriotes spp. And Lasioderma serricorne; Etc.
Orthoptera: Gryllotalpa africana, Oxya yezoensis, Oxya japonica; Etc.
Of the arthropod pests, anchovy, lepidoptera, anthracnose, anthracnose, rice weevil and rice beetle are preferable.
The arthropod pest controlling composition of the present invention can prevent plant diseases such as rice blast caused by Magnaporthe grisea or Rhizoctonia solani caused by Rhizoctonia solani.
The arthropod pest controlling composition of the present invention can be used in agricultural or non-agricultural lands such as fields, paddies, fields, lawns and orchards. The arthropod pest controlling composition of the present invention can also be used for pest control in agricultural lands such as "plants"
Examples of plants to which the arthropod pest controlling composition of the present invention may be applied include as follows:
Crops: corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco;
Vegetables: vegetables and vegetables (eggplant, tomato, bell pepper, red pepper, potato), pak and vegetables (cucumber, zucchini, watermelon and melon), flat vegetables and vegetables (radish, turnip, horseradish, kohlrabi), cabbage, cabbage, shredded cabbage, broccoli, cauliflower, flatland, etc.), chrysanthemum vegetables (burdock, artichoke, lettuce, etc.), lilies and vegetables (eg, onion, garlic, and asparagus) (Such as carrots, parsley, celery, parsnip, etc.), honeybees and vegetables (spinach, modern), lentils and vegetables (Japanese basil, mint, basil, etc.), strawberries, sweet potatoes, Etc;
Fruit trees: Citrus fruits (apple, pear, Japanese pear, quince and queen), nuclear fruits (peach, plum, peach, Japanese plum, cherry, apricot, prune) (Such as Satsuma mandarin, orange, lemon, lime and grapefruit), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia nuts, etc.), enteric foods (such as blueberries, cranberries, blackberries, raspberries, , Grapes, persimmons, olives, loquats, bananas, coffee, jujubes, coconuts, oil palm trees and the like;
Trees other than fruit trees; (Such as rhododendron, camellia, hydrangea, rhododendron, rhododendron, cherry, tulip tree, acacia, orange osmanthus, etc.), aster family tree (ash tree, birch tree, eucalyptus, ginkgo tree Japanese lilac, maple, oak, poplar, bamboo tree, Chinese sweet gum, sycamore, zelkova, Japanese arborvitae, fir, Japanese hemlock, juniper, pine, spruce Corn tree, podocarpus, cedar, cypress, persimmon, Euonymus japonicus, photinia glabra, etc.), and the like. ;
Grass: Zoysia (Korean zoysiagrass, Zoysia matrella, etc.), Bermuda grass (Cynodon dactylon, etc.), bent grass (Agrostis alba, creeping bent grass, hiland bent, etc.), bluegrass (meadow grass, bird grass, etc.), fescue (toll skew tall fescue, chewings fescue, creeping red fescue, etc.), ryegrass (darnel, rye grass, etc.), orchard grass, , Timothy grass, etc .;
Other: Flowers (roses, carnations, chrysanthemums, prairie gentian, pomegranate, gerbera, marigold, sage, petunia, verbena, tulip, lotus flower, lily, lily, pansy, cyclamen, orchid, ), Biofuel plants (such as jatropha, safflower, camelina, switchgrass, weed, reed canary grass, etc.), ornamental cabbage, primula, poinsettia, gladiolus, cattleya, daisy, symbium, grass, yams, sheep, cassava, willow, etc.), ornamental plants.
Among the above-mentioned plants, preferable ones are maize, wheat, rice, etc., and rice is particularly preferable.
As used herein, "plant" may be those which are resistant by genetic modification techniques or breeding methods by crossing breeding.
The arthropod pest controlling composition of the present invention can be applied to the plant or plant growth area, for example, for controlling its arthropod pests. The plant includes stem and leaves of the plant, flower of the plant, fruit of the plant, seed of the plant and the like. The method of controlling arthropod pests of the present invention comprises the step of applying an effective amount of the arthropod pest controlling composition of the present invention to a plant or plant growth area.
In the method for controlling arthropod pests of the present invention, an effective amount of the arthropod pest controlling composition of the present invention is applied to a plant or plant growth area. Examples of application methods include application to plant stems and leaves, such as foliage application; Application to plant seeds; And application to plant growth areas such as soil application and submerged application. An "effective amount" of the arthropod pest controlling composition of the present invention means the total application amount of the present amide compound, triclclazol and the present plant hopper control compound, and the application amount capable of exhibiting the controlling effect against arthropod pests.
Specific examples of application to the stem and leaf of a plant include surface spraying using a manual sprayer, power sprayer, boom sprayer or pencil sprayer, application to the surface of cultivated plants such as aerosol spraying or spraying using a radio control helicopter .
Specific examples of application to seeds of plants include immersion treatment, spray treatment, spray coating treatment, film coating treatment and pellet coating treatment.
Specific examples of applications to the plant growth area include, but are not limited to, blood vessel treatment, plant foot treatment, cored bone treatment, breakfast treatment, frontal spreading, side row treatment, Incorporation of cultivation soil, incorporation of seedling photos, incorporation of paste fertilizer, water treatment, application of fresh water and the like.
When the arthropod pest controlling composition of the present invention is applied to a plant or plant growth area, the amount of application varies depending on the type of plant, the species or group size of the arthropod pests to be controlled, the form, , The total amount of the present amide compound, tricyclazole and plant hopper controlling compound is generally in the range of 0.5 to 3,000 g, preferably 5 to 300 g per 1,000 m 2 of the plant growth area.
The arthropod pest controlling composition of the present invention in the form of an emulsifiable concentrate, wettable powder or suspension concentrate is generally applied after dilution with water. In this case, the total concentration of the main amide compound, tricyclazole and plant hopper controlling compound is generally 0.00001 to 10% by weight, preferably 0.0001 to 5% by weight. The arthropod pest controlling composition of the present invention in powder or granule form is generally applied as such, without dilution.
Example
Hereinafter, the present invention will be described in more detail with reference to Formulation Examples and Test Examples, but the present invention is not limited thereto. In the examples, the term "part (s) " means part (s) unless otherwise specified.
First, a formulation example will be presented below.
Formulation Example 1
20 parts of the main amide compound, 4 parts of tricyclazole and 6.6 parts of chlorothianidine were added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic hydrated silicon oxide fine powder and the remaining diatomaceous earth Then, 100 parts of a wettable powder is obtained by sufficiently mixing under stirring.
Formulation Examples 2 to 6
The same procedure as described in Formulation 1 was repeated, except that each compound of each usage as shown in Table 1 was applied instead of 6.6 parts of clotidine, to obtain 100 parts of each of the target wettable powders.
Formulation Example 7
0.75 part of the present amide compound, 0.5 part of tricyclazole, 0.15 part of chlorothianidine, 10 parts of talc and the remaining kaolin clay are thoroughly pulverized and mixed to obtain 100 parts by mass.
Formulation Examples 8 to 13
The same procedure as described in Formulation 7 was repeated, except that each compound of each usage as shown in Table 2 was applied instead of 0.15 part of clotidine, to obtain 100 parts of each target powder.
Formulation Example 14
0.75 part of the amide compound, 1 part of tricyclazole, 0.15 part of chlorothianidine, 10 parts of talc and the remaining kaolin clay are finely pulverized and mixed to obtain 100 parts of powder.
Formulation Examples 15 to 20
The same procedure as described in Formulation Example 14 was repeated, except that each compound of each usage as shown in Table 3 was used in place of 0.15 part of clotheyanidine to obtain 100 parts of each target powder.
Formulation Example 21
30 parts of white carbon containing 50 parts of ammonium polyoxyethylene alkyl ether sulfate and 10 parts of tricyclazole, 8 parts of chlorthianidine, and 100 parts of the remaining water were finely pulverized by a wet grinding method A suspension concentrate is obtained. Here, "white carbon containing 50 parts of ammonium polyoxyethylene alkyl ether sulfate" means a mixture of ammonium polyoxyethylene alkyl ether sulfate and white carbon (1: 1 by weight).
Formulation Examples 22 to 32
The same procedure as described in Formulation Example 21 was repeated, except that each compound of each usage as shown in Table 4 was applied instead of 8 parts of clotidine, to obtain 100 parts of each of the target suspending concentrates.
Next, the effects of the present invention will be described below with reference to a test example.
Test Example 1
3 mg of the present amide compound was dissolved in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing SORGEN TW-20 (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) And diluted with water containing 0.02% by volume of a dispersing agent (trade name: Dain (registered trademark), manufacturer Sumitomo chemical garden products inc.). Each of 3 mg of tricyclazole and dinotefuran was dissolved in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing SORGEN TW-20 (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.) , And diluted with water containing 0.02% by volume of a dispersing agent [Product name: Dain (registered trademark), manufactured by Sumitomo chemical garden products inc.] So as to have a predetermined concentration. (Product name: MR.JOKER EW, manufactured by Sumitomo Chemical Company, Limited) and ethofenprox (product name: Trebon emulsifiable concentrate, manufactured by Nissan Chemical Co., Ltd., product name: KIRAPPU Flowable, manufactured by Hokko Chemical Industry Co., Ltd.), silafluofen Chemical Industries, Ltd.) was diluted with water containing 0.02% by volume of a dispersing agent (product name: Dain (registered trademark), manufacturer Sumitomo chemical garden products inc.) So as to have a predetermined concentration.
A water dilution product of the present amide compound, a water dilution product of tricyclazole and a water dilution product of dinotefuran, ethiprole, silafluofen or ethopenprox were mixed to prepare a test solution.
Each test solution was sprayed to a rice seedling (Oryza sativa, breed: Hoshinoyume) of 2.5 leaf stage, which was grown in paper in an amount of 10 ml per seedling. The rice seedlings were air-dried and placed in a glass test tube (diameter: 30 mm, height: 200 mm) containing 4.8 ml of water. The test tubes were placed in a room (25 ° C, 55% humidity) after releasing 10 larvae of 3-instar larvae in a test tube. This is called the processed-section.
In the same manner as in the treated-section, rice seedlings that were not arbitrarily treated with the test solution were placed in a test tube, the insects were released to the test tube, and the test tube was placed in the room. This is called the unprocessed - section.
After 5 days of test larvae release, insects were observed for mortality in both sections. From the observation results, the mortality rate was calculated by the following equation (1), and the corrected mortality rate was calculated by the following equation (2). For each treatment, two replicates were made. The average values are shown in Table 5.
Equation 1); Mortality (%) = (number of tested insects - number of surviving insects) / number of tested insects x 100
Equation 2); Corrected mortality (%) = {(mortality of treated section - mortality of untreated section) / (100 - mortality of untreated section)} x 100
Claims (6)
Tricyclazole and at least one plant hopper controlling compound selected from the following group (A):
Group (A): a group consisting of ethiprol and silafluophene.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011183397A JP5810749B2 (en) | 2011-08-25 | 2011-08-25 | Harmful arthropod control composition and harmful arthropod control method |
| JPJP-P-2011-183397 | 2011-08-25 | ||
| PCT/JP2012/071460 WO2013027830A1 (en) | 2011-08-25 | 2012-08-24 | Harmful arthropod control composition, and harmful arthropod control method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140059814A KR20140059814A (en) | 2014-05-16 |
| KR101946667B1 true KR101946667B1 (en) | 2019-02-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020147007171A KR101946667B1 (en) | 2011-08-25 | 2012-08-24 | Harmful arthropod control composition, and harmful arthropod control method |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5810749B2 (en) |
| KR (1) | KR101946667B1 (en) |
| CN (1) | CN103747676A (en) |
| TW (1) | TW201320894A (en) |
| WO (1) | WO2013027830A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5810748B2 (en) * | 2011-08-25 | 2015-11-11 | 住友化学株式会社 | Harmful arthropod control composition and harmful arthropod control method |
| CN115530165B (en) * | 2022-11-30 | 2023-03-03 | 北京市农林科学院 | Harmonia axyridis attractant, preparation thereof, preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008539179A (en) * | 2005-04-28 | 2008-11-13 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Combined use of active compounds |
| WO2010000790A1 (en) * | 2008-07-04 | 2010-01-07 | Basf Se | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| UA89673C2 (en) * | 2005-04-28 | 2010-02-25 | Байер Кропсайенс Аг | Active substance combination to control unwanted animal pests |
| UY30725A1 (en) * | 2006-11-21 | 2009-01-30 | Mitsui Chemicals Inc | COMPOSITION OF CONTROL OF THE DANE PRODUCED BY INSECTS AND PLANTS DISEASE, AND METHOD OF PREVENTION OF THE DANE PRODUCED BY INSECTS AND PLANT DISEASE. |
| WO2008065960A1 (en) * | 2006-11-29 | 2008-06-05 | Mitsui Chemicals, Inc. | Pest control composition and method of preventing pest damage |
| WO2009147205A2 (en) * | 2008-06-05 | 2009-12-10 | Basf Se | Synergistic fungicidal mixtures |
| JP2012136469A (en) * | 2010-12-27 | 2012-07-19 | Sumitomo Chemical Co Ltd | Noxious arthropod control composition and control method of noxious arthropod |
| JP5760781B2 (en) * | 2011-07-13 | 2015-08-12 | 住友化学株式会社 | Harmful arthropod control composition and harmful arthropod control method |
| JP5810748B2 (en) * | 2011-08-25 | 2015-11-11 | 住友化学株式会社 | Harmful arthropod control composition and harmful arthropod control method |
-
2011
- 2011-08-25 JP JP2011183397A patent/JP5810749B2/en not_active Expired - Fee Related
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2012
- 2012-08-23 TW TW101130652A patent/TW201320894A/en unknown
- 2012-08-24 WO PCT/JP2012/071460 patent/WO2013027830A1/en active Application Filing
- 2012-08-24 KR KR1020147007171A patent/KR101946667B1/en active IP Right Grant
- 2012-08-24 CN CN201280041114.XA patent/CN103747676A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008539179A (en) * | 2005-04-28 | 2008-11-13 | バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト | Combined use of active compounds |
| WO2010000790A1 (en) * | 2008-07-04 | 2010-01-07 | Basf Se | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013027830A1 (en) | 2013-02-28 |
| TW201320894A (en) | 2013-06-01 |
| KR20140059814A (en) | 2014-05-16 |
| CN103747676A (en) | 2014-04-23 |
| JP2013043867A (en) | 2013-03-04 |
| JP5810749B2 (en) | 2015-11-11 |
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