TW201213355A - Colored photosensitive resin composition, pattern forming method, method for producing color filter, color filter, and display device provided with the same - Google Patents

Abstract

To provide a coloring photosensitive resin composition useful for a color filter which is excellent in terms of line width sensitivity and linearity and can form patterns with suppressed generation of wrinkles after heating. A coloring photosensitive resin composition includes (A) a colorant, (B-1) a binder resin represented by the general formula (I) and having an acid group, (B-2) a binder resin having a structural unit represented by the general formula (II) and a structural unit with an acid group, (C) a polymerizable compound, (D) an oxime photopolymerization initiator, and (E) a solvent. The ratio of contents of (B-1) to (B-2) is 3:7 to 7:3.

Description

201213355 SUMMARY OF THE INVENTION [Technical Field] The present invention relates to a coloring photosensitive resin composition, a pattern forming method, a method for producing a shirt color filter, and a display device. Nine-Piece and Others [Prior Art] In recent years, the development of liquid crystal display devices has been used for personal computers and monitors with a small screen size. -4 large i and if used for TV, it is required to have higher image quality than the previous one, that is, the benefit ratio is increased, and the color purity is improved. The particle size of the colorant (organic pigment, etc.) of the color photosensitive resin composition used for forming the color light-emitting sheet and the '^^ sheet, μ ^ + , ^ , , eight small is required The second color of the finer material improves the color purity. In the case where the coloring photosensitive resin composition is required to be more: the content of the coloring agent (organic pigment) to be occupied is required, the particle diameter of the pigment needs to be made finer. Two: 'Requires a more dispersible pigment dispersion composition. In order to enhance the pigment, for example, on the surface of the phthalocyanine pigment, the surface of the pigment is modified with its bamboo biological compound and the polar functional group having a surface which is easy to be adsorbed on the surface of gjr for &φ# is used. Low-molecular-weight resin, etc. 刀 Μ 图 图 图 图 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料A 201213355 唪 photosensitive composition was prepared by dissolving a compound, a photopolymerization initiator, and other components, and a color filter was obtained by photolithography or the like. When the pigment is made finer and the content ratio of the pigment is increased, when the image pattern is formed by photolithography, the linearity of the line is lowered (the line width is reduced). In τν (television) use, it is particularly required to provide an inexpensive color filter, but it is necessary to increase the exposure amount in the exposure step, that is, to increase the exposure time, due to the above-mentioned problem centered on the development step. Since this has lowered the yield and deteriorated productivity, it has been required to be improved. In order to solve the above problem, there have been many proposals for improving the line width sensitivity by improving the photopolymerization initiator used for the photosensitive resin composition for color filters. For example, a photopolymerizable composition using a triazine compound of a specific structure (for example, refer to Patent Document 1), or a benzophenone type, a acetophenone type, or oxysulfur has been disclosed. A photoresist for a color filter which is used in combination with one or more of the hawthorn compound (for example, see Patent Document 2). In addition, other proposals have disclosed an average double bond equivalent in an organic compound composed of a binder resin and a polymerizable compound in a coloring photosensitive resin composition, and a specific binder resin. A technique of forming a forward tapered shape by firing (see Patent Document 3). Moreover, although it is not a color-sensitive photosensitive composition for ultraviolet laser exposure, it has been proposed to modulate high sensitivity and develop a wide tolerance by using a binder resin containing a dilute propyl group. A colored resin composition (for example, refer to Patent Documents 4 and 5). In addition, there is a kind of 201213355 amine copolymer used as the adhesive resin 5 color filter for the radiation-induced linear group of documents 6) However, if it is produced under the light step and the development step, it cannot be lowered. The productivity of the steps 5 has been proposed - the method (for example, see the patent document mercury lamp is different 5 has a straightforward small focus, does not need to be placed in the exposure step is expected, even if it will still become rough in the development step > ' In any case, it is not enough to satisfy the characteristics of the demand. In addition, 7 has been lowered, and the proposed exposure apparatus is not patented 8 'S 丨) 0 Di and has been expected to be suitable for this type of equipment by N- A proposal to provide a blue colorant with good color reproducibility (for example, referring to the patented technology, the exposure by ultraviolet light is poor, and the price of a sufficient raw color filter cannot be ensured. For lifting exposure steps, developing species Shaped laser beam exposure pattern 7). The laser is characterized by a mask for pattern formation which is generally used and has a large output power and is contractible. The above-described prior art, the line width sensitivity of the pixel surface or the pattern is insufficient, and the coloring photosensitive resin composition The viewpoint of the total cost of the t-color light-emitting sheet is to use a large mask (see, for example, a material that does not show a specific material, and therefore a proposal for a material. Especially in the case of a blue colored photosensitive resin composition, it is caused by After the binder resin is used, after the post-baking, the adhesive resin which is transparent to visible light will develop color, so that when the coloring pattern used for the color filter is used, there is a problem that the luminance is lowered, so There is an urgent need for a binder resin that is not colored even after baking after application. In addition, the blue colorant is absorbed at 355 nm or 365 nm. 'If exposed by ultraviolet laser light, then light Hardening cannot fully carry out the deep part of 201213355 to the colored layer, and there is a problem of wrinkle after post-baking, so it has been eager for an ultraviolet laser. 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. 9] 曰本特开 2008_5 1 866号 [Inventive content] [Problems to be solved] Straight-series colored photosensitive resin composition, high C-degree, linearity of the formed color pattern and buckled, p After the post-baking, the coloring or wrinkles are produced by the coloring of the suppression. The exhibition is suitable for use in ultraviolet laser exposure. k (, - can be formed using # a photosensitive tree The pattern of the colored pattern which is excellent in the composition of the composition is formed by the method of the eve and the 201213355 method of the double-color/de-sand filter, and provides a colored pattern having a pattern shape and a good luminance. A color filter and a display device including the color filter. [Method for Solving the Problem] The inventors of the present invention have deliberately studied the results and found that the above problem can be solved by the following method: < 1 > The photosensitive resin composition contains at least (A) a colorant, (B-1) a binder resin represented by the following general formula (I) and having an acidic group in the molecule, and (B-2) containing the following a binder resin represented by the formula (II) and a binder resin having a structural unit having an acidic group, (C) a polymerizable compound, (D) a photo-polymerization initiator, and (E) a solvent, and wherein the ratio of the (B-1) binder resin to the (B-2) binder resin on a mass basis is from 3:7 to 7:3.

In the formula (I), R3 represents a (m + n ) valent organic linking group, R4 and R5 each independently represent a single bond or a divalent organic linking group, and A2 represents at least one selected from the group consisting of organic pigment structures and impurities. Ring structure, acidic group, group having an inert nitrogen atom, a gland group, an amino phthalate group, a group having a coordinating oxygen atom, a hydrocarbon group having 4 or more carbon atoms, an alkoxyalkyl group, an epoxy group , an isocyanate group, and a partial structure of a hydroxyl group, an organic group, η of A2, R4 may be the same or different, m is 1 to 8, η is 2 to 9, and m + n is 3 Up to 10, Ρ2 is a polymer skeleton, and m of P2 and R5 may be the same or different; 201213355

3 i— V---/ ___>

RIC

— 2 — RIC^R In the formula (II), R11 to R15 each independently represent a hydrogen atom, a halogen atom, a cyano group, an alkyl group or an aryl group, and R16 represents a hydrogen atom or a fluorenyl group. The colored photosensitive resin composition of the item (1), wherein the (D) fluorene-based photopolymerization initiator is a ketone monthly loss represented by the following general formula (III) (ket ο X ime) ) Photopolymerization initiator:

〇(X)r (III) In the formula (III), R and X each independently represent a monovalent substituent, A is a divalent organic group, Ar is an aryl group, and η is an integer from 0 to 5. When X is present in plural, the plural X is each independently representing a monovalent substituent and may be the same or different. &lt; 3 &gt; The colored photosensitive resin composition of the item &lt; 1 &gt; or &lt; 2 &gt;, which is used for ultraviolet laser exposure. &lt; 4 &gt; A pattern forming method comprising: applying a colored photosensitive resin composition according to any one of items <1> to <3> to a substrate 201213355 to form a coloring layer The layer forming step, the step of exposing the colored layer to the exposed portion by exposure to ultraviolet light, and the developing step of developing and removing the uncured portion of the colored layer to form a pattern. The pattern forming method of the item <4>, wherein the ultraviolet laser has an exposure wavelength in a range of 300 nm to 380 nm. &lt;6&gt; The pattern forming method of the item &lt;4&gt; or &lt;5&gt;, wherein the ultraviolet laser is a pulse that oscillates at a frequency of 20 Hz to 2000 Hz. &lt;7&gt; A method of producing a color filter, comprising the step of forming a colored pattern on a substrate according to the pattern forming method according to any one of <4> to <6>. &lt; 8 &gt; A color filter manufactured according to the manufacturing method of the item <7>. &lt;9&gt; A display device comprising the color filter of the item &lt;8&gt; [Effect of the invention] ' According to the present invention, it is possible to provide a colored photosensitive resin composition having a high line width sensitivity The formed color pattern is excellent in linearity and scratch resistance: even after post-baking, a color pattern capable of suppressing color development or opening can be formed, and it can also be applied to ultraviolet laser exposure. Further, by using the above-described green resin composition of the present invention, it is possible to provide a pattern forming method capable of forming a coloring pattern excellent in shape and brightness, a method of manufacturing a color filter, and having a second degree of curvature A color passing film with a good coloring pattern and a display device having the color/color filter.

[Best Mode for Carrying Out the Invention] Hereinafter, a coloring photosensitive resin composition of the present invention will be described in detail for carrying out the mode of the present invention. And (B) is a binder resin having (B-1) an acid group having an acidic group in the molecule of the following formula (I) (hereinafter, the sphere is "(B-1) binder resin"), (b-2) A structural unit resin having a structure represented by 7 (Π) and a resin having an acidic group (hereinafter, appropriately referred to as "(B_2) binder"), (c) a polymerizable compound, ( D) a bismuth photopolymerization bow and (E) solvent, and wherein the (B-1) binder resin and (the mixture resin are contained in a mass ratio of 3:7 to 7:3, hereinafter, the present invention The coloring photosensitive resin composition component is described in detail. <(A) Colorant> The coloring photosensitive resin composition of the present invention contains at least a coloring agent. The content of the colored photosensitive resin composition of the present invention is preferably from 5% by mass to 6% by mass based on the solid mass fraction of the colored photosensitive resin composition (the content of the colorant is When it is less than 15% by mass, there is a possibility that the desired hue is caused, and the film thickness has to be set to be thick so as not to cause a problem, or the production interval is prolonged. In addition, the content of the toner (A) is When it exceeds 6% by mass, r is at least in the form of L and is referred to as 'the general formula------------------ To: (A) If the system is used for display, it will lead to the case that the 201213355 shadow time becomes longer and the contour shape will be the same. &amp; 曰 is again the shape of the inverted edge shape. The so-called coloring salt of the present invention is β^ ^ "Solid knives" of the resin composition 疋S month in the container made of 1 gram of the composition, at 16 〇. (: drying 60 minutes of the color of the photosensitive resin of the present invention, the color of the photosensitive resin group夕芏A 曰,, and the composition, including the color of the (E) solvent The entire composition of the resin composition. In the coloring photosensitive tree of the present invention, the phase cake in the base tree "(A) colorant is more preferably 20% by mass to 5% by mass. Solid component '0/〇 to 40% by mass β V is more preferably 25 mass (A) The colorant is suitably used from the viewpoint of heat resistance and the like, and is preferably used as a pigment. The colorant is made from organic pigments, which are made from ancient $ M i ... , , ·, ., , , machine pigments or useful particles. The one time is better than the average particle size.伟气+ Λ 至 To 'better in 〇.〇1&quot; In the scope of the present invention; ^w 0.05#m. The polymer dispersant described, the size of the pigment is:::, 'Because after use In addition, even if the color is good, the color is excellent in dispersibility, and the color is excellent in purity. The dryness is thin and can be formed in J. In the present invention, the coloring photosensitive tree is "made into eight". The pigment is such that the secondary particle size is less than the 曰.. and the total amount of the pigment contained in the product is preferably less than 1% by weight? The proportion of the pigment in the pigment of 〇.0^m is ° °: the grain is more than <in the heart t is less than 5%. -J2-

S 201213355 If the primary particle size is less than 0 · 0 2 # m of 1 Ο %, the heat resistance is good, and the ratio of the pigment which prevents the chromaticity from exceeding 0.0 8 // m is less than the coloring photosensitive resin composition The stability of the stabilizer expires. The viewpoint that the primary particle diameter is small, the pigment of 0.02# m, and the chromaticity prevention are more preferably the primary particle diameter is more than 3% of the pigment ratio of 〇_ 〇8 # m, preferably less than 3%. . The primary particle size of the pigment can be determined using TEM ( ). That is, by focusing the TEM photograph on the particle size distribution. The particle size distribution can be grasped by measuring, for example, the total number of particles in 3 to i 、 and the number of particles smaller than 〇 〇 2 // m and super. More specifically, the sub-microscope observes the long diameter of the primary powder of the pigment powder 顚 / 疋 10 〇 30,000 to 100,000 times and calculates the ratio of the primary particles of small 0 · 〇 8 // m. The operation is carried out at 3 places of the changing leaves, and the results are averaged and used as the metal compound of the inorganic pigment, the metal complex salt, etc. of the coloring agent (A), cobalt, aluminum, cadmium, lead, steel, titanium, magnesium, chromium, a compound 'and a composite oxide of the foregoing metal, and the like. The above "organic pigment" is exemplified by the case where CI·Pigment Red 1, 2, 3, 4, 5, 6, 22, 23, 31, 38, 41, 48:1, 48:2 pigment ratio is less than And if the primary particle size is 5%, the contrast is good, good, and the ratio of the difference can be prevented, and the heat resistance is less than 5%. The ratio is improved from the observation of the transmission electron microscope by image analysis, and the sample with a sample of 0.08//m is used for transmission, and the transmission type is used, and the photo is taken, then 0.02 # m and more than the powder. The body part may be exemplified by metal oxygen, specifically, oxygen of metals such as iron, zinc, and antimony such as 7'9, 10, 14, 17, 48:3, 48:4, 49, 201213355 49: 1, 49:2, 52:1, 52:2, 53:1, 57:1, 60:1, 63:1, 66, 67, 81:1, 81:2, 81:3, 83, 88, 90, 105, 112, 119, 122, 123, 144, 146, 149, 150, 155, 166, 168, 169, 170, 171, 172, 175, 176, 177, 178, 179, 184, 185 '187' 188, 190, 200, 202, 206, 207, 208, 209, 210, 216, 220, 224, 226, 242, 246, 254, 255, 264, 270 '272 '279; CI Pigment Yellow 1, 2, 3 , 4, 5, 6, 10, 11, 12, 13, 14, 15, 16, 17, 18, 20, 24, 31, 32, 34, 35, 35:1, 36, 36:1, 37, 37 :1, 40, 42, 43, 53, 55, 60, 6 1, 62, 63, 65, 73, 74, 77, 81, 83, 86, 93, 94, 95, 97, 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 148' 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193, 194, 199, 213, 214; CI Pigment Orange 2, 5, 13, 16, 17: 1, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, έ2, 64' 71, 73 CI Pigment Green 7, 10, 36, 37, 58; CI Pigment Blue 1, 2, 15, 15:1, 15:2, 15:3, 15:4, 15:6, 16, 22, 60, 64 , 66, 79, the substitution of 79 Cl substituents to OH, 80;

S -14- 201213355 C.I. Pigment Violet 1, 19, 23, 27, 32, 37, 42; C.I. Pigment Brown 25, 28, etc. Among these, the pigments which are suitable for use are as listed below. However, the invention is not limited thereto. CI Pigment Yellow 11, 24, 108, 109, 110, 138, 139, 150, 151 '154, 167, 180, 185; CI·Pigment Orange 36, 71; CI·Pigment Red 122, 150, 171, 175, 177 , 209, 224, 242, 254 '255 '264; CI Pigment Violet 19, 23, 32, 58; CI Pigment Blue 15:1, 15:3, 15:6, 16, 22, 60, 66; C · I · Pigment Green 7, 3 6, 3 7 . These organic pigments can be used in combination or in combination for improving the color purity. Specific examples of the combination are as follows. For example, "pigment for red layer (R)" can be used: lanthanide pigment, flower pigment, diketopyrrolopyrrole pigment alone or at least one of these and disazo pigments, isoindole a mixture of a yellow pigment such as a forest pigment or a quinophthalone pigment; or an anthraquinone pigment, an anthraquinone pigment, a diketone ratio, and at least one of a rhodium pigment and an anthraquinone pigment, an anthraquinone pigment A mixture of a pigment, a condensed disazo-based pigment, a red pigment such as a Biha-pyrrolidine pigment, etc., for example, a CI pigment red 177, a lanthanoid series Examples of the pigment include CI Pigment Red I" and ci·Pigment Red 224, and the condensed disazo-based red pigment is CI Pigment Red 2 4 2, and the diketone ratio is exemplified by the Ci pigment. Red 254, from the viewpoint of color reproducibility, is better than 201213355 as a mixture of CL Pigment Red 254 and CI Pigment Yellow 139 or CI Pigment Red 177. Further, the mass ratio of the red pigment to other pigments (red pigment: other pigments) is preferably from 100:5 to 1 〇〇:8 Å. If it is 1 〇〇:4 or less, it is difficult to suppress the light transmittance from 400 nm to 500 nm, and the color purity cannot be improved. Further, when it is 1 〇〇: 81 or more, there is a case where the coloring power is lowered. In particular, the mass ratio is optimally in the range of 1 〇〇:1〇 to 1〇〇%. Further, when the red pigments are combined with each other, they can be adjusted in accordance with the chromaticity. Further, the "pigment for green layer (G)" is a phthalocyanine pigment alone, or a disazo yellow pigment, a quinophthalone yellow pigment, or a methine azo yellow. A mixture of pigments or isoporphyrin yellow pigments. For example, such examples are preferably a mixture of C.I. Pigment Green 7, 36', 3/, 58 and C.I. Pigment Yellow 138, C I Pigment Yellow 139, c丨 Pigment Astragalus Pigment Yellow 180 or CM•Pigment Yellow 185. The ratio of the quality of green pigments to yellow pigments, from obtaining sufficient color purity, and suppressing from NTSC (National Television Systems Committee; 仏心(10)

TelevisionSystemC〇inmittee) The viewpoint of the shift of the target hue is preferably 1 〇〇: 5 to 100: 1 50. The quality bit is preferably in the range of 1〇〇 3〇 to 100:120. The "pigment for blue layer (B)" can be used: 酞 菁 菁 菁 alone or as a mixture with two purple pigments. For example, a mixture of c Pigment Blue 15:6 and C.I. Pigment f 23 is preferred. The blue pigment should be purple. The quality of the pigment is preferably 100:...〇〇:5〇, 1〇〇:5 100:30 〇

S -16-201213355 The color-sensitive photosensitive composition of the present invention is particularly suitable for a blue colored photosensitive composition, and since the colored layer is heated by post-baking or the like, it is not colored yellow. Particularly effective. In the present invention, in particular, the coloring agent is an organic pigment, and it is preferred to use a pigment in a micronizing step or a dispersing step to coat the pigment with a polymer compound. It is more preferable to use a pigment coated with a polymer compound to coat the pigment, which is suppressed by the formation of a secondary pigment aggregate which is finely refined, and which can be dispersed in the state of primary particles to be dispersed, and dispersed. The primary particles can stably maintain the coated pigment excellent in dispersion stability. In the present invention, the strong coating layer of the compound produced by the south molecular compounding and refining, that is, the coating of the compound of the present invention, which is an almost unsuitable mode, has a high surface activity and an electrostatic effect. Obtaining a more clear coated organic solvent to obtain free. The so-called "coating is a coating, the new interface of the pigment becomes s-molecularized, and the pigment after high dispersion stability, that is, the washed, coated pigment" is a pigment that can be forcibly mixed with the polymer. The strong coating of the pigment. Combine the highly soluble rij molecules

The "coated pigment" in the present invention is a polymer compound such as an organic pigment which has a polar group having a polar group such as a heterocyclic ring in a side chain, and is coated by the polymer compound / &quot; U-face - Part or all of the effect of high dispersion stability: and the general polymer dispersant is absorbed in the Yanmen. This state of coverage is the free amount of different knife compounds by the following right secret warriors (Free: 疋P can be determined to be forbearing. That is, only -17- borrowed and 5 times the temperature of the material is covered by the % ya 5 and the smaller the liberation rate, the dispersion stability is preferably 20. The polymer compound formed by sorption at 201213355 can be made mostly, and specifically, more than 65%, but the pigment coated on the surface as in the present invention is extremely less than 30%. The amount of free (free rate) is calculated by washing the oxy-2-propanol in the coating, that is, by adding 1 ml of 1-methoxy-2-propanol, shaking for 3 hours, and then The pigment was sedimented by a centrifugal separator at 8 hours. The amount of the free amount of the commercially available pigment such as the ratio of the mass of the solid component to the mass of the polymer compound to be treated (method of the method, that is, the sulfone monodecylcarbamide which can dissolve the pigment, Formic acid, sulfuric acid, etc. Spears J are separated by an organic solvent by cold solution, and are counted as "&amp;

The quality of the object I. Further, in addition, the amount of the polymer compound obtained by 1-methoxy-2- is divided by the mass of the polymer compound to be treated, and the coating of the pigment is more excellent. The preferred lower liberation ratio is preferably 15% or less. The washing of the organic solvent will be freed and removed. The free pigment will be used as a pigment in the chamber at 8 〇, 00 rpm. The calculated liberation rate (rate) is a high-molecular alcohol-washing pigment which can be treated with a south molecular compound after the dimethyl gluten-soluble pigment as a whole, and will be used for the detachment rate of the pigment ( %) Strong, and the dispersion range is 30 ° /. The following is ideal for 〇〇 / 〇.

S -18- 201213355 The coating treatment is preferably carried out in the step of miniaturizing the pigment by the following steps: in (i) the soluble inorganic salt, (iii) substantially no water-soluble organic solvent, And (iv) a step of obtaining a mixture by mechanical kneading, such as macromolecularization, θ Uling step))); stirring the mixture into a slurry-like group, filtering, washing, and optionally Drying with respect to the above salt mill is more specifically described below. A mixture of a stack of pigments and (u) a water-soluble inorganic salt) a water/compatibility organic solvent as a wetting agent to knead the soil 5 and then put the mixture into water to be slurried at a high speed and A is slurried. Next, the slurry is dried as needed to obtain a refined varnish which is used in a varnish to obtain a processed pigment (|cake). For the rinsing method, it is dispersed in an oily varnish. In addition, in the dispersion of water, the treated pigment does not need to be dried and can be used in varnish. By using at least a part of the solvent which is a solvent at the time of salt grinding, the (iv) polymer compound is fine, and the surface is coated with the resin and dried, and the pigment is carried out, and (ii) water &gt; valley Solution (丨丨) of the lesser, to the kneading machine (called "salt grinding step into the water, with a high step; and the step of the slurry. First, in (i) there is 1, add a small amount (iii machine, etc. Mix it with a strong mixer, etc., and wash it with water. In addition, in the case of ', you can also dry it for the filter cake (filter removes water, while the varnish is split directly on the cake) Dissolved in (iii) organic matter, you can get more pigment agglutination to less 201213355 Dan 'IV) high score; knife ten ^ compound shirt y θ „ . Add all of them, can be * 疋 can be in the salt grinding step In the initial stage, L is added in the step of $, 丨.夭. ^ 4. Addition. In addition, when it is dispersed in the polymer of the pigment, the sorbent base of the pigment may be used as long as it has For a polymer compound with a heterocyclic ring. / Pu Ke. Tejia is in the side chain The resin is also preferably used as a polymer compound which can be used for the adhesion of Β 1 1 : : : : : : : : : : : : : : : : 口 口 口 口 口 口 口#8291号# w &lt; Paragraph code [0029] to [0030], 曰本特开2 0 0 9 - 6 2 4 5 7 公郝夕£n_ ϋ Λ报的段码[0044] to [0047 In the case of using the above-mentioned coated pigment, it is more preferred to use at least one dispersant to disperse the pigment to be used as a pigment dispersion composition. Further, the dispersibility of the pigment is further increased. For example, a conventional pigment dispersant or a surfactant can be appropriately selected. Specifically, a plurality of compounds can be used, and examples thereof include, for example, organic polyoxoxime. Polymer ΚΡ341 (Shin-Etsu Chemical Co., Ltd.), (acrylic) acrylic (co)polymer POLYFLOW No. 75, No. 90, No. 95 (Chemistry) (Kyoeisha Chemical c〇., Ltd.)) W001 (Yu Shang ( "Cational surfactant" by the company (Yu sho Co., Ltd.); polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene octane Phenyl ether, polyoxyethylene fluorenyl

S -20- 201213355 "Non-ionic surfactants" such as phenyl ether, polyethylene glycol dilaurate, polyethylene glycol distearate, sorbitan fatty acid ester; W004, W005, W017 "Anionic surfactants" (such as Yusei Co., Ltd.); EFKA-46, EFKA-47, EFKA-47EA, EFKA POLYMER 100, EFKA POLYMER 400, EFKA POLYMER 4 (H, EFKA POLYMER 450 (all For Ciba Specialty Chemicals Co., Ltd., DISPERSE AID 6, DISPERSE AID 8, DISPERSE AID 15 ' DISPERSE AID 9100 (all are San Nopco Co., Ltd.) "polymer dispersant"; SOLSPERSE 3000, 5000, 9000, 12000, 1 3240, 13940, 17000, 24000, 26000, 28000, etc. Various SOLSPERSE dispersants (Sakamoto Lubrizol (shares) (Lubrizol Japan, Ltd) .)); Adekapluronic L3 1, F38, L42, L44, L6 1, L64, F68, L72, P95, F77, P84, F87, P94, L101, P103, F108, L121, P-123 ) (ADEKA Corporation) and ISONET S-20 (Sanyo Chemical Co., Ltd.) Mical Industries Co., Ltd.), DISPERBYK 101, 103 '106 '108 ' 109, 111, 112, 116, 130, 140, 142, 161, 162, 163, 164 ' 166 ' 167 ' 170 ' 171 ' 174, 176, 180' 182, 2000, 2001, 2050, 2150 (manufactured by BYK Chemie Corp.). Others include acrylate copolymers and the like, and have polarities at the molecular terminal or side chain. The content of the dispersant in the pigment dispersion composition is preferably from 1 to 丨〇〇% by mass, more preferably from 3 to 70% by mass, based on the mass of the pigment described. -21 - 201213355 A pigment derivative is one of the polymer compounds coated with a pigment, and is added to the pigment dispersion composition as needed. The pigment m having a moiety having affinity with a dispersing agent or a polar group is used on the surface of the pigment and used as a absorbing point of the dispersing agent, whereby the pigment can be dispersed in the photosensitive layer by fine particles. In the resin composition, it is possible to prevent it from agglomerating, which is effective in forming a color filter having high contrast and excellent transparency. Specifically, the "pigment derivative" is a compound in which an organic pigment is used as a matrix of the parent, and an acidic group or an organic group or an aromatic group is introduced as a substituent in the side chain. "Organic Pigment" 'Specifically,' can be cited. She is a pigment, a oligophthalocyanine pigment, an azo pigment, a t-shirt pigment, an isotreline pigment, an iso-p-phenone pigment, a quinoline pigment, Dione. It is a mixture of pigments, benzopyrene pigments, and the like. Generally, there is no T: a pale yellow aromatic polycyclic compound such as a naphthalene, an anthracene, a triazepine or a quinoline of a pigment is also included in the above organic pigment. The pigment bamboo organism can be used as disclosed in Japanese Unexamined Patent Publication No. Hei. No. 1 89732, Japanese Unexamined Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. 2005-234478, Japanese Laid-Open Patent Publication No. Hei No. Hei No. Hei. The content of the pigment derivative in the pigment dispersion composition is preferably from i% by mass to 3% by mass, more preferably from 3% by mass to 20% by mass based on the mass of the pigment. If the content is within the above range, the viscosity can be lowered while the dispersion is good, and the dispersion is improved.

S -22- 201213355 Dispersion stability' A high transmittance and excellent color characteristics are obtained, and a high contrast with good color characteristics can be formed when manufacturing a color filter. The dispersion method is carried out, for example, by premixing a pigment with a dispersant and predispersing it by a homogenizer or the like by microdispersion using a bead disperser or the like using a bead or the like. When a dye is used as the (A) coloring agent in the present invention, a uniformly colored colored photosensitive resin composition can be obtained. The dye which can be used as the (A) coloring agent is not particularly limited, and a conventional dye which has been conventionally used as a color filter can be used. For example, Japanese Laid-Open Patent Publication No. Sho 64-90403, Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. , 8〇.8,5〇1 唬, US Patent No. 5,667,920, US Patent No. 5,059,500, Japanese Patent Laid-Open No. 5_3332〇7, and Sakamoto Kaiping 6-3 5 1 83 Japanese Patent Publication No. Hei 6-51115, Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Unexamined Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Publication No. Hei 8-146215, Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. - Μ 222 Gazette, Japanese Patent Laid-Open No. 2_14223, 曰The dye described JP 8-302224, Japanese Unexamined Patent Publication No. 8_73758 -23-201213355, said present 8-1791 Laid Open Publication No. 20, this said Publication Laid-Open No. 8-151531 and the like are exposing. "Chemical structure" is available: Bisazozoline, anilinoazo, triphenylnonane, anthraquinone, acridone, benzoquinone, Oxonol. ratio. Sit three. Sitting on the azo system, ° than the ketone azo system, cyan (c y a n i n e) system, the body of the body. Dyes of more than ° 曱 曱 偶 偶, d 星 糸, S 化 糸 糸, benzoquinone α 糸 糸, 散 蓝糸寺. &lt;(Β-1) A binder resin represented by the formula (I) and having an acidic group in the molecule&gt; The (Β-1) binder resin used in the present invention is of the following formula (I) a polymer compound represented by an acid group in a molecule. The (Β-1) binder resin of the present invention has at least one acidic group in the molecule. The acidic group may be contained in the substituent Α2 in the following general formula (I), or may be included in the polymer skeleton represented by Ρ2, but from the viewpoint of efficacy, it is preferably contained in Ρ2. In the polymer skeleton shown, it is more preferable to contain an acidic group in both of Α2 and Ρ2.

In the above formula (I), R3 represents a (m + n ) valent organic linking group, and R4 and R5 each independently represent a single bond or a divalent organic linking group; and A2 represents at least one selected from the group consisting of organic pigment structures, Heterocyclic structure, acidic group, group having an inert nitrogen atom, ureido group, amino decanoic acid sulfonate group, group having a coordinating oxygen atom, hydrocarbon group having 4 or more carbon atoms, alkoxyalkylene group, epoxy Part of the structure, isocyanate group, and hydroxyl group

S -24- 201213355 Monovalent organic base table 1 to 8, which means that the high score is in the above-mentioned organic dye structure, gland base, amine is 4 or more, and hydroxy group is the same or different, that is, 7 structure, heterocyclic ring is as acidic The base group, the oxygen-containing calcined base material has the sorption, and the carbon atom of the partial dance (adsorbing s, or may also contain an organic group), and 1 to 400 linkages. That is, R疋 can be the same or different. η is 2 to q ^ θ J'm疋 to 9, m + n疋 can satisfy 3 to sub-framework, m of p2, R5 β pass U η / is the same Or different. In the formula (1), A2 is a compound containing at least ^^_, a heterocyclic ring selected from the group consisting of a heterozygous "acidic acid group, a basic nitrogen group having a basic nitrogen atom, and having a complex oxygen. : Hydrocarbyl 1 oxy (tetra), epoxy group, = acid; ^ organic group, and n of a2 can be deducted A is representative of containing at least one of the 谌 细 fine & ν, like organic pigment 冓 pain a structure having a sorption energy for a pigment, or a group having a basic nitrogen atom, a group of a hydrazine, an aminomethyl hydrazine, and an oxygen atom; The carbon number is 4, the enthalpy of the arsenic, the decidyl base, the isodecanoate group, the genus of the genus &amp; In the following, it is appropriately referred to as "the warfare / 颂 具有 具有 荽 荽 荽 荽 荽 荽 荽 荽 荽 构 构 构 构 构 构 构 构 构 。 。 。 · · · · · · · · · · · · · · · · · · · · · · In the present invention, at least two or more are included. In the present invention, "the right 曰A3 has at least one type of sorption site" - (4) the sorption site and i 3 to 20 Nitrogen atoms, one gas, 100 oxygen atoms, i 虱 atoms, and 0 to 40 bismuths, all of which are formed into a valence organic group. The portion itself -25-201213355 is a case where a monovalent organic group can be formed, and the absorbing portion itself can also represent a one-valent organic group represented by A2. First, the absorbing portion constituting the above A2 will be described below. The structure is exemplified by, for example, phthalocyanine insoluble azo, azo lake, lanthanide, quinophthalone, quaternary, and bis. The ratio of σ is greater than that of 1 series, 蒽 ° ratio. The structure of the ketone, ketone ketone ketone ketone, ketone, ketone, oxime, thioindigo is a preferred example; More preferably, the phthalocyanine system, the azo lake system, the 酉Kun series, the Erqi listener system, and the diketone group have a ratio of 11. The pigment structure of each line is preferably 酞 菁 菁, 蒽醌, and The ketone-pyrrolopyrrole-based color structure. The above-mentioned "heterocyclic structure" is exemplified by, for example, α-phene- sulene, stellate, stell. Two" f · Mao Shao, ° ratio. Sitting 0, Lin,. ratio. Sit and set. Meter. Sit, sit down today. Sai D sits, this two. Sitting, three. All diazole, ° whisper. Than ° °, ° bottom bite, two today burn, 咐 咐.荅 、 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Lin Ketone and imidazolidinone, benzothiazole, amber imine, phthalic acid naphthalene imine, hydantoin, α 啥 啥, σ card. Sitting, biting, biting ketone, and awakening are preferred examples; Biting more than 0. ratio. Sitting, ° ratio. Sitting dripping, ° ratio. sit. Fixed, 0 meters. Sitting ° sitting, ° ratio α, ° bottom °, yinlin, tower ° well, ° dense ° Ding, sent to listen, Sannitrogen 吲哚 Lin, 吲哚 吲哚 ° linkesone, benzopyrone, benzene and. Plug. Sodium, succinimide, phthalimide, naphthalene diimide, hydantoin (B). card. sit,.丫 π set, α丫 σ determinin, onion brewing. For the system, the sigma, the pigment, the sputum: the special knot, the fur, the 0 ratio, the mouth opening, the aniline, the mouth, the better, the third, the sputum

Further, the "organic dye structure" or the "heterocyclic structure" may further have a substituent, and the "substituent" may be, for example, a fluorenyl group or an ethyl group having a carbon number of 1 to 20 Carbon number of an alkyl group, a phenyl group, a naphthyl group or the like having 6 to 16 carbon atoms, a hydroxyl group, an amine group, a carboxyl group, a sulfonylamino group, an N-sulfonylamino group, an ethoxy group or the like An alkoxy group having 1 to 20 carbon atoms, a halogen group such as a gas or a bromine group, a methoxycarbonyl group, an ethoxycarbonyl group or a cyclohexyloxy group having 1 to 6 carbon atoms, an anthraceneoxy group, an ethoxy group or the like. The carbon number of the carbonyl group or the like is an alkoxycarbonyl group of 2 to 7 or a carbonate group such as a cyano group or a tertiary butyl carbonate. Here, the substituents may be bonded to an organic dye structure or a heterocyclic ring via a structural unit described below or a combination of the structural units. Η Η 〇 Ο 〇 Η Η —C- -Ο ——S——Ν- -C- -S- -S- -C=N ——C=C-

H Ο H

Η Η H

-C=C- H-C=C- -C=C-I

The above-mentioned "acid group" is exemplified by, for example, a carboxylic acid group, a sulfonic acid group, a monosulfate group, a phosphoric acid group, a monophosphate group, or a boric acid group; more preferably a formic acid group, a repeating acid group, The monosulfuric acid is a carboxylic acid group, a sulfonic acid group or a phosphoric acid group; Further, the above "base having a basic nitrogen atom" may, for example, be an amine group (mono NH2), a substituted amine group (a NHR8, a NR9R10, wherein R8, R9, and R1g are each independently represented. The alkyl group having a carbon number of 1 to -27 to 201213355 20, an aryl group having 6 or more carbon atoms, and an aralkyl group having 7 or more carbon atoms) is represented by the following formula (al), and has the following formula ( The amidinyl gr〇up represented by U f is a preferred example. R11—N 12 V~N-R1 —NH Η (a1)

R13—N (a2) wherein p 1 2 a . in the formula (al), to 20, wherein 疋 each independently represents an alkyl group having a carbon number of 1 main W and an alkyl group having 6 carbon atoms. &lt; In the formula (a2) wherein the number of aryl groups is 7 or more, the alkyl group of ri3 14 to 20 and the carbon oxime each independently represent a carbon number of 1 alkyl group. "', the above aryl group, a aryl group having a carbon number of 7 or more, - a group (-NHR8, ~ 9 is preferably an amine group (-NH2), and the substituted amine independently represents a carbon number i, here, R8, R9, and R1 are each of the above formula (al), to the alkyl group, the phenyl group, the benzyl group, and are each independently represented: a thiol group (in the formula (al)) , RU and R12 are, in the above formula (a2), to 10, a pyrene group, a phenyl group, a phenyl fluorenyl group, R14 are each independently substituted for the lung base (in the formula (a2), R13 and methyl] Etc. The alkyl group having a carbon number of 1 to 10, phenyl, benzene is particularly suitable for use of θ (—NHR8, . ' group (—NH 2 ), substituted amine group represents the carbon number i, here, R 8 , R9, and R1 G are each of the so-called (al) households, the phenyl group, the phenyl group, the phenyl group, the former 丨 表 表 自 自 from the independent generation * base (in the formula (al), R11 and R12 is an alkyl group, a stupid base, a benzyl group, which is mainly composed of eight mosquitoes.

S -28- 201213355 The pulse base represented by the above formula "2" (formula, r&quot; and ballad 4 are each independently representing a carbon number of i 1 5, a phenyl group), etc. 4 | The term "Nr15c〇Nr16r17" is as follows: wherein R', r10, and r17 each independently represent a hydrogen atom, or an alkyl group having a number of two to 20, and an aryl carbon number of 6 or more. 7: the above aralkyl group is a preferred example; more preferably - nrI5c〇nhr1 where 'R15 and R' each independently represent a hydrogen material, or an alkyl group having a carbon number of i to 1 Å, a carbon number An aryl group of 6 or more, an aryl group having a carbon number of 7 or more; particularly preferably -NHC0NHR&quot; (here, R 7 is an alkyl group representing a gas atom or an anisotropy of 1 to 10, and a carbon number of 6 The above aryl group, an aralkyl group having a carbon number of 7 or more. The above-mentioned amino phthalate group is exemplified by, for example, an NHC〇〇r18, -NR19C00r2〇, -〇c〇nhr21, -〇c〇 Nr22r23 (here

R 18

R R20, R21 22 . and R 23 are each preferably a case in which an alkyl group having 2 to 20 carbon atoms, an aryl group having 6 or more carbon atoms, and an aralkyl group having 7 or more carbon atoms are each independently preferable;佳为一NHCOOR18,一OCONHR21 (in 舲, R18 d2| e Λ ν where R and R疋 each independently represent a carbon number of from i to 20, and the number of aryl carbons having a carbon number of 6 or more is 7 or more The aralkyl 8 group) is preferably -NHC〇〇Rl8, - 〇C〇NHR21 (here, R and R21 each independently represent an alkyl group having 1 to 10 carbon atoms and a carbon number of 6 Å. An aromatic &amp; an aralkyl group having a carbon number of 7 or more. The term "having a group having a coordinating oxygen atom" may, for example, be a ketone group, a crown ether or the like.

R -29- £ 201213355 The above-mentioned "hydrocarbon group having 4 or more carbon atoms" is exemplified by an alkyl group having 4 or more carbon atoms, an aryl group having 6 or more carbon atoms, and an aralkyl group having 7 or more carbon atoms. a preferred example; more preferably an alkyl group having 4 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, etc.; particularly preferably having a carbon number of 4 to 15 An alkyl group (e.g., octyl, dodecyl, etc.), an aryl group having 6 to 15 carbon atoms (e.g., phenyl, naphthyl, etc.), an aralkyl group having a carbon number of 7 to 15 (e.g., benzoinyl, etc.) )Wait. The above "alkoxyalkylene group" may, for example, be a trimethoxy fluorene group or a triethoxy group. In the case where the occlusion site is bonded to an organic linking group, the organic linking group is preferably from 1 to 100 carbon atoms, 0 to 10 nitrogen atoms, 0 to 50 oxygen atoms, and 1 to 200. An organic linking group composed of one hydrogen atom and 0 to 20 sulfur atoms, and the organic linking group may be unsubstituted or further substituted. Specific examples of the organic linking group include the following structural unit or a group composed of the structural unit. I Η Η 1 Η 0 0 〇Η ι -ο -c- -ό- —S~ -Ν- -Ν II II —c—S— —s— —C=N—C=C— ι 1 Η II 〇 1 1 Η Η Η Η Η -c: =Ν- -ό= =C- -ό: :c-- -ό= c- HC=C-- c=c- 1 Η

When the above-mentioned organic linking group has a substituent, the "substituent" may, for example, be an alkyl group having a carbon number of 1 to 20 such as a mercapto group or an ethyl group, a phenyl group, a naphthyl group or the like. a fluorenyl group having 1 to 6 carbon atoms, such as an aryl group having 6 to 16 carbon atoms, a hydroxyl group, an amine group, a carboxyl group, a sulfonylamino group, an N-sulfonylguanamine group, an ethoxylated group or the like. The alkoxy group having 1 to 6 carbon atoms such as an oxy group or an ethoxy group, a halogen atom such as a gas or a bromine group, a methoxycarbonyl group, an ethoxycarbonyl group, a cyclohexyloxycarbonyl group or the like has a carbon number of 2 to 7 A carbonate group such as an alkoxycarbonyl group, a cyano group or a tertiary butyl carbonate. In the above, the above A2 is preferably one of the sites containing at least one selected from the group consisting of an organic dye structure, a heterocyclic structure, an acidic group, a group having a basic nitrogen atom, a urea group, and a hydrocarbon group having 4 or more carbon atoms. Organic base. The above A2 is more preferably a one-valent organic group represented by the following general formula (4).

In the above formula (4), B1 represents the sorption site (that is, selected from the group consisting of an organic dye structure, a heterocyclic structure, an acidic group, a group having a basic nitrogen atom, a urea group, a urethane group, a group having a coordinating oxygen atom, a hydrocarbon group having 4 or more carbon atoms, an alkoxyalkyl group, an epoxy group, an isocyanate group, and a hydroxyl group), and R24 represents a single bond or an (a+ 1 ) valence organic linking group. ; a is an integer representing 1 to 10, and a of B1 may be the same or different. The absorbing portion represented by the above B 1 is the same as the absorbing portion constituting A2 of the above formula (1), and preferred examples are also the same. 201213355 It is preferably a site selected from the group consisting of an organic dye structure, a heterocyclic structure, an acidic group, a group having a basic nitrogen atom, a urea group, and a hydrocarbon group having 4 or more carbon atoms. R24 represents a single bond or an (a+1)-valent organic linking group, and a represents 1 to 10; preferably a is 1 to 7, more preferably a is 1 to 5, and particularly preferably a is 1 to 3. The (a+1)valent organic linking group is exemplified by 1 to 100 carbon atoms, 0 to 10 nitrogen atoms, 0 to 50 oxygen atoms, 1 to 200 hydrogen atoms, and 0 to 20 a group of sulfur atoms, and may be unsubstituted or further substituted. The above (a+1)-valent organic linking group, specific examples thereof may be exemplified by the following structural unit or a group in which the structural unit is combined (may also form a ring structure).

I Η Η I Η Ο Ο Ο Η I

—C—C—C—〇—S—Ν—Ν—C—I 1 Η

III I I Η II II 1 I

R24 is preferably a single bond, or from 1 to 50 carbon atoms, 0 to 8 nitrogen atoms, 0 to 25 oxygen atoms, 1 to 100 hydrogen atoms

(a+1)-valent organic linking group composed of S-32-201213355 and 0 to 1 sulfur atom, more preferably a single bond, or from 〗 〖To 3 碳 carbon atoms, 〇 to 6 nitrogen (a+1)valent organic linking group consisting of 15 atomic oxygen atoms, 1 to 5 atomic hydrogen atoms, and argon to 7 sulfur atoms, particularly preferably a single bond, or 1 to 丨(a + 1 ) valence organic link composed of one carbon atom, five nitrogen atoms, one to one oxygen atom, one to three hydrogen atoms, and five to five sulfur atoms base. In the above, when the (a+丨)valent organic linking group has a substituent, the "substituent" may be an alkyl group having a carbon number of 1 to 20 such as a mercapto group or an ethyl group, or a phenyl group. a naphthyl group having a carbon number of 6 to 16 such as an aryl group, a hydroxyl group, an amine group, a carboxyl group, a sulfonylamino group, an N-sulfonylguanamine group, an ethyl ethoxy group, etc., having a carbon number of 1 to 6 The number of carbon atoms such as an alkoxy group having 1 to 6 carbon atoms, a halogen atom such as a gas or a bromine group, an ethoxycarbonyl group, an ethoxycarbonyl group or a cyclohexyloxycarbonyl group, such as an oxy group, a decyloxy group or an ethoxy group. In the above formula (I), R4 and R5 each independently represent an alkoxycarbonyl group of 2 to 7 or a cyano group, and a divalent organic link. base. η of R4 can be the same or not. , 冋. In addition, 'm' of R5 may be the same or different. The carbon atom to 2 Å and may be an undivalent organic linking group may be exemplified by 丨 to 1 、, 0 to 10 nitrogen atoms, 0 to 50 oxygen atoms, hydrogen atoms of i, And a group consisting of 0 to 20 sulfur atoms, substituted or further substituted. Specific examples of the monovalent organic linking group described below may be exemplified by a structural unit or a group composed of the structural unit. -33- 201213355

V C - I -S=c— - H-C-ο--H- - H=c H-c-H H-C

I - h-n I ouc

C-H II H-C I I N II H-C I〇-s-=o I OMS

R, preferably a single bond 'or by! a divalent organic link consisting of 5 carbon atoms, argon to 8 nitrogen atoms, 0 to 25 oxygen atoms, i to 1 hydrogen atoms, and 0 to 1 sulfur atoms More preferably a single bond, or from ii 30 carbon atoms, hydrazine to 6 nitrogen atoms, 0 to 15 oxygen atoms, i to 50 gas atoms, and 〇 to 7 sulfur atoms a divalent organic linking group; particularly preferably a single bond, or a carbon atom of 1 to 10, a nitrogen atom of 5 to 5, an oxygen atom of 1 to 30, a hydrogen atom of 1 to 30, and A divalent organic linking group composed of five sulfur atoms. In the above, when the divalent organic linking group has a substituent, the "substituent" may be, for example, a fluorenyl group such as a fluorenyl group or an ethyl group, and a phenyl group such as a phenyl group or a naphthyl group. The aryl group having a carbon number of 6 to 16 or a thiol group having a carbon number of from 6 to 16 such as a carboxyl group, an amine group, a carboxyl group, a sulfonylamino group, an N-sulfonylguanidino group or an ethoxycarbonyl group; The carbon number of the alkoxy group having a carbon number of 1 to 6 such as a methoxy group or an ethoxy group, a halogen atom such as a gas or a bromine group, a methoxy rotyl group, an ethoxycarbonyl group or a cyclohexyloxycarbonyl group is A carbonate group such as an alkoxy group of 2 to 7, a cyano group, a butyl butyl carbonate or the like. In the general formula (I), 'R3 is a (m+n)-valent organic linking group. m + n can satisfy 3 to 10. S -34- 201213355 The (m + n ) valence organic linking group represented by the above R3 is exemplified by: 1 to 60 carbon atoms, 0 to 10 nitrogen atoms, 0 to 50 oxygen atoms, 1 Specific examples of the (m + n )-valent organic linking group of the above-mentioned (m + n )-valent organic linking group may be enumerated as a group consisting of 100 hydrogen atoms and 0 to 20 sulfur atoms, and may be unsubstituted or further substituted. : The structural unit described below or a group composed of the structural unit (which may also be a ring structure). I Η Η I Η Ο Ο Η Η ι

I ι ι I ι π ιι ιι ι I

The (m + n ) valence organic linking group preferably has from 1 to 60 carbon atoms, from 0 to 10 nitrogen atoms, from 0 to 40 oxygen atoms, from 1 to 120 hydrogen atoms, and from 0 to 10 a group consisting of sulfur atoms; more preferably 1 to 50 carbon atoms, 0 to 10 nitrogen atoms, 0 to 30 oxygen atoms, 1 to 100 hydrogen atoms, and 0 to 7 a group consisting of sulfur atoms; particularly preferably 1 to 40 carbon atoms, 0 to 8 nitrogen atoms, 0 to 20 oxygen atoms, 1 to 80 hydrogen atoms, and 0 to 5 The group consisting of sulfur atoms. -35-201213355 In the above, when the (m + n )-valent organic linking group has a substituent, the "substituent" may, for example, be an alkyl group having 1 to 20 carbon atoms such as a methyl group or an ethyl group. The carbon number of the aryl group, the trans group, the amine group, the thiol group, the acid-reductive amine group, the N-continuous acid amine group, the ethoxy group, etc. having a carbon number of 6 to 16 such as a phenyl group or a naphthyl group. a halogen atom having 1 to 6 carbon atoms, a halogen atom such as a gas or a bromine group, a methoxycarbonyl group, an ethoxycarbonyl group or a cyclohexyloxy group having 1 to 6 carbon atoms, a methoxy group, an ethoxy group or the like. The carbon number of the carbonyl group or the like is an alkoxycarbonyl group of 2 to 7 or a carbonate group such as a cyano group or a tertiary butyl carbonate. Specific examples (specific examples (1) to (17)) of the (m + n )-valent organic linking group represented by the above R3 are shown below. However, the present invention is not limited to these.

II U -CH2-CH2-C-〇-CH2^ ^C^-OC-CHj-CHj- h3c-ch^ vch2-oc-ch2-ch2--ch2-co-ch2 xh2-oc-ch2-(1) (2 H3C-CHf xCH2-〇-C-CH2--CH2-CH2-NH-C-0-CHj,CH2-0-C-NH-CHi-CH^-bis(3)H3C-CH2 vch2-oc-nh-ch2 -ch2- -ch2-ch2-oco-ch2 xh2-o-6-o-ch2-ch2- 乂(4) H3C-CH2 ch2*oco-ch2-ch2- I CH2-CH2-CH2-CH2-NH-C -〇-CH2-CH2- (7)

M丄WO^Nv^O (6) O^N^O (5) 丫丫ο V r ο · —CH2-CHiNYN, CH2-CH2-—CH2-CH2-〇-C-HN-CH2-CH2Ny N'CH2-CH2- NH-C-〇-CH2-CH2- r\ r\ /CH2 勹xCH2 •0.rj^Xr

'CH (8) , ch2

•ch2 HN.^OCHiNT^T

, CH (9) , XH, s -36- (11) 201213355 ο ο —CHg-C-0~CH2 -CHj-OC~CH2— , C&quot;^ -CH2-C-〇-CHr VCH2-0-C -CH2-o o -ch2-ch2-co-ch2 ch2-oc-ch2-ch2-, c, -CH2-CH2-C-〇-CH^ ^cH2-〇-C-CH2-CH2- ό 0 -CH2 -CH2-NH-C-〇-CH2\ /CH2-0-C-NH-CH2-CH2- ~ch2-ch2-nh-co-ch^ ^ch2-oc-nh-ch2-ch2- 6 〇oo CH2-CH2—0-CN^Siix^C~〇-CH2-CH2—(12) TT 03) o 6 op ~CH2—CH2'0-Cx-0^Si^C-〇-CH2'CH2--CH2 -CH2-〇-p 人Y^-〇-CH2-CH2· oo ~'CHj-CH2_0~C 0 oo -ch2-ch2-co-ch2 ch2-oc-ch2-ch2- 9 .ch2^ Nsch2-oc- Ch2-ch2--ch2-ch2-co-ch2 ch2-o ^ , c' -CH2-CH2-C-〇-CH2^ ^CH2*〇-C-CH2-CH2- ¢16) δ 0 -CH2-CH2 /CH2-CH2-, (i5) -ch2-ch2 ch2-ch2- I &gt; •N,,夂N -CH2-CH^ \cH2-CH2- -ch2-co-ch2 .ch2 ch2-co-ch2 Ch2-oc-ch2-)cC 〇/CH2 CHj-O-C-CH2--CHz-C-0-CH2 II * o CH2~〇~C-CH2 (17) In the above specific examples, from the raw material From the viewpoints of availability, ease of use, and solubility in various solvents, the optimum (valent) organic linking group is the following group. m + n -ch2-ch2-co-ch2 /ch2-oc-ch2-ch2- H3C-CHrCvCH2-〇-C-CH2-CH2- (1) —ch2-co-ch2 ,ch2-oc-ch2- H3c-ch; (2) ch2-oc-ch2- o -ch2-ch2-co-ch2 ch2-oc-ch2-ch2-xc' -ch2-ch2-co-ch^ ^ch2-oc-ch2-ch2- o o (Π) —CH2-C-0_CH2 XH2~〇—c_ch2—〇M /CHf, CH2-〇-C-CH2- _CH2-C-〇-CH2\ /CH2-0 ^ One CH〗-C_0_CH^&quot ;,CH;[-〇_C-CH2_ η n C17) -CH2-C-〇-CH2, /CH2-0-C-CH2--ch2-co-ch^ xch2-oc-ch2- oo -ch2- Ch2-co-ch2 ch2-oc-ch2-ch2-o ^ch2-oc-ch2-ch2- -CH2-CH2-C-〇-CH2 CH2-0 o , c'-CH2-CH2-C-〇-CHr CH2-〇-C-CH2-CH2- (16) In the above formula (I), m represents 1 to 8. m is preferably 5, more preferably 1 to 4, particularly preferably 1 to 3. Further, in the above formula (I), η represents 2 to 9. η is more than 2 to 8, more preferably 2 to 7, and particularly preferably 3 to 6. Further, the oxime 2 in the general formula (I) represents a polymer skeleton, and is selected from a conventional polymer or the like according to the purpose and the like. m of 2 can be either or different. 1 to good for the same reason 37- 201213355

In the polymer-graft copolymer of the south molecular vinyl monomer, the amino phthalic acid, the polyoxyl group containing the polyether/poly monomer: more preferably selected from the group consisting of a molecule, an ether-based high-mass or a copolymer The polymer of the monomer is more likely to be dispersed and stabilized than the organic solvent. In the present invention, at least one acid in the south molecule can be used by utilizing cross-linking, as will be described later, from the viewpoint of cost, acidity. The base model. Here, "酉. The list is listed as Z. The choice of 糸rlj is divided into points. For example, a vinyl polymer, a lower ester type, and a higher vinyl group. If used together, it cannot be confirmed: Constituting polymer bone, = or copolymer 1 series polymer: 酉 糸 糸 two molecules, aerospace / polymer, Γ 糸 polymer, epoxy, A ® wenbei or copolymer * base &quot; , poly-copolymer, etc. (Yiguang 'Hesheng's self-contained Baike U is made of ': a polymer or copolymer of a dilute monomer, a knife, a broad-based vinegar-based polymer, and a group of such At least or copolymer in the group. To - especially good for the above-mentioned high scores early π ^ sub- 〉 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷 谷In the case of a weak absorbing layer, a sufficient absorbing layer is required. Among them, a polymer bony group represented by P2 is preferred. The method of introducing a human acid group in the skeleton is a vinyl group having no specific acidic group. a method of introducing a body, a side chain to add an acidic group, and a method of introducing it, etc., and introducing a quantity from the @九性基The viewpoint of the ease of synthesis and the synthesis is preferably that the polymer skeleton is formed by a structural unit derived from a monomer having a radical monomer, and the acidic group is introduced in the same manner as in the above-mentioned A2. The base J is preferably a carboxyl group.

-38- 201213355 The above "ethylene monomer" is not particularly limited, for example, (mercapto) acrylates, crotonates, vinyl esters, enedic acid diesters, fumaric acid Diesters, itaconic acid diesters, acrylamides, styrenes, vinyl ethers, ethylenes, olefins, maleimide, (mercapto) acrylonitrile are acidic Based on vinyl monomers and the like. In the following, preferred examples of such vinyl monomers are given. Examples of the "(meth) acrylates" include: () decyl acrylate, ethyl (meth) acrylate, (meth) propyl propyl acrylate, isopropyl (meth) acrylate, (fluorenyl) Acrylate, isobutyl (meth)acrylate, tertiary (meth)acrylic acid, amyl (meth)acrylate, n-hexyl (meth)acrylate, cyclohexyl acrylate, (mercapto)acrylic acid 2-ethylhexyl hexylcyclohexyl (meth) acrylate, tertiary ((meth) acrylate, dodecyl (meth) acrylate, 18 (meth) acrylate, acetamidine (meth) acrylate Oxyethyl ester, (meth)acrylic acid, 2-hydroxyethyl (meth)acrylate, 2-propyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, (mercapto) propylene Hydroxybutyl ester, 2-methoxyethyl (meth)acrylate, 2-(2-decyloxy)ethyl (meth)ethyl 2-ethoxyethyl acrylate (meth) 3-phenoxy-2-hydroxypropyl acrylate, 2-chloroethyl acrylate, glycidyl (meth) acrylate, methacrylic acid -3,4-epoxycyclohexylmethyl ester, (mercapto) acrylate, (mercapto)acrylic acid-2-phenylvinyl ester, (mercapto) propylene is preferably cis-butyl ketone N-butyl butyl acrylate (methyl ester, octyl ester acetophenone hydroxy acid 4- 4-) propylene ethoxy (methyl methacrylate-1-39-201213355 acrylate, (mercapto) allylic acrylate, (fluorenyl)-2-allyloxyethyl acrylate, propargyl (mercapto) acrylate, benzoyl (meth) acrylate, diethylene glycol decyl ether (mercapto) acrylate, ) Diethylene glycol monoethyl ether acrylate, triethylene glycol monomethyl ether (meth) acrylate, triethylene glycol monoethyl ether (meth) acrylate, polyethylene glycol (meth) acrylate Ethyl ether ester, polyethylene (ethyl methacrylate) monoethyl ether ester, β-phenoxy ethoxyethyl (meth) acrylate, decyl phenoxy ethylene glycol (meth) acrylate , (fluorenyl) dicyclopentenyl acrylate, dicyclopentenyloxyethyl (meth)acrylate, trifluoroethyl (decyl) acrylate, octafluoropentyl acrylate , (fluorenyl) perfluorooctyl ethyl acrylate, dicyclopentanyl (meth) acrylate, tribromophenyl (meth) acrylate, tribromophenoxy (meth) acrylate, (曱Examples of the "crotonate" include butyl crotonate and hexyl crotonate. Examples of "vinyl esters" are exemplified by vinyl acetate. Ester, gas vinyl acetate, vinyl propionate, vinyl butyrate, vinyl oxyacetate, vinyl benzoate, etc. Examples of "succinic diesters" are: Examples of the "fumarate diester" such as dinonyl phthalate, diethyl maleate, and dibutyl maleate are exemplified by diammonium fumarate. Examples of the "Ikonic acid diester" such as an ester, diethyl fumarate, and dibutyl fumarate include dinonyl isonate and diethyl itaconate. And dibutyl acetylate and the like.

S -40- 201213355 "(Indenyl) acrylamide" is exemplified by decylamine, N-methyl(fluorenyl) acrylamide, N-acetamide, N-propyl (decyl) acrylamide , N-isodecylamine, N-n-butyl(decyl)acrylamide, acrylamide, N-cyclohexyl(meth)acryloxyethyl)(fluorenyl) acrylamide, hydrazine , Ν-dienylamine, hydrazine, hydrazine-diethyl(fluorenyl) acrylamide, acrylamide, hydrazine-nitrophenyl acrylamide, hydrazine-; decylamine, hydrazine-benzyl group Acrylamide, (morpholine, diacetone acrylamide, hydrazine-hydroxymethylpropenyl acrylamide, vinyl (fluorenyl) acrylamide (fluorenyl) acrylamide, hydrazine-allyl ( Examples of "styrenes" include benzoic acid, dinonyl styrene, trimethyl styrene, ethyl styrene, butyl styrene, hydroxystyrene, butoxy styrene. Ethyl styrene styrene, gas phenylene, bromostyrene, gas sulfenyl styrene, hydroxystyrene protected by a removable group such as a tertiary butoxycarbonyl group (t-Boc: t, etc.) Vinyl benzyl benzene Etc. Examples of "vinyl ethers" are: ethyl vinyl ether, 2-gas ethyl vinyl ether, hydroxyl, propyl vinyl ether, butyl vinyl ether, hexyl vinyl ether, methoxy Ethyl ethyl vinyl ether and phenyl: (fluorenyl) propenyl (fluorenyl) propyl propyl (fluorenyl) propane N-tertiary butyl (nonylamine, N-(2-methylindenyl) C, N-phenyl (fluorenyl L-N-phenylacryloyl) propylene decyl amide, N-hydroxyethyl, hydrazine, hydrazine-diallyl acrylamide, etc. Ethylene, fluorenyl Phenylethyl styrene, isopropoxy styrene, ethylene, diethylene glycol, deprotected from acidic substances - butoxycarbonyl) methyl formate, and α-mercapto vinyl ether, ethyl ethyl thiol vinyl Scale, octyl vinyl ether, etc. -41 - 201213355 Examples of the "vinyl ketone" include methyl vinyl ethyl vinyl ketone, propyl vinyl ketone, phenyl vinyl ketone, and the like. Examples of the "class" include ethylene, propylene, isobutadiene, isoprene, etc. Examples of "m-butylene imines" are exemplified by: , butyl maleimide, cyclohexyl maleimide, phenyl maleimide, etc. (fluorenyl) acrylonitrile, vinyl is substituted (for example, vinyl) Pyridine, N-vinylpyrrolidone, vinylazole, etc.), N-vinylamine, N-vinylacetamide, N-ethylidene, ethylhexyl vinegar, etc. In addition to the above compounds It is also possible to use, for example, a functional alkenyl monomer having an amine group, a ureido group, an indoleamine group, a S group group, a quinone imine group, etc., such as an amine phthalate group or a ureido group. The mixture may be suitably formed by an addition reaction of an isocyanate group with a hydroxyl group or an amine group. Specifically, it may be a combination of a monomer having an isocyanate group and a compound having a hydroxyl group or a primary or secondary amine group. The addition reaction or the monomer having a hydroxyl group or the addition reaction of a primary or secondary amine monomer with a monoisocyanate is appropriately synthesized. Next, a vinyl monomer having an acidic group will be described by introducing an acidic group into the polymer skeleton P2. Examples of the above-mentioned "vinyl monomer having an acidic group" may be: a vinyl monomer having a slow group or a vinyl group having a carboxyl group; a "vinyl monomer having a carboxyl group" is exemplified: For example, a olefinic acid, a vinyl benzoic acid, a maleic acid (maleic acid), a cis ketone, a butenyl diimine heterocyclic sulfonium carboxylic acid, for example, a base of a compound Listed.) Propylene

S-42- 201213355 Dialkyl monoacid, fumaric acid (fumaric acid), itaconic acid, crotonic acid, cinnamic acid, acrylic acid dimer, and the like. Further, it is also possible to use a monomer having a hydroxyl group such as 2-hydroxyethyl acrylate or a cyclic anhydride such as maleic anhydride or phthalic anhydride or cyclohexane dicarboxylic anhydride. The reactants, ω-rebel-polyhexyl vinegar-(meth)acrylic acid, and the like. Further, an anhydride-containing monomer such as maleic anhydride, itaconic anhydride or citraconic anhydride may be used as the carboxyl precursor. Further, among these, from the viewpoints of copolymerizability, cost, solubility, and the like, (meth)acrylic acid is particularly preferable. In addition, the "vinyl monomer having a sulfonic acid group" may, for example, be 2-propenylamine-2-mercaptopropanesulfonic acid or the like; and the "vinyl monomer having a phosphate group" may be exemplified by phosphoric acid (2). - propylene methoxyethyl ester), mono(1-methyl-2-propenyloxyethyl phosphate), and the like. Further, the "vinyl monomer having an acidic group" may be a vinyl monomer containing a phenolic hydroxyl group or a vinyl monomer containing a sulfonamide group. In the case where the polymer skeleton Ρ 2 contains a structural unit derived from a vinyl monomer having an acidic group, the content of the structural unit derived from the vinyl monomer having an acidic group in the polymer skeleton is preferably 3 mol. % to 40% by mole, more preferably in the range of 5 moles to 20 moles. Among the polymer compounds represented by the above formula (I), it is preferable to satisfy all of R3, R4, R5, Ρ2, m, and η shown in the following 〇R3: the above specific examples (1), ( 2) , ( 1 0 ), ( 1 1 ), (:16), or (17) °

S -43- 201213355 R4: Single bond, or "1 to 10 carbon atoms, 0 to 5 nitrogen atoms, 0 to 10 oxygen" composed of the following structural units or a combination of the structural units a divalent organic linking group composed of an atom, one to 30 hydrogen atoms, and 0 to 5 sulfur atoms (may also have a substituent, and the "substituent" is exemplified by, for example, fluorenyl group and ethyl group. An aryl group having a carbon number of 1 to 20, a phenyl group, a naphthyl group or the like having 6 to 16 carbon atoms, a transamination group, an amine group, a thiol group, an acid group, and an N-continuation group. An alkoxy group having 1 to 6 carbon atoms such as an alkoxy group, an ethoxy group or the like having a carbon number of 1 to 6 or a methoxy group such as a methoxy group or an ethoxy group; The carbonic acid group such as a carbonyl group, an ethoxycarbonyl group or a cyclohexyloxycarbonyl group having 2 to 7 carbon atoms, a cyano group or a carbonate group such as a butyl cyanocarbonate. Η Η Ο Η Η Η —C- 一〇—一S—Ν C——C~C--C~C—

I I

Η H H H~C=C--C=C-

R5: a single bond, an ethyl group, a propyl group, a group (a), or a group (b) below. Further, in the following group, R12 represents a hydrogen atom or a methyl group, and 1 represents represents 1 or 2. 〇9 -CH2-CH-C-〇-CH2-CH-CH2-〇-C-(CH2)- (8) R12 0H 1 0 —CH2_CH-C_〇_CH2-CH2— (b) R12 s -44- 201213355 2 P. a copolymer of a vinyl monomer having a carboxyl group and another vinyl monomer; a polymer or copolymer of a vinyl monomer having no acidic group; an ester oxime molecule, an ether polymer, and an amine selected from the group consisting of a bismuth phthalate-based polymer and such a modified substance, and may also contain a high score of at least one acidic group - 〇m : 1 to 3 〇 η : 3 to 6 〇 in the (Β -1 ) bonding of the present invention The content of the acidic group in the resin can be appropriately determined depending on the acid value of the (Β -1 ) binder resin. (Β-1) The acid value of the binder resin is preferably from 3 Torr to 2 Torr (mgK 〇 H/g), more preferably from 40 to 160 (mgKOH/g), particularly preferably from 50 to 120 (mgKOH/g). ). When the acid value is less than 30 (mgKOH/g), the alkali developability of the colored photosensitive resin composition may be insufficient, and if the acid value is more than 200 (mgKOH/g), a pigment is used. (A) In the case of a coloring agent, there is a concern that the dispersibility and dispersion stability of the pigment may be adversely affected. The molecular weight of the (B-1) binder resin is preferably from 3,000 to 100,000, more preferably from 5,000 to 80,000, particularly preferably from 7,000 to 60,000, in terms of weight average molecular weight. When the weight average molecular weight is within the above range, the effect of the plurality of adsorption sites introduced at the end of the polymer can be sufficiently exhibited, and the adsorption property on the solid surface, the cell formation ability, and the interface activity are excellent. Performance. Hereinafter, the exemplified compound of the (B_丨) binder resin of the present invention will be listed, but the present invention is not limited thereto, and any structure may be adopted as long as it is contained in the formula (I). -45 - 201213355

-46- 201213355

-47 - 201213355

HOjC

H02C HOjC' (Β-l) binder resin structure

pV Molecular Weight -R3-S^^t JrA2 co2ch3 co2h (n=3.5, m=2.5) R3= CH2~CH2—d-O-CHj CH2~0~0~CH2~CHj— '

—CH2-CH2-C-〇-CHi O

H02C (B-l-22) ho2c* 90:10 25000 :h;5 pH} CH2~0~C&quot;*CH2~CH2~ 2, 严-0 CHj-O-* C-CHj-CH2-

JrA2 [ co2ch3 co2h (ns3.5, m=2.5) R3= O _ —CH2-CH2-ii-0-CH2v ^CH2-0-^-CH2-CH2- 0 ch2 'ch2-oc-ch2-ch2- — CH2-CH2-C-0-CH2x p\r-0 ° —CH2-CH2-C-0-CHr CH2-0-C-CH2-CH2- ό 0 ho2c co2ch3 co2h 95:5 25000 11 (ns3.5, m=2.5) R3= (Bl-22) 0 O -ch2-ch2-co-ch2v ^ch2-oc-ch2-ch2-di2 'ch2-oc-ch2-ch2- —CH2-CH2-S-0-CH2 /CH2-0' 6 -ch2-ch2-co-ch^ vch2-oc-ch2-c h2— δ 6 90:10 20000 In the above-mentioned (B -1 ) binder compound, in the polymer skeleton The content ratio of the structural unit having a carboxylate to the structural unit having a carboxyl group (P1: P2) is preferably in the range of 95:5 to 80:20 in terms of mass. Among the above-exemplified compounds, a content ratio of a structural unit having a carboxylate in a polymer skeleton and a structural unit having a carboxyl group in a structure represented by the above B-1-22 is particularly preferable. In the case of a conversion, a compound having a molecular weight of 20,000 and an acid value of 82 is 90:10.

S-48-201213355 The (B-1) binder resin represented by the above formula (1) is synthesized by, for example, the method disclosed in JP-A-2006-278118. In the colored photosensitive resin composition of the present invention, the (B-1) adhesive resin is a solid knife of the coloring photosensitive resin composition, and the solid knife of the coloring photosensitive resin composition is more than the main + r 10 The range of 5 mass% to 70 mass% is more preferably in the range of <b shellage% to 50 mass%.义(Β·;2) Person 3 has a structural unit represented by the general formula (Π) and a binder resin having a king base of „ , , , , , , , , , , , , , , , , , , , , , , , , , , The system comprises: (Β-2) having the following structural units represented by the formula (10), (4), and a binder resin having an acid group retention-early 7 C JS ^ΐϊ ^ Qiao (Π) Representative structural unit] {ch2—CR16^— C=〇(II) r14 R13 R11

III 〇-c-c = c R15 R12 In the formula (n), Rl1 to R15 each independently represent a hydrogen atom, a cyano group, an alkyl group or an aryl group, and R10 represents a hydrogen atom or a ruthenium atom. R1 to R15 in (u) are preferably each independently a dentin atom, a cyano group, an alkyl group having a carbon number of 1 to 12, or a carbon which can be synthesized in an acid containing a hydrogen number of -49-201213355. The aryl group of 5 to 14, more preferably a hydrogen atom, a bromine atom, a gas atom, a cyano group, an alkyl group having 1 to 7 carbon atoms or an aryl group having 5 to 10 carbon atoms. The alkyl group may have a substituent, and the substituent may be a straight chain, a branch, or a ring, and examples thereof include a decyl group, a n-propyl group, an isopropyl group, a tertiary butyl group and the like, and preferably a carbon number. It is an alkyl group of 1 to 7. Further, the above aryl group may have a substituent, and the substituent may, for example, be an alkyl group having 1 to 7 carbon atoms or an aryl group having 5 to 14 carbon atoms, and the like, preferably a phenyl group, a furyl group or a naphthyl group. . Among these, as the general formula (II), it is preferred that R11 to R15 are each independently a hydrogen atom, a fluorenyl group, a phenyl group or an il atom, and R16 is a hydrogen atom or a fluorenyl group. (B-2) The binder resin may contain a plurality of structural units represented by the above formula (II). In the (B-2) binder resin, the structural unit represented by the above formula (II) is preferably contained in the molecule in an amount of 20 mol% or more and 90 mol% or less, more preferably 50 mol%. The above 80 mol% or less, and more preferably 60 mol% or more and 80 mol% or less. In the binder resin, when the total amount of each of the above structural units is within the above range, the development latitude becomes good, the film reduction at the time of development after exposure is small, and the surface of the obtained cured film is smooth. Sex becomes good. [Structural unit having an acidic group] Further, the (B-2) binder resin contains a structural unit having an acidic group in the molecule. The structural unit having an acidic group is a structural unit derived from an unsaturated monomer having a carboxyl group. "Carboxy unsaturated monomer" is available

S -50- 201213355 Listed: "unsaturated monocarboxylic acids" such as acrylic acid, mercaptoacrylic acid, crotonic acid, α_gas acrylic acid, cinnamic acid, etc.; maleic acid (maleic acid), maleic anhydride, Unsaturated carboxylic acid or its anhydrides such as anti-succinic acid (fumaric acid), itaconic acid, itaconic anhydride, stanganic acid, citraconic anhydride, mesaconic acid, etc.; a polycarboxylic acid or an anhydride thereof; succinic acid mono-2-(indenyl) propylene oxyethyl ester, phthalic acid mono [2-(indenyl) propylene oxyethyl ester] One of the divalent or higher polycarboxylic acids [(indenyl) acryloxyalkyl] ester; poly(indenyl)acrylic acid ω-carboxycaprolactone and the like having a carboxyl group and a transbasic group at both ends One of the molecules (mercapto) acrylates and the like. Among these unsaturated monomers containing a buffer group, mono(2-propenyloxyethyl) succinate and mono(2-propenyloxyethyl) phthalate are respectively The trade names of -5300 and Μ-5400 (made by Toagosei Co., Ltd.) are sold on the market. The above carboxyl group-containing unsaturated monomer may be contained in the resin singly or in combination of two or more. Among these, the preferred structural unit having an acidic group is a chalcogen analog derived from a slow acid, a reductive acid, a slow-radical acid [RC(= ΝΝΗ2)0Η], a carboxyimidic acid [RC] (=NH)OH], sulphuric acid [rs(〇)2〇h], sulfinic acid [RS(0)0H], sulfenamide [RS0H], decanoic acid [RSe(0)20H], selenite [RSe(0)0H], selenate [RSeOH], phosphoric acid and its acid-related compounds, structural units of citric acid, boric acid analogs; particularly preferred are structural units derived from acrylic acid, methacrylic acid, and acid . The content of the structural unit having an acidic group in the (B - 2 ) binder resin is preferably 5 mol% or more and 50 mol% or less, more preferably 1 mol% % -51 - 201213355 or more. %the following. When it is in this range, the surface smoothness and heat resistance are good. (Β-2) The binder resin is in addition to the aforementioned structural units to further contain other structural units. The other structural unit is a structural unit which can cite a source of an unsaturated monomer. Styrene, α-mercaptostyrene, o-vinyltoluene, m-nonylbenzene, p-vinyl toluene, p-chlorostyrene, o-methoxybenzomethyleneoxystyrene, p-nonyloxystyrene, o-ethylene Phenyl phenyl ether, m-vinyl benzoyl methyl ether, p-vinylphenyl fluorenyl, o-vinyl benzoyl epoxy propyl ether, m-vinyl benzyl ether, p-vinyl benzoyl ring "Aromatic compound" such as oxypropyl ether; "anthracene" such as hydrazine, 1-mercaptopurine, etc.; (fluorenyl methacrylate), n-propyl (meth) acrylate), (A) Isopropyl acrylate, (n-butyl acrylate, isobutyl (meth) acrylate, (dibutyl methacrylate, butyl ketone), 2-hydroxyethyl methacrylate , (mercapto) 2-hydroxypropyl acrylate, (3-hydroxypropyl acrylate, 2-hydroxybutyl (meth) acrylate) 3-hydroxybutyl acrylate, 4-hydroxy (meth) acrylate (methyl) Alkenyl acrylate, benzyl (meth) acrylate) cyclohexyl acrylate, phenyl (meth) acrylate, (methacrylic acid) 2-methoxyethyl ester, 2-phenoxyethyl fluorenyl (meth) acrylate decyloxy diethylene glycol acrylate, (glyme) triethylene glycol acrylate, (mercapto) acryloxy propylene glycol Ester, (in the case of the film, it can be found in the following: ethyl, decyl decyl ether, ethylene propylene, (fluorenyl) propylene) propylene sulfhydryl) , (mercapto) propyl ester, (decyloxymethyl)

S -52- 201213355 decyloxydipropylene glycol acrylate, isobutyl (meth) acrylate, tricyclo [5.2.1.0''6] decane-8-yl acrylate, () 2-hydroxy acrylate "Unsaturated carboxylic acid esters" such as -3-phenoxypropyl acrylate, mono(indenyl) acrylate, etc.; 2-aminoethyl acrylate (mercapto) acrylate, decylamino propyl (mercapto) acrylate Ester, 2-aminopropyl (meth) acrylate, (2-didecylaminopropyl methacrylate, 3-amino) (meth) acrylate, 3-dimethylaminopropyl (meth) acrylate "Unsaturated aminoalkyl esters" such as esters; "glycidyl carboxylates" of (meth)acrylic acid propyl acrylate; "unsaturated" (fluorenyl) oxetane "Carboxylic acid oxetane"; "vinyl carboxylate", vinyl butyrate, vinyl benzoate, etc. "Carboxylic esters"; Vinyl nonyl ether, vinyl ethyl ether, alkenyl "Unsaturated ethers" such as propyl epoxide; (cyanyl) acrylonitrile, a-gas acrylonitrile, cyanide vinyl compounds such as dicyandiethylene; "Unsaturated guanamines" such as a-gas acrylamide, N-2-hydroxy(indenyl) acrylamide; maleimide, N-phenyl maleimide, N - "unsaturated quinone imines" such as cis-butenylene diimide; aliphatic conjugated dienes such as 1,3-butadiene, isoprene, and chloroprene (gas flat)" Polystyrene, poly(indenyl) decyl acrylate, poly(nonyl enoate-n-butyl ester, polyoxyalkylene, etc., macromonomers of mono(indenyl) acrylonitrile at the end of the polymer molecular chain; Classes; S-methyl propyl 3- 2 -diyl) propylene carboxylic acid unsaturated esters, etc., propylene-vinyl bond "ethyl cyclohexyl" C-53-201213355 derived from such unsaturated monomers The structural unit may contain one type or two or more types. Hereinafter, exemplified compounds (1 to 1 to -8 and 2 to 20) of (B-2) binder resin are shown. (B-2) The binder resin is Not limited to such exemplified compounds.

S exemplified compound composition Mohr ratio Weight average molecular weight 1-1 C〇2^^ co2h 80/20 35000 1-2 Same as above 50/50 35000 1-3 Same as above 40/60 35000 1-4 Same as above 80/20 100000 1-5 Same as above 80/20 10000 1-6 Same as above 80/20 20000 1-7 Same as above 80/20 50000 1-8 Ibid. 95/5 35000 -54- 201213355 Exemplary compound composition Mohby weight average molecular weight 2 -(ch2-ch4- (ch2-ch-)-c=oi〇OH A-ch2-ch=ch2 80/20 35000 3 ch3 ch3 C=0 COOH och2ch=ch-^^ 80/20 35000 4 —^CH2—CH-^— ^CH2-CH-)— 0=0 COOH A-ch—c=ch2 0iH3 80/20 35000 5 -(CH2-CH-)- -^CH2-CH-)— 0=0 COOH icH2CH=CH— 80/ 20 35000 6 ch3 ch3 -^CH2————^CH2~C-)- C=0 COOH 1 och2ch=ch CN 80/20 35000 7 ch3 ch3 -^-CH2-C-)- -(·ΟΗ2—C- )- C=0 ioOH 1 och2ch=ch i丨80/20 35000 8 cof^^ co2h co2 70/20/10 35000 -55- £201213355 Exemplary compound composition molar ratio Weight average molecular weight 9 1 C c _ ό 70/ 20/10 35000 10 C ;O^N^ C &gt;r Ϊ02Η ζ) 70/20/10 35000 s -56- 201213355 The composition of the molar specific gravity sub-flat 11

Γύ°Υ^ COf^Ns^ C02H qAqA^J o OH 70/20/10 35000 12 c〇r^ co2h 70/20/10 35000 13 CO Guang'^ co2h C〇2— 70/20/10 35000 όορ^ C02H 〇^〇,^°Η 70/20/10 35000 15 ^ΤΫ H 0 t〇2H -°YN-C6H,fY% 0 C2Hs 70/20/10 35000

COfNs^ C02H Zha. ) 'CHa 70/20/10 35000 17 coP^ co2h

H 70/20/10 35000 70/20/10 35000 c〇r^ C02H 〇&lt;^〇

70/20/10 35000 20 70/20/10 35000 -57- 201213355 Β·2) The weight average molecular weight of the binder resin is preferably in the range of from 100 to 100000', more preferably from 1 to The range of 5〇〇(10) is further preferably in the range of 1〇〇〇〇 to 4〇〇〇〇. When it is in this range, the developability and linearity of the formed pattern become good. 0 In the colored photosensitive resin composition of the present invention, () the content of the binder resin is relative to the colored photosensitive resin. The solid of the composition: the fraction ' is preferably in the range of 10% by mass to 5% by mass, more preferably in the range of 15% by mass to 40% by mass. The colored photosensitive resin composition of the present invention contains (B-1) a binder resin and (B 2 ) a binder resin, as described above, two kinds of bonding d ^, but (B-丨) binder resin and () The content ratio of the binder resin on a mass/base basis must be from 3% to 7, preferably from 4.6 to 6:4. When the content ratio is within the above range, the heat resistance of the cured film formed becomes good, and the effect of suppressing generation of wrinkles after baking can be effectively suppressed. In the range of the content of each of the above-mentioned binder resins, the (B_i) binder resin is prepared in a ratio of 胄4 & The range of 7:3. The colored photosensitive resin composition of the present invention may contain the resin of the structure other than the ruthenium (B]) #合剂树脂&(b_2) another factory having a specific composition in the present invention. (B _ () Binder Resin (B-2) A resin other than the binder resin, as long as it is a coloring agent acting as a binder, and in the case of producing a color light, in the development processing step thereof The developer to be used is not particularly limited as long as it is soluble in the -58-201213355 test developer, and is preferably an acrylate-based copolymer having a carboxyl group, particularly an ethylenic bond having one or more carboxyl groups. a copolymer of an unsaturated monomer and another copolymerizable ethylenically unsaturated monomer. In the present invention, it has a structure other than the above (B-1) binder resin and (B-2) binder resin. Specific examples of the resin which can be used in combination are: (fluorenyl)acrylic acid/(mercapto)acrylic acid decyl ester copolymer, (mercapto)acrylic acid/(fluorenyl)acrylic acid benzyl ester copolymer, (meth)acrylic acid/ (fluorenyl) 2-hydroxyethyl acrylate / (mercapto) phenyl acrylate copolymer, (meth) acrylate / (mercapto) acrylate / polystyrene macromonomer copolymer, (mercapto) acrylic acid / (meth) acrylate / polyacrylic acid Ester macromonomer copolymer, (mercapto)acrylic acid / (benzyl) benzyl methacrylate / polystyrene macromonomer copolymer, (mercapto) acrylic acid / benzyl (meth) acrylate / polymethacrylic acid Anthracene macromonomer copolymer, (mercapto)acrylic acid/(hydroxy)(hydroxy)(2-hydroxyethyl)(meth)acrylic acid/polystyrene macromonomer copolymer, (meth)acrylic acid/( Mercapto) 2-hydroxyethyl acrylate / benzoyl (meth) acrylate / fluorenyl methacrylate macromonomer copolymer, etc. Further, an epoxy ring or an oxo group containing the following may also be used. Butane ring resin: -59- 201213355 Styrene/mercaptoacrylic acid/methacrylic acid tricyclo [5.2.1. 〇2'6] yttrium-8-based vinegar/glycidyl methacrylate copolymer, Styrene/acrylic acid/acrylic tricyclo[5.2.1.02'6]decyl vinegar/glycidyl acrylate copolymer, benzyl methacrylate/mercaptoacrylic acid/3-(methacryloxycarbonyl) Oxetane/mercaptoacrylic acid tert-butyl butyl ester copolymer, benzyl methacrylate/methacrylic acid/3-(methacryloxycarbonyl)-3-ethyl Oxetane/styrene copolymer, butadiene/styrene/methacrylic acid/trimethyl methacrylate [5.2.1 .〇2,6]decane-8-yl ester/mercapto-acrylic acid Glycidyl acrylate copolymer, butadiene/mercapto acrylate/methacrylic acid tricyclo [5.2.1. 〇2'6] decane-8-yl ester / methacrylic acid propylene acrylate copolymer, styrene /methacrylic acid/trimethyl methacrylate [5.2.1.02'6] decane-8-yl ester / methacrylic acid-6,7-epoxyheptyl ester copolymer, styrene / acrylic acid / maleic acid Anhydride/mercaptoacrylic acid-6,7-epoxyheptyl ester copolymer, butyl methacrylate/acrylic acid/maleic acid/methionate-6,7-epoxyheptyl ester copolymer , styrene/mercaptoacrylic acid/methyl methacrylate/methylol τ T burst acrylic propylene acrylate copolymer, p-methoxystyrene/mercapto acrylonitrile/acrylic hydrazine 匕鲳 匕鲳/曱 enoic acid Glycidyl acrylate copolymer. %C &lt; (C) Polymerizable Compound&gt; The colored photosensitive resin composition of the present invention is a compound of the octapeptide. 3 (C) Polymerization-60-201213355 The polymerizable compound which can be used in the present invention is an addition polymerizable compound having at least one ethylenically unsaturated double bond, which is selected from the group consisting of &gt; A compound having two or more terminal ethylenically unsaturated bonds. These compound groups are widely known in the industrial field. In the present invention, these can be used without particular limitation. These have, for example, a chemical form of a monomer, a prepolymer, i.e., a dimer, a trimer, and an oligomer, or a mixture thereof, and the like. Examples of the monomer and the copolymer thereof include an unsaturated carboxylic acid (for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, isocrotonic acid, maleic acid (maleic acid), etc.) Or an ester thereof or a guanamine, preferably an ester of an unsaturated carboxylic acid and an aliphatic polyol compound, an amide of an unsaturated carboxylic acid and an aliphatic polyamine compound. Further, it is also suitable to use an addition reaction of an unsaturated carboxylic acid ester or a guanamine having a nucleophilic substituent having a hydroxyl group, an amine group, a thiol group or the like with a monofunctional or polyfunctional isophthalate or an epoxy group. And a dehydration condensation reaction product with a monofunctional or polyfunctional carboxylic acid, and the like, and an unsaturated carboxylic acid ester or guanamine having an isocyanate group or an electrophilic substituent such as an epoxy group, and a monofunctional or poly Functional addition of alcohols, amines, and thiols' and has! A substituted carboxylic acid ester such as a sulfhydryl group such as a sulfhydryl group or a fluorenyl sulfonyloxy group or a hydrazine-based amine may be suitable as a substitution reaction product of a monofunctional or polyfunctional alcohol or an amine thiol. Further, as another example, a compound group of an unsaturated phosphonic acid, stupid ethylene 'vinyl anthracene or the like which is used in place of the above unsaturated carboxylic acid may be used. Further, in the present specification, the acrylate and the methacrylate are collectively referred to as "(fluorenyl) acrylate". -61 - 201213355 Specific examples of the monomer of the aliphatic polyol compound and the unsaturated carboxylic acid ester are exemplified by the following: "(meth) acrylate" includes: di(methyl) Ethylene glycol acrylate, triethylene glycol di(meth)acrylate, 1,3-butanediol di(meth)acrylate, tetramethylene glycol bis(decyl)acrylate, bis(fluorenyl) Propylene glycol acrylate, neopentyl glycol di(indenyl)acrylate, trishydroxypropyl propane tris(meth)acrylate, tris(hydroxy)propenyl tris((methyl) propylene oxypropyl) ether, Trimethylolethane tris(meth)acrylate, hexanediol di(meth)acrylate, 1,4-cyclohexanediol di(mercapto)acrylate, tetraglycol di(meth)acrylate Alcohol ester, neopentyl glycol di(meth)acrylate, neopentyl glycol tri(meth)acrylate, pentaerythritol tetrakis(meth)acrylate, dipentaerythritol di(meth)acrylate S, five (fluorenyl) dipentaerythritol acrylate, hexa(indenyl) propylene pentaerythritol ester, tripropylene Sorbitol sorbate, sorbitan tetra(decyl) acrylate, sorbitan pentoxide, sorbitol hexa(meth) acrylate, tris(meth) propylene oxime Ethyl ethyl ester, polyester (meth) acrylate oligomer, tri(indenyl) acrylate modified with EO (ethylene oxide), bis(indenyl) acrylate bisphenol A ester, bis(mercapto)acrylic acid bisphenol A ester EO modified product, tris(mercapto)acrylic acid trimethylolpropane ester, trishydroxypropyl propane tris((fluorenyl) propylene methoxypropyl)ether, Tris(indenyl)trihydroxydecyl acrylate, tetraethylene glycol di(meth)acrylate, neopentyl glycol diacrylate, neopentyl glycol tri(meth)acrylate, tetrakis(fluorenyl) Neopentyl glycol acrylate, tetra(methyl) propyl

S-62- 201213355 Ethyl neopentaerythritol vinegar, tetrapropionic acid pentaerythritol g EO modified substance, hexaerythritol hexaerythritol ester EO modified substance, and the like. "Iconic acid ester" includes: ethylene glycol di-conconate, propylene glycol di-conconate, 1,3-butylene glycol di-conconate, 1,4-butylene glycol di-conconate , diisodecyl glycol, ikonic acid neopentyl glycol ester, tetrasorbic acid sorbitol ester, and the like. "crotonate" includes: ethylene glycol dioctanoate, tetramethylene glycol dicrotonate, neopentyl glycol dicrotonate, and sorbitol tetracrotonate. "Isocrotonate" includes ethylene glycol diisocrotonate, neopentyl glycol diisocrotonate, and sorbitol tetraisocrotonate. "maleate" includes: ethylene glycol maleate, triethylene glycol dimaleate, pentaerythritol dimaleate, tetrabutylene Sorbitol ester and the like. Examples of other esters are also suitable for use: for example, the aliphatic alcohol-based esters disclosed in Japanese Patent Publication No. Sho 57-47334, and Japanese Laid-Open Patent Publication No. SHO 57-196263, or In the case of an aromatic skeleton disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. The amine group or the like as disclosed in the 3rd bulletin. Further, specific examples of the monomer of the aliphatic polyamine compound and the decylamine of the unsaturated carboxylic acid include: fluorenylene bis-acrylamide, fluorenylene bis-methyl acrylamide, 1,6-hexa Mercapto bis-acrylamide, 1,6-hexamethylene bis-mercapto acrylamide, di-ethyltriamine propylene amide, hydrazinyl bis decylamine, hydrazinyl bis-decyl propylene Amidoxime and the like. Other preferred examples of the oxime-based monomer are those having a cyclohexylene structure as disclosed in Japanese Patent Publication No. Sho 54-2 1726. Further, it is also suitable to use an amino acid succinic acid s which is produced by an addition reaction of an isocyanate and a trans group to form an addition polymerizable compound, and a specific example thereof is exemplified by, for example, 曰本特公昭48- A polyisophthalic acid-containing compound having two or more isocyanate groups in one molecule as disclosed in Japanese Unexamined Patent Publication No. Publication No. No. No. No. No. No. No. No. No a &amp; dilute urethane compound having two or more polymerizable ethylene groups in one molecule. General formula (V) CH2=C(R4)COOCH2CH(R5)OH (V) (However, R4 and R5 each independently represent hydrazine or CH3). In addition, the amines disclosed in the publication of the Japanese Patent Publication No. 5 1 -37 1 93, the Japanese Patent Publication No. 2 - 3 2 2 3 3, and the Japanese Patent Publication No. 2 -1 6 7 6 5 The phthalic acid ester acrylates are disclosed in Japanese Patent Publication No. Sho 58_4986(), Japanese Patent Publication No. Sho 56-17654, Japanese Patent Publication No. 62-3 9417, and Japanese Patent Publication No. 62-3941. The amine phthalate compounds having an ethylene oxide-based skeleton as disclosed are also suitable. In addition, the addition of an amine-based structure or a sulfide structure in the molecule as disclosed in Japanese Laid-Open Patent Publication No. SHO63-277653 In the case of a polymerizable compound, a light-taking composition having a very excellent light-sensing rate can be obtained. ^ + Other examples of the poor are: polyester acrylates as disclosed in each of the publications of Japanese Patent Publication No. Sho 48-64183, Japanese Patent Publication No. SHO 49-43191, and Japanese Patent Publication No. a class of acrylic acid epoxy esters which react with xenon-oxygenated vegetable fat and (mercapto)acrylic acid, etc. ^ a 53⁄4 -64 - 201213355 a fine ist S曰 or a mercapto acrylate. In addition, the specifics disclosed in Japanese Patent Publication No. 4-6 - 4 3 9 4 6 , 曰 特 丨 丨 丨 4 4 4 3 3 3 3 3 曰 曰 曰 1 - - - - - - - - - The unsaturated compound is a vinyl phosphonic acid compound or the like as disclosed in JP-A No. 2-2549. Further, a structure containing a perfluoroalkyl group as disclosed in Japanese Laid-Open Patent Publication No. 61-22〇48 is also suitably used. Further, the 'commercial product is preferably an amino phthalate oligomer UAS-10 UAB-140 (manufactured by Sanyo Kokusaku Pulp Co., Ltd.); DPHA (Sakamoto Chemical Co., Ltd.) (Nipp〇n Kayaku Co., Ltd.), UA-306H, UA-306T, UA-306I, AH-600, T-600, AI-600 (manufactured by Kyoeisha Co., Ltd.). It can also be used as photohardenability in Nipp〇ri gecchaku Kyokai Shi [Journal of the Adhesion Society of Japan], Vol. 20, No. 7, pp. 300 to 3, 8 (1 984). Introduced monomer and polymer. In the colored photosensitive resin composition of the present month, a preferred mode of the (C) polymerizable compound is to use a compound having a polymerizable group of 5 or more and 15 or less in the molecule and a molecule. This s material containing one or more compounds having four or less one-complex groups. The compound containing 5 or more and 15 T-polymerizable groups in the molecule, and the following four compounds having the "lower polymerizable group" are preferably contained in the molecule. The following compounds are contained in the knife. Examples of the compound of 5 or less polymerizable groups are: i-pentyltetrakis(meth)acrylate: dipentaerythritol methyl (meth)acrylate, and 5 (mercapto) propylene mountain 4 scorpion &quot; Sorbitol (meth) acrylate, and -65-, "ύτΐη 201213355, UA-32P, UA-7200 (above is Shin-Nakamura Chemical Co., Ltd.), Ding Wei-2248, , 1 3 82 (above is made by the East Asian Synthetic Company). In addition, it is also possible to: recruit neopentyl glycol (meth)acrylate, butylene glycol (meth) acetophenate, 1,6-hexanediol oligo(meth)acrylate, oligo()acrylic acid Hydroxymercaptopropane ester, oligo(mercapto)acrylic acid neopentyl ester, urethane (meth) acrylate, and (mercapto) propyl epoxy ester contain 5 or more and 15 or less in the molecule. (The compound of the methacrylate group, but in the case of such an oligomer, the amount is preferably in the range of from 1 Å to 5,000. "The polymer contains one or more and four or less polymerizable groups in the molecule. The product is exemplified by: tris(methyl)propionic acid, dimethyl propyl sulfonium trimethylolpropane PO (propylene oxide) modified di(meth) propyl ester, trihydroxy decyl propane EO (ethylene oxide) modified bis (No. acrylate, tetrakis(meth)acrylic acid pentaerythritol ester, three (曱 neopentyl acrylate, tetrakis(meth) acrylate tetramethylol, Tetrakis(Mercapto)acrylic acid pentaerythritol ester, tetrakis(meth)acrylyl «η 〃田美) acrylic acid trimethylolpropane ester, ethoxylated four (earth In the case of using a mixture of 5 or more and 15 or less compounds in a molecule, a compound and a mixture of 5 or more and 15 compounds containing one or more and 4 or less σ 丨 人 V V V V V V V Then, the ratio of the compound having a polymerizable group in the molecule to the compound having one or more polymerizable groups in the molecule [(containing 5 in the molecule, and polymerizing in the next one in the molecule - 66 - Company 2349) , 4-mercaptotetraol dilute acid) propylene molecular compound, enoic acid 'yl) group) succinic acid dipentane tetrayl group of the following 15 or more 201213355 4 or less polymerizable group of compounds It is in the range of 60:40 to 95:5.] 'In terms of mass, it is more preferably 70:30 to 90:10 (C) of the polymerizable compound photosensitive resin composition layer: In general, in the coloring amount % to 60% by mass of the present invention, and more preferably in the solid content of A 7 , the amount of the enamel is preferably 18% by mass to 40% by mass. The enthalpy is set in the figure. Good, can effectively inhibit - the heat of the obtained cured film will become wrinkles after baking Produced. The surface of the shadow is roughened and post-baked.

The mass ratio of the (C) polymerizable) photopolymerization initiator / (C) dimerization initiator to the compound (D) in the composition described below is "(D 2 0,.^ ± t Α σ compound) It can be 0·1 or more. 〇U, preferably 〇丨 below—丄^. Above 丨·0 or less, especially preferably 0.3 or more 〇·9 F. The error is not determined to be on the test β and H 4 attack In the range, the pattern formation property is good and the adhesion to the substrate is excellent. When the thickness is large, the mask after exposure and development is sufficient, and the pattern peeling can be suppressed. (D) Polymerization Initiator&gt; In the present invention, (D) a special photopolymerization initiator: a compound which is a structure and which can initiate and promote a compound of the above (c) polymerizable compound, can be used without limitation. A person skilled in the art may, for example, employ a compound, and employ a compound, etc. Specifically, for example, a §---------- .2 Touching the polymerization initiator described in the following general formula (D), which is disclosed in the Japanese Patent Laid-Open No. _5i-67-No. Initiator and the like, to suppress the coloration of baking from the viewpoint, preferably the following representatives of the oxime-based photopolymerization initiator.

Hardening sensitivity or general formula (III

(D-1) a sulphur group, or a COR samarium or a halogen group. In the above formula (D-1), X1 represents a hydrogen atom, and a halogen 'R1 represents a R, an OR, a COR, an SR _ CN, R2 and R3 each independently represent an R, an SR, or an NRR. R and R' are each a separate group, an aralkyl group or a heterocyclic group, and one of the groups consisting of an atom and a heterocyclic group is constituted by the alkyl group and the aryl group. The carbon of the alkyl group may be substituted by an unsaturated bond, an ether bond, or an ester bond to form a ring. 〇 〇

In the formula (III), R and X are each independently, and A represents a divalent organic group, and Ar represents an aryl group. number. When X has a complex number, the complex X is the respective independent base. A prime atom, or a CONRR, an OR, a ground represents an alkyl group which may be selected from one of the atoms substituted by the above, R and R' are a group, and the total valence is (III). The monovalent substitution η is 0 to 5 Site representative

S-68-201213355 The one-valent substituent represented by the above R is preferably a monovalent non-metal atom group represented by the following. "A non-metal atomic group J represented by R is an alkyl group which may have a substituent, an aryl group which may have a substituent, an alkenyl group which may have a substituent, an alkynyl group which may have a substituent, may have Alkylsulfinyl group of a substituent, an arylsulfinylene group which may have a substituent, an alkylsulfonyl group which may have a substituent, an arylsulfonyl group which may have a substituent, and a substituent which may have a substituent Alkoxycarbonyl group which may have a substituent, an aryloxycarbonyl group which may have a substituent, a phosphinylene group which may have a substituent, a heterocyclic group which may have a substituent, an alkylthiocarbonyl group which may have a substituent, An arylthiocarbonyl group which may have a substituent, a dialkylaminocarbonyl group which may have a substituent, a dialkylaminothiocarbonyl group which may have a substituent, etc. The "alkyl group which may have a substituent" is preferably a carbon number The alkyl group of 1 to 30' may, for example, be an alkyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group, a decyl group, a dodecyl group, an octadecyl group, an isopropyl group or an isobutyl group. , secondary butyl, tert-butyl, ethyl decyl, cyclopentyl, cyclohexyl, trimethyl, 2 - Ethylhexyl, benzoquinonemethyl, 丨_naphthylfluorenyl, 2-naphthylmethyl, 4-methylsulfanylbenzoyl fluorenyl, 4-phenylthiobenzophenone Sulfhydryl, 4-dimethylaminophenyl fluorenyl, 4-n-benzylbenzimidylmethyl, 4-methylabendyryl, 2-methylbenzhydryl, 3_Itbenzin Methyl, 3-trifluoromethylbenzoic acid methyl, % nitrobenzimidyl methyl and the like. The "group which may have a substituent" is preferably an aryl group having 6 to 30 carbon atoms, and examples thereof include a phenyl group, a biphenyl group, a fluorenyl-naphthyl group, a 2-naphthyl group, and a 9-enyl group. 9-phenanthryl, 1-indenyl, 5-condensed tetraphenyl, 丨-fluorenyl, 2-foundation-69-201213355, 9-diyl, triphenyl, tetraphenyl, o-, m-, And p-tolyl, diphenyl phenyl, o-, m-, and p-isopropylphenyl, mesityl group, ruthenium pentylene, dinaphthyl, dinaphthyl, hydrazine Nylidene, cycloheptatrienyl, terphenyl, dicyclopentadienylphenyl, propadienyl fluorenyl, fluorenyl, vinyl fluorenyl, propylene naphthyl, anthracenyl, fluorenyl,联,感基,联二恩基,联四恩基,恩喧淋基, phenanthryl, triphenylene, fluorenyl, chrysenyl group, slightly tetraphenyl, heptaenyl, starting , fluorenyl, bis-pentaphenyl, fused pentaphenyl, bis-phenylene, iso-hexa-phenyl, hexa-phenyl, ketone, benzyl, bis-naphthyl, iso-hexaphenyl, stilbene Base, Youji, and base. The "alkenyl group which may have a substituent" is preferably an alkenyl group having 2 to 10 carbon atoms, and examples thereof include a vinyl group, an allyl group, a styryl group and the like. The "alkynyl group which may have a substituent" is preferably an alkynyl group having a carbon number of 2 to 10, and examples thereof include an ethynyl group, a propynyl group, a propynyl group and the like. The "alkylsulfinyl group which may have a substituent" is preferably an alkylsulfinyl group having a carbon number of from 1 to 20, and examples thereof include a mercaptosulfinyl group and an ethylsulfinyl group. Propylsulfinyl, isopropylsulfinyl, butylsulfinyl, hexylsulfinyl, cyclohexylsulfinyl, octylsulfinyl, 2-ethylhexylsulfinium A group, a fluorenyl sulfinyl group, a decyl sulfonyl group, an octadecyl amide group, a cyano fluorenyl group, a decyloxymethyl sulfinyl group, and the like. The "arylsulfinyl group which may have a substituent" is preferably an arylsulfinyl group having a carbon number of from 6 to 30, which may, for example, be a phenylsulfinyl group or a 1-naphthylsulfinium group. , 2-naphthylsulfinyl, 2-phenylphenylsulfinyl, 2-nonylphenylsulfinyl, 2-decyloxysulfinyl, 2-butoxy

S -70- 201213355 Phenylsulfinyl, 3-oxophenylsulfinyl, 3-trifluoromethylphenylphosphazene, 3-cyanophenyl ylidene, 3-nittan 4-phenylphenylsulfinyl, 4-cyanophenylsulfinyl, 4-methoxyphenylsulfinyl, 4-mercaptosulfanylphenyl Sulfosyl, 4-phenylsulfanylphenylsulfinyl, 4-didecylaminophenylsulfinyl, and the like. The "alkylsulfonyl group which may have a substituent" is preferably an alkylsulfonyl group having 1 to 20 carbon atoms, and examples thereof include a methylsulfonyl group, an ethylsulfonic acid group, and a propionic acid group. , isopropyl base, butyl stellite, hexylsulfonyl, cyclohexylsulfonyl, octylsulfonyl, 2-ethylhexylsulfonyl, decylsulfonyl, twelve A sulfonyl group, an octadecylsulfonyl group, a cyanosulfonylsulfonyl group, a methoxymethylsulfonyl group, a perfluoroalkylsulfonyl group, and the like. The "arylsulfonyl group which may have a substituent" is preferably an arylsulfonyl group having a carbon number of from 6 to 30, which may, for example, be a phenylsulfonyl group, a 1-naphthylsulfonyl group, or a 2- Naphthylsulfonyl, 2-oxophenylsulfonyl, 2-mercaptophenylsulfonyl, 2-methoxyphenylsulfonyl, 2-butoxyphenylsulfonyl, 3-chloro Phenylsulfonate, 3-trifluorodecylphenylsulfonyl, 3-cyanophenylsulfonium basket, 3-nitrophenyl ruthenium, 4-fluoro&gt; phenyl triazole , 4-oxophenylsulfonyl, 4-methoxyphenyl fluorenyl, 4-methylsulfanylphenyl tartaric acid, 4-phenylsulfide:); - Dimethylaminophenyl hydrazine basket and the like. The "thiol group which may have a substituent" is preferably a fluorenyl group having a carbon number of 2 to 20, and examples thereof include, for example, an ethyl group, a propyl group, a butyl group, a trifluoromethylcarbonyl group, a amyl group, and a berylylene group. , 1-naphthylmethyl, 2-naphthyl, 4-methylsulfanylphenyl, 4-phenylsulfanylphenyl, 4-71-201213355 Didecylamine Benzobenzyl, 4-diethylaminobenzimidyl, 2-oxobenzylidene, 2-methylphenylhydrazino, 2-decyloxyphenylhydrazine, 2-butoxy Benzyl fluorenyl, 3- gas phenyl fluorenyl, 3-trifluoromethylphenyl fluorenyl, 3-cyanophenyl fluorenyl, 3-nitrophenyl fluorenyl, 4-fluorophenyl fluorenyl, 4-cyanobenzoinyl, 4-methoxybenzimidyl and the like. The "alkoxycarbonyl group which may have a substituent" is preferably an alkoxycarbonyl group having 2 to 20 carbon atoms, and examples thereof include an anthraceneoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, and a butoxycarbonyl group. , hexyloxycarbonyl, octyloxycarbonyl, decyloxycarbonyl, octadecyloxycarbonyl, trifluoromethoxycarbonyl, and the like. The "aryloxycarbonyl group which may have a substituent" is exemplified by a phenoxycarbonyl group, a 1-naphthyloxycarbonyl group, a 2-naphthyloxycarbonyl group, a 4-methylsulfanylphenoxycarbonyl group, a 4-phenyl group. Sulfoalkylphenoxycarbonyl, 4-didecylaminophenoxycarbonyl, 4-diethylaminophenoxycarbonyl, 2-cyclophenoxycarbonyl, 2-methylphenoxycarbonyl, 2 -Methoxyphenoxycarbonyl, 2-butoxyphenoxycarbonyl, 3-chlorophenoxycarbonyl, 3-trifluorodecylphenoxycarbonyl, 3-cyanophenoxycarbonyl, 3-nittan A phenoxycarbonyl group, a 4-fluorophenoxycarbonyl group, a 4-cyanophenoxycarbonyl group, a 4-decyloxyoxycarbonyl group, and the like. The "phosphinylene group which may have a substituent" is preferably a phosphinylene group having a total carbon number of 2 to 50, and examples thereof include, for example, a dimercaptophosphinyl group, a diethylphosphinylene group, and a dipropylphosphinyl group. , diphenylphosphinyl, dimethoxyphosphinyl, diethoxyphosphinyl, benzhydrylphosphinyl, bis(2,4,6-tridecylphenyl)phosphinyl Wait. The "heterocyclic group which may have a substituent" is preferably an aromatic or aliphatic heterocyclic ring containing a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom. It can

S-72- 201213355 Listed: for example, thienyl, benzo[b]thienyl, naphtho[2,3-b]thienyl, thienyl, furyl, piperanyl, isobenzofuranyl, decene Chromenyl group, xanthenyl group, homogenate, 2H-pyrrolyl, pyrrolyl, imidazolyl, pyrazolyl, pyridyl, pyridyl, pyrimidinyl, fluorenyl, morphine Base, isoindolyl, 3H-fluorenyl, fluorenyl, 1H-. Borazolyl, fluorenyl, 4H-quinucinyl, isoquinolinyl, quinolinyl, blown bell, naphthyridinyl group, indole, hydrazine.坐琳基, cinil〇iinyi gr0Up, disc bite, 4aH-carbazolyl, carbazolyl, β-carbolinyl, phenanthryl, acridinyl, perimidinyl group, Pynolinyl, morphinyl, morphinyl, isothiathiol, morphine, morphine, nickname. Sitrate, sulfhydryl, morphine, isochromanyl group, chromanyi gr〇Up, n specific pyridine, pyrrolinyl, imidazolidinyl, imidazolinyl, Pyrazolyl, pyrazolinyl, piperidinyl, hexahydropyridinyl, porphyrinyl, isoindolyl, quinuclidinyl group, morpholinyl, thioxanthenyl group )Wait. The "alkylthiocarbonyl group which may have a substituent" is exemplified by, for example, mercaptothiocarbonyl, propylthiocarbonyl, butylthiocarbonyl, octylthiocarbonyl, mercaptothiocarbonyl, octadecylthiocarbonyl, trifluoro Mercaptothiocarbonyl and the like. &quot;T has a substituent thiol group" is exemplified by: naphthylthiocarbonyl, 2-naphthylthiocarbonyl, 4-methylsulfanylphenylthiocarbonyl, 4-phenylsulfanylphenylthio Carbonyl, 4-dimethylaminophenylthiocarbonyl, 4-diethylaminophenylthiocarbonyl, 2-chlorophenylthiocarbonyl, 2-nonylphenylthiocarbamate, 2-methoxyphenyl Thiocarbonyl, 2-butoxyphenylthiocarbonyl, 3-phenylphenylthio, 3-trifluoromethylsulfanyl, 3-cyanothio: sulfur-73- 201213355 carbonyl, 3-nittan A thiocarbonyl group, a 4-fluorophenylthiocarbonyl group, a 4-alkylphenylthiocarbonyl group, a 4-decyloxyphenylthiocarbonyl group or the like. The "dialkylaminocarbonyl group which may have a substituent" may, for example, be a dimercaptoamine group, a monoethylaminocarbonyl group, a dipropylamino group or a dibutylaminocarbonyl group. The "dialkylaminothiocarbonyl group which may have a substituent" may, for example, be a dimercaptoalkylthio group, a dipropylaminothiocarbonyl group or a dibutylaminocarbonylcarbonyl group. The above R, from the viewpoint of high sensitivity, is more preferably an unsubstituted or substituted aryl group. Specifically, it is preferably an unsubstituted or substituted ethyl fluorenyl group, a propyl fluorenyl group, or a benzoquinone.醯基, T本T » base. The above-mentioned πm is a base represented by a structural formula such as α, and preferably any of (dl) (d-4) R (A ^ / long ld-5) 0 - ch3 (d-1 ) (d-2)

(d-4) CH3 eleven CH3 (d-3) CH3

(d-6) "The divalent organic group represented by the above A" is exemplified by an alkylene group having a carbon number of 1 to 12 which may have a substituent, which may have a substituent; a cyclohexyl group which may have a substitution The base is an alkynyl group.

S-74-201213355 An aryloxy group, a methoxycarbonyl group or an alkoxy group which may be introduced into a substituent such as a substituent of such a group, a chlorine atom, a bromine atom, a moth ethoxy group or a tertiary alkoxy group. a methoxy group such as a carbonyl group or an aryloxycarbonyl fluorenyloxy group, an ethenyl fluorenyl group, a methacryl fluorenyl group, a thioalkyl group, a tertiary butyl sulfanyl group, a p-tolyl sulfanyl group or the like. An arylamino group, a mercapto group, an ethyl alkyl group, a phenyl group, a p-fluorenylphenyl group, or the like, which is an alkyl group such as an arylamino group, a dialkyl group or a dialkyl group. a carboxylic acid group, a thiol group, a thiol group, a thiol group, a nitro group, a cyano group, a trifluoromethyl group, a phosphinico group, a trimethylxyl group, or the like, an aryl group such as a fluorenyl group or a phenanthryl group. Dimethyl squara and the like. Wherein, the above A, from the viewpoint of improving the coloration, is preferably a group (for example, a mercapto group, an ethyl group, a tertiary alkyl group, an alkenyl group (for example, a vinyl group via an aryl group (for example, a phenyl group, a p-tolylphthyl group, Examples of the fluorenyl group, the phenanthryl group, and the styryl group include a halogen atom such as a fluorine atom, a methoxy group, an oxy group, a phenoxy group, a p-tolyloxybutoxycarbonyl group, a phenoxycarbonyl group, and the like. An alkyl group such as an oxy group, a propyl methoxy group, a phenyl group, a benzamyl group, an isobutyl fluorenyl group or a methoxy oxalyl group; an alkylthioalkyl group such as a methyl group; a phenylsulfanylsulfanyl group; Amino, cyclohexylamino, diethylamino, phenyl, phenylamino, p-tolylamine, tert-butyl, dodecyl, etc. The base may also be exemplified by a hydroxyl group, a carboxyl group, a sulfonyl group, a p-toluenesulfonyl group, an amine, a trichloroindenyl group or a trimethylsulfonyl group. 'phosphonic acid group (phosphono ammonium group, triphenylbenzene) Mercapto sensitivity, inhibition of unsubstituted extended alkyl, alkylene, dodecyl substituted, allyl group due to heating over time a substituted alkyl group substituted with an alkyl group, a benzyl group, a xylyl group, a cumyl group or a group. The aryl group represented by the above Ar is preferably an aryl group having 6 to 30 carbon atoms, and may have a substituent. Specifically, Ar is exemplified by phenyl, biphenyl, 1-naphthyl, 2-naphthyl, 9-fluorenyl, 9-phenanthryl, 1-fluorenyl, 5-fused tetraphenyl, 1- Indenyl, 2-methyl, 9-fluorenyl, triphenyl, tetraphenyl, o-, m-, and p-nonylphenyl, diphenyl, o-, m-, and p- Phenyl phenyl, a certain group, and a ruthenium di-branched group, a combination of a ruthenium group, a dinaphthyl group, a dinaphthyl group, a decylylene group, a phenyl group, a dicyclopentadienyl group, Propylene base, dangerous base, ethyl thiol, propyl naphthyl, anthracenyl, fluorenyl, hydrazino, hydrazinyl, hydrazino, quinolinol, phenanthryl, hydrazine Triphenylene, ketone, shake, slightly tetraphenyl, heptadecyl, fluorenyl, aryl, pentaphenyl, fused pentaphenyl, phenylene, hexaphenyl, hexabenzene A group, a ketone group, a thiol group, a bis-naphthyl group, a hetero-hexaphenyl group, a hexaphenyl group, a fluorenyl group, a fluorenyl group, and the like. Among them, a substituted or unsubstituted phenyl group is preferred from the viewpoint of improving sensitivity and suppressing coloring due to heating by time. When the phenyl group has a substituent, the "substituent group" may, for example, be a halogen atom such as a fluorine atom, a gas atom, a bromine atom or an iodine atom, a decyloxy group, an ethoxy group or a tertiary butoxy group. An alkyloxy group such as an alkoxy group, a phenoxy group, a phenoxy group or the like, an alkyloxy group such as an aryloxy group, a mercaptothio group, an ethylthio group or a tributylthio group. An alkoxycarbonyl or aryloxycarbonyl group such as an aryl group, an aryloxycarbonyl group, a butyloxycarbonyl group, a phenoxycarbonyl group or the like, an ethoxycarbonyl group, an ethoxycarbonyl group, an ethoxycarbonyl group Oxyloxy, benzylidene, benzhydryl, etc.

S-76-201213355, isobutyl fluorenyl, acryl fluorenyl, methacryl fluorenyl, methoxy oxalate, etc. alkylsulfonyl group such as mercapto, mercaptosulfanyl, tert-butylsulfanyl, etc. , an alkylthio group such as a phenylthioalkyl group or a p-tolylsulfoxy group; an alkylamino group such as a mercaptoamine group or a cyclohexylamino group; a dimercaptoamine group; a diethylamino group; An alkyl group or a hydroxy group of an arylamino group such as an alkyl group, a phenylamino group, a p-nonylphenylamino group, an ethyl group, an ethyl group, a tertiary butyl group or a dodecyl group. ,carboxy,carbomethyl, thiol, sulfo, fluorite, p-toluene, amine, succinyl, aryl, tris, trichloromethyl, trimethyl decane A monovalent, monobasic phosphate group, a phosphonic acid group, a trimethylammonium group, a dimethylammonium group, a triphenylphenyl fluorenyl group or the like. In the general formula (III), when the structure of "S Ar" formed by Ar and the adjacent S is the structure shown below, it is preferable from the viewpoint of sensitivity. -77- 201213355

The above-mentioned "valent substituent represented by x" may, for example, be an alkyl group which may have a substituent, an aryl group which may have a substituent, an alkenyl group which may have a substituent, an alkynyl group which may have a substituent, or may have Alkoxy group of a substituent, an aryloxy group which may have a substituent, an alkylthio group which may have a substituent, an arylthio group which may have a substituent, a halogenated alkyl group which may have a substituent, on N An anthracene group which may have a substituent, which may have a substituent

S-78-201213355 oxy, an alkylthioalkyl group which may have a substituent, an arylsulfanyl group which may have a substituent, an alkylsulfinyl group which may have a substituent, an aryl group which may have a substituent a sulfonyl group, an alkylsulfonyl group which may have a substituent, an arylsulfonyl group which may have a substituent, a mercapto group which may have a substituent, an alkoxycarbonyl group which may have a substituent, or an aryloxycarbonyl group Aminomercapto group having a substituent, an amine sulfonyl group which may have a substituent, an amine group which may have a substituent, a phosphinylene group which may have a substituent, a heterocyclic group which may have a substituent, a halogen atom, and the like. The "alkyl group which may have a substituent" is preferably a group having a carbon number of from 1 to 30, and examples thereof include, for example, an anthracenyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group, a decyl group, and an decyl group. Base, octadecyl, isoendyl, isobutyl, primary butyl, secondary butyl, 1-ethylpentyl, cyclopentyl, cyclohexyl, di-methyl, 2-ethylhexyl, benzene Sulfhydryl, ι_naphthylmethylmethyl, 2-naphthylfluorenyl, 4-mercaptosulfanylphenylmethyl, 4-phenylsulfanylmethyl, 4- Dimethylaminobenzoic acid methyl, 4_ phenylidene 4-methylbenzoinyl, 2-mercaptopurine, 3-fluorobenzyl, 3 -Trifluoromethylphenylhydrazine, 3-nitrophenylhydrazine methyl, and the like. The "aryl group which may have a substituent" is preferably an aryl group having a carbon number of 6 to 30, which includes, for example, a phenyl group, a biphenyl group, a fluorenyl-naphthyl group, a 2-naphthyl group, a 9-fluorenyl group, and a 9-phenanthrene group. , 1 -fluorenyl, 5-condensed tetraphenyl, 1 -indolyl, 2 -indolyl, 9-diyl, terphenyl, tetraphenyl, o-, m-, and p-tolyl, Xylyl, o-, m-, and p-cumyl, anthracene, cyclopentadienyl, binaphthyl, tris-naphthyl, tetratetraphthyl, cycloheptatrienyl, hydrazine Phenyl, dicyclopentadienylphenyl, propadienyl, hydroxy-79-201213355, vinyl fluorenyl, propylene naphthyl, anthracenyl, fluorenyl, fluorenyl, United four bases, grace.奎琳基,非基基基基基基基,Chessyl, fused tetraphenyl, heptaphenyl, fluorenyl, aryl, hydrazino, fused pentaphenyl, phenylene phenyl, iso-hexabenzene Base, hexabenzoyl, fluorenyl, tris-naphthyl, iso-hexaphenyl, hexaphenyl, fluorenyl, fluorenyl and the like. The "alkenyl group which may have a substituent" is preferably a carbon number of 2 to 10 groups, and examples thereof include a "alkynyl group which may have a substituent" such as a vinyl group, an allyl group or a phenethyl group. The number is 2 to 10 groups, and examples thereof include an ethynyl group, a propynyl group, a propynyl group and the like. The "alkoxy group which may have a substituent" preferably has a carbon number of 1 to alkoxy group, and examples thereof include a methoxy group, an ethoxy group, a propoxypropyloxy group, a butoxy group, and an isobutoxy group. , 2,4-butoxy, tert-butyl, pentyloxy, isopentyloxy, hexyloxy, heptyloxy, octyloxy, hexyloxy, decyloxy, dodecyloxy, octagonal Oxyl, ethylcarbonyl fluorenyl, 2-ethylhexyloxycarbonyl decyloxy, aminocarbonylmethyl, hydrazine, hydrazine-dibutylaminocarbonylcarbonyloxy, N-decylaminocarbonyl, hydrazine- Ethylaminocarbonylcarbonyloxy, fluorenyl-octylaminocarbonylcarbonyloxycarbonyl-fluorenyl-benzoylaminocarbonylcarbonyloxy, benzyloxy, cyanoguanidine, and the like. The "aryloxy group which may have a substituent" preferably has a carbon number of 6 to an aryloxy group, and examples thereof include a phenoxy group, a 1-naphthyloxy group, a 2-naphthalene group, a 2-epoxyphenoxy group, and a 2- Nonylphenoxy, 2-decyloxyphenoxy, 2-benzylphenoxy, 3-oxophenoxy, 3-trifluorodecylphenoxy, 3-cyano, 3-nitrophenoxy , 4-fluorophenoxy, 4-cyanophenoxy, 4, hydrazine, pentacylphenyl, tb.%· olefinic alkyne 30, isoethoxy 2-ethoxyoxyoxy , N-oxy 30 oxy-butoxyphenoxy-oxygen

S-80-201213355 phenoxy group, 4-dimercaptoaminophenoxy group, 4-mercaptosulfanyl group, 4-phenylsulfanylphenoxy group, and the like. The "alkylthio group which may have a substituent" is preferably an alkylthio group having a carbon number of 30, and examples thereof include a mercaptothio group, an oxy group, a propylthio group, and an isopropyl sulfide. Oxyl, butyl thiooxythiooxy, sec-butyl thiooxy, tert-butyl thiooxy, oxy, isopentyl thiooxy, hexyl thiooxy, heptyl thiooxy sulphur Oxyl, 2-ethylhexylthiooxy, decylthiooxy, dodecyloxy, octadecylthiooxy, benzylthiol and the like. The "arylthio group which may have a substituent" is preferably an arylthiooxy group having a carbon number of 30, and examples thereof include a phenylthiooxy group, a thiooxy group, a 2-naphthylthio group, and 2 - gas phenyl thiooxy, 2-methyloxy, 2-methoxyphenyl thiooxy, 2-butoxyphenyl thiooxyphenyl thiooxy, 3-trifluoromethyl phenyl sulphide Oxy, 3-cyanooxy, 3-nitrophenylthiooxy, 4-fluorophenylthiooxy, 4-indolylthiooxy, 4-methoxyphenylthiooxy, 4-di A mercaptoaminophenyl group, a 4-mercaptothioalkylphenylsulfide group, a 4-phenylsulfanylphenyl group, and the like. The "oxy group which may have a substituent" is preferably a carbon number of 2 j oxime, which may, for example, be an ethoxy group, a propenyloxy group, a pentyloxy group or a trifluorodecyl carbonyl oxide. A group, a benzoquinoneoxy group, a carbonyloxy group, a 2-naphthylcarbonyloxy group, or the like. The "alkylsulfide group which may have a substituent" is preferably an alkylsulfanyl group having a carbon number of 20, and examples thereof include a mercaptosulfanyl group, a alkyl group, a propyl sulfide group, and an isopropyl sulfide group. Base, butylthioalkyl phenoxy is 1 to ethyl sulphide, isobutylamyl sulphide, octylalkyl sulphide is 6 to 1 -nylphenylthio, 3-phenylthiophenylthio Alkyloxythiol L 20 butyl oxime 1-naphthyl is 1-ethylthio, hexyl-81 - 201213355 sulfanyl, cyclohexylsulfanyl, octylsulfanyl, 2-ethyl, hydrazine A thiol group, a dodecanoylthio group, an octadecyl group, a cyanodecylsulfanyl group, a decyloxythioalkyl group, and the like. The "arylthioalkyl group which may have a substituent" is preferably an arylsulfanyl group of carbon: 30, which may, for example, be a phenylsulfanylsulfanyl group, a 2-naphthylsulfanyl group, or a 2- Phenylthioalkyl, 2-decyl, 2-nonyloxyphenylthioalkyl, 2-butyrylphenylthiophenylthioalkyl, 3-trifluorodecylphenylsulfanyl , 3-cyanoalkyl, 3-bromophenylthioalkyl, 4-|tphenylthioalkyl, 4-sulfanyl, 4-methoxyphenylsulfanyl, 4-methylsulfane A base group, a 4-phenylsulfanylphenylsulfanyl group, a 4-didecylamino group or the like. The "alkyl group which may have a substituent" is preferably an alkylsulfinyl group of up to 20, which may, for example, be a fluorenylethylenesulfinyl group, a propylsulfinyl group, or an isopropyl group. Sulfosulfonyl, hexylsulfinyl, cyclohexylsulfinyl, fluorenyl, 2-ethylhexylsulfinyl, fluorenylsulfinyl sulfinyl, octadecyl Mercaptosulfonyl, cyanofluorenylmethoxymethylsulfinyl, and the like. The "arylsulfinyl group which may have a substituent" is preferably an arylsulfinylene group of up to 30, which may, for example, be a phenylene-1-naphthylsulfinyl group or a 2-naphthylsulfinyl group. Sulfhydryl, 2-oxophenyl-2-methylphenylsulfinyl, 2-decyloxyphenylsulfinyl, phenylsulfinyl, 3-phenylphenylsulfinyl, 3 -Triflumurite yellow linyl, 3-oxophenyl sulfonyl, 3-nitrophenyl hexylene thioalkylthioalkyl group 6 to 1, 1-nylphenylthioalkyl, 3-based The phenyl thiocyanophenyl phenyl thiophenyl sulfane has a carbon number of 1 cherish, base, butyl octyl sulphate, twelfstone yellow wine, carbon number 6 ash, Sulfonyl, 2-butoxyphenyl sulphate,

S -82- 201213355 4-Denyl phenyl-based sulfhydryl, 4-cyano-phenyl sulfanyl, 4-methylsulfinyl, 4-mercaptosulfanylphenylsulfinyl, Phenyl phenyl sulfinylene, 4-dimethylamino phenyl sulfinate, and the like. The "amplified base group which may have a substituent" is preferably an alkylsulfonyl group having a carbon number of 20, and examples thereof include, for example, a mercaptosulfonate, a ', a 1 to a disc substrate, Propyl continuation base, isopropyl &lt;5 yellow brewing base, Dingguoqiao acid odor sulfonyl group, cyclohexyl sulfonyl group, octyl sulfonyl group, 2 hexyl G violent base group, sulfhydryl group Sulfonyl, fluorenyl sulfonyl, quinone # ' _ ^ octadecylsulfonyl, chalcylmethylsulfonyl, decyloxysulfonyl and the like. The "arylsulfonyl group which may have a substituent" is preferably an arylsulfonyl group having a carbon number of 6 to 3 Å, which may, for example, be a phenylsulfonyl group, a naphthylsulfonyl group, or a 2- Naphthylsulfonyl, 2-chlorophenylsulfonyl, 2-fluorenyl oxime, 2-decyloxyphenylsulfonyl, 2-butoxyoxysulfonyl 7 ^ chlorophenyl Sulfonyl, 3-trifluoromethylphenylsulfonyl, 3-cyanophenyl, 3-nitrophenylsulfonyl, 4-fluorophenylsulfonyl, 4-cyanobenzene Sulfonyl, 4-decyloxyphenylsulfonyl, 4, mercaptosulfanyl, phenylsulfonyl, 4-phenylsulfanylphenylsulfonyl, 4-dimethylaminophenyl Sulfonyl and the like. The fluorenyl group which may have a substituent is preferably a fluorenyl group having a carbon number of 2 to exemplified by, for example, an ethyl fluorenyl group, a propyl fluorenyl group, a butyl fluorenyl group, a trifluoromethylcarbonyl group, a amyl group, a benzamidine group, 1-naphthylfluorenyl, 2-naphthylfluorenyl, 4-nonylsulfanylbenzyl, 4-phenylsulfanylbenzoyl, 4-didecylaminobenzimidyl, 4 -diethylaminobenzamide, 2_gas benzoyl, 2-methylphenyl fluorenyl, 2-methoxybenzylidene, 2-butoxyphenylhydrazine, 3-gas Benzopyridinyl, 3-trifluoroindolyl, 3-cyano-83- £201213355 benzhydryl, 3-nitrophenylhydrazino, 4-fluoroindole, 4-chloro Mercapto, 4-methoxybenzylidene and the like. The "alkoxycarbonyl group or aryloxy group which may have a substituent is an alkoxycarbonyl group or an aryloxy group having a carbon number of 2 to 20, such as a decyloxycarbonyl group, an ethoxycarbonyl group, a propoxy group. Alkyl, hexyl hexyloxycarbonyl 'octyloxycarbonyl, oximeoxycarbonyl, oxycarbonyl, phenoxycarbonyl, trifluoromethoxycarbonyl, fluorenyl-naphthyl, 2-naphthyloxycarbonyl, 4-mercaptosulfanyl phenyloxycarbonyl, 4-alkylphenoxycarbonyl, 4-didecylaminophenoxycarbonyl, 4-aminooxyalkyl, 2-air phenoxy group, 2-methylphenoxy, 2-methoxyphenoxycarbonyl, 2-butoxyphenoxycarbonyl, 3-carbonylcarbonyl, 3-difluorodecylphenoxycarbonyl, 3-cyanophenoxy 3 -Nitrophenoxycarbonyl, 4-fluorophenoxycarbonyl, cardiocyanophenoxy, 4-decyloxyphenoxycarbonyl, etc. "Amineyl group which may have a substituent" is preferably a total carbon number An amine methyl sulfhydryl group which may, for example, be N-decylamine methyl ethyl carbamoyl group, N-propylamine methyl sulfonyl group, N-butylamine hexyl hexylamine fluorenyl group, N- Cyclohexylamine methyl sulfhydryl, 1 octylamine N N-decylamine fluorenyl, N-eighteen Hydrazinyl, N-phenyl, N-2-mercaptophenylamine fluorenyl, N 2 _ phenyl phenyl fluorenyl isopropoxy benzyl sulfhydryl, N-2- (2 -ethylhexyl)phenylhydrazine, N-3-cyclophenylaminoindenyl, N_3_nitrophenylamine曱N-3-cyanophenylaminecarbamyl, N_4_methoxyphenylamine氰 氰 氰 苯基 苯基 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Preferably, the benzyl benzene group is exemplified by butoxy octadecyloxy phenyl thiodiethyl benzyloxy phenoxycarbonyl, carbonyl is 1 to 1, N-based, N-fluorenyl, amine曱醯:, N-2-aminoamine thiol, N-4-t 'N-4-mercapto,

S-84-201213355 Ν, Ν-dimercaptocarbamyl, N,N-dibutylaminecarbamyl, N,N-diphenylaminecarbamyl and the like. The "amine-containing sulfonyl group which may have a substituent" is preferably an amine sulfonyl group having a total carbon number of from 0 to 30, and examples thereof include, for example, an amine sulfonyl group, an N-alkylamine sulfonyl group, and an N-aryl group. Aminesulfonyl, anthracene, fluorene-dialkylamine sulfonyl, anthracene, fluorene-diarylamine sulfonyl, fluorenyl-alkyl-fluorene-arylamine sulfonyl. More specifically, it may, for example, be fluorenyl-mercaptosulfonyl, fluorenyl-ethylamine sulfonyl, fluorenyl-propylamine sulfonyl, hydrazine-butylamine sulfonyl, decyl-hexylamine sulfonate Sulfhydryl, fluorene-cyclohexylamine sulfonyl sulfonyl, fluorenyl-octylamine sulfonyl sulfonyl, fluorenyl-2-ethylhexylamine sulfonyl sulfhydryl, fluorenyl-decylamine sulfonyl sulfonyl, hydrazine-octadecylamine sulfonate Sulfhydryl, fluorenyl-phenylamine sulfonyl, indole-2-ylphenyl sulfonyl sulfonyl, fluorenyl-2-ylphenyl sulfonyl fluorenyl, fluoren-2-yloxy-based sulfhydryl Sii , Ν-2-isopropoxyphenylamine continuation, N-3-chlorophenylamine sulfonyl, N-3-nitrophenylamine sulfonyl, N-3-hydroxyphenylamine Synthetic base, N-4 -nonyloxyphenylamine retinoyl, N-4-nitrophenylamine sulfonyl, N-4-dimethylaminophenylamine sulfonyl, N-4 - mercaptosulfanylphenylamine sulfonyl, N-4-phenylsulfanylphenylamine sulfonyl, N-methyl-N-phenylamine sulfonyl, hydrazine, hydrazine-dimethyl Aminesulfonyl, N,N-dibutylamine, N,N-diphenylamine acid group, and the like. The "amino group which may have a substituent" is preferably an amine group having a total carbon number of from 0 to 50, and examples thereof include, for example, an NH 2 , an N-alkylamino group, an N-arylamino group, and an N-decylamine. , N-sulfonylamino, N,N-dialkylamino, anthracene, fluorene-diarylamino, fluorenyl-alkyl-arylene-aryl, hydrazine, fluorenyl-disulfonyl Amine and the like. More specifically, it may, for example, be a fluorenyl-methylamino group, a fluorenyl-ethylamino group, a fluorenyl-propylamino group, a fluorenyl-isopropylamino group, an anthracene-butylamino group or a fluorene-tertiary Amino group, Ν-hexylamino group, Ν-cyclohexylamino group, Ν-octylamino group, Ν-2-85-201213355 ethylhexylamino group, N-decylamino group, N-octadecane Amino group, N-phenylhydrinylamino group, N-phenylamino group, N-2-nonylphenylamino group, N-2-phenylphenylamino group, N-2 -nonyloxyphenylamine , N-2-isopropoxyphenylamino, N-2-(2-ethylhexyl)phenylamino, N-3-phenylphenylamino, N-3-nitrophenylamine , N-3-cyanophenylamino, N-3-tris(methylphenyl)amino, N-4-decyloxyphenylamino, N-4-cyanophenylamino, N 4-trifluorodecylphenylamino, N-4 -methylsulfanylphenylamino, N-4-phenylsulfanylphenylamino, N-4-didecylamine Amino group, N-methyl-N-phenylamino group, N,N-didecylamino group, N,N-diethylamino group, N,N-dibutylamino group, N,N- Diphenylamino, N,N-diethylhydrazino, n,N-dibenylamino, N,N-(dibutylcarbonyl)amine, ν,Ν-(二Amino, hydrazine, hydrazine-(diethylsulfonyl)amine, hydrazine, hydrazine (dibutylsulfonyl)amine, hydrazine, hydrazine-(diphenylsulfonyl)amine A group, a morpholinyl group, a 3,5-dimercapto-morpholino group, a ° card a sitting group, and the like. The "phosphinyl group which may have a substituent" is preferably a phosphinylene group having a total carbon number of 2 to 5 Å, which may, for example, be a dimercaptophosphino group, a diethylphosphinyl group or a dipropylphosphine. , diphenylphosphinyl, dimethoxyphosphinyl, monoethoxyphosphinyl, diphenyl phosphinyl, bis(2,4,6-trimethylphenyl)phosphine Base. The "heterocyclic group which may have a substituent" is preferably an aromatic or aliphatic heterocyclic ring containing a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom. Examples thereof include, for example, a thienyl group, a benzo[b]thienyl group, a naphtho[2,3-b]thienyl group, a thiol group, a furyl group, a piperidyl group, an isobenzofuranyl group, an anthracene group. Sylylene, cyano, 2 Η-pyrrolyl, pyrrolyl, imidazolyl, pyridyl,

S -86- 201213355 Pyridyl, pyridinyl, pyrimidinyl, fluorenyl, fluorenyl, 3H-indenyl, fluorenyl, 1H-carbazolyl, fluorenyl, isoindolyl, quinoline Base, fluorenyl, acridine, oxazolinyl, porphyrin, acridine, 4aH-carbazolyl, fluorene, non-bite, bite, bite, morphine, Sulfhydryl, isothiazolyl, phenothiaphthyl, isoxazolyl, butyl, isodentate, anthracenyl. Specific to each of the bite group, π, sylylene, imidazolinyl, oxazolidinyl, pyrazolinyl, β-bottomyl, sulfhydryl, isoindolyl, quinidine, methicone, and the like. The "halogen atom" includes a fluorine atom, a gas atom, and a moth atom. The "dental alkyl group which may have a substituent" may, for example, be a difluoroindenyl group, a trifluoromethyl group, a di-halomethyl group, a trichloromethyl group, a dibromofluorenyl group or a tribromofluorenyl group. The "amylamine group which may have a substituent on the oxime" is a dimethylamino group, an anthracene, a fluorenyl-diethylguanamine group or the like. Further, the above-mentioned substituent group which may have a substituent, an aryl group which may be substituted, an alkenyl group which may have a substituent, an alkoxy group which may have a substituent which may have a substituent, and an alkyl group which may have an aryl group which may have a substituent An oxy group, an aryl group which may have a substituent, an aryloxy group which may have a substituent, an arylthioalkyl group which may have a substituent, an aryl group which may have a substituent fluorenyl group, may have a substituent, and an aryl group which may have a substituent a sulfonyl group, an alkylsulfonyl group, an arylsulfonyl group which may have a substituent, an isodecyl group, a 4-quinone-quinuclidinyl group, a decyl group, a β-β carbroquinone group, Morphoyl, morphine, imipenyl, hexahydro. Bilinyl, sulfur 4, bromine atom, :monofluoroindolyl, monobromoindole exemplified by: anthracene, fluorene-substituted alkynyl, oxy, thioloxy, thioalkyl, The alkylsulfinyl group may have a substituent of the -87-201213355 group, an alkoxycarbonyl group or an aryloxycarbonyl group which may have a substituent, an amine group which may have a substituent, and may have a substituent The aminesulfonyl group, the amine group which may have a substituent, and the heterocyclic group which may have a substituent may be further substituted with other substituents. Examples of the "substituent" include, for example, a halogen atom such as a fluorine atom, a gas atom, a bromine atom or an iodine atom, an alkoxy group such as a methoxy group, an ethoxy group or a tertiary alkyl group, or a phenoxy group. An alkoxycarbonyl group or an aryloxycarbonyl group such as an aryloxy group such as a p-tolyloxy group, a methoxycarbonyl group, a butoxycarbonyl group or a phenoxycarbonyl group, an ethoxy group, a propyloxy group or a benzoquinone group. a fluorenyl group such as an oxy group such as an oxy group, an ethyl fluorenyl group, a benzamidine group, an isobutyl group, an acryl fluorenyl group, a fluorenyl fluorenyl group or a fluorenyl fluorenyl group; An alkylthio group such as an alkylsulfanyl group such as a thioalkyl group, a phenylsulfanyl group or a p-tolylsulfanyl group; an alkylamino group such as a mercaptoamine group or a cyclohexylamino group; An arylamino group, a mercapto group, an ethyl group, a tertiary group such as a dialkylamine group, a phenylamino group or a p-tolylamino group, such as a arylamino group, a diethylamino group, a morpholinyl group or a piperidinyl group. Examples of the alkyl group such as a butyl group or a dodecyl group, an aryl group such as a phenyl group, a p-nonylphenyl group, a xylyl group, a cumyl group, a naphthyl group, an anthracenyl group or a phenanthryl group; Carboxylate Base, formazan, thiol, contig, hydrazine, p-toluene, amine, succinyl, cyano, trifluoromethyl, trichloromethyl, trimethyldecyl, monophosphoric acid A group, a phosphonic acid group, a tridecylammonium group, a decyl ammonium group, a triphenylphenyl fluorenyl group or the like. Among these, from the viewpoint of solvent solubility and improvement of absorption efficiency in a long wavelength region, X is preferably an alkyl group which may have a substituent, an aryl group which may have a substituent, an alkenyl group which may have a substituent, May have a substituent

S-88 - 201213355 alkynyl group, alkoxy group which may have a substituent, a group which may have a substituent, a thiol oxy group which may have a substituent, a thiol group which may have a substituent, may have a substituent The halogenated alkyl group, the amide group which may have a substituent group or may have a substituent on N, more preferably an alkyl group having a substituent. Further, in the general formula (III), n is an integer representing from 〇 to 5, and is preferably an integer from 〇 to 3, and is an integer of 0 to 2. In the general formula (III), when X is present in plural, X may be or be different. The photopolymerization initiator represented by the above formula (III) is shown below. The aryloxy aryl amine can be counted, better, the same body -89- 201213355

s -90- 201213355

The compound represented by the general formula (in) used in the present invention has an absorption wavelength in a wavelength region of 250 nm to 500 nm, and more preferably has an absorption wavelength in a wavelength region of 300 nm to 380 nm. The absorbance at 308 nm and 355 nm is the highest. -91 - 201213355 The amount of f used in the present invention is preferably 3% by mass or more based on the content of the coloring photosensitive resin and the fluorene initiator. "The next (4), the second is better and the better: the range of the mass% or less. The above 15 quality in the color sensitivity of the present invention) the monthly loss of the photopolymerization initiator: in addition to the range, Containing (D); = does not detract from the invention. j. „ Lanthanide photopolymerization initiator is a different &amp; other photopolymerization initiator [Right 丨!,,. Structure polymerization initiator"]. Hereinafter, the "(D-2) other light" (D) lanthanide photopolymerization initiator is a different structure (Ε)·2) Bean photopolymerization initiator is as long as the pot is ok... 苒...) The polymerization of the compound is promoted and the above (C) polymerization is promoted. Specifically, ^ can be used without limitation, such as the prior formula, #, 11, 11. For example, a porphin-based photopolymerization initiator, an organically-patterned compound, a gas-based _ into a t g. , . Carbonyl compound, condensate &amp; benzoate compound, azo compound, coumarin::, organic peroxylated gold sulphate, azide, dimer &amp;; an organic boronic acid compound, a disulfonic acid compound, a phosphonium salt, a mercaptophosphine (oxide) compound, and the like. The "manufactured by each of the photoinitiators of (D-2)" can be exemplified by, for example, a hexaaryldiamine compound. The hexaaryl-based di-salt compound is exemplified by, for example, 2,2,_bis (: benzyl)_4'4,5,5'-tetraphenyldiimidazole, 2,2, _bis (2) 'Phenylenediene' 4,4',5,5'-肆(4-ethoxydylphenyl) with two flavors. Sit, 2,2,-(2, fluorenylphenyl).4,4, , 5,5,·肆(4 phenoxyphenyl) two

S-92- 201213355 Imidazole, 2,2'-bis(2,4-diphenyl)-4,4',5,5'-indole (4-ethoxycarbonylphenyl)biimidazole, 2 , 2'-bis(2,4-dichlorophenyl)-4,4',5,5'-indole (4-phenoxycarbonylphenyl)biimidazole, 2,2'-bis (2, 4,6-trisylphenyl)-4,4',5,5'-indole (4-ethoxycarbonylphenyl)biimidazole, 2,2'-bis(2,4,6-trichloro Phenyl)-4,4',5,5'-indole (4-phenoxycarbonylphenyl)biimidazole, 2,2'-bis(2-cyanophenyl)-4,4',5 , 5'-肆(4-ethoxycarbonylphenyl)biimidazole, 2,2'-bis(2-cyanophenyl)-4,4',5,5'-indole (4-phenoxy) Benzyl phenyl)biimidazole, 2,2'-bis(2-mercaptophenyl)-4,4',5,5'-fluorene (4-methoxycarbonylphenyl)biimidazole, 2 , 2'-bis(2-mercaptophenyl)-4,4',5,5'-indole (4-ethoxycarbonylphenyl)biimidazole, 2,2'-bis(2-indenyl) Styrene)-4,4',5,5'-indole (4-phenoxycarbonylphenyl)biimidazole, 2,2'-bis(2-ethylphenyl)-4,4',5 , 5'-肆(4-decyloxycarbonylphenyl)biimidazole, 2,2'- (2-ethylphenyl)-4,4',5,5'-indole (4-ethoxycarbonylphenyl)biimidazole, 2,2'-bis(2-ethylphenyl)-4 , 4',5,5'-indole (4-phenoxycarbonylphenyl)biimidazole, 2,2'-bis(2-phenylphenyl)-4,4',5,5'-oxime (4-decyloxycarbonylphenyl)biimidazole, 2,2'-bis(2-phenylphenyl)-4,4',5,5'-fluorene (4-ethoxycarbonylphenyl) Bis-diimidazole, 2,2'-bis(2-phenylphenyl)-4,4',5,5'-indole (4-phenoxycarbonylphenyl) in combination with two imipenones, 2,2' - bis(2-phenylphenyl)-4,4',5,5'-tetra-(4-decyloxyphenyl)biimidazole, 2,2'-bis(2-chlorophenyl)-4 , 4',5,5'-tetrakis(3-methoxyphenyl)biimidazole, 2,2'-bis(2-phenylphenyl)-4,4',5,5'-tetra- (3,4-dimethoxyphenyl)biimidazole, -93- 201213355 2,2'-bis(2,4-dioxaphenyl)·4,4',5,5'-tetraphenyl Bis-diimidazole, 2,2'-bis(2,4,6-tris-phenyl)-4,4',5,5,-tetraphenyl in combination. Rice mouth, 2,2'-bis(2,4-dibromophenyl)-4,4',5,5'-tetraphenyldiimidazole, 2,2'-bis (2,4,6 -tribromophenyl)-4,4',5,5,-tetraphenyl-bisodium saliva, 2,2'-bis(2,4-dicyanophenyl)-4,4',5, 5'-Tetraphenyldioxazol, 2,2'-bis(2,4,6-tricyanophenyl)-4,4',5,5'-tetraphenyl-bi-iso-sodium 2,2'-bis(2,4-dimercaptophenyl)-4,4',5,5'-tetraphenyldidiimidazole, 2,2'-bis(2,4,6-triterpene Phenyl)-4,4,5,5,-tetraphenylbiphenylimidazole, 2,2'-bis(2,4-diethylphenyl)-4,4,5,5 ,-tetraphenyldioxazol, 2,2'-bis(2,4,6-triethylphenyl)-4,4',5,5'-tetraphenyldiimidazole, 2,2 '-Bis(2,4-diphenylphenyl)-4,4',5,5,-tetraphenyl-bi-sigmium. Sit, 2,2'-bis(2,4,6-triphenylphenyl)-4,4',5,5,-tetraphenyldiimidazole, 2,2'-bis(2-fluorobenzene Base)-4,4,,5,5,-tetraphenylbiguanide, and the like. Among the above, particularly preferred compounds are: 2,2,-bis(2-propenyl)-4,4',5,5'-tetraphenyl-bi-misoquinone (for example, Baotu Valley Chemistry) Industrial (Hodogaya Chemical Co., Ltd.) B-CIM), 2,2,-bis(o-phenyl)-4,4',5,5'-tetra(3,4-dimethoxy Phenyl) bi-position imiazole (for example, HABI 13 1 1 manufactured by Shiberuheguna, Japan), 2 2,-bis(2-anthracenyl)-4,4,5,5'-tetraphenyldiamine. Sit (for example, Kurogane Kasei Co., Ltd.). Further, an organic compound, an oxydiazole compound, a carbonyl compound, a ketal compound, a benzoin compound, an acridine compound, an organic peroxidation compound, an azo compound, a coumarin compound, an azide compound, or a metallocene Compound, organoboric acid compound, disulfonic acid compound

Specific examples of the S-94-201213355, rust salt compound, and mercaptophosphine (oxide) compound are listed in "Bull Chem. Soc. Japan" 42, 2924 (1 969), and U.S. Patent No. 3, Japanese Unexamined Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. 1 - 1 6 9 8 3 5, Japanese Patent Laid-Open No. 6 1 -1 6 9 8 3 7 , 曰本特开昭 62-5824 No. 1, and 曰本特开昭62-212401 Japanese Patent Laid-Open No. 63_7〇243, 曰本特开昭63-298339, μ. P. Hutt, “Journal of Heterocyclic Chemistry”, 1 (No. 3), (1 970), Japan Special Fair Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Bulletin, 曰本特开平 9 -1 8 8 6 8 5, Japanese Unexamined 9-1 8 8 6 8 6 , Japanese Special Kai 9-1 8 8 7 1 0 Japanese Gazette No. 2000-131837, Japanese Laid-Open Patent Publication No. 2002-107916, Patent No. 2764769, Japanese Patent Application No. 2000_3, No. 8-8, and the like, and Kunz, Martin "Rad Tech" The organic shed salt described in '98. Proceeding April 19-22, 1998, Chicago, et al., pp. 6 -1 5 7 6 2 3, pp. 6 - 1 7 5 5 6 Bulletin No. 4, 曰本特开平 6 - 1 7 5 5 6 1 , 曰本特开平 6 -1 7 5 5 5 4, Japanese Special Kaikai 6 - 1 7 5 5 5 3, Japan Kaiping No. 9-188710, 曰本特开平6-3480 1 1号, 曰本特开平 7 -1 2 8 7 8 5 Bulletin, 日+特开平7 _ 14 0 5 8 9 Bulletin, Japan Special Kaiping 7 - 3 0 6 5 2 No. 7 Bulletin, Japanese Patent Laid-Open No. 7 _ 2 9 2 〇1 4 -95-201213355, JCS Perkin II (1979) 1653-1660, JCS Perkin II (1 979) 1 56- 1 62. Journal of Photopolymer Science and Technology (1995) 202-232, JP-A-2000-663, 85, JP-A-2000-80068, and 曰本特表 2004-5 3 47 97 A photopolymerization initiator disclosed in the publication or the like. In the present invention, the content of the (D-2) other photopolymerization initiator is preferably 100 parts by mass or less based on 100 parts by mass of the (D) fluorene-based photopolymerization initiator. Further, the total amount of the photopolymerization initiator [(D) + (D-2)] with respect to the total solid content of the colored photosensitive resin composition is preferably in the range of 5 mass% to 20 mass%. It is preferably in the range of 5 mass% to 15 mass%, and more preferably in the range of mass% to 15 mass%. Further, when a compound having no absorption at an exposure wavelength is used as (D) a specific polymerization initiator or (D-2) other photopolymerization initiator, it is preferable to use a compound having absorption at an exposure wavelength as an increase or decrease. Agent. The sensitizer will be explained later. &lt;(E) Solvent&gt; The colored photosensitive resin composition of the present invention contains (E) a solvent and can be prepared by using (E) a solvent. Further, the above pigment dispersion composition was also prepared by using (E) a solvent. (E) The solvent may, for example, be an "ester" such as ethyl acetate, n-butyl succinate, isobutyl acetate, amyl citrate, isoamyl acetate, isobutyl citrate, butyl propionate, Isopropyl butyrate, ethyl butyrate, butyrate t-butyric acid, sulphate, lactic acid, lactic acid, oxyacetic acid, oxyacetic acid, oxyacetate , methoxyacetate, methoxy

S-96- 201213355 Ethyl acetate, butyl oxyacetate, decyl ethoxyacetate, ethyl ethoxyacetate, decyl 3-oxypropionate, ethyl 3-oxypropionate, etc. "Alkyl 3-oxypropionates" (for example, decyl 3-methoxypropionate, ethyl 3-methoxypropionate, decyl 3-ethoxypropionate, and 3-ethoxyl) "2-ethyloxypropionate alkyl esters" such as ethyl propionate or the like, oxime 2-oxypropionate, ethyl 2-oxypropionate or propyl 2-oxypropionate (for example, 2) - methoxy methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, decyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, 2 -oxy-2-mercaptopropionate, ethyl 2-oxy-2-mercaptopropionate, methyl 2-nonoxy-2-methylpropanoate, and 2-ethoxy-2 -ethyl methacrylate, etc.), methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetoxyacetate, ethyl acetoxyacetate, methyl 2-oxobutanoate, 2 - ethyl acetobutanoate, 1,3-butylene glycol diacetate, etc.; "ethers" such as diethylene glycol dimethyl ether, diethylene glycol diethyl ether, tetrahydrofuran, ethylene alcohol Methyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol methyl ether, propylene glycol mono-n-propyl ether, propylene glycol n-Butyl ether, tri-propylene glycol mono-n-butyl ether, propylene glycol phenyl ether, methyl oxacillin acetate, ethyl sarbutazone acetate, propylene glycol decyl ether acetate, propylene glycol ethyl ether acetate, Propylene glycol propyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol n-propyl ether acetate, propylene glycol diacetate, propylene glycol n-butyl ether acetate, propylene glycol acetate Phenyl ether ester, dipropylene glycol monodecyl ether acetate, dipropylene glycol n-propyl ether acetate, dipropylene glycol n-butyl ether acetate, trimethyl propylene glycol decyl ether acetate, etc.; -97- 201213355 Alkoxyalkyl esters of succinic acid, such as 3-methoxy butyl vinegar acetate, 酉a @文1 methoxybutyl ester, 2-mercapto-3-methoxy butyl acetate, acetic acid 3- Methyl-3-decyloxybutyl ester, 3_mercapto-3-inoxyl butyl acetate, 2-ethoxybutyrate acetate, acetic acid 4_B Oxybutyl butylate, 2-methoxypentyl acetate 酉s S 3 methoxy ketone, acetic acid 4 _ methoxy valerate, 2-methyl-3-decyloxypentyl acetate, acetic acid 3 _ mercapto-3-methoxypentyl ester, 3-methyl-4-decyloxypentyl acetate, etc.; "酉J, such as acetone, mercaptoethyl ketone, cyclohexanone, 2-heptanone, 3-heptanone, etc.; "fermentation", such as ethanol, isopropanol, etc.; "aromatic hydrocarbons", such as toluene, xylene, and the like. Among these, suitable are: methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl sarbutazone acetate, ethyl lactate, diethylene glycol dimethyl shresh, Butyl sulphate, methyl 3-methoxypropionate, 2-heptanone, cyclohexanide, ethyl carbitol acetate, butyl carbitol acetate, propylene glycol methyl bond, propylene glycol decyl ether Ester, propylene glycol ethyl ether acetate, 3-methoxybutyl acetate, 3-mercapto-3-yl butyl acetate, and the like. (E) The solvent may be used alone or in combination of two or more. a potent component such as a sensitizer, a surfactant, or a thermosetting resin. &lt; (F) Sensitizer&gt; The photosensitive resin composition of the present invention has an absorption of the wavelength of the photosensitive resin composition. # &amp;# π μ is used in the exposure to the sensitizer as a sensitizer, to ^ The initiation of the polymerization initiator 吋 ^ _ 知 A (D) 肟 light 丨叽 efficiency. Hunting by the salty

S -98- 1 Μ absorbable wavelength 201213355 exposure, (D) 肟 光 photopolymerization initiator component free radical or polymerization reaction of polymerized compound caused by it 〇 these sensitizers can be cited: A spectral sensitizing dye or dye, or a dye or pigment that interacts with an absorbing initiator. In the present invention, preferred auxins or dyes which can be used as sensitizers are: polynuclear aromatics (e.g., phenylene); 4 vocal (e.g., fluorescent yellow, blush, red algae, bengal rose) (R 〇se B enga 1)); cyanines (eg cyanine, oxacarbocyanine): merocyanoids (eg, anthocyanins); thiazide (eg thiazide, fluorene blue, Acridine (such as acridine orange, aflatoxin, acriflavine (such as phthalocyanine, metal phthalocyanine); 卟 类 ( 卟 ° forest, replaced by central metal 卟 Lin); chlorophyll a chlorophyll compound substituted by a central metal; Further, the sensitivity of the photopolymerization radiation or the polymerization inhibition of the substance due to oxygen can be further enhanced. The "thiol compound" is exemplified by: EGTP dithiopropionate, and butylene glycol dithiopropionate. (BDTP), ginseng-based propyl ketone (TMTP), thiopropionate neopentyl alcohol I, etc. Polyfunctional thiol compound; 2-hydrothiobenzene. Reacts, will be promoted, sensitized pigment light and photopolymerization enhanced color, Yuan, Liansan, Rose B, such as thiocarbocyanin, The carbonyl moiety isaniline blue)), phthalocyanine such as tetraphenyl. (for example, chlorophyll complex shark). J ° initiator pair of polymerized ethylene glycol ester (trithiol thioacetate (PETP) and. Seywa, 2-99-201213355 thiol benzoate per oxime, 0 w, 啥 琳 琳 m base Benzene^, 2-hydrothio-4(3η)·Ρ-wind 1-naphthalene, Ν-stupyl-hydrosulfanyl benzopyrene 官能 functional thiol compound.” Spears are especially stable from time to time. The sulphur compound is preferably a monofunctional thiol oxime, and the thiol compound in the coloring photosensitive resin composition is produced by the equilibrium of the polymerization growth rate and the chain transfer. The viewpoint of the speed of hardening, the composition of the phase, the sensitivity of the tree, and the total solids of the product, more preferably: ή in the range of 5.5 mass% to 10 mass% "', · quality ® % To the range of 5% by mass. <Other Additives> (Α) Ben:: To (in addition to the essential ingredients, the (in addition to the essential ingredients), the () component and the preferred combination (F) The composition contains other additives as needed. The additives are described. The medium is a surfactant (surfactant). The colored photosensitive resin composition of the present invention is It may contain interfacial activity, so it is easy to θ Γ: when Γ concentration, the thixotropy of the coating liquid usually becomes larger. This is easy to occur after the composition on the substrate &amp; In addition, especially if:: (color layer coating film) coloring minus # w 疋 疋 疋 为 为 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用 使用When the coloring of the well-behaved tannin 4 is formed before drying, it is important to level the coating liquid to form a coating layer having a uniform thickness. Therefore, it is preferable to

S-100- 201213355 The color photosensitive resin crucible contains a suitable surfactant. The surfactants described in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. A nonionic surfactant, a fluorine-based surfactant, a quinone-based surfactant, or the like may be added to the surfactant for the coating. The ^ ion-based surfactant is exemplified by, for example, polyoxygen. Alkene-g subclass, polyoxypropylene glycol-based polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, poly(ethylene terephthalate), polyoxypropylene alkyl ether oxime, &amp; oxypropylene "Non-ionic interface interactions" such as aryl aryl ethers, polyoxy propylene alkyl esters, sorbitan hydroxy groups, and glycerol hydrazine groups. Specifically, it includes: polyoxyalkylene glycols such as polyoxyethylene diol and polyoxypropylene diol; polyoxyethylene lauryl ether, polyoxypropylene stearyl ether, polyoxyethylene oleyl ether Such as "polyoxyalkylene alkyl ethers", polyoxyethylene octyl phenyl ether, polyoxyethylene - polystyrene ether, polyoxyethylene trityl phenyl ether, polyoxyethylene - propylene polystyrene "Polyoxyethylene aryl ether" such as alkalized ether or polyoxyethylene phenyl phenyl ether; polyoxyalkylene dioxane such as polyoxyethylene dilaurate or polyoxyethylene distearate "Non-ionic surfactant" such as a base ester", a sorbitan fatty acid ester, or a polyoxyalkylene sorbitan fatty acid ester.

Specific examples include, for example, Adekapluronic, Adekanol, Tetronic (above ADEKA), EMULGEN, RHEODOL (above Kao Corporation), ELEMINOL, NONIPOL OCTAPOL -101 - 201213355, DODECAPOL, NEWPOL (above is Sanyo Chemical Co., Ltd.), PAIONIN (Takemoto Oil &amp; Fat Co., Ltd.), NISSAN NONION (曰本油(股) (made by NOF Corporation)). These commercially available persons can be used as appropriate. The preferred H L B value (hydrophilic-lipophilic balance value··H y d r 〇 p h i 1 e - L i ρ 〇 p h i 1 e Balance) is from 8 to 20, more preferably from 10 to 17. The fluorine-based surfactant is preferably a compound having a fluoroalkyl group or a fluoroalkyl group at a site of at least one of a terminal, a main chain and a side chain. Specific commercial products can be listed, for example, MEGAFACE F142D, with F172, with F173, with F176, with F177, with F183, with F780' with F781, with F782, with F784, with F552, with F554, with R30, with R08 (above is DIC (DIC)), FLUORAD FC-135, FC-170C, FC-430, and FC-431 (above is Sumitomo 3M Co., Ltd.) )), SURFLON Sl 1 2, same as S-1 1 3, same as S-1 3 1 , same as S-1 4 1 , same as S-1 45, with S-382, with SC-101, with SC-102 Same as SC-103, same SC-104, same SC-105, same SC-106 (above is Asahi Glass Co., Ltd.), EFTOP EF351, same 352, same 801, same 802 (The above is manufactured by JEMCO Co., Ltd.). Examples of the "lanthanide surfactant" include TORAY SILICONEDC3PA, DC7PA, SH11PA, SH21PA, SH28PA, SH29PA, SH30PA, SH-190, SH-193, and SZ-6032. -8428, the same DC-57, the same DC-190 (above is Toray-Dow Corning Silicone Co.), TSF-4440, TSF-4300, TSF-4445, s -102- 201213355 TSF-4446, TSF-4460, TSF_4452 (The above is - manufactured by GE-Toshiba Silicone Co., Ltd.). Among these, preferred surfactants in the present invention are the same as F784, F552 MEGAFACE F780, F781, F782, and F554 (the above is DIC). The coloring sensitivity with respect to 100 parts by mass is more preferably used in the case of these surfactants in an amount of 2 parts by mass. If the interface is active, it is easy to produce when the coating is dry. The resin composition is preferably 5 parts by mass or less, more preferably 0.5 parts by mass or more, and when the amount of the agent used is more than 5 parts by mass, the streaks or the surface are rough and smooth (thermosetting) Resin) The colored photosensitive resin composition of the present invention is a thermosetting resin containing an epoxy resin, an oxetane resin, or the like as needed. Epoxy Zhiyue 曰疋 includes: double-type A type, 曱 § divided into more varnish type, biphenyl type, alicyclic epoxy compound. For example, "bisphenol A type" is exemplified by: EPOTOHTO YD-115, YD-118T 'YD-127, YD-128, YD-134, YD-8125, YD-701 1R, ZX-105 9, YDF-8170, YDF-170, etc. (above is manufactured by Tohto Kasei Co., Ltd.), DENACOL EX-1101, EX-1102, EX-1103, etc. (The above is manufactured by Nagase ChemteX Corp.), PLACCEL GL-6 1, GL-62, G 1 0 1 , G102 (the above is manufactured by Daicel Chemical Industries, Ltd.) and the like. Other examples include bisphenol F type and bisphenol S type similar to these. Further, an epoxy acrylate such as Ebecryl 3700, 3701, 600 (the above is DAICEL-UCB (manufactured by DAICEL-UCB Company Ltd.)) can also be used. -103- 201213355 "Glycol novolac type" includes: EPETOHTOYDPN-638, YDPN-701, YDPN-702, YDPN-703, YDPN-704, etc. (above is Dongdu Chemical Co., Ltd.), DENACOL EM-125, etc. The "biphenyl type" includes "3,5,3',5'-tetradecyl-4,4'-diepoxypropylbiphenyl, and the like. "Cycloaliphatic epoxy compound" includes: CELLOXIDE 202 1 &gt;2081'2083'2085' EPOLEAD GT-3 01 'GT-3 02 ' GT-401, GT-403, EHPE-3150 (The above is Daicel Chemical ), SUNTOHTO ST-3000, ST-4000, ST-5080, ST-5100, etc. (The above is Dongdu Chemical System). Further, it is also possible to use a non-polymeric epoxy resin such as EPOTOHTO YH-434, YH-434L, or a bisphenol A type epoxy resin modified by a dimer acid. Among these epoxy resins, a novolac type epoxy compound and an alicyclic epoxy compound are preferable, and those having an epoxy equivalent of from 18 to 25 are particularly preferred. These materials are listed as EPICLON N-660, N-670, N-680, N-690, YDCN-704L (above DIC) and EHPE3150 (made by Daicel Chemical). As the "oxetane resin", ARON OXETANE OXT-101, OXT-121, OXT-211, OXT-221, OXT-212, OXT-610, OX-SQ, PNOX (the above is manufactured by Toagosei Co., Ltd.) can be used. Further, the oxetane resin may be used alone or in combination with an acrylate-based copolymer, an epoxy resin, and a maleimide resin. In particular, when used in combination with an epoxy resin, the reactivity with heat generated by ultraviolet laser exposure is high, which is preferable from the viewpoint of adhesion to the substrate.

In the present invention, the content of the epoxy resin and the oxetane resin in the colored photosensitive resin composition is preferably based on the total solid content of the colored photosensitive resin composition. From 0.5 to 15% by mass, from the viewpoint of both the solubility to the alkali and the adhesion to the substrate, it is preferably from 1 to 10% by mass. (Organic carboxylic acid) When the alkali solubility of the uncured portion is promoted and the developability of the colored photosensitive resin composition is further improved, an organic carboxylic acid may be added, and a low molecular weight organic organic compound having a molecular weight of 1,000 or less is preferable. carboxylic acid. Specifically, for example, citric acid (sugar acid), acetic acid (acetic acid), propionic acid, butyric acid (butyric acid), valeric acid (shikimic acid), tridecyl acetic acid, hexanoic acid, diethyl acetic acid, "aliphatic monocarboxylic acid" such as heptanoic acid or octanoic acid; oxalic acid (oxalic acid), malonic acid, succinic acid (succinic acid), glutaric acid, adipic acid, pimelic acid, suberic acid, hydrazine Diacid, azelaic acid (lipe acid), barium diacid (tridecanedioic acid), mercaptomalonic acid, ethylmalonic acid, dimercaptomalonic acid, mercapto succinic acid, tetradecyl "Aromatic dicarboxylic acid" such as succinic acid or citraconic acid; "aliphatic tricarboxylic acid" such as 1,2,3-propanetricarboxylic acid, aconitic acid, and samarium trisulphate; benzoic acid, orthoquinone "Aromatic monocarboxylic acid" such as benzoic acid, lauric acid, 2,3-dimethylbenzoic acid or 3,5-dimercaptobenzoic acid: phthalic acid, isophthalic acid, Terephthalic acid ' trimellitic acid (1,2,4-benzenetridecanoic acid), trimesic acid (1,3,5-benzenetridecanoic acid), pyromellitic acid (1,2 , 3,5-benzenetetracarboxylic acid), pyrophoric acid, (1,2,4,5-benzenetetradecanoic acid), etc. Aromatic polycarboxylic acids "; phenyl acetic acid, phenoxy acetic acid, acetic methoxyphenoxy, hydrogen atropic acid, cinnamic acid hydrogen, mandelic acid (mandelic acid), phenyl acid, atropic acid

S-105- 201213355, other acids such as cinnamic acid, cinnamic acid acetic acid, coumaric acid, and succinic acid. (Chane coupling agent) In the coloring photosensitive resin composition of the present invention, a decane coupling agent can be used from the viewpoint of further improving the adhesion to the substrate. The decane coupling agent is preferably one having an alkoxyalkyl group as a hydrolyzable group capable of chemically bonding with an inorganic material. Further, it is preferably a tool. The group may exhibit affinity with an interaction or bond formation with an organic resin, and these groups preferably have a (fluorenyl) acrylonitrile group, a stupid, a thiol group, a propyl group, an oxa group. The cyclobutane group is preferably one having a (meth) acrylonitrile group or an epoxy propyl group. That is, the decane coupling agent used in the present invention is preferably a compound having a methoxyalkyl group, a (meth) acryl fluorenyl group or an epoxy group, and specifically, it may be exemplified by the following structure (A) Base) propylene sulfhydryl _ = m monomethoxy zephyr compound, epoxy propyl-trimethoxy oxylate compound, and the like. 〇&quot;&quot;^=^0 八/3ί(〇〇Η3)3 (^〇8'Si(OCH3)3 The amount of addition when using a decane coupling agent is used in the colored photosensitive resin composition of the present invention. Of the total solid components, preferably at 0.2

-106- 201213355 Berry 0 / 〇 to 5 · 〇 mass% range, more preferably 〇 5 mass% 炱 3 · 0 mass%. (Polymerization Inhibitor) In the production or storage of the colored photosensitive resin composition, in order to suppress unnecessary thermal polymerization of the polymerizable compound, it is preferred to add a small amount of the thermal polymerization inhibitor. The "thermal polymerization inhibitor" which can be used in the present invention is exemplified by hydrazine (hydrhydric quinone), p-nonoxylated phenol, di-tertiary butyl-p-cresol, gallic phenol, tertiary butyl tea. Phenol, benzoquinone, 4,4,-thiobis(3-indolyl-6-tert-butylbenzene), 2,2,-indenyl bis (heart methyl-6-tertiary butylphenol) ), N-nitrosophenylhydroxylamine first sulfonium salt, morphine, thiophene, and the like. The amount of the thermal polymerization inhibitor added is preferably from 1% by mass to 5% by mass based on the coloring photosensitive resin composition. Further, it is also possible to add a higher fatty acid derivative such as saponin or succinic acid to prevent the polymerization from being hindered by oxygen, and the drying process after coating is biased on the surface of the photosensitive layer.高级 5% by mass to 1 〇 (plasticizer) The amount of the high-fat fatty acid derivative is preferably the mass of the coloring photosensitive resin composition. /〇. Further, (10) A i In the present invention, an inorganic filler or a plasticizer may be added to improve the colored photosensitive resin group. Plasticization Qi i| a 〗 疋 : 疋 疋 疋 疋 疋 i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i Trimethyl phthalate ia 'dioctyl adipate, azelaic acid-107-201213355 dibutyl ester, and adhesive 〇 〇 exposure method sensitivity and hard exposure method, from suppression to laser combination used in "pattern The present invention is suitable for liquid use. The present invention is an exposure color layer formed by forming a color-sensitive color layer in the liquid crystal forming method. It is also possible to provide a trityl glycerin or the like by roasting and developing, and the like. (C) The total mass of the polymerizable resin may be added in an amount of 1% by mass to brighten the photosensitive resin composition, which may be previously cured by exposure to ultraviolet light, and may be formed on the substrate. High density. Violet is a viewpoint that can be used for the surface reticulation in the laser exposure method and the proximity exposure method. The coloring method of the color filter of the present invention, and the colored color-sensitive photosensitive dendrite display device are described by color filter using a color-colored photosensitive resin display device, but the pattern forming method of the moon is a photo-resin composition. The step of forming the latent image by the colored layer and forming the pattern of the enamel colored layer of the colored layer by one person shadow is collectively referred to as "pattern coloring photosensitive resin composition pattern formation. The manufacturing method thereof is a fat composition and a pattern forming filter. Hereinafter, the invention in the method of forming a pattern forming a square light sheet of the composition is not limited thereto, and the feature is that it includes: Forming a coloring pattern by a violet step; and forming the developed step. And, a step (prebaking step) (baking step). Sometimes a step is formed. The amount of the compound can be as high as the external light - the more suitable method is the method that will make the method, the method of patterning, the external light thundering image of the layer of the invention, and the drying,

S-108-201213355 [Coloring layer forming step] In the coloring layer of the present invention, the coloring layer is formed by imparting a light-sensitive resin composition of the present month on the substrate. The earth plate is exemplified by, for example, a liquid crystal display glass, a soda lime glass, a borax citrate, a sputum, a ... a transparent conductive film, a glazed glass, a sapphire glass, and a U, or a solid Photoelectric conversion of imaging elements, etc. A plastic substrate can also be used. It is preferable to form the black matrix into a lattice shape or the like using these substrates, and form a color pattern in the sub-layers. t two out.丨 On these substrates, a base coat may be provided as needed to improve adhesion to the upper layer, prevent diffusion of substances, or planarize the surface of the substrate. Since the effect of the present invention can be more apparent, the substrate is preferably a large one (about one side of i square or more). A method of forming a coloring layer on a substrate to impart the coloring photosensitive resin composition of the present invention is applicable by slit coating, inkjet method, square-turn coating, cast coating, roll coating, screen printing. The method of imparting various coating methods. From the viewpoint of accuracy and speed, slit coating is preferred in the coating method. Further, a method of transferring a coating film formed on the temporary support body by the above-described coating method onto a substrate can also be applied. Regarding the transfer method, it is also suitable for use in the paragraphs [0023], [0036] to [〇〇51], or 曰本特开2006-47592 of the Japanese Patent Publication No. 2006-23696. The manufacturing method disclosed in paragraphs [0096] to [0108]. -109- 201213355 In order to obtain a sufficient color reproduction area, and the sufficient color of the panel in the present day and month is preferably formed to a thickness of 3.0/Zm after drying, more preferably 丨5# claw to 2^ with claws. [Drying step] The solvent may be dried by vacuum drying (v c D ) in the same manner as in the above-mentioned coloring photosensitive resin composition. Further, the coating film on the substrate may be further dried by heating to obtain a colored layer. The prebaking temperature of the coating film is preferably "it to l4 〇 c &gt; c, more C to 12 (TC. Further, the prebaking time is preferably 3 sec seconds to be in the 'more preferably 80 sec. [Exposure step] The exposure step in the present invention is a step of forming the coloring layer by exposure to ultraviolet light and hardening the exposed region. According to the exposure step of the present invention, In the patterned exposed region of the colored photosensitive product, (1) the initiating species generated by the specific polymerization is generated and (c) the polymerizable compounding hardening reaction is performed to form the hardened region and the unhardened region. The laser excitation medium is composed of crystal, glass, liquid, gas, etc., and can be used in a mine having an oscillation wavelength in the ultraviolet region, such as a solid laser, a liquid laser, a gas laser, or the like. From the viewpoint of the output power of the laser and the oscillation wavelength, it is a body laser and a gas laser. In the exposure wavelength of the ultraviolet laser used in the present invention, the photosensitive wavelength of the photosensitive resin composition is colored and the sensitivity is good. , after 0.5 bundles, dry (Pre-baked is a case of 80 300 seconds pattern-like latent image resin group initiator. Pigment, semi-conducting. Its I is a solid point, compared with -110- 201213355, preferably at 300 nm to The range of 380 nm, more preferably in the range of 310 nm to 3 60 nm, is particularly suitable for the laser exposure method of 355 nm wavelength. Specifically, it is particularly suitable for using solids with high output power and relatively inexpensive. The third highest order wave (355 nm) of the Nd: YAG laser (Titanium: Yttrium-Aluminum-Garnet Laser) or the Xeci (308 nm) of excimer laser light XeF ( 3 53 nm). Further, the exposure amount of the exposed object (pattern) may be in the range of 1 mJ/cm 2 to 100 mJ/cm 2 'more preferably in the range of 1 mJ/cm 2 to 50 mJ/cm 2 . When the amount of exposure is in this range, it is preferable from the viewpoint of productivity of pattern formation. From the viewpoint of productivity, the ultraviolet laser used in the present invention is preferably from 20 Hz to 2 〇〇. Pulse laser oscillating at a frequency of 〇 Hz. The exposure apparatus used in the present invention can be used without any particular limitation, and a commercially available EGI can be used. S (v Technology Co., Ltd.) or

. It is also suitable to use a split other than the above.

The linearity of the pattern can be increased. [development step]

The coloring layer of the latent family is formed and developed, and the step of patterning the -111-201213355 pattern by removing the unexposed portion in the exposed region is performed. Face Mountain &amp; Case, at the development site! The exposed area of the laser has been hardened to the unexposed step of the photo-lighting step: by performing the development process 'removing the % of the exposure (unhardened portion) to the alkaline water solution to remove 'to only & , part of the night, the hardening of the hardening 'by this can form a pattern of the scene> liquid is the organic alkali developer or inorganic alkali developer used in the combination of Shita mixture or its mixture for development, A "." "Night alkaline agent" is exemplified by, for example, hydrogen 4 servant sodium, potassium hydroxide, π * chylolysis, ammonia water, sodium ethylamine, sodium carbonate, sodium sulphate, sodium hexanoate Descending an organic test compound such as dihydrogenamine diamine, dimethylethanolamine, tetrahydrobiphenyl hydroxide-[5.4.〇], 7丄*, L8-II, and dilute compounds Preferably, the concentration is from 〇.〇1 to the release concentration of from 0.0001 to 10% by mass. Further, in the case of developing the mixture, it is usually developed by developing the developer solution of the aqueous solution of the test solution/after washing with pure water (the washing and developing temperature is preferably 2CTC to 3rc is good,...

. The development time is better Α π # #住4 23 C to 30〇C to von 30 seconds to 12 〇 seconds to... Among these, the development temperature / preferably 4 &quot; less clock combination is: ... temperature 5t is 5 〇: clock; 0: the preferred temperature is 40 seconds to 8 sec. In the case of 1 to 10 seconds, in addition, the dusting force of the spray is preferably 〇〇1 Mp is 〇.MMPa to 〇.3MPa, especially preferably 〇1^.5 milk, and better measures are selected as appropriate. , can be a to WMPa. In a rectangular shape, or a forward tapered shape. Arbitrarily designed shape

S-112-201213355 [Post-baking step] In the present invention, it is preferred to set A « Λ ^ for the baking step of the aforementioned colored layer for baking, so that the coloring salt, ^ ^ The hardening of the precursor resin composition becomes the one. The method of baking can be used to develop and wash the pattern of the liver: using a hot plate or a convection oven (hot air circulation type drying-frequency heating machine, etc., heating in a continuous or batch manner) The condition of 18〇2 roasting is the temperature is better than...5〇°C to WC, more preferably 1() 八26〇°C, the best is 2〇〇°^ 24〇°C. 1 〇 minutes to i 5 〇 八# * . Good for 20 points (four) Qn knife minutes to 120 minutes, the most knives to the benefit of 90 minutes. Coloring = 'In the formation of RGB trichrome, shading layer, etc. : The temple can repeat the formation of the colored layer by forming, exposing, developing and baking the desired color phase. It can also be formed according to the formation, exposure and development of the color layer of each color phase. All the colors yy β. j ^ σ are baked. Thereby, a color light film having a colored element including a desired hue can be obtained. "Liquid Crystal Display Device" The color filter of the present invention is suitable for manufacturing a liquid crystal display device. And the color filter manufactured by the pattern forming method of the invention is a &lt;Daily display device High-quality images. The definition of the display device or the description of each display device has been described in, for example, "Zeng 2 3 A" sub-display device (Akio Sasaki), industrial survey "&amp; w ^ (Kogyo Chosakai Publishing Co., Ltd.) 1990, "", "display device (Sumiaki Ibuki -113-201213355, industry book (share) (Sangy〇 Tosho Publishing Co., Ltd. ) Heisei published in the year of the year) and so on. Further, the liquid crystal display device has been disclosed, for example, in "Second Generation Liquid Crystal Display Technology (Edited by Tatsuo Uchida, Industrial Research Association (2014)"). The liquid crystal display device to which the present invention is applicable is not particularly limited, and can be applied to, for example, various types of liquid crystal display devices described in the "Second Generation Liquid Crystal Display Technology". The color filter for a liquid crystal display device is particularly effective for a liquid crystal display device of a color TFT (color thin film transistor) type. A liquid crystal display device of a color TFT type has been disclosed, for example, in "Color TFT Liquid Crystal Display (Kyoritsu Shuppan Co., Ltd., published in 1996)". Furthermore, the present invention is also applicable to a book cutting method such as a transverse electric field driving method such as IPS (in-plane switching type: in_piane switching) or MVA (multi-domain vertical Alignment). LCD display device that expands the viewing angle, or STN (Super Twisted Nematic), TN (Twisted Nematic), VA (Vertical Molecular Alignment: Vertical)

Alignment ), IPS, OCS (optical compensation bending type: Optically

Compensated Bend), FFS (Fringe Field Switching), and R-OCB (Reflective Optically Compensated Bend). The image display methods for such images are disclosed in, for example, "EL (Electro-Glowing), PDP (Electro-Polarization Display), LCD Display-Technology and the latest trend of the market (Dongli Research Center Research and Research Department (Research)

S -114- 201213355

Study Division of Toray Research Center, Inc_) '2〇〇1 year publication), page 43 et al. The liquid crystal display device includes, in addition to the color filter, various members such as an electrode substrate, a polarizing film, a retardation film, a backlight, a spacer, and a viewing angle compensation film. The color filter for a liquid crystal display element of the present invention is a liquid crystal display device which can be applied to such a conventional member. The components for such are published in the market for chemicals such as r, 9 4 liquid crystal display materials (Kentar〇Shima, CMC Publishing Co., Ltd.), published in 1994. """ The current status and future prospects of the liquid crystal-related market in 2003 (Volume 2) (Ryokichi Omote, Fuji Chimera Research Institute, Inc., 2003). The backlight is described in SID meeting Digest 1380 (2005) (A. Konno et al.); or the monthly display (M〇nthly DISPLay), December 2005, pages 18 to 24 (Hiroyasu Shima) )) 'Sections 25 to 30 (Takaaki Yag (1), etc. If the color filter manufactured by the pattern forming method of the present invention is used in a liquid crystal display device' and with the conventional three-wavelength of the cold cathode tube When the tube is combined, 'high contrast can be achieved, but by using the red, green and blue LED (light emitting diode) light source (rgb-LED) as the backlight, it can provide high brightness and high color purity. The liquid crystal display device having good reproducibility. [Examples] -115-201213355 However, in this example, the mass of the synthetic mixture tree was 200, and it was precipitated in a 1-all flask of an acid acrylic acid 0.185 j for 2 hours. The high score of the object is in the weight of »South, and the adhesive layer (曱基80/20, the present invention is described in more detail by way of examples. The invention is not limited to the following unless it departs from the gist thereof. In addition, unless otherwise stated In addition, "%" and "parts" are used as a benchmark. Example 1. Synthesis of base-soluble resin 1 containing propyl propyl [(B-2) viscous] &gt; f, thermometer * liter three-necked flask 'fed with 54 grams of 1-decyloxy 2 - propanol under nitrogen gas flow to 70 it. 10.07 grams of mercapto propylene, 1.93 grams of methacrylic acid, and as a polymerization A solution of the initiator 2,2, bismuth bis(2,4-dimethylvaleronitrile) dissolved in 54 g of oxy-2-propanol, and a three-necked 2.5-hour drop using a plunger pump After the completion of the dropwise addition, the mixture was further stirred at 7. After the end of the heating, it was poured into liters of water to reprecipitate it. After filtration, it was vacuum dried to obtain 9 g (yield 75%) of the sub-compound. In the above, weighed the obtained polymer of 〇·0丨克 as the average sample of the sample 1, and added about 8 ml of tetrahydroanthracene to dissolve at room temperature and then adjusted the total amount to 1 〇 ml. GPC) The solution was determined. The result was an alkali soluble resin i allyl acrylate/mercaptoacrylic acid copolymer, molar ratio = lower Structure) The weight average molecular weight 35,000

〇 alkali soluble resin 1

S-116-201213355 &lt;Synthesis Example 2: Binder Resin B-1 -1> 7.8 3 parts of pentylenetetral (3 - thiopropyl propionate) [DPMP; 琢Chemical Industry Co., Ltd. (Sakai Chemical Industry Co., Ltd.), the following structure], and 1 5.5 parts of the compound (A-1) having the following adsorption site and having a carbon-carbon double bond dissolved in 93.60 parts Mercaptoamine was heated to 70 ° C under a stream of nitrogen. 0.06 parts of 2,2,-azobis(2,4-dimethylvaleronitrile) [V-65, manufactured by Wako Pure Chemical Industries, Ltd.] was added and heated. 3 hours. Further, 0.06 part of V-65 was added, and the reaction was carried out at 7 ° C for 3 hours under a nitrogen gas stream. Next, it was cooled to room temperature to obtain a 20% solution of the reaction product of DPMP and Compound A-1.

HS-CHj-CHj-C-O-/CH2-0-C-CH2-CH2-SH

HS-CH2-CH2-C-0-CH2Sc^CH2-0^CH2 CH2~°~^~CH2-CH2-SH HS-CH2-CH2-C-〇-CH2/ XCH2—〇-C-CH2'CH2- SH / Ο 0 / and '23.4 parts of the above reaction product 20% solution, and 18 parts of decyl decyl acrylate (MMA; monomer), 2 parts of decyl propylene hydrazine mixed solution under a nitrogen stream Heat to 8 〇. Add 〇. 〇〇 7 parts of 2,2'-azobis(diisobutyronitrile) [AIBN, Wako Pure Chemical Industries, Ltd.] and heat for 3 hours, then add 〇〇〇7 parts. AIBN was reacted at 801 for 3 hours under a nitrogen stream. Then, it was cooled to room temperature and diluted with acetone. After using an excess amount of decyl alcohol to make it splash again, it was vacuum-dried to obtain 19 parts of the polymer compound of the present invention as shown below (B-1-1: polystyrene-converted weight average molecular weight: 32,000) s solid type. Further, in the following formula (b""), the content ratio '' of the structural unit included in the polymer skeleton of -117-201213355 is p1 : p2 = 90:10.

[Example 1] (Preparation of coloring photosensitive resin composition) (1 - 1. Preparation of pigment dispersion liquid 1) The pigment dispersion liquid 1 was prepared in the following manner. That is, the composition as described below was stirred with a homogenizer at a number of revolutions of 3,000 rprn. for 3 hours to mix 'to prepare a mixed solution, and then a bead disperser nanometer using 0·1 mmcp cerium oxide beads. The microparticle dispersing device (Kotobuki Industries Co., Ltd.) carried out an 8-hour dispersion treatment.

S CI Pigment Blue 15:6 [(A) Colorant] 1 1.8 parts CI Pigment Violet 23 [(A) Colorant] 1.0 part DISPERBYK 161 (BYK Chemie 24 pcs) (30% solution) Propylene glycol hydrazide Ether ester (hereinafter 63.2 parts is referred to as "PGMEA") Total 100 parts 118 201213355 (1 - 2. Preparation of photosensitive resin composition) 3 parts of the obtained 9.2 parts of pigment dispersion 1 and The mixture was stirred to prepare a blue (B) product. • Alkali-soluble resin 1 [ ( B-2 ) binder resin] • Alkali-soluble resin (B -1 -1 ) [ ( B -1 ) binder resin] • ( C ) Polymeric compound: hexa-acrylic acid Pentaerythritol ester (manufactured by Sakamoto Chemical Co., Ltd., KAY ARAD DPHA) • C) Polymeric compound: tetrapropyl decyl decyl decyl ester / Xinzhongcun Chemical Co., Ltd., NK ESTER A-TMMT • ( D ) oxime photopolymerization initiator: compound A (structure described below) • ( F ) sensitizer [monofunctional thiol compound SH-1 (structure described below)] • epoxy compound: (Dai cel chemistry (Stock), EHPE3 150) • (E) Solvent: a mixture of propylene glycol decyl ether acetate and ethyl 3-ethoxypropionate (=80/20 (mass ratio)) • Polymerization inhibitor: Pair A Oxyphenol plus the following composition of light resin group 8.2 parts 8.2 parts 3.9 parts 0.69 parts 2.74 parts 0.5 5 parts 0.60 parts 35.9 parts 0.001 parts -119- 201213355 .02 parts of surfactant 1 MEGAFACE F-554 (made by DIC company)

Cl

Compound A SH-1

r^VN I Ksh [Examples 2 to 15 and Comparative Examples 1 to 6] (B-1) binder resin, (A) colorant, (in addition to the coloring photosensitive resin composition of the above-mentioned Example 1) D) The type and content of the quinone-based photopolymerization initiator and the content ratio of the (B-2) binder resin were changed to those described in the following Tables 1 to 7, and the other examples were prepared in the same manner. 5. The colored photosensitive resin compositions of Comparative Examples 1 to 6. Further, in the following table, the numerical value of the (C) polymerizable compound is the number of functional groups representing the polymerizable compound to be used, and the r ratio "is a polymerizable compound having five or more functional groups, and one to four functional groups. The content ratio of the compound.

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201213355 Evaluation of a coloring photosensitive resin composition - (Formation of a patterned pixel) The coloring photosensitive resin compositions of Examples 1 to 15 and Comparative Examples 1 to 6 obtained as described above were described in an alkali-free glass substrate. (On the surface of Corning Incorporated, 1737, 550 mm X 660 mm), after coating with a slit coater (Hirata Corp., HC-6000), at 90 ° C Prebaking was carried out in a clean oven for 120 seconds to form a coating film (colored layer) having a film thickness of 2.0/zm to obtain a substrate with a coating film. (Coloring layer forming step) Next, the laser exposure device uses an EGIS (manufactured by V Technology, the third higher order wave of the YAG laser (3 5 5 nm), and a pulse width of 6 ns) to form a photosensitive resin composition layer. The surface of the (colored layer) was subjected to pulse irradiation of about 1 mJ/cm 2 20 times via a photomask to harden the exposed portion. (exposure step). Then, a developing device (manufactured by Hitachi High-Technol〇gies Corp.) was used as a substrate for the oxidation of the oblique developing solution c D K_ 1 (Fuji thin film electronic material (share) (F u JIFIL) ιElectronic Materials Co., Ltd.)) ι·〇% developer (1 part by mass of CDK-1 diluted with 99 parts by mass of pure water, 25° C.) set the spray pressure to 0 · 2 Development was carried out for 0 Μ P a for 5 〇 seconds, washed with pure water, and air-dried (development step). Then, post-baking was carried out in a clean oven at 230 ° C for 30 minutes to form a blue striped pixel array on the substrate.

S -128- 201213355 (Evaluation of Line Width Sensitivity) Using a mask with a green, wide and a pitch of 20 // m width, and a photosensitive tree on the substrate with a coating film ^ pa β * The gap between the surface of the layer and the mask (gap) is set to 200 // m, and the exposure of g, U 20 mJ/cm2 is exposed. The above-mentioned development is washed, air-dried, and then supplied to the girl, by the substrate obtained by the above-mentioned exposure. Obtained by optical microscopy. Line A: 30 β m or more B: 27 β m or more and less than 3〇/. m C: 25 β m or more and less than “ U m D : less than 25 &quot; m E: 益〇», method formation Pattern or fall (the evaluation of the linearity is performed by an optical microscope (20 〇 for the obtained line pattern, and the following is the case where the evaluation of the online wide sensitivity is not uniform). The linearity of the line width is evaluated (the difference evaluation reference A: benefit) »\\\ Jagged, no missing B: Although there are several differences, C: jagged and about 2 D: uneven and about 5 E: * »*, patterning, or stripping A The deviation of the line of m (evaluation of heat resistance) The line is a straight line. The substrate obtained by the evaluation of the line width sensitivity is added. (The additional baking time in the net oven is 6 minutes, using Dazhijie+Electronic-129-201213355) The spectrophotometer MCPD-2000 manufactured by Otsuka Electronics Co., Ltd. measures the color change (ΔΕ + ab) before and after additional baking. Here, the so-called "AE*ab" means L*a* The color difference in the b* color system. The following reference evaluation color change ΔΕ + ab: Evaluation criterion 5: AE^ab is 0 or more and less than 1.0 4.5: AE*ab is 1.0 or more and less than 2.0 4 : ΔΕ, !? is 2.0 or more and less than 3.0 3.5 : 3_0 Less than 3.5 3: ΔΕ, ΐ3 is 3.5 or more and less than 4·0 2.5: ΔΕ*αΐ3 is 4.0 or more and less than 5.0 2: ΔΕ, !? is 5.0 or more 1 : There is peeling. (Evaluation of wrinkles) Warp The substrate obtained by the evaluation of the wide sensitivity was baked in a clean oven at 230 ° C for 30 minutes, and the color pattern of the colored pattern before and after baking was observed with an optical microscope (magnification · 200 times), and evaluated on the following basis: Evaluation criteria 〇: No wrinkles were observed Δ: weak wrinkles were generated X: Strong wrinkles were generated. (Comprehensive evaluation) The overall line width sensitivity, linearity, and heat resistance were evaluated by the following criteria. The results are summarized in Table 8.

S -130- 201213355 Evaluation Benchmark 5 : Very Excellent 4.5 : Excellent 4 : No problem in general use 3.5 : Although the performance is slightly worse f but M. The level of the problem 3 : The level of reluctance in general use 2.5 : It is slightly lower than the limit and there is a problem 2: The performance is not enough to be used 1 : Benefit #»*&gt; The level of the evaluation method 8 Line width sensitivity Linear heat-resistant wrinkle comprehensive performance Example 1 AA 5 Ο 5.0 Example 2 AA 5 〇 5.0 Example 3 AA 5 〇 5.0 Example 4 BA 4 Δ 4.0 Example 5 BA 4 Δ 4.0 Example 6 AA 4 〇 4.0 Example 7 AA 5 〇 5.0 Example 8 AA 5 〇 5.0 Implementation Example 9 AA 5 〇 5.0 Example 10 AA 5 〇 5.0 Example 11 AA 5 〇 5.0 Example 12 AA 3 〇 4.0 Example 13 B to CA 5 〇 3.5 Example 14 AA 5 Δ 4.0 Example 15 AA 4~ 5 〇 5.0 Comparative Example 1 CC 1 X 1.0 Comparative Example 2 DC 1 X 1.0 Comparative Example 3 AA 5 X 1.0 Comparative Example 4 BB 3 〇 3.0 Comparative Example 5 BC 2 〇 2.0 Comparative Example 6 CD 3 〇 3.0 201213355 It can be understood from Table 8 that the colored photosensitive resin compositions of Examples 1 to 15 of the present invention have a good line width sensitivity and are excellent in linearity of the obtained pattern. Further, the color change is small even if the colored pattern is heated, and wrinkle generation after post-baking is suppressed, so that a good coloring pattern can be obtained. On the other hand, Comparative Example 1 which does not contain the (B-1) binder resin of the present invention, and Comparative Example 2 which uses an initiator other than the (D) fluorene-based photopolymerization initiator are line width sensitivity and pattern straight lines. (B-2) Comparative Example 3 in which the content of the binder resin was excessive, the wrinkles after post-baking were remarkable; (B-1) adhesive resin In Comparative Example 4 in which the content was excessive, and Comparative Example 5 in which the (B-2) binder resin was not contained, any of the line width sensitivity, the linearity, and the wrinkles were inferior to those of the examples. Further, Comparative Example 6 using (D) an initiator other than the fluorene-based photopolymerization initiator and a sensitizer in combination was used for the line width sensitivity and the linearity of the pattern. [Simple description of the diagram] None. [Main component symbol description] None.

S-132-

Claims (1)

201213355 VII. Patent application scope: 1. A colored photosensitive resin composition comprising at least: (A) a colorant, (B-1) represented by the following general formula (I) and having at least one acidic group. (B-2) contains a binder resin represented by the following structural formula represented by the following formula (II) and a structural unit having an acidic group, (C) a polymerizable compound, and (D) an oxime-based photopolymerization initiator; And (E) a solvent, wherein the ratio of the (B-1) binder resin to the (B-2) binder resin on a mass basis is 3:7 to 7:3: (A2 r4-s r3h-s R5—P2 (1) η In the formula (I), R 3 represents an (m + n ) valent organic linking group, R 4 and R 5 each independently represent a single bond or a divalent organic linking group, and A 2 represents at least one selected from the group consisting of Organic pigment structure, heterocyclic structure, acidic group, group having a basic nitrogen atom, ureido group, urethane group, group having a coordinating oxygen atom, hydrocarbon group having 4 or more carbon atoms, alkoxydecane a valence organic group of a partial structure of a group, an epoxy group, an isocyanate group, and a hydroxyl group, and an A2 of η R4 may be the same or different 'm is a representative of 1 to 8, η is 2 to 9, m + n is 3 to 10, P2 is a polymer skeleton, and m and P2 are the same Or different -133- 201213355 In the general formula (II), Ru 15 is a self-independent buffering moiety, a halogen atom, and a denier also represents a sulfhydryl group, an alkyl group or an aryl group, and RI6 is a methyl group.疋 represents the wind atom 2_ such as the coloring photosensitive resin of item 1 of the patent application scope, % (D) 肟 Fenggu extract U, such as a composition, the ketone two-layer photopolymerization initiator: (called the generation And a coloring layer forming step of forming a coloring layer on a substrate by applying a color photosensitive resin composition according to claim 1 or 2, and patterning the colored layer. An exposure step of curing the exposed region by exposure of each external light laser, and an unexposed portion of + s are developed and removed to form a pattern developing step. ^ As for the pattern forming method of claim 4, the exposure wavelength of the ultraviolet laser is in the range of 300 nm to 380 nm. S-134-201213355 6 The pattern forming method of claim 4, wherein the ultraviolet laser is a pulsed laser that oscillates at a frequency of 20 Hz to 2000 Hz. A method of producing a color light-passing sheet, comprising the step of forming a color pattern on a substrate according to a pattern forming method according to item 4 of the application patent. 8. A color filter manufactured according to the method of producing a color filter according to item 7 of the patent application. A display device comprising the color filter of item 8 of the patent application. -135- 201213355 IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: None 0. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: