201132818 六、發明說明： 【發明所屬之技術領域】 _本於一種環保型高阻燃織物，特別是有 關於一種^保型咼阻燃混紡導電織物及其製程。 【先前技術】 錄’飛機不論在戰備用品運輸或兵 ίϊίΐϊ 演重要角色。大戰以後，因應航空科 技的快速發展，飛機性能不僅大幅提昇寸 ，，長。當時負責承包美國軍用飛機的波音公司^ 因而轉變為目則全球最大的飛機製造商。有鑑於商 機在於賦予旅人更快捷與便利之旅程，但旅程期間之安 全防護卻是商用飛機設計製造者之最重要考量因素。 隨著紡織品應用用途不同，產品都必須達到不同的 安f檢測規範中更以飛機運輸用之安全品質規範最 為嚴格二除材料的阻燃與煙毒釋放性外，產品的發熱性 不宜過南更為材料開發的設計重點。以飛機座椅用布為 例，布種本身必須通過阻燃燃燒測試、煙濃度測試（低 煙）、煙毒性測試（共測六種毒性氣體，皆需達低毒性 ^準）、耐磨耗測試等。產品技術開發難度之高，位居 ，通運輸紡織品應用之冠。誠如前述，交通運輸用紡織 品開$涉及紗線、織物與後處理等多道次加工，相較於 傳統傢飾或衣著用紡織品，不論在製程生產技術與品質 控巧等都涉及更高技術門檻，這也是為何國際間將其列 為高科技產業用紡織品之十二大項重點技術發展領域 之一。 <近年來’全球遭逢國際石油能源短缺危機，以及氣 候暖化的急遽變遷，如何就現有生產資源的有效再利 201132818 堂；s· 改善現有產品以符合節能減碳，及降低環境危 ===，不僅已成為全球企業發展新產ί 的決塍别ί7素’更是未來與競爭者進行市場差異化 能與製^目ΐ全球航空運輸用紡織品皆朝高性 二、化的要求，航空運輸用紡織品的開發研究 杜旲声⑴統更具優越的耐用性（高阻燃/耐磨耗/導電 需朝具環保效應之生產製程，且同時滿 足嚴可之航二運輸用紡織品防火規範的方向來進行。 行紡而言，在習知技藝中常以ZIRPR0來進 層’並發生水解以有效降低燃燒熱外，尚 增许r 2^Ti〇F2等不燃氣體以快速降低可燃氣體之 濃進而達到阻燃之效果β然而，在環保問題與一貫 化連續生，成本等因素之考量下，上述ZIRPR〇阻燃加 工法也潛藏著許多的問題。例如：受限染缸壓吸作業而 不適用連續浸軋處理、對於多色樣紡織品易造成移^或 n=丨發色變或概色、廢水中會殘餘氟化物與鈦 /結等重金屬離子，增加廢棄物處理成本、常與有機演 化物共同使用以增加阻燃性，卻伴隨帶來燃燒時易產生 毒煙且不符合現今歐盟環保法規等問題。 有鑑於此，如何開發既可符合紡織品中最嚴格要求 之航空運^用紡織品的安全規範，且不會產生環保問題 之環保型高阻燃混紡導電織物已是一相當值得產業重視的 課題。 【發明内容】 鑒於上述之發明背景中，為了符合產業上之要求， 本說明書揭露一種環保型高阻燃混紡導電織物及其可 一貫化連續生產之環保製程。 、 201132818 本發明之一目的在於提供一種環 ’藉，用羊毛紗與人造纖仏=訪 '、、'夕可有效提升所形成織物的阻燃性。 、的展 本發明之另一目的在於提供一種環伴 紡導電織物，藉由使用不含重金屬成分的阻燃混 =物生產製程廢棄物的處理方面都不在會織產== 連續作業的要求，達: 紡慕ί發明之又一目的在於提供一種環保型高阻燃混 現H織物，藉由使用羊毛紗與人造纖維/金屬纖i的 據本Ϊ明I有ΐ提升所形成織物的尺寸安定性，使得根 明書之織物可耐乾洗。 紡導明之又一目的在於提供一種環保型高阻燃混 混妨ΐ織物，藉由使用羊毛紗與人造纖維/金屬纖維的 、ν，可有效減少所形成織物的單位重量。 紡導明之又一目的在於提供一種環保型高阻燃混 混紡=織物，藉由使用羊毛紗與人造纖維/金屬纖維的 、、、y ’可有效提升所形成織物的電磁波遮蔽效果。 紡導=發明之又一目的在於提供一種環保型高阻燃混 混紡糾、織物，藉由使用羊毛紗與人造纖維/金屬纖維的 金=，可讓根據本說明書之織物具備耐摩擦性、耐汗 c^午度、以及低起毽性。 根據以上所述之目的，本發明揭示了 一種環保型高 201132818 阻燃混紡導電織物及 羊w纺紗^環 紡紗可以是由羊毛紗盘非呈裒保阻燃劑。上述之羊毛現 成，其中，上述一適當比例混紡而 物。 疋之％保阻燃劑至少包含磷酸酯與氮化 高阻發明更揭示了一種環保型 電織物之製2!;==述;;型高阻燃混纺導 環保阻_以增輯物之_t整加程序中可加入 【實施方式】 訪導方向為一種環保型高阻燃混 織物及其製程。為了能徹底地瞭解 出詳盡的組成與製程步驟。顯然地，本 =^ 所周知的組成或製程㈣並未描述 中，以避免造成本發明不必要之限制。本發明的 巧佳體系會詳細描述如下’然而除了這些詳細描述之 外，本發明還可以廣泛地施行在其他的體系中，且本發 明的範圍不應受以下揭露之較佳體系所限 之後的專利範圍為準。 心而應 根據本說明書之一實施例揭露一種環保型高阻燃 混紡導電織物。上述環保型高阻燃混紡導電織物包含羊 毛混紡紗，以及環保阻燃劑。上述羊毛混紡紗可以是由 羊毛紗與非羊毛紗以一適當比例混紡而成。在根據本實 施例之一較佳範例中’上述的羊毛紗可以是短纖維天然 羊毛紗。在根據本實施例之一較佳範例中，上述羊毛^ 201132818 與非羊毛紗的比例可以是重量比為86:14至99:1。 上述之非羊毛紗可以是選自人造纖維或金屬纖維 中之一者。上述的人造纖維可以是選自下列群組中之一 者：尼龍纖維（Nylon)、高強力聚脂纖維、聚脂纖維 (MONO)、碳纖維等。上述的金屬纖維可以是選自下列 群組中之一者：不銹鋼纖維（Stainless)、銅纖維，金纖 維，銀纖維等。 在根據本實施例之一較佳範例中，上述之非羊毛紗 可以是尼龍纖維（Nylon 66)。根據本範例，上述羊毛紗 與尼龍纖維之重量比為86:14至99:1。更好的是，上述 羊毛紗與尼龍纖維之重量比約為90:10。 在根據本實施例之另一較佳範例中，上述之非羊毛 紗可以是不銹鋼纖維。根據本範例，上述羊毛紗與不銹 鋼纖維之重量比為86:14至99:1。更好的是，上述羊毛 紗與不銹鋼纖維之重量比約為90:10。 在根據本實施例之另一較佳範例中，上述環保型高 阻燃混紡導電織物之經紗與緯紗可以是分別選用不同 的羊毛混紡紗。例如，經紗選用羊毛紗與尼龍纖維之重 量比為86:14至99:1之羊毛混紡紗；緯紗選用羊毛紗與 不銹鋼纖維之重量比為86:14至99:1之羊毛混紡紗。 根據本實施例，上述環保阻燃劑包含磷酸酯，與氮 化物。上述的磷酸酯可以是選自下列群組中之至少一 者：烷基胺混合填酸脂、聚磷酸醯胺鹽。上述的氮化物可 以是選自下列群組中之至少一者：硫化尿素縮合物、芳 香族磷酸脂。上述環保阻燃劑之添加量可以是上述羊毛 混紡紗之重量百分比5%至30% (烘乾後）。在根據本實 施例之一較佳範例中，上述環保阻燃劑之添加量約為羊 毛混紡紗之最適重量百分比12%。根據本實施例，上述 201132818 燃劑不含諸如重金屬、甲_發物、以及函素揮 等’常應用於傳統製程中但不為環保法規所允許之 成分。 根據本說明書之另一實施例係關於一種環保型高 =燃混^電織物之製程。第一圖係〆根據本實施例的 %保型尚阻燃混紡導電織物之製程的一般流程示意 圖。參照第一圖，上述環保型高阻燃混紡導電織物之製 程包含一羊毛混紡紗的紡織程序1〇〇、以及一整理加工 程序200。201132818 VI. Description of the invention: [Technical field to which the invention pertains] _ This is an environmentally-friendly high-flame-retardant fabric, in particular, a type of protective 咼 flame-retardant blended conductive fabric and a process thereof. [Prior Art] Recording aircraft plays an important role in the transportation of war supplies or soldiers. After the war, in response to the rapid development of aviation technology, aircraft performance has not only increased significantly, but also long. At that time, Boeing, which was responsible for contracting US military aircraft, turned into the world's largest aircraft manufacturer. In view of the fact that the opportunity is to give travellers a faster and more convenient journey, the security protection during the journey is the most important consideration for commercial aircraft design and manufacture. As the application of textiles is different, the products must meet different safety standards. The safety and quality specifications for aircraft transportation are the most stringent. The flame retardant and smoke release properties of the materials are not limited. Design focus for material development. Take the aircraft seat cloth as an example, the cloth itself must pass the flame retardant combustion test, smoke concentration test (low smoke), smoke toxicity test (a total of six toxic gases are tested, all need to achieve low toxicity), wear resistance Test, etc. Product technology development is difficult, ranking the best in transportation and textile applications. As mentioned above, transportation textiles involve multi-pass processing of yarns, fabrics and post-treatments. Compared with traditional home decoration or clothing textiles, higher technology is involved in process manufacturing technology and quality control. Threshold, this is one of the 12 key technology development areas that are listed as high-tech industrial textiles internationally. <In recent years, the global oil shortage crisis and the rapid changes in climate warming, how to effectively reproduce existing production resources; s· improve existing products to meet energy conservation and carbon reduction, and reduce environmental risks == =, not only has become a new product for the development of global enterprises, ί7素' is the future market differentiation with competitors, and the global air transport textiles are demanding high-level, aviation, aviation Development of transport textiles Du Yusheng (1) has a superior durability (high flame retardant / wear resistance / electrical conductivity needs to be environmentally friendly production process, and at the same time meet the direction of strict fire safety regulations for transporting textiles In the case of spinning, in the conventional technique, ZIRPR0 is often used to enter the layer and hydrolysis occurs to effectively reduce the heat of combustion. In addition, non-combustible gases such as r 2^Ti〇F2 are added to rapidly reduce the concentration of combustible gas and thus resist Burning effect β However, under the consideration of environmental issues and consistent continuous production, cost and other factors, the ZIRPR〇 flame retardant processing method also has many problems. For example: Limit dyeing cylinder pressure suction operation is not suitable for continuous padding treatment, it is easy to cause shifting or n=hair color change or coloration for multi-color sample textiles, residual fluoride and titanium/junction and other heavy metal ions in waste water, increase waste Treatment costs, often used in conjunction with organic evolutions to increase flame retardancy, are associated with problems such as toxic fumes when burned and inconsistent with current EU environmental regulations. In view of this, how to develop can meet the most stringent requirements of textiles. The environmentally-friendly high-flame-flame-blend blended conductive fabric that does not cause environmental problems in air transportation is a subject worthy of attention in the industry. [Invention] In view of the above-mentioned invention, in order to comply with the industry The present specification discloses an environment-friendly high-flame-flame blended conductive fabric and an environmentally friendly process capable of consistent continuous production. , 201132818 One of the objects of the present invention is to provide a loop 'borrowing, using wool yarn and artificial fiber 仏 = visit' , , can effectively improve the flame retardancy of the formed fabric. Another object of the present invention is to provide a ring-spinning conductive The process of producing process waste by using a flame retardant mixed material containing no heavy metal component is not in the process of weaving production == continuous operation, up to: the other purpose of the invention is to provide an environment-friendly high The flame retardant blending of the H fabric, by using the wool yarn and the rayon/metal fiber i according to the present invention, can improve the dimensional stability of the formed fabric, so that the fabric of the root Ming book can be resistant to dry cleaning. One purpose is to provide an environment-friendly high-flame-flame blending and smashing fabric, which can effectively reduce the unit weight of the formed fabric by using wool yarn and rayon/metal fiber, ν. Another purpose of the spinning guide is to provide an environmental protection. Type high flame retardant blended yarn = fabric, by using wool yarn and rayon/metal fiber, y ' can effectively enhance the electromagnetic wave shielding effect of the formed fabric. Spinning guide = another object of the invention is to provide an environment-friendly high-flame-flame blending and twisting fabric, which can be made to have abrasion resistance and resistance by using the wool yarn and the rayon/metal fiber gold= Sweat c^ noon, and low squatting. According to the above object, the present invention discloses an environmentally-friendly high-grade 201132818 flame-retardant blended conductive fabric and sheep w-spun yarn ring-spinning yarn which can be made of a wool yarn disc which is not a flame retardant. The above-mentioned wool is ready for use, wherein the above-mentioned suitable ratio is blended.疋%% flame retardant contains at least phosphate ester and high-resistance nitriding invention reveals an environment-friendly electric fabric system 2;;==;; type high flame retardant blending environmental protection resistance _ to increase the content _ The t-addition procedure can be added to the [implementation method]. The interview direction is an environmentally-friendly high-flame-flame blended fabric and its process. In order to thoroughly understand the detailed composition and process steps. Obviously, the well-known composition or process (4) is not described in order to avoid unnecessarily limiting the invention. The present invention may be described in detail as follows. However, the present invention may be widely practiced in other systems in addition to the detailed description, and the scope of the present invention should not be limited by the preferred system disclosed below. The scope of the patent shall prevail. The present invention discloses an environmentally friendly high flame retardant blended conductive fabric in accordance with an embodiment of the present specification. The above environmentally friendly high flame retardant blended conductive fabric comprises a wool blended yarn and an environmentally friendly flame retardant. The above wool blend yarn may be blended from wool yarn and non-wool yarn in an appropriate ratio. In the preferred embodiment according to one of the embodiments, the above-mentioned wool yarn may be a short-fiber natural wool yarn. In a preferred embodiment according to this embodiment, the ratio of the wool to 201132818 to the non-wool yarn may be from 86:14 to 99:1 by weight. The above non-wool yarn may be one selected from the group consisting of rayon or metal fiber. The above rayon may be selected from one of the group consisting of nylon fiber (Nylon), high-strength polyester fiber, polyester fiber (MONO), carbon fiber, and the like. The above metal fiber may be one selected from the group consisting of stainless steel (Stainless), copper fiber, gold fiber, silver fiber and the like. In a preferred embodiment according to this embodiment, the non-wool yarn described above may be nylon fiber (Nylon 66). According to this example, the weight ratio of the above-mentioned wool yarn to nylon fiber is from 86:14 to 99:1. More preferably, the weight ratio of the above-mentioned wool yarn to nylon fiber is about 90:10. In another preferred embodiment according to this embodiment, the non-wool yarn described above may be a stainless steel fiber. According to this example, the weight ratio of the above-mentioned wool yarn to stainless steel fiber is from 86:14 to 99:1. More preferably, the weight ratio of the above-mentioned wool yarn to stainless steel fiber is about 90:10. In another preferred embodiment according to this embodiment, the warp yarn and the weft yarn of the above-mentioned environmentally-friendly high flame-retardant blended conductive fabric may be selected from different wool blended yarns. For example, the warp yarn is a wool blended yarn having a weight ratio of wool yarn to nylon fiber of 86:14 to 99:1; the weft yarn is a wool blend yarn having a weight ratio of wool yarn to stainless steel fiber of 86:14 to 99:1. According to this embodiment, the above-mentioned environmentally friendly flame retardant contains a phosphate ester and a nitrogen compound. The above phosphate may be at least one selected from the group consisting of alkylamine mixed fats and polyphosphorus phosphonate salts. The above nitride may be at least one selected from the group consisting of a sulfurized urea condensate and an aromatic phosphate. The above-mentioned environmentally-friendly flame retardant may be added in an amount of from 5% to 30% by weight of the above-mentioned wool blended yarn (after drying). In a preferred embodiment according to one embodiment of the present invention, the environmentally-friendly flame retardant is added in an amount of about 12% by weight based on the optimum weight of the wool blended yarn. According to this embodiment, the above-mentioned 201132818 fuel does not contain ingredients such as heavy metals, nails, and singularities that are often used in conventional processes but are not permitted by environmental regulations. Another embodiment in accordance with the present specification is directed to a process for an environmentally friendly high-fuel-electric fabric. The first figure is a general flow diagram of the process of the %-protected flame-retardant blended conductive fabric according to this embodiment. Referring to the first figure, the above-described process for environmentally-friendly high flame-retardant blended conductive fabric comprises a textile process of wool blended yarn, and a finishing process 200.
，上述之羊毛混紡紗的紡織程序1〇〇主要係產出用 來形成上述環保型高阻燃混紡導電織物的底材。上述之 羊毛混紡紗的紡織程序100可包含，混紡120、整經 140、與織布160等步驟。在根據本實施例之一較佳範 例中，上述之羊毛混紡紗的紡織程序1〇〇可以更包含染 色122、與烘乾124等步驟。其中，上述的染色步驟122、 烘乾步驟124可以是在混紡步驟12〇後執行，其目的是 依實際需求，對於混紡步驟12〇所產出之混紡紗進行上 色0 亡述之整理加工程序200主要係用來提升上述環 保型尚阻燃混紡導電織物的物性與商業價值。上述之整 理加工程序200可包含手感加工22〇、與壓吸定型24〇 在整理加工程序2〇〇中可加入環保阻燃劑以增 ，上述底材之阻燃性。在根據本實施例之一較佳範例 中’上述之手感加工步驟22G可以是—蒸壓步驟。 羊，混紡紗可以是由羊毛紗與非羊毛紗以 ΐ ^_本實_之—較佳範例 實施例丨Ϊ疋短纖維天然羊毛紗。在根據本 實施例之較佳範例中，上述羊毛紗與非羊毛紗的比例 201132818 可以是重量比為86:14至99:1。 上述之非羊毛紗可以是選自人造纖維或金屬纖維 中之一者。上述的人造纖維可以是選自下列群組中之一 者：尼龍纖維（Nylon)、高強力聚脂纖維、聚脂纖維 (MONO)、碳纖維等。上述的金屬纖維可以是選自下列 群組中之一者：不銹鋼纖維（Stainless)、銅纖維，金纖 維，銀纖維等。 在根據本實施例之一較佳範例中，上述之非羊毛紗 可以是尼龍纖維（NYLON 66)。根據本範例，上述羊毛 紗與尼龍纖維之重量比為86:14至99:1。更好的是，上 述羊毛紗與尼龍纖維之重量比約為90:10。 在根據本實施例之另一較佳範例中，上述之非羊毛 紗可以是不銹鋼纖維。根據本範例，上述羊毛紗與不銹 鋼纖維之重量比為86:14至99:1。更好的是，上述羊毛 紗與不銹鋼纖維之重量比約為90:10。 在根據本實施例之另一較佳範例中，上述環保型高 阻燃混紡導電織物之經紗與緯紗可以是分別選用不同 的羊毛混紡紗。例如，經紗選用羊毛紗與尼龍纖維之重 量比為86:14至99:1之羊毛混紡紗；緯紗選用羊毛紗與 不銹鋼纖維之重量比為86:14至99:1之羊毛混紡紗。 根據本實施例，上述環保阻燃劑之主要成分包含磷 酸酯，與氮化物。上述的磷酸酯可以是選自下列群組中 之至少一者：烷基胺混合磷酸脂、聚磷酸醯胺鹽。上述的 氮化物可以是選自下列群組中之至少一者：硫化尿素縮 合物、芳香族磷酸脂。上述環保阻燃劑之添加量可以是 羊毛混紡紗之重量百分比5%至30%。在根據本實施例 之一較佳範例中，上述環保阻燃劑之添加量約為羊毛混 紡紗之最適重量百分比12%。上述環保阻燃劑不含諸如 201132818 重金屬、曱·揮發物'以及鹵素揮發物等常應用於傳統 製程中’但不為環保法規所允許之成分。 以前述之環保型高阻燃混紡導電織物之製程所產 出之環保型高阻燃混紡導電織物可應用於諸如傳統傢 • 饰用布、衣著用布或一般紡織品用布等各種布料的使 用。更好的是，根據本實施例所產出之環保型高阻燃混 紡導電織物可符合安全品質要求最嚴格的航空器用布 之安全規範，所以，亦可適用於飛機等航空器上所使用 的布料之應用。因此，本實施例所揭露的製程具有相當 _ 可觀的產業價值。 田 、 在現有技術中，航空運輸用之阻燃織物主要仍是以 羊毛織物應用氟鈦或锆的金屬絡合物阻燃劑（Zirpr〇) 經由染紗方式處理。此一作法不但徒增廢棄物處理費 用’其製程與產品亦不具環保性。再者’應用ZIRp〇R 的製程’需透過染紅壓吸之批次處理，無法一貫化生 產。如此一來，不僅所需的織物處理時間較長，所產出 之阻燃織物也較不耐乾洗，同時容易發生色變與褪色等 現象’品質掌控方面相當困難。 • 相較於習知技藝，根據本說明書之製程並不採用含 重金屬化合物阻燃助劑，而是改以環保型的磷酸酯類配 方搭配含浸製程完成。根據本說明書，不僅所使用的阻 燃配方更具環保性，在製程方面也更可達節能減碳之效 果。此外，根據本說明書，透過結合阻燃性羊毛/非羊 毛混紡紗與使用環保阻燃劑（磷-氮型阻燃膨脹 以一貫化之含浸烘乾架橋製程來生產出環保型高阻婵 ，紡導電織物，可具備能容易且有效控制產出織物之品 質’與有效降低織物產出之製程生產成本等多重的經濟 效 。 201132818 所揭示範例為限 Example 1 以I將揭示數個根據本說明書之範例。^而 = = 以其後的專利範圍為準，而不應以下列The textile program of the above-mentioned wool blended yarn is mainly used to produce a substrate for the above-mentioned environmentally-friendly high flame-retardant blended conductive fabric. The textile program 100 of the above-described wool blended yarn may comprise the steps of blending 120, warping 140, and weaving 160. In a preferred embodiment of the present embodiment, the textile process of the above-described wool blended yarn may further comprise the steps of dyeing 122, drying 124, and the like. The dyeing step 122 and the drying step 124 may be performed after the blending step 12, and the purpose is to color the blended yarn produced by the blending step 12〇 according to actual needs. 200 is mainly used to enhance the physical and commercial value of the above environmentally friendly flame-retardant blended conductive fabric. The above-mentioned finishing processing program 200 may include a handle processing 22 〇, and a pressure absorbing setting 24 〇 in the finishing processing program 2 可 can be added with an environmentally friendly flame retardant to increase the flame retardancy of the above substrate. In a preferred embodiment according to this embodiment, the above-described touch processing step 22G may be an autoclave step. Sheep, blended yarns may be made of wool yarns and non-wool yarns. _ ^本本_ - A preferred example Example 丨Ϊ疋 short fiber natural wool yarn. In a preferred embodiment according to this embodiment, the ratio of the above-mentioned wool yarn to non-wool yarn 201132818 may be a weight ratio of 86:14 to 99:1. The above non-wool yarn may be one selected from the group consisting of rayon or metal fiber. The above rayon may be selected from one of the group consisting of nylon fiber (Nylon), high-strength polyester fiber, polyester fiber (MONO), carbon fiber, and the like. The above metal fiber may be one selected from the group consisting of stainless steel (Stainless), copper fiber, gold fiber, silver fiber and the like. In a preferred embodiment according to this embodiment, the non-wool yarn described above may be nylon fiber (NYLON 66). According to this example, the weight ratio of the above-mentioned wool yarn to nylon fiber is from 86:14 to 99:1. More preferably, the weight ratio of the wool yarn to the nylon fiber is about 90:10. In another preferred embodiment according to this embodiment, the non-wool yarn described above may be a stainless steel fiber. According to this example, the weight ratio of the above-mentioned wool yarn to stainless steel fiber is from 86:14 to 99:1. More preferably, the weight ratio of the above-mentioned wool yarn to stainless steel fiber is about 90:10. In another preferred embodiment according to this embodiment, the warp yarn and the weft yarn of the above-mentioned environmentally-friendly high flame-retardant blended conductive fabric may be selected from different wool blended yarns. For example, the warp yarn is a wool blended yarn having a weight ratio of wool yarn to nylon fiber of 86:14 to 99:1; the weft yarn is a wool blend yarn having a weight ratio of wool yarn to stainless steel fiber of 86:14 to 99:1. According to this embodiment, the main component of the above-mentioned environmentally-friendly flame retardant contains a phosphoric acid ester and a nitride. The above phosphate may be at least one selected from the group consisting of alkylamine mixed phosphates and polyphosphorus phosphonate salts. The above nitride may be at least one selected from the group consisting of a sulfided urea condensate and an aromatic phosphate ester. The above environmentally friendly flame retardant may be added in an amount of 5% to 30% by weight of the wool blended yarn. In a preferred embodiment according to this embodiment, the environmentally-friendly flame retardant is added in an amount of about 12% by weight based on the optimum weight of the wool blended yarn. The above environmentally friendly flame retardants do not contain ingredients such as 201132818 heavy metals, antimony volatiles, and halogen volatiles that are commonly used in traditional processes, but are not permitted by environmental regulations. The environmentally-friendly high-flame-flame blended conductive fabric produced by the above-mentioned environmentally-friendly high-flame-flame blended conductive fabric can be applied to various fabrics such as conventional home fabrics, clothing fabrics, and general textile fabrics. More preferably, the environment-friendly high-flame-flame blended conductive fabric produced according to the embodiment can meet the safety specifications of the aircraft with the strictest safety quality requirements, and therefore can also be applied to the cloth used on aircraft and the like. Application. Therefore, the process disclosed in this embodiment has considerable industrial value. Tian, In the prior art, the flame-retardant fabric for air transportation is mainly treated by dyeing the wool fabric with a metal complex flame retardant (Zirpr〇) of fluorotitanium or zirconium. This practice not only increases the cost of waste disposal, but also makes its processes and products environmentally friendly. Furthermore, the process of applying ZIRp〇R needs to be processed in batches by dyeing red, and it is not possible to consistently produce. In this way, not only the required fabric treatment time is long, but also the flame-retardant fabric produced is less resistant to dry cleaning, and it is prone to color change and fading, etc. The quality control is quite difficult. • Compared to the prior art, the process according to this specification does not use a heavy metal compound flame retardant, but instead uses an environmentally friendly phosphate compound with an impregnation process. According to the present specification, not only the flame retardant formulation used is more environmentally friendly, but also the effect of energy saving and carbon reduction in the process. In addition, according to the present specification, an environmentally-friendly high-resistance twist is produced by combining a flame-retardant wool/non-wool blended yarn with an environmentally-friendly flame retardant (phosphorus-nitrogen type flame retardant expansion to achieve a consistent impregnation drying bridge process). The conductive fabric can have multiple economic effects such as the ability to easily and effectively control the quality of the produced fabric' and the process cost of effectively reducing the fabric output. The examples disclosed in the example of 201132818 are limited to Example 1 and I will disclose several according to the present specification. Example. ^ and = = subject to the scope of the subsequent patent, not the following
羊毛紗-尼龍纖維混紡之環保型高阻燃混紡導電織物· A.原紗銳格: 紗材 紗材規格 重量百分 羊毛 64*S ； WOOL TOP ^ 7J Cr. 90%~~~ 尼龍 6D , NYLON 66 ； 12 microns ； 90〜100 mm ; 2 g/m —--- 10% B.環保阻燃劑使用含量範圍（溶液比例）： 磷：10%〜80% ;氮：10%〜80% (重量比） (上述環保阻燃劑所使用之磷酸酯包含燒基胺混 合磷酸脂，及聚磷酸醯胺鹽。氮化物包含硫化尿^ 縮合物，及芳香族磷酸脂，其中，上述環保阻燃 劑中的罐、氮之較佳比例為麟：氮=7:3) … 泡製之重量百分比： 10〜50%環保阻燃劑；Wool yarn-nylon fiber blended environmentally friendly high flame retardant blended conductive fabric · A. original yarn sharp grid: yarn material yarn specification weight percent wool 64*S; WOOL TOP ^ 7J Cr. 90%~~~ nylon 6D, NYLON 66 ; 12 microns ; 90~100 mm ; 2 g/m ----- 10% B. Environmentally friendly flame retardant content range (solution ratio): Phosphorus: 10%~80%; Nitrogen: 10%~80% (Weight ratio) (The phosphate ester used in the above-mentioned environmentally-friendly flame retardant includes a burnt amine mixed phosphate and a polyphosphoric acid phosphonium salt. The nitride contains a sulfurized urine condensate, and an aromatic phosphate, wherein the above-mentioned environmental resistance The preferred ratio of the tank and nitrogen in the fuel is: lin: nitrogen = 7:3) ... the weight percentage of the brewing: 10~50% environmentally friendly flame retardant;
48〜90%水； 1〜2%滲透劑》 C.織物直品規格 項目 &驗標準 測定方式 編織方法 平織提花 提花龍頭(staubil^^^mw _ 經緯紗 經紗： 緯紗： (21.25 羽 X 4 條)X 62.35¾^^ 條邊紗 =5380 60 條/INCH 布重 規格值±6〇/〇 ISO 139 〜's 原布寬度 137 ± 2 cm 137 cm '' ----- 201132818 D.檢測結果： i.檢驗項目： 項目 檢驗標準 測定方式 尺寸安定 經、緯向±2%| 乾洗20回 燃燒 垂直燃燒 FAR25.853 AppFParti 抗靜電 摩擦帶電壓 HS-1094 财磨耗 Martindale 磨耗性 20000 个 IWSTM112 ii.測試結果 試驗項目 單位 實測值 抗靜電 摩擦帶電壓（V) 儀器： ROTARYSTATIC TESTER MODEL;REP-20N J VOLT 經:32 緯:34 表面洩漏抵抗值（Ω) 儀器： SUPER MEGOHMETER MODEL SM-5E T=20〇C,RH = 40% (放置4 HR) Ω值 5χ10ηΩ 燃燒 垂直燃燒 FAR 25.853 App F Part I 5SEC| 8 INCH j 經：3 緯：4 Martindale 磨耗性 20000 个 次數 2000048~90% water; 1~2% penetrant" C. Fabric straight product specification & standard test method Weaving method Flat weave jacquard faucet (saubil^^^mw _ warp and weft warp: weft: (21.25 feather X 4 Article) X 62.353⁄4^^ Side yarn = 5380 60 pieces / INCH cloth weight specification value ± 6 〇 / 〇 ISO 139 ~ 's original cloth width 137 ± 2 cm 137 cm '' ----- 201132818 D. Test results : i. Inspection items: Project inspection standard measurement method Dimensional stability, latitude ± 2% | Dry cleaning 20 times burning vertical burning FAR25.853 AppFParti Antistatic friction band voltage HS-1094 Grinding Martindale Abrasion 20000 IWSTM112 ii. Test Result Test unit unit measured value Antistatic friction band voltage (V) Instrument: ROTARYSTATIC TESTER MODEL; REP-20N J VOLT Pass: 32 Weft: 34 Surface leakage resistance value (Ω) Instrument: SUPER MEGOHMETER MODEL SM-5E T=20〇 C,RH = 40% (place 4 HR) Ω value 5χ10ηΩ Combustion vertical combustion FAR 25.853 App F Part I 5SEC| 8 INCH j Pass: 3 latitude: 4 Martindale Wearability 20000 times 20000
Example 2 羊毛炒-不銹鋼纖維混紡之環保型高阻燃混紡導電織物： A.原紗規格： 紗材 紗材規格 重量百分比 羊毛 64，S ; WOOL TOP 90% 不銹鋼 100% Stainless Steel Sliver ； 12 microns ; 90〜100 mm ; 2 g/m 10% 12 201132818 B.環保阻燃劑使用含量範圍（溶液比例）： 磷：10%〜80% ;氮：10%〜80% (重量比） (上述環保阻燃劑所使用磷酸酯包含烷基胺混合 磷酸脂，及聚磷酸醯胺鹽。氮化物包含硫化尿素^ • 合物，及芳香族磷酸脂。其中，上述環保阻燃劑 中的磷、氮之較佳比例為磷：氮=7:3) 泡製之重量百分比： 10〜50%環保阻燃劑； 48〜90%水； 1〜2%滲透劑。 • ,_C_織物成品規格 項目 檢驗標準 測定方式 編織方法 平織提花 提花龍頭(STAUBILY) +織機(SOMAS) 經緯紗 經紗： 緯紗： (21.25羽X 4條）X 62.35扣幅+ 88條邊紗 =5380 60 條/INCH 布重 規格值± 6% ISO 139 原布寬度 137 ± 2 cm 137 cm D _檢測結果： i.檢驗項目： 項目 檢驗標準 測定方式 尺寸安定 經、緯向±20/c4 乾洗20回 燃燒 垂直燃燒 FAR 25.853 App F Part I 抗靜電 摩擦帶電壓 JIS-1094 耐磨耗 Martindale 磨耗性 20000 个 IWSTM112 13 201132818 ii.測試結果 試驗項目 單位 實測值 抗靜電 摩擦帶電壓（V) 儀器： ROTARYSTATIC TESTER MODEL;REP-20N VOLT 經:32 緯:33 表面洩漏抵抗值（Ω) 儀器: SUPER MEGOHMETER MODEL SM-5E T=20〇C,RH = 40% (放置4 HR) Ω值 5χ10πΩ 燃燒 垂直燃燒 FAR25.853 AppF Parti 5SEC| 8 INCH i 經：0 緯：3 Martindale 磨耗性 20000 个 次數 25000Example 2 Wool-fried-stainless-fiber blended environmentally-friendly high-flame-flame blended conductive fabric: A. Original yarn specifications: Yarn material, yarn specification, weight percentage, wool 64, S; WOOL TOP 90% stainless steel, 100% Stainless Steel Sliver; 90~100 mm ; 2 g/m 10% 12 201132818 B. Environmentally friendly flame retardant content range (solution ratio): Phosphorus: 10%~80%; Nitrogen: 10%~80% (weight ratio) (The above environmental protection The phosphate used in the flammable agent comprises an alkylamine mixed phosphate and a polyphosphoric acid amide. The nitride comprises a sulphurized urea compound, and an aromatic phosphate, wherein the phosphorus and nitrogen in the environmentally friendly flame retardant are used. The preferred ratio is phosphorus: nitrogen = 7:3) The weight percentage of the brewing: 10~50% environmentally friendly flame retardant; 48~90% water; 1~2% penetrant. • , _C_ Fabric Finished Product Item Inspection Standard Measurement Method Weaving Method Flat Weave Jacquard Jacquard Faucet (STAUBILY) + Loom (SOMAS) Warp and Yarn Warp: Weft: (21.25 Feather X 4) X 62.35 Button + 88 Side Yarn = 5380 60 Strip/INCH Cloth specification value ± 6% ISO 139 Original fabric width 137 ± 2 cm 137 cm D _ Test results: i. Inspection items: Project inspection standard Measurement method Dimensional stability, latitude ± 20/c4 Dry cleaning 20 times burning Vertical combustion FAR 25.853 App F Part I Antistatic friction band voltage JIS-1094 Wear resistance Martindale Abrasion 20000 IWSTM112 13 201132818 ii. Test results Test item unit measured value Antistatic friction band voltage (V) Instrument: ROTARYSTATIC TESTER MODEL; REP-20N VOLT Pass: 32 Lat: 33 Surface Leakage Resistance (Ω) Instrument: SUPER MEGOHMETER MODEL SM-5E T=20〇C, RH = 40% (place 4 HR) Ω value 5χ10πΩ Combustion vertical combustion FAR25.853 AppF Parti 5SEC| 8 INCH i by: 0 latitude: 3 Martindale wearability 20,000 times 25000
Example 3 環保型高阻燃混紡導電織物的製程： A.製造環保型高阻燃混紡導電織物的一般製程及 其檢驗項目表· 生產流程 管制項目 檢驗標準 檢測方法 支數 23/2 紗支測長機 拉力 27 kgs 拉力試驗機 紡紗 双撚度 431 T/M 撚度試驗機 縮率 1.2% 尺/試染機 均勻度/毛羽 A級 外觀板/目測 浴比 1:20(+30，-10) 液位計 染色 流量 白度 30 1/min/kg 4級以上 目視 灰色標 棉殼 無 目視 烘乾 乾燥度 碎重 PRQCISA 2000g 精度儀 整經 轉數 寬度 依標準±100rpm 依標準± 1 in 轉速表 鋼尺 201132818Example 3 Process for environmentally friendly high flame retardant blended conductive fabric: A. General process for manufacturing environmentally friendly high flame retardant blended conductive fabric and its inspection items. · Production process control items Inspection standard Test method count 23/2 Yarn length measurement Machine pull force 27 kgs Tensile test machine spinning double twist 431 T/M twist test machine shrinkage rate 1.2% ruler / test dyeing machine uniformity / hairiness A grade appearance board / visual bath ratio 1:20 (+30,-10) liquid Bit meter dyeing flow whiteness 30 1/min/kg Grade 4 or above visual gray standard cotton shell without visual drying dryness broken weight PRQCISA 2000g precision instrument warp rotation width according to standard ±100rpm according to standard ± 1 in tachometer steel ruler 201132818
結數 符合規格 目視/計算 每結長度 平均值±0.3% 計長器 回潮率 8.5% ± 1% PRQCISA 2000g 精度儀 粒數 符合規格 目視/計算 毛長 依標準±0.2 mm 毛長鏡 織布 組織 依織物規格書 目視/確認 幅寬 依標準+l，-0in 捲尺 經/緯密 依標準±2條 布紋鏡 機寬 依標準士 2.0 in 數字顯示器 壓吸定型 溫度/室 依標準±10度 溫度表 速度 依標準± 1 M/min 計速器 出布幅寬 依標準+1，-0 in 捲尺 機寬 依標準±2.0in 數字顯示器 蒸壓 溫度/室 依標準±10度 溫度表 (手感加工） 速度 依標準± 1 M/min 計速器 出布幅寬 依標準+l，-0in 捲尺 成檢 絨毛長 2.1 ± 0.2 mm 毛長鏡 總厚度 2.5 ± 0.2 mm H-30厚度計 外觀 包裝規定 目視 包裝/裝箱 數量 規格尺寸 客戶需求 客戶指定 目視 量尺 標示 客戶指定 目視 入庫 清點數量 符合入庫清單 電腦系統管制 平放 無堆積 目視 B.染色工程細部條件： 經紗 緯紗 染色程式代號 P25 染色程式代號 P25 適用範圍 棉漂白、去棉杆 棉殽雜質 適用範圍 棉漂白、去棉杆 棉縠雜質 PH 值(SC) 6.5 ± 0.5 PH值 6.5 士 0.5 浴量刻度 依機台刻度 [浴比 1:20(+30，-10)] 浴量刻度 依機台刻度 [浴比 1:20(+30，-10)] 15 201132818 流量 30 L/min/kg 流量 30 L/min/kg 溫度及時間 (分） 96°C x60 分 溫度及時間 (分） 96〇C x60 分 c.織布工程細部條件： 整經工程細部條件 整經鋼箱 25羽/英吋 整經轉速 900rpm ±100 rpm 整經速率 2/2/2 ±1 格 盤紗壓力 2kg/cm2±l kg 織布工程細部條件 織造速度 rpm 362 rpm 織前角度 311度 捲布扭力 刻度 上布70〜80 下布70〜80 胚布厚度 2.9mm ±0.2 mm 毛經多臂 9〜12片一 地經多臂 1〜8片— 拉片向度 5.5/4.8/4.2/3.5 (cm) 拉片高度 17.6/17/16.5/16 (cm) 上地經重 上刻度3.5 上地經重 左側 11.5kg* 2(粒） 鎚刻度 下刻度3.5 鎚重量 右侧 11.5kg* 2(粒） 下地經重 上刻度3.5 下地經重 左側 11.5kg* 2(粒） 鍵刻度 下刻度3.5 鎚重量 右侧 11.5kg* 2(粒） D.整理工程細部條件： 加工流程 項目 條件 (1)藥劑加工 第一次入布 上下吸塵器開啟 201132818 壓力 壓吸輪壓力3〜5kg/crri 溫度X速度 150°C x 8 m/min 機寬 56" ± 1" 第二次入布 烘乾反應 溫度X速度 140°C X 8 m/min 機寬 56.5"+1" -0 2)手感加工 入布 1 — ~~— 一 正面向下接觸鐵輪 蒸氣 全開 溫度X速度 140°C X 3 m/min 滾筒壓力 2~5kg/ cm 成品幅寬 ---- 54"十 Γ-0 綜合上述，本說明書揭露了一種環保型高阻燃混訪 導電織物及其製程。上述環保型高阻燃混紡導電織物包 含羊毛混紡紗’以及環保阻燃劑。上述羊毛混紡紗可以 是由羊毛紗與非羊毛紗以一適當比例混紡而成。上述之 非羊毛紗可以是選自人造纖維或金屬纖維中之一者。 由使用上述之羊毛混紡紗，環保型高阻燃混紡導 將可有效的提升阻齡、提升財安定性、提 ，蔽性、提升耐摩擦性，並有效降低所形成織 也 重量，以及符合環保。另一方面，上述環保型u 紡導電織物之製程包含一羊毛混紡紗的紡織程 一整理加工程序。其中，在整理加工程序 斤j及 阻燃劑以增強所產出織物之阻燃性。藉由 環保阻燃劑，不僅所使用的阻燃配方方面更具環的 17 201132818 更好的是’在製程方面可採用一貫 程ί生產出環保型高阻燃混纺導電織物二架二； 制ί出織物之品質、有效降低織物ί出之製^ 昇力程廢棄物處理費用等功效，進ΐ 顯然地，依照上面體系中的插述，本發 :的修正與差異。因此需要在其附加的心： ^乏地在其他的體系中施行。上述僅為本發 御，均應包含在下述中請專利範^成的等效改變或修 【圖式簡單說明】 電織保型高阻燃•導 【主要元件符號說明】 100 羊毛混紡紗的紡織程序 !20 混紡 122 染色 !24 烘乾 140 整經 160 織布 2〇〇 整理加工程序 220 手感加工 240 壓吸定型The number of knots meets the specifications. The average value per knot length is ±0.3%. The regain rate of the gauge is 8.5% ± 1%. PRQCISA 2000g The number of precision gauges meets the specifications. Visual/calculation of the length of the hair is ± 0.2 mm. Fabric specification visual/confirmed width according to standard +l, -0in tape measure / weft density standard ± 2 cloth mirror machine width according to standard 2.0 in digital display pressure suction setting temperature / room according to standard ± 10 degree thermometer The speed is based on the standard ± 1 M / min. The width of the speedometer is based on the standard +1, -0 in the width of the tape measure is ± 2.0in. The digital display is autoclaved. The temperature is based on the standard ± 10 degree thermometer (handle processing). According to the standard ± 1 M / min, the width of the speed gauge is according to the standard + l, -0 in the tape measure to the length of the test is 2.1 ± 0.2 mm. The total thickness of the long lens is 2.5 ± 0.2 mm. H-30 thickness gauge Appearance packaging requirements visual packaging / Packing quantity specification size customer demand customer specified visual scale indicator customer specified visual inventory count number meets warehousing list computer system control flat without accumulation visual B. dyeing engineering detail : Warp weft dyeing program code P25 Dyeing program code P25 Applicable range Cotton bleaching, cotton wool cotton Concealing impurities Applicable range Cotton bleaching, cotton swabs, cotton, cotton, impurities, pH value (SC) 6.5 ± 0.5 PH value 6.5 ± 0.5 bath scale Machine scale [bath ratio 1:20 (+30,-10)] Bath scale according to machine scale [bath ratio 1:20 (+30,-10)] 15 201132818 Flow rate 30 L/min/kg Flow rate 30 L /min/kg Temperature and time (minutes) 96°C x60 minutes temperature and time (minutes) 96〇C x60 points c. Weaving engineering details: warping engineering details condition warping steel box 25 feathers/inch warping Speed 900rpm ±100 rpm Warping rate 2/2/2 ±1 Grid pressure 2kg/cm2±l kg Weaving engineering detail conditions Weaving speed rpm 362 rpm Weaving front angle 311 degrees Rolling torque scale on cloth 70~80 Cloth 70~80 Blanket thickness 2.9mm ±0.2 mm Hairy multi-arm 9~12 pieces One-to-one multi-arm 1~8 pieces - Pulling direction 5.5/4.8/4.2/3.5 (cm) Pulling height 17.6/17 /16.5/16 (cm) Upper ground weight on the scale 3.5 Upper ground weight 11.5kg* 2 (grain) Hammer scale down 3.5 Hammer weight right 11.5kg* 2 (grain) Lower ground weight on the scale 3.5 under the ground weight 11.5kg* 2 (grain) Key scale under the scale 3.5 Hammer weight right 11.5kg* 2 (grain) D. Finishing engineering details: Processing process project conditions (1) pharmaceutical processing One-time vacuum cleaner opens 201132818 Pressure pressure roller pressure 3~5kg/crri Temperature X speed 150°C x 8 m/min Machine width 56" ± 1" Second cloth drying reaction temperature X speed 140°CX 8 m/min Machine width 56.5"+1" -0 2) Handle processing into cloth 1 — ~~— One face down contact iron wheel steam full opening temperature X speed 140°CX 3 m/min Roller pressure 2~5kg/ Cm Finished Width---- 54"Shiyan-0 In summary, the present specification discloses an environmentally-friendly, high-flame-flame blended conductive fabric and its process. The above-mentioned environmentally-friendly high flame-retardant blended conductive fabric contains wool blended yarns and environmentally friendly flame retardants. The above wool blend yarn may be blended from wool yarn and non-wool yarn in an appropriate ratio. The above non-wool yarn may be one selected from the group consisting of rayon or metal fiber. By using the above-mentioned wool blended yarn, the environmentally-friendly high-flame-flame blending guide can effectively improve the age, improve the stability of the property, improve the grip, improve the friction resistance, effectively reduce the weight of the formed fabric, and comply with the environmental protection. . On the other hand, the process of the above-mentioned environmentally friendly u-spun conductive fabric comprises a weaving process of a wool blended yarn. Among them, the processing procedure and the flame retardant are arranged to enhance the flame retardancy of the produced fabric. With environmentally friendly flame retardants, not only the flame retardant formula used is more cyclical. 17 201132818 It is better to use a consistent process in the process to produce environmentally friendly high flame retardant blended conductive fabrics. The quality of the fabric, the effective reduction of the fabric, the lifting process, the waste disposal cost, etc., obviously, according to the above system, the correction: the difference: Therefore, it needs to be attached to the heart: ^ Lack of land is implemented in other systems. The above is only for the purpose of this issue, and should be included in the following. The equivalent change or repair of the patent model is simplified [Electrical woven type high flame retardant • Guide [Main component symbol description] 100 wool blended yarn Textile program! 20 Blend 122 Dyeing! 24 Drying 140 Warping 160 Weaving 2〇〇 Finishing process 220 Hand processing 240 Pressing and setting