TW200902465A - Metal-plated glazed ceramic product - Google Patents

Metal-plated glazed ceramic product Download PDF

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Publication number
TW200902465A
TW200902465A TW96125317A TW96125317A TW200902465A TW 200902465 A TW200902465 A TW 200902465A TW 96125317 A TW96125317 A TW 96125317A TW 96125317 A TW96125317 A TW 96125317A TW 200902465 A TW200902465 A TW 200902465A
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Taiwan
Prior art keywords
metal
plated
glazed ceramic
main component
ceramic article
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TW96125317A
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Chinese (zh)
Inventor
Wen-Zeng Tian
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Glamour Tile Co Ltd
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Priority to TW96125317A priority Critical patent/TW200902465A/en
Publication of TW200902465A publication Critical patent/TW200902465A/en

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Abstract

A metal-plated glazed ceramic product mainly includes a brick billet. The surface of the brick billet is provided with a pattern. The pattern surface is covered with a plurality of transparent blocks with smooth surfaces sintered from frit powder. The recess formed between transparent blocks is filled with a metal coating. Therefore, the surface of the metal-plated glazed ceramic product of the present invention shows a sense of beauty with crystal clearness and moreover shows colorful patterns so that the patterns become more transparent and brilliant. The metallic materials such as titanium-gold, titanium-silver, is plated between the patterns so that the profile of the patterns may become clearer and stereoscopic. The beauty is unrivaled by typical glazed ceramic product and is a more delicate, noble, and ornamental glazed ceramic product.

Description

200902465 九、發明說明: 【發明所屬之技術領域】 一種拋釉陶瓷製品,尤指一種鍍有金屬 陶瓷製品者。 【先前技術】 按,金色的陶瓷軋品是一種高貴的裝饰 因其高贵而華麗深受市場上的青睞,然而現 色陶瓷製品之製作方式亦不外乎有以下幾種 1、 網印:亦即將陶瓷製品經網印後燒矣 2、 貼花紙法:即先用金水預先製成花 貼於陶瓷製品上’而後再將陶瓷製占 3、 描繪或喷塗法:即將陶瓷製品經手 或拼搶喷塗圖案後燒結而成。 然而,以上幾種作法所製作出來的陶瓷製 少立體感且略嫌呆板,視覺上所帶來的感覺 淡。 【發明内容】 本發明係提供一種鍍金屬拋釉陶瓷製品, 設計’能提供一種更能透出色彩豐富的眼案, 瓷製im圈案更具透明感及光澤感者,為主要之 的。 而本發明之另一目的,係提供一種鍍金屬 瓷製品之製作方法。 為達到前述發明目的’本發明所運用的技 為提供一種鍍金屬拋釉陶瓷製品,其主要為一 的拋釉 品’也 有的金 作法: k而成。 紙後再 ίτ燒結。 工描繪 品均缺 亦覺平 希藉此 使得, 發明目 拋袖陶 術手段 磚胚, 5 200902465 該碑胚表面設有一圖案,該圓案表面覆蓋有複數個由 熔塊粉燒結而成之表面平滑的透明塊,而透明塊之間 所形成之凹槽内填充有金屬鍍層,故其製作方式依次 可分為以下步驟: 1、 在碑胚表面製作圖案; 2、 在圖案表面鋪灑熔塊粉使得圖案輪廓處鏤 空而形成凹槽; 3、 燒成,使得熔塊粉燒結形成透明塊; 4、 於步驟3的半成品之表面鍍上鈦金、鈦銀等 金屬材料使之填滿凹槽; 5、 表面拋光,以去除覆蓋於透明塊表面的金屬 鍍層。 【實施方式】 至此,為提供本發明更詳盡之製程及特徵,現 配合囷示說明如下: 請參閱第1、2、3、4、5、6囷所示,本發明之 一種鍍金屬拋釉陶瓷製品,其主要為一碑胚10,該 砗胚10表面設有一圓案20,該圖案20表面覆蓋有 複數個由熔塊粉3 0燒結而成之表面平滑的透明塊 40,而透明塊40之間所形成之凹槽50内填充有金屬 鍍層60,其中,該熔塊粉30係為由下列成份混合而 成之粉狀物: A 、 Si〇2 ; B ' MgO ; C、 A12〇3 ; 200902465 D ' K2O ; E 、 Fe2〇3 ; F 、 Na2〇 ; G 、 Ca〇 ; H' ZnO ; I ' Ba〇 ; J 、 Zr〇2 ; K ' B2O3 〇 請參閱第7圓所示, 本·發明夕 瓷製品之製作方法依次 分為以 π 1、請參閱第1、2 ® & 1 明所示, 碑胚1 0表面清洗乾淨, 然後於磚月 20,其中,該圖案20之匍也 取作可採 搶或印花機等方式製作,而# 或寶石紋理為佳’若以網印製成則1 度約為200〜300目; 2、請參閱第3、4圖所示,在 熔塊粉30使得圖案20輪廓處鏤空 該熔塊粉30的鋪灑厚度要適中、老 缺少立體感、若鋪灑過厚則透明度心 熔塊粉30之膨脹係數略小於磚胚1 熔塊粉30之顆粒粗度約為80〜200 30的絲網密度為40~60目’其主要 比如下: S1O2 55 - 6 5 % Mg〇 0-2-0.3% •種鍍金屬拋釉陶 步騍: 用棉布及純水將 1 〇表面製作圖案 1網印、手繪、喷 2〇尤以天然石材 5網印之絲網的密 圖案20表面補灑 而形成凹槽50, :舖m過薄則成品 不理想,其中,該 0之膨脹係數,且 目’而鎮設溶塊粉 成份之質量百分 Al2〇3 8-9% 200902465 Κ2〇 2-4% Fe2〇3 0.1-0.2% Na2〇 8-9% CaO 2-3% ZnO 2. 5-4% BaO 8-9% Zr〇2 0.1-0.5% B2〇3 15-20% 3、 燒成,將經上述之步驟的陶瓷確實的作三次 的反覆燒成,燒成後,會使得熔塊粉30燒結形成透 明塊40,使得圖案20因透明而更顯晶瑩剔透; 4、 請參閱第5圖所示,於步驟3的半成品之表 面鍍上鈥金、飲銀等金屬材料使之填滿凹榜50及透 明塊40 ; 5、 表面拋光,如第6圓所示,係為去除復蓋於 透明塊40表面的金屬鍍層60,且留於凹槽50内的 金屬鍵層60,如此一來會讓金屬鍵層60與透明塊4〇 形成一種視覺上的層次及觸感,其中,用於表面拋光 之拋光粉的主要成份是Al2〇3。 經上述步驟後所得之最後成品,其圖案2 〇表面 平滑且晶瑩剔透,且可透過透明塊40看見斑爛炫麗 的圖案20,而金屬鍍層60環繞透明塊40所勾勒出 的那種強烈的裝飾效果,亦有如寶石、珍珠的繽紛, 其中,本發明之一種鍍金屬拋釉陶瓷製品經測試後秦 以下物理性質: - 抗酸等級:A級 抗鹼等級:A級 耐磨等級:2級 硬度:莫氏硬度6級 【圖式簡單說明】 8 200902465 第1圖為本發明碑胚之外觀立體囷。 第2囷為本發明碑胚繪製圖案後之外觀立體囷。 第3圖為本發明碑胚繪製圓案後之側視圖。 第4圖為本發明碑胚之圖案表面舖灑熔塊粉使得圖 案輪廓處鏤空而形成凹槽之側視示意囷。 第5圖為本發明碑胚於表面鍍上鈦金、鈦銀等金屬 材料使之填滿凹槽的側視示意圖。 第6囷為本發明碑胚表面之金屬鍍層去除後的側視 示意圓。 第7圖為本發明之製造流程圖。 【主要元件符號說明】 10、碑胚 20、圖案 30、熔塊粉 40、透明塊 50、凹槽 60、金屬鍍層 9200902465 IX. Description of the invention: [Technical field to which the invention pertains] A glazed ceramic product, especially one coated with a metal ceramic product. [Prior Art] According to the golden ceramics, the noble decoration is favored by the market because of its nobleness. However, the production methods of modern ceramics are nothing more than the following: 1. Screen printing: It is also about to burn ceramic products after screen printing. 2. The method of decals: firstly, the flowers are pre-made with gold water and then attached to the ceramic products. Then the ceramics are taken up. 3. The painting or spraying method: the ceramic products are handled by hand or Squeeze the spray pattern and sinter it. However, the ceramics produced by the above several methods have less three-dimensionality and are slightly dull, and the visual feeling is light. SUMMARY OF THE INVENTION The present invention provides a metal-plated polished glazed ceramic product, which is designed to provide a more transparent eye-catching case, and the porcelain-made im-circle case is more transparent and glossy. Another object of the present invention is to provide a method of making a metallized porcelain article. In order to achieve the aforementioned object, the present invention employs a technique of providing a metallized glazed ceramic article which is mainly a glazed article of the same as the gold method: k. After the paper, ίτ is sintered. The lack of paintings is also known as Pingxi. Invented by the invention, the surface of the monument is covered with a pattern, and the surface of the round is covered with a plurality of surfaces sintered by frit. a smooth transparent block, and the groove formed between the transparent blocks is filled with a metal plating layer, so the manufacturing method can be divided into the following steps: 1. Making a pattern on the surface of the monument; 2. Spreading the frit on the surface of the pattern The powder is hollowed out to form a groove; 3, firing, so that the frit powder is sintered to form a transparent block; 4. The surface of the semi-finished product in step 3 is plated with a metal material such as titanium gold, titanium silver or the like to fill the groove. 5, the surface is polished to remove the metal coating covering the surface of the transparent block. [Embodiment] So far, in order to provide a more detailed process and features of the present invention, the following description is in conjunction with the following description: Please refer to the first, second, third, fourth, fifth, and sixth embodiments, a metallized glaze of the present invention. The ceramic product is mainly a monument 10, and the surface of the embryo 10 is provided with a circle 20, and the surface of the pattern 20 is covered with a plurality of transparent blocks 40 which are sintered by the frit powder 30, and the transparent block is transparent. The groove 50 formed between 40 is filled with a metal plating layer 60, wherein the frit powder 30 is a powder obtained by mixing the following components: A, Si〇2; B'Mg; C, A12〇 3 ; 200902465 D ' K2O ; E , Fe 2 〇 3 ; F , Na 2 〇 ; G , Ca 〇 ; H ' ZnO ; I ' Ba 〇 ; J , Zr 〇 2 ; K ' B2O3 〇 See the 7th circle The manufacturing method of the present invention is divided into π 1 , as shown in the first, 2 ® & 1 , the surface of the monument 10 is cleaned, and then on the brick month 20, wherein the pattern 20匍 is also made by picking up or printing machine, and # or gemstone texture is better. If it is made by screen printing, it is about 1 to 200 mesh; 2 Please refer to Figures 3 and 4, in the frit powder 30, the contour of the pattern 20 is hollowed out. The thickness of the frit powder 30 should be moderate, the old one lacks the three-dimensional sense, and if the shop is too thick, the transparent core frit powder 30 The expansion coefficient is slightly smaller than that of the brick. The particle thickness of the frit powder 30 is about 80~200. The density of the screen is 40~60 mesh. The main ones are as follows: S1O2 55 - 6 5 % Mg〇0-2-0.3 % • A kind of metal-plated glazed pottery enamel: Use 1 piece of cotton cloth and pure water to make a pattern on the surface of 1 网 screen, hand-painted, spray 2 〇 以 天然 天然 天然 天然 天然 天然 天然Slot 50, : If the shop is too thin, the finished product is not ideal, wherein the expansion coefficient of 0, and the mass percentage of the composition of the dissolved powder component is Al2〇3 8-9% 200902465 Κ2〇2-4% Fe2 〇3 0.1-0.2% Na2〇8-9% CaO 2-3% ZnO 2. 5-4% BaO 8-9% Zr〇2 0.1-0.5% B2〇3 15-20% 3. After firing, it will be The ceramics of the above steps are surely subjected to three times of repeated firing. After firing, the frit powder 30 is sintered to form a transparent block 40, so that the pattern 20 is more crystal clear due to transparency; 4. Please refer to FIG. In step 3 The surface of the semi-finished product is plated with metal materials such as sheet metal and silver to fill the intaglio 50 and the transparent block 40. 5. The surface is polished, as shown in the sixth circle, to remove the metal covering the surface of the transparent block 40. The plating layer 60 is left in the metal key layer 60 in the recess 50, so that the metal key layer 60 and the transparent block 4 are formed into a visual layer and a touch, wherein the polishing powder for surface polishing is used. The main ingredient is Al2〇3. After the above steps, the final product obtained has a pattern 2 平滑 smooth and crystal clear, and the sleek pattern 20 can be seen through the transparent block 40, and the metal plating 60 surrounds the strong decoration of the transparent block 40. The effect is also as colorful as gemstones and pearls. Among them, the physical properties of a metal-plated polished glazed ceramic product of the present invention after testing are as follows: - acid resistance grade: grade A alkali resistance grade: grade A wear grade: grade 2 hardness : Mohs hardness 6 [Simplified illustration] 8 200902465 The first picture shows the appearance of the monument. The second one is the appearance stereoscopic shape after the pattern is drawn by the monument. Figure 3 is a side view of the monument of the invention after drawing a round case. Fig. 4 is a side view showing the groove of the pattern on the surface of the monument of the present invention, so that the contour of the pattern is hollowed out to form a groove. Fig. 5 is a side elevational view showing the surface of the monument of the present invention plated with a metal material such as titanium gold, titanium silver or the like to fill the surface. The sixth aspect is a side view schematic circle after the metal plating of the surface of the monument is removed. Figure 7 is a manufacturing flow chart of the present invention. [Description of main component symbols] 10. Stone monument 20, pattern 30, frit powder 40, transparent block 50, groove 60, metal plating 9

Claims (1)

200902465 十、申請專利範園: 1 、一種鍍金屬拋釉陶瓷製品,其主要為一碑 胚’該磚胚表面設有一圓案,其特徵在於: 該囷案表面覆蓋有複數個由熔塊粉燒結而成之 表面平滑的透明塊’而透明塊之間所形成之凹槽内填 充有金屬鍍層。 2、 如申請專利範圃第1項所述之一種鍍金屬 拋釉陶瓷製品’其中,該金屬鍍層可為鈦金。 3、 如申請專利範圍第1項所述之一種鍍金屬拋 釉陶瓷製品,其中,金屬鍍層可為鈦銀。 4、 一種鍍金屬抛轴陶瓷製品,其製作方法依 次可分為以下步驟: A、 先用棉布及純水將磚胚表面清洗乾淨,然後 於磚胚表面製作圖案; B、 在圈案表面鋪滬熔塊粉使得圓案輪廓處鏤 空而形成凹槽; C、 燒成,將經上述之步驟的陶瓷確實的作三次 的反覆燒成使得熔塊粉燒結形成透明塊; D、 將步琢C的半成品之表面鍍上鈥金、鈦銀等 金屬材料使之填滿凹槽及透明塊; E、 表面拋光,去除覆蓋於透明塊表面的金屬鍍 層,且留凹槽内之金屬鍍層。 5、如申請專利範圍第4項所述之一種鍍金屬拋 釉陶瓷製品,其中,圈案之製作可採用網印方式製 作。 10 200902465 6、如申請專利範圍第4項所述之一種鍍金屬 拋釉陶瓷製品,其中,圓案之製作可採用手繪方式製 作。 7、 如申請專利範圍第4項所述之一種鍍金屬拋 釉陶瓷製品,其中,圊案之製作可採用喷搶方式製 作。 8、 如申請專利範圍第4項所述之一種鍵金屬拋 釉陶瓷製品,其中,圖案之製作可採用印花機方式製 作。 9、 如申請專利範圍第4項所述之一種鍍金屬拋 釉陶瓷製品,其中,步驟B的熔塊粉係為由下列成份 混合而成之粉狀物: A 、 Si〇2 ; B 、 MgO ; C、A 12〇3 ; D 、 K2〇 ; E 、 Fe2〇3 ; F 、 Na2〇 ; G ' CaO y H 、 ZnO ; I 、 BaO ; J 、 Zr〇2 ; K 、 B2O3 。 1 0、如申請專利範圍第7項所述之一種鍍金屬 拋轴陶瓷製品,其中,該熔塊粉主要成份Si 〇2之質 量百分比為55〜65%。 1 1、如申請專利範圍第7項所述之一種鍍金屬 11 200902465 拋釉陶瓷製品,其中,該熔塊粉主要成份MgO之質量 百分比為0. 2~0. 3%。 1 2、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份Al2〇3之質 量百分比為8〜9%。 13、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份K20之質量 百分比為2~4%。 1 4、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份Fe2〇3之質 董百分比為0. 1 ~0. 2%。 1 5、如申請專利範圍第7項所述之一種鍍金屬 拋轴陶瓷製品,其中,該熔塊粉主要成份Na2〇之質 量百分比為8~9%。 1 6、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份CaO之質量 百分比為2〜3%。 1 7、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份ZnO之質量 百分比為2. 5~4%。 1 8、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份BaO之質量 否分比為8〜9%。 1 9、如申請專利範圍第7項所述之一種鍍金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份Zr〇2之質 量百分比為0.卜0.5%。 2 0、如申請專利範圍第7項所述之一種鍵金屬 拋釉陶瓷製品,其中,該熔塊粉主要成份B2〇3之質 量百分比為15~20%。 12 200902465 2 1、如申請專利範圍第4項所述之一種鍍金屬 拋釉陶瓷製品,其中,步驟E的拋光中所用之拋光粉 的主要成分為Al2〇3。 13200902465 X. Application for Patent Fanyuan: 1. A metal-plated polished glazed ceramic product, which is mainly a monumental embryo. The surface of the brick embryo is provided with a round case, which is characterized in that: the surface of the file is covered with a plurality of frit powders. The sintered surface is smooth and transparent, and the grooves formed between the transparent blocks are filled with a metal plating. 2. A metal-plated glazed ceramic article as claimed in claim 1, wherein the metal plating layer is titanium metal. 3. A metal-plated polished glazed ceramic article according to the first aspect of the invention, wherein the metal plating layer is titanium silver. 4. A metal-plated shaft-throwing ceramic product, the manufacturing method thereof can be further divided into the following steps: A. First clean the surface of the brick embryo with cotton cloth and pure water, and then make a pattern on the surface of the brick embryo; B. Spread the surface of the circle The Shanghai frit powder makes the contour of the round case hollow and forms a groove; C. firing, the ceramic of the above steps is reliably repeated three times to make the frit powder sintered to form a transparent block; D, will step C The surface of the semi-finished product is plated with a metal material such as sheet metal or titanium silver to fill the groove and the transparent block; E. The surface is polished to remove the metal plating layer covering the surface of the transparent block, and the metal plating layer in the groove is left. 5. A metal-plated polished glazed ceramic article according to item 4 of the patent application, wherein the production of the circle pattern can be produced by screen printing. 10 200902465 6. A metal-plated glazed ceramic article as described in claim 4, wherein the production of the round case can be made by hand-painting. 7. A metal-plated polished glazed ceramic product according to item 4 of the patent application, wherein the production of the smashing case can be carried out by means of a spray blasting method. 8. A key metal glazed ceramic article according to claim 4, wherein the pattern is produced by a printing machine. 9. A metal-plated glazed ceramic article according to claim 4, wherein the frit powder of step B is a powder obtained by mixing the following components: A, Si〇2; B, MgO C, A 12〇3; D, K2〇; E, Fe2〇3; F, Na2〇; G 'CaO y H, ZnO; I, BaO; J, Zr〇2; K, B2O3. A metal-plated shaft-throwing ceramic article according to claim 7, wherein the mass fraction of the main component of the frit powder, Si 〇 2, is 55 to 65%. 1 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。. A metal-plated glazed ceramic article according to the seventh aspect of the invention, wherein the mass percentage of the main component of the frit powder, Al2〇3, is 8 to 9%. 13. A metal-plated glazed ceramic article according to item 7 of the patent application, wherein the mass percentage of the main component K20 of the frit powder is 2 to 4%. 1 至2. 2%。 The percentage of the mass of the main component of the mass of the frit is 0. 1 ~ 0. 2%. A metal-plated shaft-throwing ceramic article according to item 7 of the patent application, wherein the mass percentage of the main component of the frit powder, Na2〇, is 8 to 9%. A metal-plated glazed ceramic article according to the seventh aspect of the invention, wherein the mass percentage of the main component of the frit powder is from 2 to 3%. 5〜4%。 The mass percentage of the main component of the ZnO is 2. 5~4%. 18. A metal-plated glazed ceramic article according to claim 7, wherein the mass fraction of the main component of the frit powder is 8 to 9%. A metal-plated glazed ceramic product according to claim 7, wherein the mass percentage of the main component Zr〇2 of the frit powder is 0. A key metal glazed ceramic product according to claim 7, wherein the mass percentage of the main component B2〇3 of the frit powder is 15-20%. A metal-plated glazed ceramic article according to the fourth aspect of the invention, wherein the polishing powder used in the polishing of the step E has a main component of Al2〇3. 13
TW96125317A 2007-07-12 2007-07-12 Metal-plated glazed ceramic product TW200902465A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110856441A (en) * 2018-05-31 2020-02-28 法国圣戈班玻璃厂 Transparent element with diffuse reflection

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110856441A (en) * 2018-05-31 2020-02-28 法国圣戈班玻璃厂 Transparent element with diffuse reflection
CN110856441B (en) * 2018-05-31 2023-07-04 法国圣戈班玻璃厂 Transparent element with diffuse reflection

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