CN107915500A - A kind of Ceramic Tiles with outstanding light effect - Google Patents

A kind of Ceramic Tiles with outstanding light effect Download PDF

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Publication number
CN107915500A
CN107915500A CN201711147262.0A CN201711147262A CN107915500A CN 107915500 A CN107915500 A CN 107915500A CN 201711147262 A CN201711147262 A CN 201711147262A CN 107915500 A CN107915500 A CN 107915500A
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Prior art keywords
ceramic
ceramic tiles
tiles
temperature
outstanding
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CN201711147262.0A
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CN107915500B (en
Inventor
吴宇风
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Enping Huachang Ceramics Co Ltd
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Enping Huachang Ceramics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

Abstract

The invention discloses a kind of Ceramic Tiles with outstanding light effect, the Ceramic Tiles apply the ceramic glaze of ceramic high temperature light bead and bismuth-containing compound, and the specific production stage of the Ceramic Tiles is:(1) prefabricated ceramic matrix, it is dry;(2) after ceramic matrix drying, one layer of ground-coat enamel is first applied on 110 120 DEG C of ceramic matrix surface, is then carried out ink-jet printed;(3) on the carcass after stamp, the ceramic glaze of bismuth oxide is stamped by specific design;(4) ceramic high temperature light bead is uniformly sprayed on the surface again, after the bonding of blend compounds water, high temperature sintering;(5) sanding and polishing is carried out to the surface of semi-finished product, makes the gloss of 30~44 degree of the surface light bead generation of Ceramic Tiles;The Ceramic Tiles of the present invention had not only carried the pattern of certain decorative effect but also had had soft and glittering and translucent light bead, and ceramic brick surface, which yet forms both, to produce the outstanding blink line of different visual patterns in different visual angles, generation cuts in and out, indistinct peculiar decorative effect.

Description

A kind of Ceramic Tiles with outstanding light effect
Technical field
The present invention relates to the technical field of Ceramic Tiles, more particularly to a kind of Ceramic Tiles with outstanding light effect and its preparation side Method.
Background technology
Ceramic Tiles are a kind of metope and land protection and ornament materials that current building trade uses, as people are to life The raising that level is pursued, ceramic material often set various decorative patterns and pattern, or natural imitation to pursue natural stype on surface Rock patterns etc., these patterns can be formed by modes such as cloth, glaze spraying material or printings, i.e. the manufacture in ceramic product Different working processes is carried out in journey to its surface, stone pattern, flowing water line, wood grain are such as formed by mould compacting or glazing technique Deng Natural decoration effect, but these processing, processing method carry fairly obvious artifact, become the surface of ceramic product Change is dull, texture texture is stiff, such as changes the position of people, sees the surface of these Ceramic Tiles from different directions, is respectively provided with identical The decorative pattern of visual pattern, can not embody natural stype true to nature.Such as existing Antique Imitation Tiles product decoration face decorative pattern on the market is fixed, Color and luster dumb light low-key is inflexible;Polished bricks product decoration face decorative pattern is fixed, and of light color with low uncertainty, pattern is few, and gloss is too strong.
The content of the invention
A kind of present invention seek to address that above-mentioned mentioned technical problem, there is provided Ceramic Tiles and its system with outstanding light effect Preparation Method.
To achieve the above object, technical solution provided by the invention is:
A kind of Ceramic Tiles with outstanding light effect, the Ceramic Tiles include the ceramics of ceramic high temperature light bead and bismuth oxide Glaze.
Preferably, the chemical composition of the ceramic glaze of the bismuth oxide includes by weight percentage:SiO258~ 63%th, Al2O310~12%, Fe2O3< 0.5%, TiO2< 0.5%, CaO < 0.5%, MgO < 0.5%, k2O 1.5~2%, Na2O 5~6.5%, ZnO 10~15%, B2O31~3%, Bi2O38~12%.
Preferably, the chemical composition of the ceramic high temperature light bead includes by weight percentage:SiO261~64%, Al2O313~15%, Fe2O3< 0.5%, TiO2< 0.5%, CaO 10~12%, MgO 1~2%, k2O 2~3.5%, Na2O 4~5.5%, ZnO 2~3%, B2O31~2%, BaO 1~3%.
The specific production stage of the above-mentioned Ceramic Tiles with outstanding light effect is:
(1) prefabricated ceramic matrix, it is dry;
(2) after ceramic matrix drying, one layer of ground-coat enamel is first applied on 110-120 DEG C of ceramic matrix surface, then carries out ink-jet Stamp;
(3) on the carcass after stamp, the ceramic glaze of bismuth oxide is stamped by specific design;
(4) ceramic high temperature light bead is uniformly sprayed on the surface again, after the bonding of blend compounds water, high temperature sintering;
(5) sanding and polishing is carried out to the surface of semi-finished product, makes the gloss of 30~44 degree of the surface light bead generation of Ceramic Tiles.
Preferably, in step (2), the chemical composition of the Ceramic Tiles ground-coat enamel includes by weight percentage:SiO257~ 59%th, Al2O316~19%, Fe2O3< 0.5%, TiO2< 0.5%, CaO 6~8%, MgO 1~2%, k2O 1~ 2.5%th, Na2O 3.5~4.5%, ZnO 2~3%, BaO 3~5%, ZrO23~5%.
Preferably, in step (4), the ceramic high temperature light bead fineness is between 100~150 mesh.
Preferably, in step (4), the high temperature sintering temperature is burnt till at 1200-1220 DEG C, by 55~80min.
China is Bi Chan states maximum in the world, exported country.Bismuth has a series of good characteristic, such as than great, fusing point Volume expands with cold and contracts with heat during low, solidification, and the nontoxic and not carcinogenicity of especially bismuth makes bismuth have many special purposes.Bismuth is because of it Many property and be widely used in metallurgy, chemical industry, electronics, aerospace, medicine and other fields already.
Inventor gropes to study by long-term, finds bismuth with Bi2O3Form be added in ceramics and can significantly improve material Performance, addition bismuth oxide greatly increases Ceramic Tiles glaze layer proportion and refraction coefficient, in specific silicate component environment and Metallic luster peculiar and different from all traditional ceramics brick surface effects are produced under conditions of pyroreaction, thus successfully should Decoration functions for ceramic surface.
The beneficial effect of the method for the present invention is:Through Ceramic Tiles made of above-mentioned production technology, both with certain decorative effect Pattern have soft and glittering and translucent light bead again, ceramic brick surface, which yet forms both, to produce different visual patterns in different visual angles Outstanding blink line, produce cut in and out, indistinct peculiar decorative effect.
Embodiment
Technical scheme is further illustrated below by embodiment.
Embodiment 1:
A kind of Ceramic Tiles with outstanding light effect, the Ceramic Tiles include the ceramics of ceramic high temperature light bead and bismuth oxide Glaze.
The chemical composition of ceramic glaze includes by weight percentage:SiO258%th, Al2O310%th, Fe2O30.4%th, TiO20.4%th, CaO 0.4%, MgO 0.4%, k2O 2%, Na2O 6.5%, ZnO 15%, B2O33%th, Bi2O312%.
Ceramic high temperature light bead chemical composition includes by weight percentage:SiO261%th, Al2O313%th, Fe2O3 0.4%th, TiO20.4%th, CaO 12%, MgO 2%, k2O 3.5%, Na2O 5.5%, ZnO 3%, B2O32%th, BaO 3%.
The specific production stage of Ceramic Tiles with outstanding light effect is:
(1) prefabricated ceramic matrix, it is dry;
(2) after ceramic matrix drying, one layer of ground-coat enamel is first applied on 110 DEG C of ceramic matrix surface, is then carried out ink-jet printed;
(3) on the carcass after stamp, the ceramic glaze of bismuth-containing compound is stamped by specific design;
(4) the ceramic high temperature light bead that granularity is 100 mesh is uniformly sprayed on the surface again, after the bonding of blend compounds water, 1200 55min is sintered at DEG C;
(5) sanding and polishing is carried out to the surface of semi-finished product, makes the gloss of 30 degree of the surface light bead generation of Ceramic Tiles.
In step (2), the chemical composition of Ceramic Tiles ground-coat enamel includes by weight percentage:SiO257%th, Al2O316%th, Fe2O30.4%th, TiO20.4%th, CaO 8%, MgO 2%, k2O 1%, Na2O 3.5%, ZnO 3%, BaO 5%, ZrO2 3%.
Embodiment 2:
A kind of Ceramic Tiles with outstanding light effect, the Ceramic Tiles include the ceramics of ceramic high temperature light bead and bismuth oxide Glaze.
Ceramic glaze is put into chemical composition to be included by weight percentage:SiO263%th, Al2O312%th, Fe2O30.1%th, TiO20.1%th, CaO 0.1%, MgO 0.1%, k2O 1.5%, Na2O 5%, ZnO 10%, B2O31%th, Bi2O38%.
The chemical composition of ceramic high temperature light bead includes by weight percentage:SiO264%th, Al2O315%th, Fe2O3 0.1%th, TiO20.1%th, CaO 10%, MgO 1%, k2O 2%, Na2O 4%, ZnO 2%, B2O31%th, BaO 1%.
The specific production stage of Ceramic Tiles with outstanding light effect is:
(1) prefabricated ceramic matrix, it is dry;
(2) after ceramic matrix drying, one layer of ground-coat enamel is first applied on 120 DEG C of ceramic matrix surface, is then carried out ink-jet printed;
(3) on the carcass after stamp, the ceramic glaze of bismuth-containing compound is stamped by specific design;
(4) the ceramic high temperature light bead that granularity is 150 mesh is uniformly sprayed on the surface again, after the bonding of blend compounds water, 1220 80min is sintered at DEG C;
(5) sanding and polishing is carried out to the surface of semi-finished product, makes the gloss of 44 degree of the surface light bead generation of Ceramic Tiles.
In step (2), the chemical composition of Ceramic Tiles ground-coat enamel includes by weight percentage:SiO259%th, Al2O319%th, Fe2O30.3%th, TiO20.3%th, CaO 6%, MgO 1%, k2O 2.5%, Na2O 4.5%, ZnO 2%, BaO 3%, ZrO2 5%.
Embodiment 3:
A kind of Ceramic Tiles with outstanding light effect, the Ceramic Tiles include the ceramics of ceramic high temperature light bead and bismuth oxide Glaze
The chemical composition of ceramic glaze includes by weight percentage:SiO259%th, Al2O310.5%th, Fe2O30.2%th, TiO20.2%th, CaO 0.2%, MgO 0.2%, k2O 1.8%, Na2O 5.5%, ZnO 11.9%, B2O31.5%th, Bi2O3 9%.
The chemical composition of ceramic high temperature light bead includes by weight percentage:SiO262%th, Al2O313.5%th, Fe2O3 0.2%th, TiO20.2%th, CaO 10.5%, MgO 1.5%, k2O 2.5%, Na2O 4.5%, ZnO 2.5%, B2O31.3%th, BaO 1.3%.
The specific production stage of Ceramic Tiles with outstanding light effect is:
(1) prefabricated ceramic matrix, it is dry;
(2) after ceramic matrix drying, one layer of ground-coat enamel is first applied on 115 DEG C of ceramic matrix surface, is then carried out ink-jet printed;
(3) on the carcass after stamp, the ceramic glaze of bismuth oxide is stamped by specific design;
(4) uniformly spray ceramic high temperature light bead on the surface again, after the bonding of blend compounds water, 65min is sintered at 1210 DEG C;
(5) sanding and polishing is carried out to the surface of semi-finished product, makes the gloss of 35 degree of the surface light bead generation of Ceramic Tiles.
In step (2), the chemical composition of Ceramic Tiles ground-coat enamel includes by weight percentage:SiO258%th, Al2O318%th, Fe2O30.1%th, TiO20.2%th, CaO 7%, MgO 1.5%, k2O 2%, Na2O 4%, ZnO 2.5%, BaO 4%, ZrO2 4%.
The above embodiments are merely illustrative of the technical solutions of the present invention and is not limited, all without departing from the present invention Any modification of spirit and scope or equivalent substitution, it should all cover the scope in technical solution of the present invention.

Claims (7)

1. a kind of Ceramic Tiles with outstanding light effect, it is characterised in that the Ceramic Tiles include ceramic high temperature light bead and bismuth-containing oxygen The ceramic glaze of compound.
2. the Ceramic Tiles with outstanding light effect according to claim 1, it is characterised in that the ceramics of the bismuth oxide The chemical composition of glaze includes by weight percentage:SiO258~63%, Al2O310~12%, Fe2O3< 0.5%, TiO2< 0.5%th, CaO < 0.5%, MgO < 0.5%, k2O 1.5~2%, Na2O 5~6.5%, ZnO 10~15%, B2O31~ 3%th, Bi2O38~12%.
3. the Ceramic Tiles with outstanding light effect according to claim 1, it is characterised in that the change of the ceramic high temperature light bead Study point includes by weight percentage:SiO261~64%, Al2O313~15%, Fe2O3< 0.5%, TiO2< 0.5%, CaO 10~12%, MgO 1~2%, k2O 2~3.5%, Na2O 4~5.5%, ZnO 2~3%, B2O31~2%, BaO 1~3%.
A kind of 4. production method of the Ceramic Tiles with outstanding light effect any one of claim 1-3, it is characterised in that Including step is produced by below:
(1) prefabricated ceramic matrix, it is dry;
(2) after ceramic matrix drying, one layer of ground-coat enamel is first applied on 110-120 DEG C of ceramic matrix surface, is then carried out ink-jet printed;
(3) on the carcass after stamp, the ceramic glaze of bismuth oxide is stamped by specific design;
(4) ceramic high temperature light bead is uniformly sprayed on the surface again, after the bonding of blend compounds water, high temperature sintering;
(5) sanding and polishing is carried out to the surface of semi-finished product, makes the gloss of 30~44 degree of the surface light bead generation of Ceramic Tiles.
5. the production method of the Ceramic Tiles according to claim 4 with outstanding light effect, it is characterised in that the Ceramic Tiles The chemical composition of ground-coat enamel includes by weight percentage:SiO257~59%, Al2O316~19%, Fe2O3< 0.5%, TiO2 < 0.5%, CaO 6~8%, MgO 1~2%, k2O 1~2.5%, Na2O 3.5~4.5%, ZnO 2~3%, BaO 3~ 5%th, ZrO23~5%.
6. the production method of the Ceramic Tiles according to claim 4 with outstanding light effect, it is characterised in that in step (4), The ceramic high temperature light bead fineness is between 100~150 mesh.
7. the production method of the Ceramic Tiles according to claim 4 with outstanding light effect, it is characterised in that:In step (4), The high temperature sintering temperature is 55~80min in 1200-1220 DEG C, sintering time.
CN201711147262.0A 2017-11-17 2017-11-17 Ceramic tile with qi light effect Active CN107915500B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108975891A (en) * 2018-08-27 2018-12-11 佛山石湾鹰牌陶瓷有限公司 Ink-jet infiltration spends beautiful matter polished bricks and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128246A (en) * 1994-11-17 1996-08-07 山东省硅酸盐研究设计院 Leadless cadmiumless ceramic glazing pigment
CN105985142A (en) * 2015-02-15 2016-10-05 广东嘉俊陶瓷有限公司 Formula and manufacturing method of imitated natural marble super-flat and full-polished porcelain tiles
CN106746651A (en) * 2017-01-16 2017-05-31 佛山市道氏科技有限公司 A kind of dry granular glaze with diamond luster effect

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128246A (en) * 1994-11-17 1996-08-07 山东省硅酸盐研究设计院 Leadless cadmiumless ceramic glazing pigment
CN105985142A (en) * 2015-02-15 2016-10-05 广东嘉俊陶瓷有限公司 Formula and manufacturing method of imitated natural marble super-flat and full-polished porcelain tiles
CN106746651A (en) * 2017-01-16 2017-05-31 佛山市道氏科技有限公司 A kind of dry granular glaze with diamond luster effect

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周晓燕: "《陶瓷坯釉料制备技术》", 31 August 2017, 江西高校出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108975891A (en) * 2018-08-27 2018-12-11 佛山石湾鹰牌陶瓷有限公司 Ink-jet infiltration spends beautiful matter polished bricks and preparation method thereof

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