TW200900466A - Polyamide resin composition - Google Patents

Abstract

A resin composition comprising, as an essential component, a polyamide elastomer containing at least 50% by mass of a polyetheramide elastomer (X) obtained by polymerization of components including (A): a diamine compound (A) comprising a triblock polyetherdiamine compound (A1) represented by a formula shown below and at least one diamine compound (A2) selected from the group consisting of branched saturated diamines having 6 to 22 carbon atoms, branched alicyclic diamines having 6 to 16 carbon atoms, and norbornanediamine, (B): a polyamide-forming monomer (B), and (C): a dicarboxylic acid compound; and also comprising, as an accompanying component, at least one of (a) a thermoplastic resin and (b) a flame retardant or magnetic powder. This resin composition offers improved flexibility and shock-absorbing properties, and has excellent resistance to hydrolysis.

Description

200900466 IX. Description of the invention: [Technical field to which the invention pertains] The product of the invention relates to a tree-like composition comprising a poly-branched amine as a hard segment and a tricyclic polyether as a soft segment. Polyamide-based elastomer, and according to the prior art, the amine resin is widely used for riding, hose, wire and wire, and resin for the sake of wealth, solvent, heat resistance and toughness. For the recording or impact resistance, a proposal has been made to cooperate with an ionic polymer tree or a modified polyolefin resin. (4) In the Japanese Patent Publication No. 55-41659 (Patent Document 1), it is proposed that the ionic polyamine-based elastomer is blended with the bis-resin-containing non-acid copolymer ί==4 shot i61,1 (Patent Document 7) A resin group containing a polyanthracene resin and a polyamide-based elastomer = a fat composition, which is suitable for use in automobiles, and is imparted to a polyamine tree 002915 2) t ^t " 5 2〇〇1~ Surface area 嶋二上2004 —352790 ^ί=ΐΐίΐ Filling agent 5~100 f parts. In Japan, the special elastic body and the 9) ’ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ In Japanese Patent Laid-Open No. 2 to 138197, a poly-polyamine composition is disclosed in (Patent Document 3), and it is disclosed that (refractory is composed of (A), (8), (C), and (D), which is characterized in that: When the polyacetamide composition is formed into a pellet shape according to the UL94 specification, the pellet is formed by the two-dimensional number qn *early position. / or alicyclic binary formation early =: = diamine composition unit and the measurement of the view is sen ~ 3 (% / 1 Μ η ί range negative ^ = agglomeration «: 20 ~ 80 f amount%. (8) benefit machine, point : Compound oxidized by a compound of 290 C (tetra) benzene (= 〇 〜 1 ~ 10 曰 曰) 3 锑 compound and / or zinc containing: amount %; Bell, on the fine, (8), (C), (9) component of the gamma ^mlmtTirX A] 5 two parts by mass, and three lions two 1 〇) A 0 i. Insulting literature 丨 1), the composition of the polyamine containing the flame retardant can be described as: f, known as a resin magnet. The resin magnet is shaped into a product shape, and even a complicated shape can be used in various fields. In order to improve the softness of the resin magnet, it has been revealed that the technique of the olefin-based elastomer is not disclosed. In the magnetic properties of the resin magnet, it is necessary to increase the content and orientation of the magnetic powder. However, if the content of the magnetic powder is increased, there is a problem that the alignment of the powder of the H and the powder is also deteriorated. In order to solve this problem, a humanized test was added with a plasticizer in the tree raft to improve the flow of the resin during the refining of the resin. Shuyue·2-2 Li 9 (Paste Document 5), reveals that the polyamine amine, the axial magnetic powder and the polyamine resin are characterized in that the poly is composed of =2 Aramid resin magnets, 纟3~20 range, Τι:/~ΓΒ Ω or more and water absorption is less than 〇. Aromatic polyamine, and a mixture of aliphatic polyamines having a melting point of 265 water rate less than 2. (10) Composition. In the Japanese Patent Publication No. 3-041116 (Patent Document 6), it is disclosed that the poly (A) and (6) imitation materials are characterized by: (A) magnetic powder, (8) "amine resin, = amine resin of 3 to 30 masses. % below R1 - Qing 1 Japanese special 9 ^ 1 and saturated fatty acid guanamine, obtained by kneading. In the No. 4 publication (Patent Document 12) and the Japanese special product, the molded article, and the resin "Magnetite^Document 13), the prefecture poly_resin composition iiriif1] Japanese special public Zhaoyang-41659 bulletin [i spear Japan special open Cong-Hid 15th Bulletin 2; f3] 曰本特开__138197 曰本特开_〇67号公告 [ί= 特开2〇〇3-_16号 [PTL 8] 曰ί特开Leg No. 161964 Gazette "tff^004-352789^ [容容ί 1本特开2〇04-352790号 rii41 ^10] Japanese Patent Laid-Open No. 2004-352794, i Li Tekai 2_-352795 Text f12] Japanese special open 2GQ4-352791 on the Gongle 'Document 13】 Japanese Special Open 2004 - 352792 recorded in the publication [invention] 200900466 (invention to solve the problem) broadcast people ΙΞΪ ΙΞΪ thermal resin resistance or impact, In the thermoplastic resin, the ten-part enthalpy viscosity becomes higher than that of the basic thermoplastic resin, and this condition, the material is deteriorated and the use is limited. The underlying plasticity tree is provided with a resin composition which does not change the moldability for improving flexibility or durability, and can cause problems such as bleeding of the plasticizer in the amount of ϋ λ of the present invention. In the case of the case, it is required to use the nf piece or the like in a harsh environment under high temperature and high humidity, and the case may be caused by hydrolysis. Performance issues in this environment.曰 ... 、 、 决 决 决 决 决 决 作为 作为 作为 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使 即使Brother, the resin is not deteriorated by hydrolysis, and the magnetic properties of the resin magnet can be increased. However, if the magnetic powder is u liter, it is necessary to make the magnetic powder contain enough, and there is a problem that cracking or the like occurs. [The softness of the resin magnet is not used as a bonding resin, and there is a sensation in this case, using polyamine resin. In order to improve the softness of the resin magnet, the heat resistance or hydrolysis resistance of the t-elastomer is insufficient, and the elastomer component which is too complex, w, and the inner body of the present invention is in the form of the invention; According to 200900466, under the high temperature and high humidity, the adhesive resin is not improved due to hydrolysis, and the magnetic properties are required to be formed. =:Ξ=='ϊ!ΐί: Resin magnet, elasticity is magnetic property The excellent material is: (2) ^ is good, so it can be made not only on the surface of the finished product, but also in the electrical and electronic components that require dimensional stability. Moreover, especially in the outside of the house and / or shouting _, _ heat caused by two j; s: repeated temperature changes caused by the resin magnet;; =; some - =; one aspect of the invention, the purpose is to provide - A resin magnet that is inserted into a metal component. 7 In a harsh environment, Yudougu, Xigu, Jingxia: Renyang provides a resin magnet, which has a performance drop ^ _ (4) order not (four) hydrolysis Deterioration of the bonding resin (method of solving the problem) The present invention relates to the matters specified in the following [1]. [1] A resin composition characterized in that the polyamine-based elastomer package 200900466 contains a polyether phthalamide elastomer (χ) in an amount of 5 % by mass or more, (A), The components of (Β) and (C) are obtained by polymerization; the polyether phthalamide elastomer (X) contains at least one of (a) and (6) as a total (4): an amine compound (4), including the following (==================================================================================================== a) thermoplastic resin; (b) flame retardant or magnetic powder; um3 Π 1 - r 9H3 h2n- -chch2o · -CH2CH2CH2CH2-〇i 1 ch2cho- rn XL _ y _ ch3 I CH2CH—Nhl· (1) where x An integer of 1 to 20 is represented, y represents an integer of 4 to 50, and z represents an integer of 20. Representative aspects of the invention are as follows. [2] The resin composition according to the above [1], which comprises the aforementioned thermoplastic resin.

[3] The resin composition according to the above [2], wherein the aforementioned thermoplastic resin contains polyamine. [4] The resin composition according to the above [2] or [3], which comprises 95 to 50% by mass of the thermoplastic resin and 5 to 5% by mass of the polyamine-based elastomer. [5] The resin composition according to any one of the above [2] to [4], which further comprises 1 to 30 masses based on the total mass of the polyamine-based elastomer and the thermoplastic resin (8) parts by mass. A portion of plasticizer. [6] The resin composition according to the above [1], wherein the flame retardant is contained in an amount of 5 to 4 parts by mass based on 1 part by mass of the polyamine-based elastomer. The resin composition of the above-mentioned thermoplastic resin and the flame retardant, and the amount of the flame retardant is 5, based on 100 parts by mass of the person of the polyamine-based elastomer and the thermoplastic resin. ~40 parts by mass. σ [8] The resin composition of the above [7], wherein the thermoplastic resin is a polyether female [9], such as the resin composition of the above [7] or [8], wherein the toramine "physical body" The total amount of the above-mentioned threats is 10 to 50% by mass, and the polyamine-based elastomer is 5 to 5% by mass. ',,, Polyether: Two: Sex: ==: ==2 ΓΙΟΙ . ΜΠΊ 4-' 4^Γ, containing a ratio of 5 to 20% by mass. Further comprising a resin domain of polysulfonium. S 11], wherein the pre-hybrid resin, the monthly system contains such The molded article of the composition. In the present invention, the preferred embodiment is as follows.

The di-lowering acid compound (6) is represented by the formula (2).

HOOC—fR1-)—C〇〇H (2) (R: R represents a condensed amide-forming monomer (β) containing _, soil: not recorded as 0 or 1.) Amine amine compound, diamine and _ ^Self-selected from: a polyamine-forming monomer (Β) from a group consisting of an amino acid compound, at least one aliphatic, an alicyclic acid, a synthon, and the like; . The substance (B1) is at least one of the following formula (4) #, 匕3, an amino group carboxylic acid represented by the following formula (3), and a lactam compound (B2). 13 (3) 200900466

H2N - R2 COOH (only R2 represents the linking group of the hydrocarbon chain.)

(R3 only represents a linking group containing a hydrocarbon chain.)

Acidified phthalic acid compound (6), which is an aliphatic bis-compound and/or an alicyclic bismuth relative to a diamine compound (Α), a poly-formative monomer compound (c), a polyamine forming property The ratio of monomer (Β) is 1〇~95 mass〇/〇. The ratio of the polyamine forming monomer (Β) is 15 to 8 相对 with respect to the total amount of the monoamined product (Α), the polyamine forming monomer (β), and the dicarboxylic acid compound (c). A mass of 0/〇, a monobasic compound (Α), and a dicarboxylic acid compound (the total amount of the compound is 2 〇 to 85% by mass. R 2 of the formula (3) contains an alkylene group having 2 to 20 carbon atoms. R3 includes an alkylene group having 3 to 20 carbon atoms. X of the formula (1) represents an integer of 2 to 6, y represents an integer of 6 to 12, and z represents an integer of 1 to 5. Formula X (1) An integer of 2 to 10, y represents an integer of 13 to 28', and z represents an integer of 1 to 9. Relative to the diamine compound (A), the polyamine forming monomer (B), and the dicarboxylic acid compound ( The ratio of the diamine compound (A2) is 0.5 to 10 mass ° / 〇. The branched type saturated diamine having a carbon number of 6 to 22 is selected from 2, 2, 4 - 3 Methyl-1,6-amino-hexane, 2,4,4-trimethyl- 1,6-diaminohexanone, 1,2-diaminopropane, 1,3-diaminopentane Alkane, 2-methyl-1,5-diaminopentane, 2-mercapto-1,8-diaminooctane or mixtures thereof a branched amine alicyclic amine having a carbon number of 6 to 16 is selected from the group consisting of 5-amino-2,2,4-trimethyl- 1 1-cyclopentanylamine, 5-amino-1,3 , 3 - trimethylcyclohexanemethylamine or 14 200900466 a mixture of such diamines. The norbornane diamine is selected from 2,5~noranediamine, 2,6-norbornane Diamine or a diamine of such a mixture. 'M of the formula (2) is 1, and R1 represents an alkylene group having 1 to 2 carbon atoms. [Embodiment] (Best Mode for Carrying Out the Invention) A representative aspect of the resin composition of the invention is as follows. [First aspect] The resin composition according to the first aspect of the present invention contains a polyamine-based elastomer as an essential component, and the polyamine-based elastomer contains a polyether. 50% by mass or more of the phthalamide elastomer (X) obtained by polymerizing the components (a), (B), and (C); and including (a) as a coexisting component (A). The monoamine compound (A), which comprises the triblock polyether diamine compound (A1) represented by the formula (1), and a branched saturated diamine having a carbon number of 6 to 22, carbon number; 6 to 16 branched alicyclic diamine At least a quinone binary compound (A2) in a group consisting of norbornane diamine; (B): polyamine forming monomer (B); (C): dicarboxylic acid compound (C); (a) thermoplastic Resin. The team is a resin composition that is excellent in softness or ducking, and which is excellent in water resistance and excellent water resistance. The resin composition of the aspect is composed of a thermoplastic resin 95 > 50 quality «system of elastomer 5~5G quality! : % is preferable, more preferably 10% by mass of the thermoplastic resin and 10 to 40% by weight of the polyamine-based elastomer, and particularly preferably 15% by mass of the thermoplastic and 75% by mass of the polyamine-based elastomer. 30% by mass. However, the total of the 埶 plastic ^ polyamine-based elastomer was 100% by mass.曰/, 15 200900466 Explanation of Polyamide Amine Elastomer and Thermoplastic Resin Material] Item Description. (The composition of each component and the resin composition of this aspect is excellent in melt formability, excellent in impact resistance, excellent in impact resistance, hydrolysis resistance, and excellent in wire workability, and resin is obtained. The method of forming a product is not particularly limited and can be used. For example, 'applicable to' thermoplastics such as amines or various additives as needed, both quantitative, v-type 作, sex, J low-speed rotary mixer or Henschel ear turn high Lai Guan, Xiao (gH uniaxial extrusion Machine, double-axis extrusion machine #进魏融ϊϊiitSr: speed agent is both quantitative: injection molding machine or extrusion molding machine, direct === this kind of resin composition, can be used for heavy machinery ·Electric precision machine gears·Connectors 2, 丨u's surface materials, materials, various tubes, hoses, sheets, film materials, 4 cars, side, sealed joints, dust jackets, yiyi, '糸&amp Vehicle mirror dust jacket, etc. = fat composition 'the elongation at break after hydrolysis is a composition of the composition, and can be used for extrusion, injection molding, etc., to a tube, a filament, a sheet, A molded product such as a film. A known molding method, !Second aspect] The resin composition of the second aspect of the invention is in the form of the former scent, relative to the polyamine-based elastic ^^ ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

The day g is q Α 月 J J and the hydrolysis resistance 彳 can reach the entangled whirl, excellent recording, excellent resin composition containing plasticizer. This person's description of the [Description of each component and material] will be described later. 16 200900466 Excellent in excellent hydrolysis resistance. The resin composition containing a plasticizer, a molding method such as blow molding, and the like, and a molded article such as a tube or a film obtained by injection molding, extrusion molding, and a composition of the second aspect, and a film are obtained. The same various methods are known. /Unspecially, it is possible to use the resin composition containing the plasticizer in the first state, the gear of the material, the mechanical and electrical precision machine, the "sports shoe material, the surface seal material for the skis, various tubes, hoses, sheets, Thin t · Sealing material, automotive trim, constant velocity joint boot, covering material, etc. The enamel, the early fibril, the mirror dust cover for automobiles, and the resin composition containing the plasticizer are preferably 100% or more. The retention ratio of the elongation of the coating is 90%. [Third aspect] The resin composition of the third aspect of the present invention, the polyamine-based elastomer is used as the essential ether amide amine elastomer (x) 5 (% by mass) Taking a knife, the far-stranded amine-based elastomer contains poly(8), (the component of the oxime is polymerized, the phthalamide elastomer (1) is (A), and (b) is a coexisting component; (A): monoamine Compound (A) comprising 4 gates, a main compound (10), and a branched alicyclic diamine saturated diamine which is selected from a triblock polyether diamined carbon number 6 to 22 ja)f = Carbon number 6 to 16 compound (A2); at least one type of diamine in the group of females in January (B): polyamine forming monomer (〇: dicarboxylic acid compound (〇; ' (b ) The flame retardant. Yesterday, according to the third aspect of the woman's ability to achieve even the high temperature and high thirst, the seal + & + the moon is not due to hydrolysis degradation, can maintain as a composition of the lower tree. Description of the flame retardant resin with excellent performance of the body. Description of the polyamine elastomer and refractory agent] Item description. Chaos, this (4) 卩 'Yu New [components and materials 17 200900466 brother 3, the difficult sword 4 denier parts, 5 to 40 parts by mass, more "V-phase amine elastomer _ mass ~ 30 parts by mass. 0 to 35 A parts, and more preferably 15 to obtain the composition of the third aspect is also known. Various methods. The special ship system can be used to make the resin composition (4) and the state of the resin, without impeding its characteristics, such as an external absorbent, a light stabilizer, an antioxidant, and a heat-resistant agent, a purple crystal nucleating agent. Adhesive imparting agent, sealing agent, slip agent, material, dye, perfume, reinforcing material, etc. 蜊, release agent, and this resin composition, excellent melt formability, = quality, elongation recovery The resin composition can be obtained by injection molding and extrusion into a shape 幵ν method to obtain a molded product. The product is formed into a molded article of the resin composition, and a material having high toughness, elasticity, and low specific gravity. For example, it is preferably a wild ball, a soccer ball, a rebounding substrate, and other injection molded articles, such as a mechanical and electric precision machine = a shoe sealing material in the field, a car edging, a sealing material, etc. Gear • Connector · This resin composition can be used for sports shoes and bone sleigh; 2 , The gear connector sealing member, each of r sealing surfaces s

Si sleeves, sheets, films, monofilaments, mirror sleeves for automobiles, etc. Li [4th aspect] The formation of a material, which is based on the third aspect of the resin group machine armor, It also contains a thermoplastic resin. In other words, the resin composition of the fourth aspect of the present invention contains a polyamine-based elastomer as an essential component, and the polyamine-based elastomeric conjugated amine elastomer (X) is 5 mass% or more. Poly-_elastomer (1) is a compound obtained by polymerizing the components of (heart 18 200900466 (B), (C); and (a) and (b) as coexisting components; (A) :-guanamine compound ( A) comprising a polystyrene diamine compound (A1) represented by the formula (1), and a branched aliphatic diamine having a carbon number of 6 to 22, and a branched alicyclic diamine having a carbon number of 6 to 16. And at least a ruthenium compound (A2) in a group consisting of norbornanediamine; a bismuth-forming composition (B): a polyamine-forming monomer (β); (C): a dicarboxylic acid compound (〇; (a) (b) a flame retardant. According to the fourth secret, it is a flame retardant tree that can be used as an elastomer for the deterioration of the high temperature and high nail strength. The details of the thermoplastic resin and the flame retardant are described in the [Explanation of each component and material] item. The silly 100 ί 旦 于 于 聚 聚 里 里 里 里 里The ratio of the wound and the flame retardant is preferably from 5 to 40 parts by mass to 30 parts by mass, more preferably from 2 to 30 parts by mass. The soil is 0%, and the polyamine is preferably used, particularly preferably. Resin composition of resin composition Zhong Ba 95 ^ 50 f 5 ^ 5 树脂 resin 90 ~ 60% by volume with polyamine elastomer (more ^ two j plastic lion ~ 70 mass _ amine elastomer 15 ~ rouge The total amount of the polyamine-based elastomer is 100% by mass.), 里°(", 』, Sex tree external absorbent, light stability: not,:: 'Addition of heat-resistant agent, violet lubricant, slip agent性 ft electric agent, conductive filler, this contains difficult materials, flame retardant, reinforcing materials, etc. ^ 丨 娜 娜 娜 娜 娜 娜 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 In the resin composition containing the flame retardant, the resin composition containing the flame retardant is not limited by the tree-shaped group i1, and the same method as the first aspect can be used. The object can be obtained by a method of injection molding and extrusion molding. The plastic molding is a molded article of the resin composition, and can be applied to a tube. A component that requires flame retardancy, such as a component or an automobile component. The molded article of the resin composition, if it is in the middle of the body = deteriorates due to hydrolysis, can be applied to such a harsh ^=== official, Hose, wire covering, electrical component, automobile component, etc. The resin composition containing the flame retardant is used in the lower part, and more preferably 95% or more after hydrolysis. The clothing 1 is kept at 90%. [Fifth Aspect] The invention of the fifth aspect of the present invention is directed to the resin magnet, and the amine (tetra) is used as an essential component, and the polyether is read above, and the polyether_elastomer (1) A component obtained by polymerizing the components of (4): and (C); and (b) as a coexisting component; the r-amine compound (A) 'containing the three-bond polyether of the lower group (1) = compound U1), And a branched-type saturated diamine having a carbon number of 6 to 22, a branched alicyclic diamine having a carbon number of β of 16, and a lower diamine compound (A2); ): Polyamine forming monomer (B); (〇: dicarboxylic acid compound (〇; (b) magnetic powder. Here, in the poly-amine elastomer (1), at least a part of the binder resin for agglomerating the magnetic powder is present. According to the fifth aspect, it is possible to achieve a resin magnet which does not deteriorate in performance due to deterioration of the binder resin by hydrolysis in a severe environment, in particular, at a high temperature and a high temperature. 20 200900466, the resin is collected in a quantity of (10)f, the resin is about 50% by mass of the resin and 20% to 5f of the binder resin, preferably 15 to 5% by mass of the magnetic resin and the binder resin, more preferably Magnetic powder 9 〇, , : / ', 丄, ° tree month to 1 〇 ~ 5 mass% ratio. The remaining ίίΐϊϊί polyamine-based elastomer G~1GG mass% (excluding G mass%), denier resin, especially poly-polyamine 0~100% by mass (excluding 100% by mass) (1 amidoxime elasticity) The total of the body and the polyamine is 100% by mass). ο sticky, the resin is a composition of the poly-branched compound and the polyamine, and the composition of the bismuth body i~30% by mass and the _amine 95-70% by mass is preferably Λ, the substance tr, the amine system The amount of the elastomer ig~25 f% and the amount of the amine (10) to 75 f% of the constituents, the thermoplastic resin of the physical body and the structuring agent, especially fine, 1 [Description of each component and material] item description . Makeup (formation, the bonding resin and magnetic (10) can be simply or melted. The composition can be formed by (4) forming and extrusion forming method. The molded product can be used as a resin magnet. The resin magnet member is formed by combining with a metal member. For example, a resin magnet member is inserted and inserted into the resin magnet member, and after being immersed for 2,000 hours in the heat, the resin is not deteriorated by hydrolysis, and the resin magnet member is not produced. In order to be able to withstand long-term users, the disc-shaped metal member shown in Fig. 1 is inserted into a stone member, and the metal member is added to the metal member. b state] The resin composition of the hair-like state is related to the resin magnet, and the above-mentioned 5th sample contains a plasticizer, and particularly, in the above-mentioned viscosity j = , the proportion of the plasticizer is 5 to 20% by mass. Berry is in accordance with the sixth aspect, in the resin magnet member in which the metal member is inserted, 21 200900466 2.:: Even in the low temperature environment outside the winter house and in the summer, and/or the heat generated in the machine High temperature environment The repeated temperature change in the actual use environment, 'Ttt cracking two and even in the high temperature environment, the resin magnet with less dimensional change. The spot is formed under the harsh @°环^', especially under high temperature and high humidity. Resin magnet which is degraded by the hydrolysis of the sputum station... The composition of the magnetic powder and the binder resin in the resin composition of the tifu tii, the first product = the second fat, preferably contains the resin component, 80 quality denier 0 / = f can be plasticized 1 20 ~ 5 stomach amount%, more preferably contains resin components 80 ~ 10 amount |) °. . (4) 2〇~1〇% by mass (the total of the resin component and the plasticizer is (10) the resin component in the resin, including the poly(tetra) elastomer (10), the thermoplastic resin, especially the ~(10) shell b) (The total amount of amine-based elastomer and poly-_ is (10) The quality of the tree is composed of polyamine-based elastomers & $,) Polyamine-based broad green body 10~25% by mass and _amine 9G~ 7 Further, Μ (the combination of poly _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ It is said that the agent of polyamine can also be described in the following [Description of each component and material] in January. In addition, the plastic-derived or benzoic acid and the material of the four: 'especially' The compound may be a touch, or a compound of 2^==, the plasticizer 'containing a derivative derived from p- or benzoyl styrene. _above, more preferably r r--. 』] combination of 2 kinds The above alcohol having a side chain of 12 to 22 carbon atoms can be used, ioctyl octanol, 2 octyl ― 22 200900466 2 — decyldodecanol, 2- 3 - octanol, 2-ethyl 12 Alcohol, 2— Base dodecanol decyl sterol, 2-hexyl decyl alcohol, 2-ethyl decyl alcohol, etc. The plasticizer 'is biomimulated from the compound of p- or hydroxy phenyl sterol, for example, _ _ acid; Side chain hydroxybenzoic acid 2-octyl-3~xin, fluorenyl cis oxime, para or ortho-, or p- ortho-benzoic acid to formic acid 2-ethyldodecyl 12, or adjacent It can be used alone or in combination with two or more kinds of plastics, which can be used alone or in combination with 2-methyl benzoic acid (2-benzoic acid). ====, Polyamide-based Elastamine-based Elastomers The resin composition can be formed by a molding method such as injection molding or extrusion molding, and a molded product can be obtained by molding. This shaped product can be used as a tree member. This is a tree magnetized in the form of a metal magnet inserted into a metal member. The tree is partially reinforced by repeated cycles. The environment can be as shown in Figure 1. The disc-shaped metal member 1 is inserted into a metal member or the rod-shaped metal member 3 as shown in FIG. 2 is inserted into the I-shaped resin magnet member, etc. 23 200900466 The resin composition and the molded article of the present invention have a mass reduction rate of less than 0.4%, more preferably 0.4% or less. 2b or less. In the nylon resin composition and the molded article, the size is changed to 0.25% or less, more preferably 〇·2% or less, and particularly preferably Q. 15% or less. β is preferably [components and materials. Explanation] Each component and material will be described below. «Polyurethane-based elastomer" ♦ Amidoxime-based elastomer may contain a known polyamine elastomer. Elastomer. Polyamide can be used. The subtle segment is selected from Nylon 6, Nylon 66, Parallel u, with flat oxygen 4 ΐΐΓίΓ, and the spine ether block is selected from polyoxyethylene, polyoxypropylene, and elastic elastomers. The plasticity of the poly-block and the poly-segment is preferably 15 to 7q, more preferably 18, and more j is 20 to 70, and particularly preferably 25 to 7 Å. The elastic modulus of the body is preferably 2 〇 to the right side of the Pa, and more preferably 20 to 35 MPa, and particularly preferably 2 〇 to 3 MPa. It is preferred that the amine-based elastomer ' has an elongation at break of 嶋 or more. In the body fat, the elastomeric body containing the polyetheramide bomb is more preferably 80% or more, more preferably 90% by mass or more (1〇〇0/ surgery, and the content of the body (1) is large. Poly-based elastomer, excellent water resistance, excellent melting, extensibility, low temperature and softness, low temperature impact resistance, "Excellent properties, excellent sound-absorbing properties, rubber properties and transparency" Is the formation of the diamine compound (4) and the polyamine, whether it is a three-stage poly-diamine compound (10) represented by the formula (1), and a branching type of saturated salt of 2:6:22 from 2:6:22 At least one diamine compound (A2) in the group consisting of a monoamine, a branched alicyclic diamine and a norbornane diamine having a carbon number of 6 to 16. um3 Μ 1 - ch3 h2n- -chch2o- — -CH2CH2CH2CH2 - 〇 - 1 ch2cho- - y - J2 CH, wherein 'X represents an integer from 1 to 20, y represents an integer from 4 to 50, and Z represents an integer from 1 to 20. (1) - „The flexibility of the polyether amide of the present invention One of the particularly preferable aspects of the body (x) is a polyether phthalamide elastomer (X) 'based on the diamine compound (A) and the polyamine forming monomer (B) and the formula (2) - Carboxylation The compound (C) is polymerized to obtain: a diamine complex (A) comprising an XYX-type triblock polyether diamine (jl) represented by the formula (1) (Y is a polyoxybutylene), and is selected from carbon. a branching type saturated diamine of 6 to 22, a branched alicyclic diamine having a carbon number of 6 to 16, and at least a diamine compound (A2) of a decane diamine; a polyamine-forming monomer (B) is selected from the group consisting of the aminocarboxylic acid compound (B1) represented by the formula and the indoleamine compound (B2) represented by the formula (4).

In the polyether amide elastomer (χ) used in the present invention, the diamine compound (A), the indigo blue & c-forming monomer (B), and the dicarboxylic acid compound (c) are contained. The terminal carboxylic acid or carboxyl group and the terminal amine group are preferably in a ratio of approximately equimolar. In particular, in the case where one of the polyamine-forming monomers (β) is an amine group at the end and the other end is a carboxylic acid or a carboxyl group, the amine group of the diamine compound (Α) and the dicarboxylic acid compound ( The carboxyl group of C) is preferably in a ratio of approximately equimolar. In the diamine compound (Α), the χγχ type triblock polyether diamine compound (Α1) represented by the formula (1) can be used by two of poly(oxytetradecyl) diols and the like. A polyether diamine produced by reacting propylene oxide at the end to form polypropylene glycol and reacting ammonia or the like at the end of the polypropylene glycol. In the χγχ type triblock polyether diamine compound (A1), X and z are from 1 to 20, preferably from 1 to 18', more preferably from 1 to 16, more preferably from 丨 to 14, especially preferably 丨. 〜12, y is 4 25 200900466 ~ 50, preferably 5 to 45, more preferably 6 to 40, and even more preferably 7 to 35, especially preferably ~ 30 〇ΧΥΧ type diblock polyether diamine compound (Α1 In the case where \ and 2 are each smaller than the above range, among the characteristics of the obtained elastomer, especially the transparency is lowered, and y is smaller than the upper circumference: the rubber elasticity becomes low. Further, when x and z are larger than the above range, or when y is larger than the above range, the compatibility with the polyamide component becomes low, and sometimes the tough elastomer is obtained. Specific examples of the XYX-type diblock polyether diamine compound (A1) can be XTJ-533 manufactured by HUNTSMBN Co., Ltd. (in the formula (1), x is about 12, y is about u, z is about 11), and XTJ - 536 (in the formula (1), x is about 8.5, y is about i7, z is about 7. 5/, XTJ - 542 (in the formula (1), 'X is about 3, y is about 9, z is About 2), and χτ]-559 (in the formula (1), 'X is about 3, y is about 14, z is about 2), etc. Further, the XYX-type diterpenoid polyfluorinated diamine compound (Μ), Χγχ-1 can be used (in the formula (1), 'X is about 3, y is about 14, Z is about 2), χγχ-2 (in the formula (1), χ is about ic; about 2), and χγχ-3 (formula) In (1), χ is about 3, y is about 19, z is about 2), etc. Heart Λ ΥΧ 三 纽 ? 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 侧 总量Preferably, it is 11 Å to 78% by mass. In the case of the above range, the buckling fatigue property and the like are not sufficiently expressed as the properties of the elastomer, and sometimes it is used as a poly _ system. The elastomer is not good. χγχ type _2, the ratio of the compound (Α1) is larger than the above range, due to the polyamine content The scorpion bomb exhibits the excellent mechanical strength of polyamine, sometimes as a polyamine, and in the 9=monoamine compound (Α2), the branching type of carbon 6~22 and the diamine, _ mouth. 2, 2,4-Dimethyl-I 6-hexamethylenediamine, 2,4,4-trimethyl-11-6-hexane: 1,2,diaminopropanone, iota,3-diamine Kefen, 2-methyl-j 5__ j kekenol 2-mercapto-1,8-Second-small fresh. Scales can be used in combination with two or more kinds in appropriate proportions. 26 200900466 Diamine compounds ( In A2), the carbon number R~1C \丄如:5—Amino-(1)-trimethyl-Bujubs: The diamine of the formula II can be cis and trans. One, makeup"), etc. Again, these two secrets can be used alone, or a mixture of structures. Use X. Mix 2 or more kinds of diamine compounds (A2) in appropriate proportions,宿烧' : 2 2 == _ etc. These two

Mv ‘Too’s not doing anything, sometimes it’s not good. When the ratio of the diamine compound is larger than the above range, the crystallinity of the poly-forming monomer is lowered, and sufficient mechanical strength cannot be exhibited, and sometimes it is not preferable. Further, the 'diamine compound (4)' may contain other diamine compound (10) other than the triblock (tetra)$-amine compound (10). Oral material (9) and a further diamine compound (10), for example: ethylenediamine, trimethylenediamine, tetraammine: oxime, methylene-7-methylenediamine, octamethylenediamine, IX Sub-soil "female, ten-decyldiamine, deca-methylenediamine, dodecamethylenediamine, 2,24" trimethylhexamethylenediamine, 2, 4, 4- Aliphatic diamines such as trimethylhexylimidyldiamine, 3-carbazone, fluorenyldiamine, bis(4-aminocyclohexyl)methane, bis(4-aminocyclohexyl) Propylene, 13-diaminomercaptocyclohexene, hydrazine-diamine fluorenylcyclohexane; ka-aliphatic cyclic monoamine; m-diphenylene diamine, p-xylene diamine and other aromatic diamine Etc., the squamous diamine may be used alone, or two kinds of compounds may be used in combination. Next, in the polyamine-forming monomer (B), the aminocarboxylic acid compound (β1) and the indoleamine compound (B2) In the aminocarboxylic acid compound (B1), R2 is a molecular chain of a hydrocarbon having 2 to 20 carbon atoms, particularly 27, 200900466, preferably having an alkyl group having 2 to 20 carbon atoms, more preferably a carbon number of 3 ~ chain, especially with a carbon atom of 3 to 18 alkyl, more preferably The molecular sub-chain of the number δ is especially composed of a carbon atom of 4 to 15 and is preferably a charcoal. The molecular chain of the molecule has a carbon atom of 10 to 15 in particular. In the amine compound (Β2), R3 is a carbon number of 3 to 2 Å. A stretching group having a carbon atom of 3 to 20 is preferred, and more preferably a number of knives, especially a carbon atom of 3 to 18 The ship base, more preferably the Wei ^ sub-chain, especially has a carbon-based 4~15 base, especially a carbon number 1Q: f sub-chain, chain, especially preferably a carbon atom 10~15 alkyl group. Hydrocarbon molecular amine carboxylic acid compound (B1), for example: 6-aminohexanoic acid, 7 aminooctanoic acid, 10-amino decanoic acid, u-aminoundecanoic acid, fat of 5 to 20 Family ω - amino decanoic acid, etc. 7 ~ amino heptanoic acid, 8 amino octanoic acid ω - anaerosamine amine, 2 - π ratio slightly η makeup compound magic, for example: ε - caprolactam (enantholactam), omega-deca-indoleamine, ω-dodecanone, etc., aliphatic decylamine having a carbon number of 5 to 20, etc. η is formed by the polyamine relative to all components of the polyether amide amine elastomer (1) The ratio is preferably 10 to 95% by mass, more For 15~95皙1 Early body () 15~趴明吾〇/士,灶去^更住为b, and more preferably 85 贝夏/«, especially good for 15~8〇% by mass. Relative to poly The proportion of the ether 醯 分 'polyamine-forming monomer (8) is less than the above range, the crystallinity of the amine formation* is low, and the mechanical properties such as strength and modulus are low, which is relative to the poly-weidiamide elastomer (全部) All components, kinophilic formability is soft, and ii is large, because it is difficult to exhibit rubber elasticity or flexibility 4 as an elastomer's function and performance, it is sometimes poor. Dicarboxylic acid compounds (〇, ^ represents carbon The number of 丨 罚 罚 且 且 且 且 且 且 J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J Jiawei and Lidangshi 9 10 soil is the molecular chain of the hydrocarbons with the number 2~12, the chain U is the extension of Si, and the molecule of the hydrocarbon is 4~1〇. Extend the L base. m represents G or 1, preferably represents a compound (6), which may be derived from at least one dicarboxylic acid or a derivative thereof from an aliphatic, alicyclic or aromatic carboxylic acid. Specific examples of the monocarboxylic acid compound (C) include, for example, oxalic acid, arsine, pentane, hexamethylene, pimelic acid, suberic acid, azelaic acid, sebacic acid, and decanoic acid. a chain aliphatic diwei, or a dimerized aliphatic 4酉〇 having a carbon number of 14 to 48 and a hydride (hydrogenated dimer acid) by dimerizing the triglyceride g ) such as aliphatic dicarboxylic acid, i 4 bis (^ sulphuric acid and other alicyclic second ships, and terephthalic acid, isophthalic acid = diwei. dimer acid and hydrogenated dimer acid, can be used ", square = 1006", "Plyp〇1 1009", "Plypol 1〇13", etc. P1_ For the production method of the polyether amide elastomer (1) used in the present invention, a polyamine-forming monomer (8) can be used. , χγχ type three-new scales = material (8), diamine compound (Α2), and two ugly compounds (6), a total of 40% ^ two-sand combination 'as needed, and then under the reduced pressure to carry out the melt-polymerization step Alternatively, it is also possible to use the four components of the hetero-amine-shaped haplo-type di-diamine compound (A1), the diamine compound (A2), and the di-compound (C) simultaneously under pressure and/or Jingxian County under normal pressure It is necessary to carry out the step-by-step configuration method of the county polymerization under reduced pressure. The polyamine-forming monomer (8) and the second component of the dicarboxylic acid compound (6) are first polymerized to make the XYX-type second-stage poly-diamine (A1). Polymerization of polyether amide with diamine compound (10), addition method for the production of physique (1), addition of I, amine I forming monomer (B), χγχ type triblock poly-diamine The addition ratio of the compound (A1), the compound (A2), and the dicarboxylic acid compound (c) is preferably 丨〇95 to 95% by mass, particularly preferably 5 to 重量%, based on the entire portion of the polyamine-forming monomer (8). The range of %, the XYX type three-stage polydiamine compound (A1), preferably 2, more preferably 7 to 78% by mass, the diamine compound (A2), preferably ◦. 5~1〇 The mass % ' is particularly preferably 1 to 5 mass%. The χγχ type tri-nuclear polyamine diamine compound (A1) and the diamine compound (A2) and the dicarboxylic acid compound (c) are preferably administered so that χγχ type ^ The block poly-diamine compound (Α1) and the amine group of the diamine compound (10) and the bis-acid acid; the carboxyl group of the compound (C) becomes substantially equimolar. 29 200900466 Preferably, the polymerization temperature is preferably 150. ~ · c, more inferior, 靡 14 m ~ 25 (rc. Polymerization temperature is lower than the above temperature sometimes can not get good physical properties of the polymer. In the heat of the knife corner, D ° amine flexibility The body (1) can be produced by a method in which the ω-amino group is used as the amine (4) or the substance (8), and the method of performing the step of performing the vacuum polymerization is carried out, and then the _ is used as the poly In the case of the forming monomer (8), it can be produced by a method of entangled left melt polymerization and/or vacuum melt polymerization. The feed amine elastomer (x) can pass the polymerization time f Q 5 ♦ ♦ & time If it is shorter than the above range, then each of the circumferences will be produced by the secret decomposition of 'the right is longer than the above-mentioned fan-like physical properties, so that it can not be worn, the amine elastomer (1) can be manufactured, and the batch can also be connected. Shore = early, with or with a combination of batch reverse, single-tank or multi-thickness should be flat, official continuous reaction device. 'Lian,,, Beibei

The polyether amide elastomer (1) of Wn is relatively inferior in the range of relative viscosity 2 to .. Berry/various amount of decyl phenol solution, 25 ° C). . In the manufacture of the ether elastomer (1), if necessary, in order to stabilize the melt viscosity during the forming process, or to make a fine-densamine such as diamine or m-xylene diamine, the moon, the girl Base P-cabin eight-can find makeup in January, acetic acid, benzoic acid, stearic acid, 夂, 六, @夂, dodecanedioic acid and other monocarboxylic acids or two are preferably added, so that The most common line is the amount of ^ j money, ^ 3.5 (0.5 1.2 polyether amide elastomer (1) in the manufacture of the above-mentioned - amine and two and a few acid special addition amount, preferably set in the aunt The range of the characteristics of the imaginary B-small scorpion (X). In the manufacture of the poly-amine elastomeric polyamine elastomer (1), if necessary, phosphoric acid, _acid, 30 200900466 poly-acid, etc. may be added. For the catalyst, and in order to get the touch, the sub-tank acid, and the metal salt of the test, the genus ^ 5 〇 〇 〇 ^ 加 加 加 加 加 加 加 加 加 加 加 加 加 加 加 加 加 加 加 加Slip agent, crystallize, antistatic agent, sole <<thermoplastic resin> Branch, fragrance, flame retardant, reinforcing material, etc. Paste _ 'Aromatic and other modified substances, etc. _ The second forming temperature is preferably lower than the boot, preferably less than the boot, and IS:; broad polyamine as the fiber. Polyamide can be used. Used alone, polyamine polyvinyl chloride, and other thermoplastic trees. The modified polyolefins such as beryllium acetonitrile and acid-modified polyacrylonitrile have the acid _ bond (-_-) in the primary bond of lanthanum. It is possible to use a polymer obtained from at least one of the two components of the r-aromatic group, which is obtained by polymerization of at least one of the aliphatic and alicyclic groups or at least two components of the alicyclic group. Among the aliphatics, etc., the amines are preferred. In particular, the aliphatic polyamines are preferably obtained from the internal sense, the amino acid, or the histamine of the diamine and the dicarboxylic acid. The acid amine 'for example: ε - caprolactam, ω - heptane ruthenium such as: oxime mei 2 f, α - ° ratio side, α - 派 ° 酉 酉 equivalent, amine oxo acid 12-amine — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — 31 200900466 Ethylenediamine, Siam Diamine, pentamethylenediamine, hexamethylenediamine, octamethyldiamine, nonamethylenediamine, decamethylenediamine, eleven methylenediamine, tridecane Diamine, tetradecanediamine, fifteen, one makeup, ten, alkane-amine, heptadecanediamine, octadecanediamine, nonadecane dioctadecene diamine, 2-methyl-; [8-octylamine diamine, 2, 2, methyl diamine and other aliphatic diamines; - cyclohexyl diamine, 4 double if A) Γ (, 3 double (diamine hexyl) propane, double ( 3-Methyl-4-aminocyclohexane Γ —— - Aminocyclohexyl (4) End" I diaminomethyl hexamethylene, oxime-2, 2,4-trimethyl-b ring Ethyl pentaamine, 5-amino-1,3,3-dimethylcyclohexanemethylamine, bis(aminopropyl):-equal aryl alicyclic (tetra) dioxane: citric acid, fourteen Alkanedioic acid, pentadecanedioic acid, hexadecandioic acid, acid: one ^ ^; ^ ten = acid and other aliphatic ditolic acid; U / U - cyclohexyl dicarboxylic acid - dicarboxylic acid, hail An alicyclic dicarboxylic acid such as an alkanedicarboxylic acid; an acid such as an aromatic acid or an acid such as a diterpene acid or a h 4/1, 8/2, 6/2, 7-naphthalene or the like. These polyamines may be used singly or in combination of two or more kinds thereof to form a copolymerized polyamine. On nucleophilic 'for example, polyhexyl-(hetero-6), polyamino-deca-acid (diamine-resistant 4-methyl-January-based succinic acid (and Yulun-610), polyhexamethyleneamine妓 = polymer of alkane diacid (Nylon ~ 612), caprolactam / lauryl ^ 6 / 1 ^ Do not (Nylon - 6 / 12), hexene / silk ten - burnt acid copolymerization (Resistance - 己 醯 舰 舰 舰 舰 舰 / hexamethylene diamine adipic acid copolymer (resistant round ~ 6 / post), 6 / 66 / 〗 〖 hexamethylene diamine adipic acid /Aminododecanediic acid (Nylon-J, caprolactam / hexamethylenediaminediamine adipic acid / lauryl decylamine (Nylon 32 200900466 - 6/66/12), within Indoleamine/hexamethylenediaminediamine has been removed, and the base: alkanoic acid (valence 2) and other (co)polyamine resins can be used individually or in combination with 2's. Km 1 6' 66 ^ 610 ^ 12 and at least one aliphatic polyamine in nylon 612. Two «plasticizers" Taisu is a compound selected from esters and alkylamines. ··丁 π 本一甲驮一曱酉曰, o-benzed diacetate diethyl ester, o-benzoic acid, o-phthalic acid Λ Λ Γ: acid diisoindole 1, phthalate Acid di-trifluoroanthracene vinegar, butyl phthalate, butyl phthalate, phthalic acid, phthalic acid, ketone, phthalate, phthalate Alkyd butyl fatty acid tetrahydroortylene methyl hexanoic acid, etc. Diisobutyl adipate with / / ^ For example: adipic acid di ", adipic acid dibutyl hydrazine, r 曰, adipic acid di-positive 4-,: bis-diol vinegar, di-2-ethyl adipic acid. Acid di-n-halo-dimethoate-^ diisoindole S, adipic acid diisoindole vinegar, hexamethylene-ethyl Hex vinegar, ': acid-methyl ketone, dibutyl succinate, azelaic acid 222 succinic acid bis 2-ethyl hexyl vinegar, di-2-ethylhexyl mixed acid series, tanic acid double卩一 fAet f special binary saturated carboxylic acid ester; dibutyl fumarate, rich acid: ethyl vinegar vinegar; oleic acid butyl r;;; day, maleic acid double 2-ethylhexyl vinegar, etc. Unsaturated Sa-Dingsong A 7 曰 oil ^ isobutyl vinegar, ricinoleic acid butyl vinegar, vinyl lemon 酉 2 JS day and acetic acid 2-ethyl hexanate, etc. Single different ίί: Γ Purpose? Ίί体体甲" ' 4 4 -Dimethyl- 1,3 -pentanediol diisobutyrate, diethyl 33 200900466 diol diphenyl Acid, triethylene glycol di-2-ethylbutyrate, pentaerythritol monooleic acid vinegar, pentaerythritol monostearic acid g, pentaerythritol three;): vinegar, moringa oleic acid monoglyceride, 2-B Pyridyl triglyceride, triacetin, glyceryl tributyrate, etc. Specific examples of the metal sulphate S are, for example, trimethyl sulfonate, triethyl phosphate, tributyl phthalate, Tri-2-ethylhexyl phosphate, tributoxyethyl phosphate, triphenyl phosphate, n-octyl diphenyl phosphate, nonylphenol diphenyl phosphate, triterpene phosphate, tris-xyl phosphate And 2-ethylhexyl diphenyl phosphate and the like. Specific examples of trimellitates such as tributyl trimellitate, tri-2-ethylhexyl trimellitic acid, tri-n-octyl trimellitate, and triisophthalic acid triisophoric acid An oxime ester, a triisodecyl trimellitate and a tri-methanol ester of trimellitic acid. Specific examples of hydroxybenzoic acid esters, for example, o- or p-hydroxybenzoic acid ethyl hexanoic acid, or o- or e-benzoyl hexyl hydrazine, o- or phenylbenzoic acid ethyl hydrazine, hydrazine or P-hydroxy acyl octyl octyl octyl acrylate, o- or p-hydroxybenzoic acid decyl dodecyl ester, o- or p-hydroxybenzoic acid methyl ester, o- or p-hydroxybenzoic acid butyl ester, o- or p-hydroxybenzamide 1 Benzoyl phthalate n-octyl, o- or _-p-benzoate hydrazine and o- or p-decyl decanoate. class. 'T-toluene-based decylamine or stupid calcined base> Specific examples of the fluorene-based sulfonyl group and amines, for example, Ν-ethyl-o-butyl decylamine, hydrazine-ethyl pair Butyl decyl sulfonate, 2-ethylhexyl _, N-ethyl-p-toluene acid 2-ethyl = acid ϊ Γ 2 ΐ 体 , , , , , , , , , , , , , , , , , , Among the plasticizers such as hydrazine, it is preferred to use: dibutyl phthalate? Terephthalic acid esters such as di-2-ethylhexyl phthalate, ketones such as hydroxyphosphoric acid butylamine and benzoin-2-ethylhexyl decylamine, the "flammable agent" The lock flame retardant 'can be used> odor-based flame retardant and triterpenoid flame retardant. Desertification and flame retardant, 34 200900466 Z!·/Smell self-chemical phenoxy tree, filling polycarbonate, simmering double cage, knee ethylene, brominated polyphenylene ether and so on. For the deuterated polyethylene and polybrominated dimorphic flame retardant, melamine diocyanide or the like can be used. a stomach 4, " cyanuric acid, melamine, ~ 40 = ^; relative to the fine security of the fine elastomer (10), the mass of the sage, preferably 1 〇 ~ 3 〇 υ υ 里 里 , 5 Flame-retardant additives, can be used to contain bismuth:: chemical recording, pentoxide recording, osmium tetroxide, recording i scale. 5 matter 'e.g., trioxane', is. .W2 parts by mass of resin, 〇. Quality Brominated flame retardants are used together to improve flame retardancy. ,know. In the magnetic powder used in the present invention, a powder such as a ferrite-based magnetic material such as a barium ferrite or a lysate such as a boron-based rare earth magnetic material can be used. Lead bismuth, condensed-iron - The pulverized powder of the present invention is used after being surface-treated for the purpose of improvement and rectification of the decane coupling agent, titanate coupling agent, and stearic acid: 丄: '" Brake Aluminum Coupling Agent (Example) Embodiments, and Examples and Comparative Ships (4) The present invention is not limited to these characteristics and is measured in the following manner. 1) Relative viscosity (7/0 (0.5 mass/capacity% cresol solution, 25t:)) Between the test drug grade cresol as a solvent, at a concentration of 5g/dm3, using an Ostwald viscometer at 25° C. Measurement 2) Bending test (bending elastic modulus): A test piece having a test piece size of 6.35 mm x 12.1 mm x 27 mm was used, and measurement was carried out in accordance with astm D790. 35 200900466 3) Impact strength (with Iz〇d notch): A test piece of size 3·18 mm×12·7_Xl27 mm was measured at 23 ° C according to the leg D256. 4) Melt flow rate: The pellet was measured using a pellet at a temperature of 235 t: and a load of 2160 g. 5) Hydrolysis resistance (1): A sample cut out from a 1 viscera 3 〇〇 厚度 厚度 厚度 JIS 3 dumbbell formed by injection molding, and placed in a stainless steel without overlapping The container is filled with about 2 liters of distilled water, and after being capped, the tensile tester is used, and the distance between the chucks is 5 〇 _ clamping, and the tensile test is performed by the knife, the tooth, and the speed, and the tensile test is performed. Sheet [=' with the following formula (1), _ extension fracture 100 (1) tensile fracture retention (%) = hydrolysis treatment of the sample elongation of the tensile elongation of the specimen to treat the tensile elongation of the specimen 牟 6) Extensibility: Use ASTM No. 1 tablet, according to ASTM D638 7) Evaluation of flammability: Order test. A test piece of 0.8 mmxl2. 7 mmxl27 mm was used, and it was measured according to the 'resin composition containing the magnetic powder'. Example of the sixth aspect: Comparative Example) The physical properties of the resin magnets are as follows: 5 and 8) The measurement of the mass change rate of the resin magnet composition, and the resin magnet pellets are formed into a thickness by a compression molding machine. The size of 25 faces xl5Q_ was used as a test piece. The sheet is cut from the hot air circulation type strange temperature tank of ◦C, and then the amount of the test is reduced by 120. To the dish, the sputum quality 9) Determination of the dimensional change rate of the resin magnet composition 36 200900466 The resin magnet pellet is made into a compression molding machine, and the sheet is cut to a size of 25_150_, as a test 2, :: 2: The material is changed from the hot air of t to the "thermometer" for 14 days, and then the size of the direction of the 120 is changed. Nw 剞 to / dish, measuring length 10) the surface of the resin magnet composition paste (stick This sheet is made into a sheet of thickness 压缩 by a compression molding machine, from which the size of 25mnixl50mm is cut out, as a test piece 1 = t hot air circulation type strange temperature tank 14th 'by finger contact test ^ surface," and ^ ^ Π) resin magnet molding products due to temperature changes, the turtle will be shown in Figure 1, diameter 30_, thickness 30 coffee The cylindrical shape of the shellfish is a resin magnet with a diameter of 4Qmni, and a resin magnet i gold test piece is produced, and after 1000 cycles of 3 cycles, the job magnetic field is confirmed; δ part 妓; Occurrence (4). Heat 12) Evaluation of hydrolysis resistance of resin magnetite molded article. As shown in Fig. 1, a cylindrical shape of a metal having a diameter of 30 and a thickness of 30 is a resin magnet of the total amount of 40_, and a resin magnet is produced. The test piece with gold and δ was soaked in warm water of 80 ° C for 2 hours, and the test piece was confirmed to have cracks. Printing [Production Example 1: Production of PAE1] Agitator was attached , thermometer, torque meter, pressure gauge, nitrogen inlet, , in the 7G liter pressure vessel of the whole device and the polymer outlet, add Ube; production (Mountain) 12-aminododecanoic acid 10. 354kg, adipic acid 1. 581kg, XY) (type ^ three embedded Segment polyether diamine (XTJ-542 manufactured by HUNTSMAN Co., Ltd. (in the formula (1), x is about 3, y is about 9, z is about 2), amine price: 1.94 meq/g) 7.452 kg, isophorone Diamine (trade name: VESTAMIN Ιρ〇) manufactured by DegUssa Co., Ltd. 612 612 kg, sodium hypophosphite 1 hydrate 6 g, and heat-resistant agent (TOMINOX917 manufactured by Jifu Pharmaceutical Co., Ltd.) 60 g. After the inside of the vessel was sufficiently substituted with nitrogen, nitrogen gas was used as 186. The liter/hour supply is adjusted to 0. 05 MPa, and the temperature is raised from room temperature to 23 (rc^ 200900466, and the pressure in the container is adjusted to 〇5 MPa, on the side of 2 After hourly polymerization, the polymer was obtained. After the end of the polymerization, the disruption was stopped, and the colorless transparent polymer in a molten state was taken out from the polymer outlet in the form of a rope, and about 15 kg of the pellet was obtained by water cooling. The obtained pellet was colorless and translucent. Strong and rich in rubber elasticity: compound, 7? r = l. 96. Person [manufacturing example 2: manufacture of PAE2] Thermometer, twisting, pressure gauge, I gas inlet, pressure adjusting device and polymer take out 70 liters of pressure vessel towel of CT, adding 12-aminododecanoic acid system of Ube Hiroshi (share) 7. 557kg, two Acid 1· 691kg, XYX type triblock polyether diamine (XTJ-542 manufactured by HUNTSMAN Co., Ltd. (in the formula (1), x is about 3 is about 9, z is, about 2), and the amine price is 丄94meq/ g) 10,517 kg, isophora diamine (trade name: VESTAMIN IpD, manufactured by Degussa Co., Ltd.) 〇234 kg, sodium hypophosphite 1 hydrate, ρ and heat-resistant agent (TOMINOX917 manufactured by Jifu Pharmaceutical Co., Ltd.) 6 〇g. After the inside of the vessel was sufficiently substituted with nitrogen, the pressure in the vessel was adjusted to G, 〇 5 MPa, and the temperature was raised from room temperature to 230 X: while the nitrogen gas was supplied at 186 liters/hour. The pressure inside is adjusted to 〇〇5 MPa, and polymerization is carried out at 23 (rc for 4 hours, = to the polymer. After the end of the polymerization, the stirring is stopped, and the colorless transparent polymer in a molten state is taken out from the polymer outlet in a rope shape, after water cooling Granulation, about 15 kg of pellets were obtained. The pellet obtained was a colorless, translucent, tough, rubber-elastic polymer, β r = 1.96. [Manufacturing Example 3: Production of PAE3] , a thermometer, a torque meter, a pressure gauge, a nitrogen gas inlet, a pressure adjusting device, and a 7-liter liter pressure vessel for the polymer outlet, and added 12-aminodialic acid 〇 〇 37〇 from Ube Industries Co., Ltd. Kg, barium adipate · 585 kg, χγχ type triblock polyether diamine (XTJ-542 manufactured by HUNTSMAN Co., Ltd. (in the formula (1), X is about 3, 7 is about 9, 2 is about 2), amine Price: 1.9411^9/&) 7.4761^, 2,2,4—trimethyl-1,6-diaminohexane and 2, 4, 4 - Triterpene hydrazine, a mixture of 6-diamino hexane (manufactured by Degussa Co., Ltd., trade name: vestamin TMD) 0. 569 kg, sodium hypophosphite monohydrate 6 g and heat-resistant agent (T〇MIN manufactured by Jifu Pharmaceutical Co., Ltd.) 〇X917)6〇g. Container 38 200900466 仃, after the substitution, a biliary nitrogen gas is supplied at 186 liters / hour, the pressure of the - surface is adjusted to G. G5MPa, and it takes 3.5 hours to warm up from room temperature to 23 〇 The pressure in the vessel was adjusted to G·G5 MPa on the re-surface, and the polymer was applied to the polymer at 23 {rc for 4 hours. After the completion of the polymerization, the stirring was stopped, and the grafted red color was removed from the polymer outlet. The material is extracted, water-cooled, granulated, and the pellet is obtained. The obtained pellet is colorless, translucent and rubbery, and has a rubbery elasticity of 8.9 r = 1.98. m [manufacturing example 4: manufacture of PAE4] There are scrambler, thermometer, torque meter, pressure gauge, nitrogen inlet, pressure = adjustment, and the polymer is taken out of the pressure of 7G liters of π, adding Yubu Xingchan (share) 4 12 - amine base ten Diacid 1〇. 426kg, adipic acid 1. 582kg, χγχ type triblock polyether diamine (XTJ-542 made by HUNTSMAN) (in formula (1), χ It is about 3, y is about 9, Ζ is about 2), amine valence: 1.94 meq/g) 7. 436 kg, normane 1 amine (trade name: 井A, manufactured by Mitsui Chemicals Co., Ltd.) 0. 556 kg, sodium hypophosphite丄 Hydrate ^ and ^ heat agent (TOMINOX917 made by Jifu Pharmaceutical Co., Ltd.) 60g. After fully replacing the inside of the container with nitrogen, the nitrogen gas is supplied at 186 liters/hour, and the force in the container is adjusted to 0. 05 MPa. The temperature was raised from room temperature to 230 ° C for 5 hours, and the pressure in the vessel was adjusted to 0. 05 MPa, and polymerization was carried out at 23 (TC for 4.5 hours) to obtain a polymer. After the completion of the polymerization, the stirring was stopped, and the colorless transparent polymer in a molten state was taken out from the polymer outlet in a rope form, and granulated by water cooling to obtain pellets of about 15 kg. The pellets of 彳^到 are colorless, translucent, tough, rubber-filled polymer, [Production Example 5: Production of PAE5] with a scrambler, thermometer, torque meter, pressure gauge, nitrogen inlet, The pressure adjusting device and the 70 liter pressure vessel of the polymer outlet are added with a 12-aminododecanoic acid 7. 985 kg, adipic acid 1. U5 kg, χγχ type triblock polyether. Diamine (XTJ-559 manufactured by HUNTSMAN Co., Ltd. (in the formula (1), x is about 3 is about 14, z is about 2), amine price is 1.40 meq/g) l〇·900 kg, sodium hypophosphite} hydration 6 g and a heat-resistant agent (TOMINOX917 manufactured by Jifu Pharmaceutical Co., Ltd.) 60 g. After the inside of the container is fully replaced by the milk, the gas is supplied at 186 liters/hour, and the pressure in the crying 39 200900466 is reduced to 〇. 5 MPa, and the temperature is increased from room temperature to 5,000 rpm. 23〇. Then, the pressure in the vessel was adjusted to M5 MPa on the surface, and polymerization was carried out for 2 hours on 2 to obtain a polymer. After the completion of the polymerization, the lion is stopped, and the color transparent polymer of the smelting state is taken out from the polymer, and the water is cooled and granulated to obtain a pellet of about 15 丸 pfe, which is colorless, translucent and strong. Rubber-rich elastic polymer, 77r = [Manufacturing Example 6: Manufacturing of PAE6]

K Addition of dodecanoic acid (Ube Hiroshi Co., Ltd.) to a pressure vessel equipped with a mixer, a thermometer, a torsion, a pressure gauge, a nitrogen inlet for 5 weeks, and a polymer outlet. 12.897kg and adipic acid Q.嶋g (special grade). After the volume H was sufficiently nitrogen-substituted, the nitrogen gas was supplied at a flow rate of _ / hour while slowly heating. Stirring was carried out at a speed of 2 rpm. At the time of flowering, the temperature was raised to 24 Gt at room temperature: at 23 GX: polymerization was carried out for 4 hours to synthesize a nylon-derived oligomer. In this oligomer, polytetradecyl--monohydric alcohol is added (BASF Corporation,

PolyTHFlGGG) 6.197kg, tetrabutyl phthalate oxime. 02 (3⁄4 and antioxidant (including pharmaceutical manufacturer, trade name: TOMINOX917) 0. 050kg. After fully carrying out the container, nitrogen gas at a flow rate of 300 liters / When the supply is small, I slowly add I: and mix at a speed of 20 rpm. It takes 3 hours to raise the temperature from room temperature to 21 (rc, heating at 3 hours, then slowly depressurizing, taking 1 hour to become 5 〇Pa, and performing 2 polymerization. After that, it takes another 30 minutes to heat up, and the pressure is reduced. At 23 ° C, about 3 〇 pa Huai 8 , the hour polymerizes 'and ends. The second owes, stops the disturbance, and gives pressure to the polymerization layer. Returning to normal pressure. Secondly, the polymer in the molten state is taken out from the polymer outlet, and then granulated by water cooling to obtain about 9 grains of about 13 Å. Poly-p-amine, the pellet is white _ and the soft polymer, 7^=1.99. Field property [manufacturing example 7: manufacture of PAE7] with a mixer, thermometer, torque meter, pressure gauge, nitrogen The pressure adjusting device and the 70 liter pressure vessel of the polymer outlet are: ^ ^ 丄 B ~ amine 40 200900466 Dodecanoic acid (manufactured by Ube Industries Co., Ltd.) 9.456 kg and bismuth adipic acid. The emblem is graded. After the container is sufficiently substituted with nitrogen, the nitrogen gas is slowly heated while being supplied at a flow rate of 3 liters/liter. Stirring is carried out at a speed of 20 rpm. It takes 3 small you = g to heat up to 240 C, and is polymerized at 23 (TC for 4 hours, synthesizing oligosaccharide 12). In this polymer, polytetramethylene glycol (BASF) is added. 752kg, tetrabutyl acid _ 〇 · G2Qkg and antioxidant = kosher, trade name: TGMINGX917) (). _kg. Fully carry out the container in the field, a gas (10) speed 3 (30 liters / hour supply ' Slowly heating on one side: dialing and squeezing at 20 rpm. It takes 3 hours to raise the temperature from room temperature to 21 〇. 〇, heating at 2 = 3 hours, followed by slow decompression, taking i hours to make 5 coffees, 4 times, then It takes 30 minutes of material temperature to carry out the pressure reduction, and ends at 23 () t S, and ends with f. Secondly, the search is stopped, and the supply of the second layer of the polymer in the polymerization layer is returned to normal. Secondly, the outlet is taken from the polymer. There is no π in the fused state. ♦ The s objects are taken out in a rope shape, granulated after water cooling, and the granules of the granules are obtained. The phthalamide's pellet is a white silk and rubber-elastic soft polymer, 7^ = 2.04. Field 胗 elasticity [Example of the first aspect] [Examples A1 to A7, Comparative Examples A1 to A3] The mixture shown in the ratio is a double-axis kneading machine with a 40-gauge diameter. The 乍 乍 乍 H H 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 揉 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤 挤Feng Wei e 〇P, into the lamp pull, get the inner diameter of 6mm, the outer diameter of 8 coffee tube. 200900466 [Table 1] Composition (lean X) Composition: 匕Evaluation results 耐 醯 醯 系 弹 弹 弹 弹 弹 弹 Izod Melt flow rate hydrolysis treatment 12 species body elastic rate Impact rate rupture elongation retention (MPa) (J/m) (g/10min.) (3⁄4) Example A1 80 20 PAE-1 960 280 17 > 100 Example A2 70 30 "PAE-1 820 305 17 > 100 Example A3 80 20 PAE-2 890 350 17 > 100 Example A4 70 30 PAE-2 765 430 18 > 100 Example A5 80 20 PAE - 3 970 290 18 > 100 Example A6 80 20 PAE-4 950 270 16 > 100 - Example A7 80 20 PAE - 5 900 250 16 > 100 Comparative Example A1 100 0 ~ 1,450 60 17 > 100 ___- - Comparative Example A2 80 20 PAE-6 1000 285 18 75 ^ Comparative Example A3 1 - 80 20 - PAE-7 ' 920 360 18 40 -----1 [Example of the second aspect] [Examples B1 to B6, Comparative Examples B1 to B3]

A mixture of the ratios shown in Table 2 was used, and a biaxial pinch of a cylinder of 40 mm was used at 240. (: Melt kneading, extruding into a belt shape, cooling with a water tank, using pellets to make pellets. The pellets obtained are obtained by injection molding bending test and weighing test = test. The evaluation results of the film are shown in Table 1. Ube Hiroshi (share) system resistance theory 12 3020U ° 棬 ,, to control the size, plabor tube forming machine, formed into a tubular shape. Cooling and pulling, manufacturing inner diameter 6_, Deng 42 200900466 [Table 2] Composition (Quality phantom polyamide elastomer type composition evaluation results only * 12 Polyamide elastomer plasticizer plasticizer type Flexural modulus (MPa) Izod impact enthalpy (J/m) Elongation at break (%) after hydrolysis treatment Example B1 72 18 10 PAE-1 - 280 Unbroken > 100 Example B2 72 18 10 PAE -1 Ethylhexyl p-hydroxybenzoate 265 unbroken > 100 Example B3 72 18 10 PAE-2 Butyl decyl benzene sulfonate 255 Unbroken > 100 Example B4 72 18 10 PAE-3 Base amine 275 unbroken > 100 Example B5 72 18 10 ΡΛΕ-4 Benzene sulfonate butyl hydrazine 285 Unbroken > 100 Example B6 72 '18 10 PAE-5 phenyl sulfonamide 280 uncracked > 100 Comparative Example B1 90 0 10 - butyl decyl benzene sulfonate 420 210 > 100 Comparative Example B2 72 18 10 ΡΛΕ - 6 butyl decyl benzene sulfonate 300 unbroken 80 Comparative Example B3 72 18 10 PAE-7 Butyl decyl benzene sulfonate 260 Not broken 45 [Example of the third aspect] [Examples C1 to C7, Comparative Examples C1 to C3] The mixture of the ratios shown in Table 1 was melted and kneaded at 240 C using a biaxial kneading machine having a cylinder bore of 40 faces, and extruded into a belt shape, and then cooled by a water tank. Pellet is produced using a granulator. [Table 3] Polyurethane elastomer flame retardant, flame retardant, Baoqu elastic modulus (MPa) Izod impact enthalpy (J/m) Elongation at break (%) After flammability hydrolysis treatment Elongation at break elongation_丨n J· 1 - - (°/〇) __ 43 200900466 Example C1 PAE1 100 parts by weight of flame retardant A 20 parts by weight of antimony trioxide 8 parts by weight 190 NB > 300 V-0 96 Example C2 PAE1 100 parts by weight of flame retardant B 20 parts by weight of trioxide in 8 parts by weight of 205 NB > 300 V-0 95 Example C3 PAE1 100 parts by weight Flame Retardant C 20 parts by weight without 175 NB > 300 V-2 > 100 Example C4 PAE2 100 parts by weight of flame retardant A 20 parts by weight of antimony trioxide 8 parts by weight 120 NB > 300 V-0 93 Example C5 PAE3 100 parts by weight of flame retardant A 20 parts by weight triple emulsified 8 parts by weight 185 NB > 300 V-0 95 Example C6 PAE4 100 parts by weight of flame retardant A 20 parts by weight of oxidized 8 parts by weight 200 NB &gt 300 V-0 94 Example C7 PAE5 100 parts by weight of flame retardant A 20 parts by weight of trioxide 8 parts by weight 195 NB > 300 V-0 94 Comparative Example C1 PAE6 100 parts by weight of flame retardant A 20 parts by weight Oxidation record 8 parts by weight 195 NB > 300 V-0 3 Comparative Example C2 PAE6 100 parts by weight of flame retardant C 20 parts by weight without 170 NB > 300 V-2 5 Comparative Example C3 PAE7 100 parts by weight of flame retardant A 20 Parts by weight of antimony trioxide 8 parts by weight 115 NB > 300 • V-0 2 Flame retardant A: brominated phenoxy resin flame retardant (YPB - 43C manufactured by Tohto Kasei Co., Ltd.) Flame retardant B: brominated polycarbonate Flame Retardant (BC-58, manufactured by Great Lakes) Flame Retardant C: Trimeric amide isocyanate flame retardant [Example of the fourth aspect] 1 [Examples D1 to D7, Comparative Example D1~ D3 The mixture ratio shown in Table 4, the use of the cylinder diameter 40mm biaxial kneading machine, melt-kneaded at 240 ° C, extruded as a ribbon, cooled in a water tank, pellets were produced by using a pelletizer. [Table 4] Polyamide polyamine elastomer flame retardant flame retardant auxiliary bending elastic modulus (MPa) elongation at break retention after combustion hydrolysis treatment (%) Example D1 nylon 12 80 parts by weight PAE1 20 weight Incombustant A 20 parts by weight of antimony trioxide 8 parts by weight 980 V-0 98 44 200900466 Example D2 Financial 12 80 parts by weight PAE1 20 parts by weight of flame retardant B 20 parts by weight of antimony trioxide 8 parts by weight 1050 V- 0 97 Example D3 Nylon 12 80 parts by weight PAE1 20 parts by weight of flame retardant C 20 parts by weight without 950 V-2 > 100 Example D4 Resistance 12 80 parts by weight PAE2 20 parts by weight of flame retardant A 20 parts by weight Antimony trioxide 8 parts by weight 940 V-0 95 Example D5 Nylon 12 80 parts by weight PAE3 20 parts by weight of flame retardant A 20 parts by weight of antimony trioxide 8 parts by weight 960 V-0 97 Example D6 Financial 12 80 Weight Part of PAE4 20 parts by weight of flame retardant A 20 parts by weight of antimony trioxide 8 parts by weight 1000 V-0 96 Example D7 and only 12 80 parts by weight of PAE5 20 parts by weight of flame retardant A 20 parts by weight of P3 ruthenium 8 weight Parts 990 V-0 96 Comparative Example D1 Nylon 12 80 parts by weight PAE6 20 parts by weight of flame retardant A 20 parts by weight of antimony trioxide 8 Dosage 1000 V-0 4 Comparative Example D2 Nylon 12 80 parts by weight a PAE6 20 parts by weight of flame retardant C 20 parts by weight without 980 V-2 5 Comparative Example D3 Nylon 12 80 parts by weight PAE7 20 parts by weight of flame retardant A 20 parts by weight of antimony trioxide 8 parts by weight 940 V-0 3 flame retardant A: brominated phenoxy resin flame retardant (YPB - 43C manufactured by Tohto Kasei Co., Ltd.) Flame retardant B: desertification polycondensate is difficult to burn Agent (BC-58, manufactured by Great Lakes) Flame retardant C: Melamine cyanuric acid flame retardant (MC610 manufactured by Nissan Chemical Industries Co., Ltd.) [Example of the fifth aspect] [Examples E1 to E8, Comparative Examples E1 to E4 】 The melted kneading pellets f, which are shown in Table 5, are melted and kneaded by a mixer, and then mixed by a mixer, and then obtained by using a kneading machine. . Further, the obtained pellets were molded, and [Table 5] j was used as a magnet. 45 200900466 'One''-γ- Adhesive composition resin (% by mass) Evaluation result of composition No. 12 Polyamide type elastomeric polyamine-based elastomer type Baoqu elastic modulus (GPa) 8〇°C Trace cracking after hot water treatment Example El 0 100 PAE-1 2.3 Example E2 did not occur 0 100 PAE-2 2.1 Example E3 did not occur 0 100 PAE-3 2.0 Example E4 0 100 PAE-4 2.2 did not occur Example E5 did not occur. 80 PAE-1 12.5 Example E6 did not occur 80 20 1 PAE-2 10.9 Example E7 did not occur 0 100 PAE-5 2.1 Example E8 did not occur 80 20 PAE-5 10.8 Comparative Example E1 did not occur 100 0 — 18.5 Comparative Example E2 0 100 PAE-6 2.2 Comparative Example E3 — 0 100 PAE —7 2.0 Comparative Example E4 —1 1 80 20 PAE-6 12.9 Occurred

[Examples of the sixth aspect] [Examples F1 to F9, Reference Example pi, Comparative Examples F1 to F3] Nylon 12 (made by Ube Industries, Ltd. 3014U) and polyamine-based heat 1 °«!5 The evaluation of the pellets passed to the capsule is the result of the sigh, and can be used as shown in Table 6. Further, the obtained pellets were formed, and [Table 6] was used.

46 200900466 Quality % Mass % Mass % (%) (%) Example F1 81 PAE1 9 10 2-Hydroxybenzoic acid 2-ethyl oxime 0.21 0.12 No occurrence did not occur Example F2 81 PAE1 9 10 Hydroxybenzene 2-hexyl decyl formate 0. 05 0.07 No occurrence did not occur Example F3 81 PAE1 9 10 2-Hydroxybenzhydranoate 0.08 0.06 No occurrence did not occur Example F4 81 PAE1 9 10 Hydroxybenzene Formic acid 2-dodecyl twelve §1 0.07 0.07 No occurrence did not occur Example F5 81 PAE2 9 10 2-ethyl decyl p-hydroxybenzoate 0. 19 0. 10 No occurrence did not occur Example F6 81 PAE3 9 10 2-hydroxydecyl p-hydroxybenzoate 0.20 0, 11 None did not occur Example F7 81 PAE4 9 10 2-ethyldecyl p-hydroxybenzoate 0.22 0.12 No occurrence did not occur Example F8 81 PAE5 9 10 p-Hydroxybenzoic acid 2-ethyldecyl ester 0.21 0. 12 None did not occur Example F9 81 PAE1 9 10 n-Butylbenzenesulfonamide 1.02 0.33 No occurrence of reference Example F1 90 PAE1 10 — None - No occurrence has not occurred Comparative Example F1 81 PAE6 9 10 Pair 2-ethylhexyl benzoate 0.69 0.26 No occurrence occurred Comparative Example F2 90 — 0 10 2-octyloctyl p-hydroxybenzoate 0.06 0.08 No occurrence occurred _ Comparative Example F3 81 PAE7 9 10 2-ethyl decyl benzoate 0.20 0.08 No occurrence (industrial use) According to the first aspect of the present invention, a resin composition can be provided which does not affect the melt viscosity of the base thermoplastic resin and does not form The change in properties can improve the flexibility and impact resistance, and is excellent in chemical hydrolysis. Further, the resin composition is excellent in strong blade edge, melt moldability, low-temperature flexibility, and impact resistance, and is excellent in hydrolysis resistance. According to a second aspect of the present invention, a resin composition containing a plasticizer can be provided, which is excellent in sharp edge property, melt moldability, low temperature flexibility, and impact resistance, and is excellent in hydrolysis property" 47 200900466 The sample can provide a flame retardant resin composition, that is, you can maintain the excellent performance as an elastomer by reducing the resin in the environment under the harsh environment. Μ 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明 发明In the fifth aspect of the Japanese invention, a resin magnet member can be provided, and even if the magnetic property of the resin magnet is increased to increase the magnetic powder content, the molded article is less likely to be broken, which is soft and in a harsh environment, especially high temperature. Under high humidity, the binder resin is not deteriorated by hydrolysis, and cracking does not occur even under high temperature and high humidity. According to the sixth aspect of the present invention, it is possible to provide an excellent resin magnet member by using the resin composition of the present invention, even if the dimensional change in a high-temperature environment is small, and the metal member is inserted into the resin magnet member, even if In the actual use environment of the low temperature ring outside the winter house and the summer house and/or the high temperature environment caused by the heat generated in the machine, the dimensional change or crack does not occur after repeated temperature changes. Further, it is possible to provide a resin magnet member which does not cause deterioration of the binder resin due to hydrolysis even under high temperature and high humidity, and does not cause cracking even in the case of wetness in the south. [Simple description of the map]

Fig. 1 is a schematic view showing a resin magnet member in which a rod-shaped metal member is inserted and molded. Fig. 2 is a schematic view showing a resin magnet member in which a cylindrical metal member is inserted and formed. [Description of main component symbols] 1: Metal member 2: Resin magnet 3: Metal member 4: Resin magnet 48

Claims (1)

200900466 X. Patent application scope: 1. A resin composition characterized in that a polyamine-based elastomer is used as an essential component. The polyamine-based elastomer comprises a polyether phthalamide elastomer (X) of 50% by mass or more. The polyether phthalamide elastomer (X) is obtained by polymerizing components (a), (B), and (C), and contains at least one of (a) and (b) as a coexisting component; : a diamine compound (A) comprising a triblock polyether diamine compound (A1) represented by the following formula (1), and a branched type saturated diamine having a carbon number of 6 to 22, carbon number At least one diamine compound (A2) in a group consisting of 6 to 16 branched alicyclic diamines and norcapine diamine; (B): polyamine forming monomer (B); (C) : Dicarboxylic acid compound (C); (a) Thermoplastic resin; (b) Flame retardant or magnetic powder; ch3 Γ | 1 - - ch3 "11 ch3 I 3 -chch2o. X -ch2ch2ch2ch2-o y 1 -ch2cho- 1 ~ ch2ch - nh2 t 2 (1) (except that X represents an integer from 1 to 20, y represents an integer from 4 to 50, and z represents an integer from 1 to 20). 2. Resin as claimed in claim 1 Composition 'which contains 3. The thermoplastic resin according to claim 2, wherein the thermoplastic resin comprises polyamine. 4. The resin composition of claim 2 or 3, wherein 95% by mass of the thermoplastic resin and 5 to 50% by mass of the polyamine-based elastomer. The resin composition of the second or third aspect of the invention, wherein the polyamine-based elastomer is The thermoplastic resin is 100 parts by mass in total, and further contains 1 to 30 parts by mass of a plasticizer. 49 200900466 . The resin composition of claim i, wherein 9. For the patent composition, the resin composition of item 7 "8, the total amount of the amide amine elastomer and the thermoplastic resin" (10) mass ', scoop, 95 to 50% by mass of the resin, the polyamide The elastic body is 5 to 5 ◦ mass ^ 3 cough thermoplastic 10. The resin composition of the ninth aspect of the patent application, to a ratio of 1 to 5% by mass of the bonding resin, 5 to 2 〇 ^, And the poly-amine elastomer (1) has a powder as a binder resin, and the total of the magnetic powder and the binder resin is 1% by mass, and the powder and the binder resin are each 80 to 95% by mass. And 2〇~5 mass%^ ratio=reading property 11. The resin composition of the patent application range 帛10 can be 2% by mass. 12. The resin composition of the resin composition of the first or the seventh aspect of the patent application further comprises a polyamine. 13. As claimed in the claims s to 3, 6 to 8, 1 〇, u resin composition 'wherein the dicarboxylic acid compound (6) is represented by the following formula (2) ^ HOOC-(-R1^j-CO〇H (2) ( Wherein R1 represents a linking group containing a hydrocarbon chain, and 丨n represents hydrazine or hydrazine. 14. As claimed in the scope of claims 〖 to 3, 6 to 8, 1 50 (3) At least one of 200900466: H2N - R2 - COOH (only R2 represents the linking group of the hydrocarbon chain) (4) (R3 only indicates a linking group containing a hydrocarbon chain). The resin composition according to any one of claims 1 to 3, 6 to 8, 10, and 11, wherein the dicarboxylic acid compound (C) comprises an aliphatic dicarboxylic acid compound and an alicyclic group. At least one of the two oxic acid compounds. A molded article comprising the resin composition of any one of claims 1 to 15. A resin magnet member comprising a structure in which a resin composition according to any one of claims 10 to 12 is combined with a metal member. XI. Schema: 51