TW200720306A - Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins - Google Patents

Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins

Info

Publication number
TW200720306A
TW200720306A TW095128871A TW95128871A TW200720306A TW 200720306 A TW200720306 A TW 200720306A TW 095128871 A TW095128871 A TW 095128871A TW 95128871 A TW95128871 A TW 95128871A TW 200720306 A TW200720306 A TW 200720306A
Authority
TW
Taiwan
Prior art keywords
group
polymerization
substituted
fluorenyl
flu
Prior art date
Application number
TW095128871A
Other languages
English (en)
Chinese (zh)
Inventor
Vladimir Marin
Abbas Razavi
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology filed Critical Fina Technology
Publication of TW200720306A publication Critical patent/TW200720306A/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0263—Planar chiral ligands, e.g. derived from donor-substituted paracyclophanes and metallocenes or from substituted arenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
TW095128871A 2005-08-17 2006-08-07 Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins TW200720306A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/205,934 US7335711B2 (en) 2005-08-17 2005-08-17 Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins

Publications (1)

Publication Number Publication Date
TW200720306A true TW200720306A (en) 2007-06-01

Family

ID=37758333

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095128871A TW200720306A (en) 2005-08-17 2006-08-07 Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins

Country Status (6)

Country Link
US (4) US7335711B2 (enExample)
EP (1) EP1915401A4 (enExample)
JP (1) JP2009504888A (enExample)
KR (1) KR20080039424A (enExample)
TW (1) TW200720306A (enExample)
WO (1) WO2007022244A2 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006123759A1 (ja) * 2005-05-18 2006-11-23 Mitsui Chemicals, Inc. オレフィン重合用触媒、オレフィン重合体の製造方法、プロピレン系共重合体の製造方法、プロピレン重合体、プロピレン系重合体組成物およびこれらの用途
US7514509B2 (en) * 2005-12-16 2009-04-07 Fina Technology, Inc. Catalyst compositions and methods of forming isotactic polyproyplene
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
US7538167B2 (en) * 2006-10-23 2009-05-26 Fina Technology, Inc. Syndiotactic polypropylene and methods of preparing same
WO2008059974A1 (en) * 2006-11-17 2008-05-22 Mitsui Chemicals, Inc. Method for producing syndiotactic propylene polymer
US8293856B2 (en) 2008-08-19 2012-10-23 Mitsui Chemicals, Inc. Process for preparing olefin polymer using mixed catalyst
JP5178470B2 (ja) * 2008-11-19 2013-04-10 三井化学株式会社 フルオレン誘導体の製造方法
EP2204375A1 (en) * 2008-12-12 2010-07-07 Total Petrochemicals Research Feluy Preparation of mono-aryl-substituted methylene-bridged substituted cyclopentadienyl-fluorenyl ligands and zirconium complexes derived thereof
KR101362991B1 (ko) * 2010-05-28 2014-02-13 주식회사 엘지화학 메탈로센 촉매의 제조방법
SG11201404656RA (en) 2012-02-08 2014-09-26 Lubrizol Corp Method of preparing a sulfurized alkaline earth metal dodecylphenate
JP5972056B2 (ja) * 2012-06-06 2016-08-17 三井化学株式会社 オレフィン重合体の製造方法
KR101784463B1 (ko) * 2014-10-06 2017-10-11 주식회사 엘지화학 리간드 화합물, 메탈로센 화합물 및 이를 이용하는 올레핀계 중합체의 제조방법
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
WO2018182984A1 (en) * 2017-03-28 2018-10-04 Exxonmobil Chemical Patents Inc. Metallocene compounds
CN113906059B (zh) * 2019-04-12 2024-03-12 博里利斯股份公司 催化剂体系
CN110922286B (zh) * 2019-11-23 2022-08-16 上海化工研究院有限公司 一种非对称芳基取代富烯化合物及其制备方法与应用

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4767735A (en) * 1987-02-02 1988-08-30 Cosden Technology, Inc. Catalyst pretreatment process
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
JP2927881B2 (ja) * 1990-04-24 1999-07-28 三井化学株式会社 シンジオタクチックポリα―オレフィンの製造方法
JPH072935A (ja) * 1993-06-15 1995-01-06 Showa Denko Kk ポリオレフィン製造用触媒成分およびポリオレフィンの製造方法
US6313242B1 (en) * 1996-05-20 2001-11-06 Fina Technology, Inc. Stereorigid bis-fluorenyl metallocenes
JP3320619B2 (ja) * 1996-10-02 2002-09-03 三井化学株式会社 新規メタロセン化合物とそれを用いたオレフィンまたはジエンの重合方法
DE19719103A1 (de) * 1997-05-06 1998-11-12 Targor Gmbh Stereorigide Metallocenverbindung
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
CN101434668B (zh) * 1999-10-08 2012-02-22 三井化学株式会社 聚烯烃
EP1241188B1 (en) * 2000-09-13 2009-01-21 Japan Polychem Corporation Component of catalyst for olefin polymerization
JP4367686B2 (ja) * 2002-11-22 2009-11-18 三井化学株式会社 オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法
KR100785840B1 (ko) * 2002-09-27 2007-12-13 미쓰이 가가쿠 가부시키가이샤 가교 메탈로센 화합물, 올레핀 중합 촉매 및 올레핀의 중합방법
JP2005200453A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc α−オレフィン（共）重合体の製造方法
WO2005100410A1 (ja) * 2004-03-31 2005-10-27 Mitsui Chemicals, Inc. オレフィン重合体の製造方法
US7214749B2 (en) * 2004-07-09 2007-05-08 The Texas A&M University Systems Catalyst system for high activity and stereoselectivity in the homopolymerization and copolymerization of olefins
JP2006176760A (ja) * 2004-11-26 2006-07-06 Mitsui Chemicals Inc 合成潤滑油および潤滑油組成物
US7094938B1 (en) * 2005-05-20 2006-08-22 Fina Technology, Inc. Process for the preparation of substituted fluorenes
JP5105772B2 (ja) * 2005-07-25 2012-12-26 三井化学株式会社 シンジオタクティックα−オレフィン重合体の製造方法

Also Published As

Publication number Publication date
WO2007022244A3 (en) 2007-11-01
US20080026935A1 (en) 2008-01-31
KR20080039424A (ko) 2008-05-07
WO2007022244A2 (en) 2007-02-22
US7335711B2 (en) 2008-02-26
EP1915401A4 (en) 2012-03-21
US20130237719A1 (en) 2013-09-12
US8093418B2 (en) 2012-01-10
US20070043183A1 (en) 2007-02-22
EP1915401A2 (en) 2008-04-30
JP2009504888A (ja) 2009-02-05
US20120095175A1 (en) 2012-04-19

Similar Documents

Publication Publication Date Title
TW200720306A (en) Preparation and use of tetrasubstituted fluorenyl catalysts for polymerization of olefins
ATE386043T1 (de) Metallocene und von ihnen abgeleitete katalysatorzusammensetzungen
EP2261269A3 (en) Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
ATE400591T1 (de) Polymerisationsverfahren
DE60103702D1 (de) Organometallische verbindung die als cokatalysator bei der polymerisation von olefinen verwendbar ist
WO2004099269A3 (en) Process for polymerizing 1-butene
JP2006521436A5 (enExample)
DK0752428T3 (da) Metallocenkatalysator til (co)polymerisation af alfa-olefiner
CA2570874A1 (en) Acidic activator-supports and catalysts for olefin polymerization
KR910007971A (ko) 신디오택틱 중합체의 제조방법 및 이에 사용되는 촉매
ATE391735T1 (de) Mehrkerniger metallocenkatalysator
DE602004019647D1 (de) Bisindenyl-zirconium-komplexe zur olefinpolymerisation
KR970065549A (ko) 치환 인데닐 언브리지드 메탈로센
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
EP1512700A4 (en) polymerization catalyst
AU2003260432A1 (en) Process for the copolymerization of ethylene
DE60205368D1 (de) Aktivierung von "single site" polymerisationskatalysatoren durch (dialkylalumino)broronsäureester
EP1475383A4 (en) TRANSITION METAL COMPLEXES, LIGANDS, CATALYSTS FOR THE POLYMERIZATION OF OLEFINES, AND METHOD FOR THE PRODUCTION OF OLEFIN POLYMERS
JP2009504888A5 (enExample)
MXPA02005494A (es) Compuestos de metaloceno unidos con puente, proceso para su preparacion y su uso como catalizadores para la polimerizacion de olefinas.
ATE423797T1 (de) Katalysatorzusammensetzungen für die polymerisation und copolymerisation von alpha- olefinen
DE60211013D1 (de) Zweistufen-polymerisationsverfahren
EP1586589A4 (en) OLEFIN POLYMERIZATION CATALYSTS AND METHODS FOR PRODUCING OLEFIN POLYMER
WO2004060942A3 (en) Group iii bridged metallocene based on cyclopentadienyl-fluorenyl ligands
ATE319726T1 (de) Übergangsmetallverbindungen, deren herstellung und verwendung in katalysatorsystemen für die polymerisation und copolymerisation von olefinen