TW200503987A - Process for preparing isobutene from tert-butanol - Google Patents

Process for preparing isobutene from tert-butanol

Info

Publication number
TW200503987A
TW200503987A TW093116732A TW93116732A TW200503987A TW 200503987 A TW200503987 A TW 200503987A TW 093116732 A TW093116732 A TW 093116732A TW 93116732 A TW93116732 A TW 93116732A TW 200503987 A TW200503987 A TW 200503987A
Authority
TW
Taiwan
Prior art keywords
butanol
tert
isobutene
reactor
preparing isobutene
Prior art date
Application number
TW093116732A
Other languages
English (en)
Inventor
Andreas Beckmann
Wilfried Buschken
Gerda Grund
Dieter Reusch
Original Assignee
Oxeno Olefinchemie Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxeno Olefinchemie Gmbh filed Critical Oxeno Olefinchemie Gmbh
Publication of TW200503987A publication Critical patent/TW200503987A/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0005—Catalytic processes under superatmospheric pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/144—Purification; Separation; Use of additives using membranes, e.g. selective permeation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW093116732A 2003-06-17 2004-06-10 Process for preparing isobutene from tert-butanol TW200503987A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10327215A DE10327215A1 (de) 2003-06-17 2003-06-17 Verfahren zur Herstellung von Isobuten aus tert.-Butanol

Publications (1)

Publication Number Publication Date
TW200503987A true TW200503987A (en) 2005-02-01

Family

ID=33394844

Family Applications (1)

Application Number Title Priority Date Filing Date
TW093116732A TW200503987A (en) 2003-06-17 2004-06-10 Process for preparing isobutene from tert-butanol

Country Status (10)

Country Link
US (1) US7235704B2 (zh)
EP (1) EP1489062B1 (zh)
JP (1) JP4800584B2 (zh)
KR (1) KR101104106B1 (zh)
CN (1) CN1331829C (zh)
DE (1) DE10327215A1 (zh)
ES (1) ES2400558T3 (zh)
PL (1) PL1489062T3 (zh)
SG (1) SG153629A1 (zh)
TW (1) TW200503987A (zh)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10241762A1 (de) * 2002-09-10 2004-03-18 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von wasserfreiem tert.-Butanol
EP1431264B1 (de) * 2002-12-19 2010-01-20 Evonik Oxeno GmbH Verfahren zur Herstellung von tert.-Butanol
DE10260991A1 (de) * 2002-12-24 2004-07-08 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von tert.-Butanol mittels Reaktivrektifikation
RU2419595C2 (ru) * 2005-07-06 2011-05-27 Бп Кемикэлз Лимитед Реакционная ректификация для дегидратации смешанных спиртов
CN101381273B (zh) * 2007-09-06 2012-08-22 四川古杉油脂化学有限公司 一种用叔丁醇制备异丁烯的方法及装置
EP2070896A1 (en) 2007-12-12 2009-06-17 BP p.l.c. A process for the conversion of n-butanol to di-isobutene and propene
EP2105428A1 (en) 2007-12-12 2009-09-30 BP p.l.c. A process for the conversion of n-butanol to di-isobutene
EP2070894A1 (en) 2007-12-12 2009-06-17 BP p.l.c. A process for the conversion of n-butanol of n-butanol to di-isobutene and pentene
US8067655B2 (en) * 2008-05-29 2011-11-29 Lyondell Chemical Technology, L.P. Diisobutylene process
US8912373B2 (en) * 2009-07-29 2014-12-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
CN102020526B (zh) * 2009-09-09 2013-04-24 中国石油天然气股份有限公司 一种采用叔丁醇制备异丁烯的方法
KR101161845B1 (ko) * 2010-04-26 2012-07-03 송원산업 주식회사 알켄 화합물의 제조 방법
WO2013085964A2 (en) 2011-12-05 2013-06-13 Saudi Arabian Oil Company Hydrophilic membrane integrated olefin hydration process
DE102012105879A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isononylderivaten
DE102012105876A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Terephthalsäure und ihren Derivaten
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
DE102012105877A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Diisobuten
DE102012105874A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isononansäurevinylestern
CN103804116B (zh) * 2012-11-08 2016-03-30 中国石油化工股份有限公司 一种甲基叔丁基醚裂解制聚合级异丁烯的方法
EP3228384B1 (en) 2014-12-03 2020-07-01 China Petroleum & Chemical Corporation Catalyst and preparation method thereof, and method for preparing isobutylene by applying the same
KR20170035621A (ko) 2015-09-23 2017-03-31 롯데케미칼 주식회사 터트-부탄올로부터 이소부틸렌의 제조 방법
KR101880741B1 (ko) 2016-09-27 2018-07-20 롯데케미칼 주식회사 터트-부탄올로부터 이소부틸렌의 제조 방법
KR101899136B1 (ko) 2016-09-27 2018-09-14 롯데케미칼 주식회사 터트-부탄올로부터 이소부틸렌의 제조 방법
CN109776247A (zh) * 2018-03-30 2019-05-21 住友化学株式会社 异丁烯的制造方法及异丁烯的制造装置
CN109550520A (zh) * 2018-11-06 2019-04-02 丹东明珠特种树脂有限公司 叔丁醇脱水制备高纯度异丁烯用催化剂、其制备方法和其脱水应用
FR3102070B1 (fr) * 2019-10-17 2021-09-24 Commissariat Energie Atomique Réacteur échangeur à tubes et calandre permettant l’injection étagée d’un réactif
KR102325331B1 (ko) 2019-12-20 2021-11-10 한화토탈 주식회사 터트-부탄올로부터 이소부틸렌의 제조방법
CN111187137B (zh) * 2020-02-13 2024-02-09 浙江信汇新材料股份有限公司 一种tba制备聚合级异丁烯的工艺

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3665048A (en) 1970-01-14 1972-05-23 Atlantic Richfield Co Process to produce high purity isobutylene
DE2913796A1 (de) * 1978-04-10 1979-10-11 Nippon Oil Co Ltd Verfahren zum kontinuierlichen abtrennen und gewinnen von isobuten
US4208540A (en) 1978-12-22 1980-06-17 Nippon Oil Co., Ltd. Process for separation and recovery of isobutene
DE3151446A1 (de) * 1981-12-24 1983-07-14 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von hochreinem isobuten durch dehydratisierung von tertiaer-butanol
JPH0788318B2 (ja) * 1986-08-06 1995-09-27 三菱レイヨン株式会社 イソブチレンの製造法
EP0591504A1 (en) 1992-04-22 1994-04-13 BP Chemicals Limited Process for the production of olefins
DE4322712A1 (de) 1993-07-08 1995-01-12 Huels Chemische Werke Ag Verfahren zur Durchführung chemischer Reaktionen in Reaktionsdestillationskolonnen
FR2747120B1 (fr) * 1996-04-09 1998-05-15 Inst Francais Du Petrole Procede de production d'olefine(s) tertiaire(s) par decomposition de l'ether correspondant a l'aide d'un catalyseur particulier
DE19936675A1 (de) * 1999-08-04 2001-07-05 Borsig Energy Gmbh Verfahren zum Betreiben eines kontinuierlich arbeitenden Reaktors sowie nach diesem Verfahren arbeitender Reaktor
EP1431264B1 (de) 2002-12-19 2010-01-20 Evonik Oxeno GmbH Verfahren zur Herstellung von tert.-Butanol

Also Published As

Publication number Publication date
SG153629A1 (en) 2009-07-29
KR101104106B1 (ko) 2012-01-12
DE10327215A1 (de) 2005-01-13
US7235704B2 (en) 2007-06-26
US20050014985A1 (en) 2005-01-20
EP1489062B1 (de) 2012-12-19
ES2400558T3 (es) 2013-04-10
JP2005008618A (ja) 2005-01-13
EP1489062A1 (de) 2004-12-22
CN1609082A (zh) 2005-04-27
CN1331829C (zh) 2007-08-15
KR20040111120A (ko) 2004-12-31
JP4800584B2 (ja) 2011-10-26
PL1489062T3 (pl) 2013-05-31

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