TW200503987A - Process for preparing isobutene from tert-butanol - Google Patents
Process for preparing isobutene from tert-butanolInfo
- Publication number
- TW200503987A TW200503987A TW093116732A TW93116732A TW200503987A TW 200503987 A TW200503987 A TW 200503987A TW 093116732 A TW093116732 A TW 093116732A TW 93116732 A TW93116732 A TW 93116732A TW 200503987 A TW200503987 A TW 200503987A
- Authority
- TW
- Taiwan
- Prior art keywords
- butanol
- tert
- isobutene
- reactor
- preparing isobutene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
- C07C11/09—Isobutene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0005—Catalytic processes under superatmospheric pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/144—Purification; Separation; Use of additives using membranes, e.g. selective permeation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- C07C2531/08—Ion-exchange resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10327215A DE10327215A1 (de) | 2003-06-17 | 2003-06-17 | Verfahren zur Herstellung von Isobuten aus tert.-Butanol |
Publications (1)
Publication Number | Publication Date |
---|---|
TW200503987A true TW200503987A (en) | 2005-02-01 |
Family
ID=33394844
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW093116732A TW200503987A (en) | 2003-06-17 | 2004-06-10 | Process for preparing isobutene from tert-butanol |
Country Status (10)
Country | Link |
---|---|
US (1) | US7235704B2 (zh) |
EP (1) | EP1489062B1 (zh) |
JP (1) | JP4800584B2 (zh) |
KR (1) | KR101104106B1 (zh) |
CN (1) | CN1331829C (zh) |
DE (1) | DE10327215A1 (zh) |
ES (1) | ES2400558T3 (zh) |
PL (1) | PL1489062T3 (zh) |
SG (1) | SG153629A1 (zh) |
TW (1) | TW200503987A (zh) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10241762A1 (de) * | 2002-09-10 | 2004-03-18 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von wasserfreiem tert.-Butanol |
EP1431264B1 (de) * | 2002-12-19 | 2010-01-20 | Evonik Oxeno GmbH | Verfahren zur Herstellung von tert.-Butanol |
DE10260991A1 (de) * | 2002-12-24 | 2004-07-08 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von tert.-Butanol mittels Reaktivrektifikation |
RU2419595C2 (ru) * | 2005-07-06 | 2011-05-27 | Бп Кемикэлз Лимитед | Реакционная ректификация для дегидратации смешанных спиртов |
CN101381273B (zh) * | 2007-09-06 | 2012-08-22 | 四川古杉油脂化学有限公司 | 一种用叔丁醇制备异丁烯的方法及装置 |
EP2070896A1 (en) | 2007-12-12 | 2009-06-17 | BP p.l.c. | A process for the conversion of n-butanol to di-isobutene and propene |
EP2105428A1 (en) | 2007-12-12 | 2009-09-30 | BP p.l.c. | A process for the conversion of n-butanol to di-isobutene |
EP2070894A1 (en) | 2007-12-12 | 2009-06-17 | BP p.l.c. | A process for the conversion of n-butanol of n-butanol to di-isobutene and pentene |
US8067655B2 (en) * | 2008-05-29 | 2011-11-29 | Lyondell Chemical Technology, L.P. | Diisobutylene process |
US8912373B2 (en) * | 2009-07-29 | 2014-12-16 | The United States Of America As Represented By The Secretary Of The Navy | Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes |
CN102020526B (zh) * | 2009-09-09 | 2013-04-24 | 中国石油天然气股份有限公司 | 一种采用叔丁醇制备异丁烯的方法 |
KR101161845B1 (ko) * | 2010-04-26 | 2012-07-03 | 송원산업 주식회사 | 알켄 화합물의 제조 방법 |
WO2013085964A2 (en) | 2011-12-05 | 2013-06-13 | Saudi Arabian Oil Company | Hydrophilic membrane integrated olefin hydration process |
DE102012105879A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Isononylderivaten |
DE102012105876A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Terephthalsäure und ihren Derivaten |
DE102012105878A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Isopentanderivaten |
DE102012105877A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Diisobuten |
DE102012105874A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Isononansäurevinylestern |
CN103804116B (zh) * | 2012-11-08 | 2016-03-30 | 中国石油化工股份有限公司 | 一种甲基叔丁基醚裂解制聚合级异丁烯的方法 |
EP3228384B1 (en) | 2014-12-03 | 2020-07-01 | China Petroleum & Chemical Corporation | Catalyst and preparation method thereof, and method for preparing isobutylene by applying the same |
KR20170035621A (ko) | 2015-09-23 | 2017-03-31 | 롯데케미칼 주식회사 | 터트-부탄올로부터 이소부틸렌의 제조 방법 |
KR101880741B1 (ko) | 2016-09-27 | 2018-07-20 | 롯데케미칼 주식회사 | 터트-부탄올로부터 이소부틸렌의 제조 방법 |
KR101899136B1 (ko) | 2016-09-27 | 2018-09-14 | 롯데케미칼 주식회사 | 터트-부탄올로부터 이소부틸렌의 제조 방법 |
CN109776247A (zh) * | 2018-03-30 | 2019-05-21 | 住友化学株式会社 | 异丁烯的制造方法及异丁烯的制造装置 |
CN109550520A (zh) * | 2018-11-06 | 2019-04-02 | 丹东明珠特种树脂有限公司 | 叔丁醇脱水制备高纯度异丁烯用催化剂、其制备方法和其脱水应用 |
FR3102070B1 (fr) * | 2019-10-17 | 2021-09-24 | Commissariat Energie Atomique | Réacteur échangeur à tubes et calandre permettant l’injection étagée d’un réactif |
KR102325331B1 (ko) | 2019-12-20 | 2021-11-10 | 한화토탈 주식회사 | 터트-부탄올로부터 이소부틸렌의 제조방법 |
CN111187137B (zh) * | 2020-02-13 | 2024-02-09 | 浙江信汇新材料股份有限公司 | 一种tba制备聚合级异丁烯的工艺 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665048A (en) | 1970-01-14 | 1972-05-23 | Atlantic Richfield Co | Process to produce high purity isobutylene |
DE2913796A1 (de) * | 1978-04-10 | 1979-10-11 | Nippon Oil Co Ltd | Verfahren zum kontinuierlichen abtrennen und gewinnen von isobuten |
US4208540A (en) | 1978-12-22 | 1980-06-17 | Nippon Oil Co., Ltd. | Process for separation and recovery of isobutene |
DE3151446A1 (de) * | 1981-12-24 | 1983-07-14 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von hochreinem isobuten durch dehydratisierung von tertiaer-butanol |
JPH0788318B2 (ja) * | 1986-08-06 | 1995-09-27 | 三菱レイヨン株式会社 | イソブチレンの製造法 |
EP0591504A1 (en) | 1992-04-22 | 1994-04-13 | BP Chemicals Limited | Process for the production of olefins |
DE4322712A1 (de) | 1993-07-08 | 1995-01-12 | Huels Chemische Werke Ag | Verfahren zur Durchführung chemischer Reaktionen in Reaktionsdestillationskolonnen |
FR2747120B1 (fr) * | 1996-04-09 | 1998-05-15 | Inst Francais Du Petrole | Procede de production d'olefine(s) tertiaire(s) par decomposition de l'ether correspondant a l'aide d'un catalyseur particulier |
DE19936675A1 (de) * | 1999-08-04 | 2001-07-05 | Borsig Energy Gmbh | Verfahren zum Betreiben eines kontinuierlich arbeitenden Reaktors sowie nach diesem Verfahren arbeitender Reaktor |
EP1431264B1 (de) | 2002-12-19 | 2010-01-20 | Evonik Oxeno GmbH | Verfahren zur Herstellung von tert.-Butanol |
-
2003
- 2003-06-17 DE DE10327215A patent/DE10327215A1/de not_active Withdrawn
-
2004
- 2004-03-29 JP JP2004096756A patent/JP4800584B2/ja not_active Expired - Fee Related
- 2004-04-02 SG SG200401997-2A patent/SG153629A1/en unknown
- 2004-04-21 PL PL04101656T patent/PL1489062T3/pl unknown
- 2004-04-21 EP EP04101656A patent/EP1489062B1/de not_active Expired - Lifetime
- 2004-04-21 ES ES04101656T patent/ES2400558T3/es not_active Expired - Lifetime
- 2004-06-10 TW TW093116732A patent/TW200503987A/zh unknown
- 2004-06-16 CN CNB2004100495231A patent/CN1331829C/zh not_active Expired - Fee Related
- 2004-06-17 KR KR1020040045140A patent/KR101104106B1/ko not_active IP Right Cessation
- 2004-06-17 US US10/868,904 patent/US7235704B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
SG153629A1 (en) | 2009-07-29 |
KR101104106B1 (ko) | 2012-01-12 |
DE10327215A1 (de) | 2005-01-13 |
US7235704B2 (en) | 2007-06-26 |
US20050014985A1 (en) | 2005-01-20 |
EP1489062B1 (de) | 2012-12-19 |
ES2400558T3 (es) | 2013-04-10 |
JP2005008618A (ja) | 2005-01-13 |
EP1489062A1 (de) | 2004-12-22 |
CN1609082A (zh) | 2005-04-27 |
CN1331829C (zh) | 2007-08-15 |
KR20040111120A (ko) | 2004-12-31 |
JP4800584B2 (ja) | 2011-10-26 |
PL1489062T3 (pl) | 2013-05-31 |
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