SU906990A1 - @ ,W-бис-[W-(хлорметилфенил)алкилОВЫЕ ЭФИРЫ @ , @ -АЗО-БИС-ИЗОМАСЛЯНОЙ КИСЛОТЫ В КАЧЕСТВЕ ИНИЦИАТОРОВ РАДИКАЛЬНОЙ ПОЛИМЕРИЗАЦИИ ЭТИЛЕННЕНАСЫЩЕННЫХ СОЕДИНЕНИЙ И КАК ПРОМЕЖУТОЧНЫЕ ПРОДУКТЫ ДЛЯ ПОЛУЧЕНИЯ РЕАКЦИОННОСПОСОБНЫХ ПОЛИМЕРОВ - Google Patents
@ ,W-бис-[W-(хлорметилфенил)алкилОВЫЕ ЭФИРЫ @ , @ -АЗО-БИС-ИЗОМАСЛЯНОЙ КИСЛОТЫ В КАЧЕСТВЕ ИНИЦИАТОРОВ РАДИКАЛЬНОЙ ПОЛИМЕРИЗАЦИИ ЭТИЛЕННЕНАСЫЩЕННЫХ СОЕДИНЕНИЙ И КАК ПРОМЕЖУТОЧНЫЕ ПРОДУКТЫ ДЛЯ ПОЛУЧЕНИЯ РЕАКЦИОННОСПОСОБНЫХ ПОЛИМЕРОВ Download PDFInfo
- Publication number
- SU906990A1 SU906990A1 SU782682430A SU2682430A SU906990A1 SU 906990 A1 SU906990 A1 SU 906990A1 SU 782682430 A SU782682430 A SU 782682430A SU 2682430 A SU2682430 A SU 2682430A SU 906990 A1 SU906990 A1 SU 906990A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- bis
- omega
- chloromethylphenyl
- azo
- initiators
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title claims description 13
- 239000003999 initiator Substances 0.000 title claims description 6
- 238000010526 radical polymerization reaction Methods 0.000 title claims description 4
- 229920013730 reactive polymer Polymers 0.000 title claims description 4
- VBZBISQOWJYWCC-UHFFFAOYSA-N 2-(2-carboxypropan-2-yldiazenyl)-2-methylpropanoic acid Chemical compound OC(=O)C(C)(C)N=NC(C)(C)C(O)=O VBZBISQOWJYWCC-UHFFFAOYSA-N 0.000 title description 2
- 239000013067 intermediate product Substances 0.000 title description 2
- 125000005907 alkyl ester group Chemical group 0.000 title 1
- -1 chloromethylphenyl Chemical group 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 3
- 239000000543 intermediate Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 24
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000921 elemental analysis Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 125000004965 chloroalkyl group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 1
- SSIMHHUMYMHNID-UHFFFAOYSA-N 4-(chloromethyl)phenol Chemical compound OC1=CC=C(CCl)C=C1 SSIMHHUMYMHNID-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782682430A SU906990A1 (ru) | 1978-11-09 | 1978-11-09 | @ ,W-бис-[W-(хлорметилфенил)алкилОВЫЕ ЭФИРЫ @ , @ -АЗО-БИС-ИЗОМАСЛЯНОЙ КИСЛОТЫ В КАЧЕСТВЕ ИНИЦИАТОРОВ РАДИКАЛЬНОЙ ПОЛИМЕРИЗАЦИИ ЭТИЛЕННЕНАСЫЩЕННЫХ СОЕДИНЕНИЙ И КАК ПРОМЕЖУТОЧНЫЕ ПРОДУКТЫ ДЛЯ ПОЛУЧЕНИЯ РЕАКЦИОННОСПОСОБНЫХ ПОЛИМЕРОВ |
| FR7927564A FR2440942A1 (fr) | 1978-11-09 | 1979-11-08 | Derives des ethers a,o-bis-alkyliques de l'acide a,a'-azo-bis-isobutyrique et procede de preparation et application desdits derives |
| DE19792945151 DE2945151C2 (de) | 1978-11-09 | 1979-11-08 | α, ω -Bis-alkylesterderivate der α, α '-Azo-bis-isobuttersäure und Verfahren zu ihrer Herstellung |
| NL7908160A NL7908160A (nl) | 1978-11-09 | 1979-11-08 | Werkwijze voor het bereiden van alfa,omega- -bisalkylesterderivaten van alfa,alfa'-azobis- isoboterzuur. |
| JP14456879A JPS5581847A (en) | 1978-11-09 | 1979-11-09 | Alpha*omegaabissalkylester derivative of alpha*alpha**azoobissisobutyric acid and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782682430A SU906990A1 (ru) | 1978-11-09 | 1978-11-09 | @ ,W-бис-[W-(хлорметилфенил)алкилОВЫЕ ЭФИРЫ @ , @ -АЗО-БИС-ИЗОМАСЛЯНОЙ КИСЛОТЫ В КАЧЕСТВЕ ИНИЦИАТОРОВ РАДИКАЛЬНОЙ ПОЛИМЕРИЗАЦИИ ЭТИЛЕННЕНАСЫЩЕННЫХ СОЕДИНЕНИЙ И КАК ПРОМЕЖУТОЧНЫЕ ПРОДУКТЫ ДЛЯ ПОЛУЧЕНИЯ РЕАКЦИОННОСПОСОБНЫХ ПОЛИМЕРОВ |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU906990A1 true SU906990A1 (ru) | 1982-02-23 |
Family
ID=20792734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU782682430A SU906990A1 (ru) | 1978-11-09 | 1978-11-09 | @ ,W-бис-[W-(хлорметилфенил)алкилОВЫЕ ЭФИРЫ @ , @ -АЗО-БИС-ИЗОМАСЛЯНОЙ КИСЛОТЫ В КАЧЕСТВЕ ИНИЦИАТОРОВ РАДИКАЛЬНОЙ ПОЛИМЕРИЗАЦИИ ЭТИЛЕННЕНАСЫЩЕННЫХ СОЕДИНЕНИЙ И КАК ПРОМЕЖУТОЧНЫЕ ПРОДУКТЫ ДЛЯ ПОЛУЧЕНИЯ РЕАКЦИОННОСПОСОБНЫХ ПОЛИМЕРОВ |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS5581847A (enrdf_load_stackoverflow) |
| SU (1) | SU906990A1 (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61160997U (enrdf_load_stackoverflow) * | 1985-03-26 | 1986-10-06 |
-
1978
- 1978-11-09 SU SU782682430A patent/SU906990A1/ru active
-
1979
- 1979-11-09 JP JP14456879A patent/JPS5581847A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5581847A (en) | 1980-06-20 |
| JPS5719099B2 (enrdf_load_stackoverflow) | 1982-04-20 |
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