SU212693A1 - METHOD OF ELECTRIC SEDIMENTATION OF GOLD ALLOYS WITH METALS OF THE IRON GROUP - Google Patents
METHOD OF ELECTRIC SEDIMENTATION OF GOLD ALLOYS WITH METALS OF THE IRON GROUPInfo
- Publication number
- SU212693A1 SU212693A1 SU1126463A SU1126463A SU212693A1 SU 212693 A1 SU212693 A1 SU 212693A1 SU 1126463 A SU1126463 A SU 1126463A SU 1126463 A SU1126463 A SU 1126463A SU 212693 A1 SU212693 A1 SU 212693A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- metals
- iron group
- gold alloys
- iron
- gold
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title description 19
- 239000002184 metal Substances 0.000 title description 7
- 229910052751 metal Inorganic materials 0.000 title description 7
- 229910001020 Au alloy Inorganic materials 0.000 title description 3
- 150000002739 metals Chemical class 0.000 title description 3
- 239000003353 gold alloy Substances 0.000 title description 2
- 238000004062 sedimentation Methods 0.000 title 1
- 229910052742 iron Inorganic materials 0.000 description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 4
- 238000004070 electrodeposition Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- -1 cyanide compound Chemical class 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010953 base metal Substances 0.000 description 1
Description
Известен способ электроосаждени сплавов золота с металлами группы железа из цианистых растворов.The known method of electrodeposition of alloys of gold with metals of the iron group from cyanide solutions.
Дл улучшени качества покрыти предложено процесс электроосаждени вести при температуре 50°С, плотности тока 0,5-1 а1дм и рН 7 из электролита следующего состава, г/л:To improve the quality of the coating, an electrodeposition process has been proposed to be carried out at a temperature of 50 ° C, a current density of 0.5-1 a1 dm and a pH of 7 from an electrolyte of the following composition, g / l:
золото (в пересчете на металл)0,03-3gold (in terms of metal) 0.03-3
в виде цианистого соединени in the form of a cyanide compound
железо (в пересчете на металл)1-3iron (in terms of metal) 1-3
в виде виннокислого комплексаin the form of tart-acid complex
сегнетова соль150segnetov salt150
борна кислота20-30boric acid 20-30
Состав получаемого сплава регулируют изменением соотношени концентраций золота и железа в растворе и плотностью тока.The composition of the resulting alloy is controlled by changing the ratio of the concentrations of gold and iron in the solution and the current density.
Так, например, при содержании золота 2,6 и железа 1,0 г/л осаждают сплав с содержанием ЗО/о железа, а при содержании золота 0,3 г/л и железа 3 г/л содержание железа в сплаве возрастает до Эбо/оПредлагаемый способ позвол ет получать сплав с высокими физико-химическими свойствами и прочным сцеплением с основным металлом издели .For example, when the gold content is 2.6 and iron is 1.0 g / l, the alloy is precipitated with an iron / iron content of 3/3, and when the gold content is 0.3 g / l and iron is 3 g / l, the iron content in the alloy increases to The proposed method allows to obtain an alloy with high physicochemical properties and strong adhesion to the base metal of the product.
Предмет изобретени Subject invention
Способ электроосаждени сплавов золота с металлами группы железа из цианистых растворов , отличающийс тем, что, с целью улучшени качества покрыти , процесс ведут при температуре 50°С, плотности тока 0,5-1 а/с1м и рН 7 из электролита следующего состава, г/л:The method of electrodeposition of gold alloys with metals of the iron group from cyanide solutions, characterized in that, in order to improve the quality of the coating, the process is carried out at a temperature of 50 ° C, a current density of 0.5-1 A / cm and pH 7 of the electrolyte of the following composition, g / l:
золото (в пересчете на металл)0,03-3gold (in terms of metal) 0.03-3
в виде цианистого соединени in the form of a cyanide compound
железо (в пересчете на металл)1-3iron (in terms of metal) 1-3
в виде виннокислого комплексаin the form of tart-acid complex
сегнетова соль150segnetov salt150
борна кислота20-30boric acid 20-30
Publications (1)
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SU212693A1 true SU212693A1 (en) |
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