SU1342425A3 - Гидравлическа жидкость - Google Patents

Гидравлическа жидкость Download PDF

Info

Publication number
SU1342425A3
SU1342425A3 SU843715903A SU3715903A SU1342425A3 SU 1342425 A3 SU1342425 A3 SU 1342425A3 SU 843715903 A SU843715903 A SU 843715903A SU 3715903 A SU3715903 A SU 3715903A SU 1342425 A3 SU1342425 A3 SU 1342425A3
Authority
SU
USSR - Soviet Union
Prior art keywords
pyrrolidone
benzotriazole
methyl
epoxy compound
liquid
Prior art date
Application number
SU843715903A
Other languages
English (en)
Inventor
Фрэнсис Анзербергер Джозеф (Старший)
Original Assignee
Стауффер Кемикал Компани (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Стауффер Кемикал Компани (Фирма) filed Critical Стауффер Кемикал Компани (Фирма)
Application granted granted Critical
Publication of SU1342425A3 publication Critical patent/SU1342425A3/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/74—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16—Ethers
    • C10M129/18—Epoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/66—Epoxidised acids or esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38—Heterocyclic nitrogen compounds
    • C10M133/44—Five-membered ring containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/042—Epoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/003—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/023—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/0405—Phosphate esters used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049—Phosphite
    • C10M2223/0495—Phosphite used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/0603—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/08—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-nitrogen bonds
    • C10M2223/083—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-nitrogen bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/10—Phosphatides, e.g. lecithin, cephalin
    • C10M2223/103—Phosphatides, e.g. lecithin, cephalin used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/02—Esters of silicic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

Изобретение относитс  к составам гидравлической жидкости на основе сложных эфиров фосфорной кислоты. Цель изобретени  - повышение кислото- устойчивости жидкости. Гидравлическа  жидкость согласно изобретению содер- жит в качестве основы алкилариловьш эфир фосфорной кислоты и 0,.08- 0,14 мас,% присадки, представл юш;ей собой смесь эпоксисоединени  (ЭС),И- метш1-2-пирролидона (МП) и бензотриа - зола (БТА). В качестве эпоксисоединени  используют моноокись лимонена или 3,4-эпоксициклоалкш1-3,4-эпокси- циклоалкилкарбоксилат. Массовое соотношение М11:ЭС составл ет 1:1,2-6 или 1,3:1, МП:БТА - 1:1-2 или 1,9-4:1 и ЭС:БТА-2,5:1 или 3:1. При использовании жидкости согласно изобретению кислотное число в 6-10 раз ниже по сравнению с известной жидкостью и нарастание кислотности происходит более полого, 1 ил., 2 табл. СО :о 4 N3 iU tsO сл см

Description

1
Изобретение относитс  к составам гидравлической жидкости на основе сложных эфирен фосфорной кислоты, которые наход т применение в тех слу ча х, когда требуетс  огнестойкость и высокотемпературна  стабильность.
Целью изобретени   вл етс  повы- шение кислотоустойчивости жидкости.
Предлагаема  гидравлическа  жидкость состоит из основного компонента - алкиларилового сложного эфира фосфорной кислоты, смешанного с 0,09-0,15 мас.% кислотостойкой присадки , содержащей (1) Н-алкил-2-пир- ролидон, (2) эпоксисоединение и (3) бензотриазол.
В качестве эпоксидного соединени  используют моноокись лимонена, 3,4- зпоксициклоалкил-3,4-эпоксициклоал- килкарбоксилат. Особенно предпочтительным эпоксидным соединением  вл етс  моноокись лимонена, поскольку она не склонна к образованию осадков и высоко совместима с основным компонентом - алкилариловым сложным эфиром фосфорной кислоты.
Примерами подход щих сложных эфи- ров фосфорной кислоты  вл ютс : бу- тилфенилфосфаты, крезилфенилфосфаты, 2-этилгексилфенилфосфаты, октилфенил фосфаты, изодецилфенилфосфаты, кре- зилфосфаты, ксилилфосфаты, ксилилфе- нилфосфаты, ксилилкрезилфосфаты, изо пропилфенилфенилфосфаты, втор-бутил- фенилфенилфосфаты, трет-бутилфенил- фенилфосфаты и их смеси. Особенно предпочтительны из соображений термостабильности и однородности основные компоненты, содержащие смеси моно- трет-бутилфенилдифенилфосфата и ди- трет-бутилфенилфенилфосфата.
Жидкость готов т путем диспергировани  трехкомпонентной присадки
, 10
0,05
424252
в основе - алкилариловом эфире фосфорной кислоты с получением однородной смеси. Смешивание может.быть осуществлено без труда, поскольку композици  полностью растворима в эфире фосфорной кислоты при концентраци х не более 1 мас.% в расчете на гидравлическую жидкость. Жидкость
Q стабильна при хранении, но должна содержатьс  в герметичных емкост х, чтобы избежать загр знени  водой и воздействи  воздуха.
Пример. Данный пример иллюст15 рирует изменение свойств гидравлических жидкостей на основе алкилари- ловых эфиров фосфорной кислоты, содержащих различные типы и количества присадок.
2Q Около 800 г трет-бутилфенилфенил- фосфата загружают в трехгорлую круг- лодонную колбу на 1 л. Колба снабжена средствами регулировани  температуры , рубашкой обогрева, мешалкой
25 и вьшуском с предусмотренным конденсатором , охлаждаемым холодной водой (дл  исключени  уноса воды). Дл  того , чтобы вызвать гидролиз в колбу к жидкости добавл ют чистый кусочек
30 меди и 8-10 г воды. Содержимое колбы перемешивают и нагревают при 93,3 С и кислотное число жидкости измер ют на 10-миллилитровых аликвот- ных пробах, отбираемых спуст  выбранные интервалы времени. Кислотность жидкости измер ют по методике испытани  ASTM D974 (нейтрализацион- ное число методом титровани  с цветовым индикатором - миллиграммы КОН на грамм жидкости).
35
40
Составы гидравлической жидкости и результаты титровани  кислоты приведены в табл.1.
Таблица 1
О 24
0,012 0,068
Примечание. 5 Таи
6
7
10
11
EST 12
Результаты испытаний.
Образцы A,B,C,D,E,F и G соотйет- ствутот контрольным экспериментам при отсутствии одного или нескольких компонентов присадки согласно изобретению . Образцы Н, I,J,K,L,M,N и О - жидкости согласно изобретению.
После расстановки образцов в пор дке возрастани  оценочного титруемого кислотного числа спуст  100 ч (TAN согласно стандарту ASTM D-974), получаютс  спецуюш е данные, приведенные в табл.2.
-Полное титруемое кислотное число, определенное по методике стандарта ASTM D-974.
-Образец обезвожен.
-Жидкость обработана активированным углем перед проведением испытани .
-Fyrgnel 220 - товарна  трет-бутилфени фенилфосфатна  жидкость, в зкость 42- 50 сСт при 37,8°С, производитель фирма Стауффер кемикл компани.
-3,4-Эпоксициклоалкил-3,4-эпоксицикло- алкилкарбоксилат вместо монсокиси лимонена в качестве эпоксидного компонента.
-Fyrgnel 150 - товарна  трет-бутилфени /фенилфосфатна  жидкость, в зкость 29-37 сСт при 37,8°С, производитель фирма Стауффер кемикл компани.
-Fyrgnel GT - товарна  гидравлическа  жидкость Fyrgnel 150 с добавкой стабилизатора.
-Оценка за 100 ч рассчитана методом наименьших квадратов по регрессии значений TAN свыше 0,07 во времени
с помощью уравнени : (.100) m (врем , часы)+Ъ.
Таблица 2
Приведенна  расстановка образцов показьшает, что составы, содержащие три компонента присадки согласно изобретению, имеют более низкие кислотные числа, чем контрольные эксперименты в отсутствии одного или нескольких компонентов.
На чертеже даны три кривые, полученные на основе данных дл  проб Е, Си L, указанных в примере.
Образец Е - жидкость Fyrnel 150 + + бензотриазол про вл ет сравнительно быстрое увеличение кислотности. Образец G - жидкость Fyrnel 150 + фе нил-об-нафтиламин + моноокись .лимоне0
5
на + бензотриазол про вл ет несколько улучшенную временную задержку роста кислотности по сравнению.с образцом Е. Образец L - жидкость Fyrnel 150 + фенил-об-нафтиламин + моноокись лимонена + Н-метил-2-пирролидон + + бензотриазол соответствует изобретению и про вл ет наибольшую задержку образовани  кислоты во времени . Следует отметить также, что угол наклона (кислотное число/врем ) крайней правой кривой пробы при высоких значени х кислотности меньше, чем угол наклона кривых дл  проб Е или G. Образование кислоты в пробе L не только отсрочено в большей степени , но и нарастание ее содержани  происходит более полого, чем в случае Q контрольных проб.

Claims (1)

  1. Формула изобретени 
    Гидравлическа  жидкость, содержа- 5 Ща  алкилариловый эфир фосфорной кислоты и присадку на основе эпокси- соединени , отличающа с  тем, что, с целью повышени  стабильности и кислотоустойчивости жидкости , в качестве присадки она содержит 0,09-0,15 мае. смеси эпокси- соединени , выбранного из группы, содержащей моноокись лимонена, 3,4- эпоксициклоалкил-3,4-эпоксициклоал- килкарбоксилат, Ы-метил-2-пирролидона и бензотриазола при массовом соотношении К-метил-2-пирролидон:эпокси- соединение 1:1,2-6 или 1,3:1, N-ме- тил-2-пирролидон:бензотриазол 1:1-2 или 1,9-4:1 и эпоксисоединение:бензотриазол 2,5:1 или 3:1.
    0
    5
    0
    Редактор Ю.Середа
    го 0 60 во
    Составитель Л.Иванова Техред И.Попович
    Корректор И. Муска
    4447/58
    Тираж 462Подписное
    ВНИИПИ Государственного комитета СССР
    по делам изобретений и открытий П3035, Москва, Ж-35, Раушска  наб., д.4/5
    Производственно-полиграфическое предпри тие, г.Ужгород, ул.Проектна ,4
SU843715903A 1983-04-01 1984-03-30 Гидравлическа жидкость SU1342425A3 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/481,436 US4461713A (en) 1983-04-01 1983-04-01 Acid-resistant phosphate ester functional fluids

Publications (1)

Publication Number Publication Date
SU1342425A3 true SU1342425A3 (ru) 1987-09-30

Family

ID=23911938

Family Applications (1)

Application Number Title Priority Date Filing Date
SU843715903A SU1342425A3 (ru) 1983-04-01 1984-03-30 Гидравлическа жидкость

Country Status (12)

Country Link
US (1) US4461713A (ru)
EP (1) EP0121852B1 (ru)
JP (1) JPS59223796A (ru)
KR (1) KR840008684A (ru)
AU (1) AU562116B2 (ru)
BR (1) BR8401371A (ru)
DE (1) DE3472972D1 (ru)
DK (1) DK81584A (ru)
ES (1) ES8606468A1 (ru)
IL (1) IL70955A (ru)
SU (1) SU1342425A3 (ru)
ZA (1) ZA841057B (ru)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4568474A (en) * 1985-01-07 1986-02-04 Ford Motor Company Polymeric particle acid neutralizers with reactive epoxy core for engine oils
US4568473A (en) * 1985-01-07 1986-02-04 Ford Motor Company Amine bearing polymeric particles as acid neutralizers for engine oils
US5374354A (en) * 1992-09-24 1994-12-20 Sundstrand Corporation Method of increasing service life of oil and a filter in an integrated drive generator or constant speed drive and improved oil filter for use therein
US5552040A (en) * 1992-09-24 1996-09-03 Sundstrand Corporation Method of increasing service life of oil and a filter for use therewith
US5779774A (en) * 1996-04-02 1998-07-14 Paciorek; Kazimiera J. L. Rust inhibiting phosphate ester formulations
DE19918199A1 (de) * 1999-04-22 2000-10-26 Basf Ag Hydraulische Flüssigkeiten, enthaltend cyclische Carbonsäurederivate
US6866797B1 (en) 2000-08-03 2005-03-15 Bj Services Company Corrosion inhibitors and methods of use
US6599866B2 (en) 2001-04-20 2003-07-29 Exxonmobil Research And Engineering Company Servo valve erosion inhibited aircraft hydraulic fluids
CA2890867A1 (en) 2012-11-16 2014-05-22 Basf Se Lubricant compositions comprising epoxide compounds

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3071549A (en) * 1959-12-17 1963-01-01 Monsanto Chemicals Preservative-type functional fluids
GB1132604A (en) * 1965-05-07 1968-11-06 Shell Int Research Improvements in or relating to polymer concentrates
US3718596A (en) * 1970-02-16 1973-02-27 Monsanto Co Functional fluid compositions
US3649721A (en) * 1970-03-02 1972-03-14 Chevron Res Low alkali metal content hydraulic fluids and their preparation
BE792993A (fr) * 1971-12-20 1973-06-19 Monsanto Co Compositions de fluides fonctionnels contenant des stabilisantsepoxyde
US3957668A (en) * 1973-09-24 1976-05-18 Mcdonnell Douglas Corporation Novel epoxy compounds and functional fluid compositions containing such compounds
US3941708A (en) * 1974-02-11 1976-03-02 Stauffer Chemical Company Hydraulic fluid antioxidant system
US3926823A (en) * 1974-10-07 1975-12-16 Continental Oil Co Turbine oil compositions
US3923672A (en) * 1974-10-07 1975-12-02 Continental Oil Co Turbine oil compositions
US4169800A (en) * 1977-12-02 1979-10-02 Fmc Corporation Turbine lubricant

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Патент US № 3707500, кл. 252-78, 1972. Патент US № 3071549, кл. 252- 78.5, 1963. . Патент US № 3718596, кл. 252-49.8, 1973. Патент СССР № 652900, кл. С 10 М 141/06, 1979. *

Also Published As

Publication number Publication date
IL70955A0 (en) 1984-05-31
AU562116B2 (en) 1987-05-28
EP0121852A3 (en) 1986-02-12
DK81584A (da) 1984-10-02
AU2609784A (en) 1984-10-04
ES531170A0 (es) 1986-04-01
BR8401371A (pt) 1984-11-06
ZA841057B (en) 1984-09-26
ES8606468A1 (es) 1986-04-01
EP0121852B1 (en) 1988-07-27
DE3472972D1 (en) 1988-09-01
IL70955A (en) 1987-10-20
EP0121852A2 (en) 1984-10-17
JPS59223796A (ja) 1984-12-15
DK81584D0 (da) 1984-02-21
KR840008684A (ko) 1984-12-17
US4461713A (en) 1984-07-24

Similar Documents

Publication Publication Date Title
SU1342425A3 (ru) Гидравлическа жидкость
US3324033A (en) Ester-amides of alkenyl succinic anhydride and diethanolamine as ashless dispersants
JPH08225500A (ja) 新規なグルカミン誘導体
US3158572A (en) High barium content complex salts of sulfonic acids and method for preparing same
US3004916A (en) Lubricating oil
JPH061986A (ja) ガソリン組成物
JPS62292892A (ja) 塩基性塩の製法
CA1082676A (en) Preparation of neutral to slightly overbased calcium synthetic sulfonate compositions
AU9032698A (en) Process for improving shelf stability of liquid overbased calcium carboxylates, mixed metal stabilizers containing same, and stabilizing halogen-containing polymers therewith
US2378442A (en) Mineral oil composition
US4758360A (en) Process for synthesizing overbased additives under constant pressure of carbon dioxide
US2533300A (en) Morpholine mahogany sulfonate as a rust inhibitor for petroleum oils
US3476838A (en) Di(2,6-diisopropylphenyl) mono halo phosphite or (thio) phosphate
DE69020998T2 (de) Schwefelgekoppelte alkylabgeleitete Merkaptobenzothiazol-Addukte als multifunktionelle verschleissschützende Zusätze und diese enthaltende Zusammensetzungen.
US2326483A (en) Stabilized mineral oil composition
DE69109751T2 (de) Mit Sulfit behandelte überbasische Produkte und Verfahren zu ihrer Herstellung.
US3956001A (en) Retarding skin formation on asphalt in hot storage
US4474672A (en) Reducing the cloud point of hydrodewaxed base stocks
US2251953A (en) Stabilized hydrocarbon composition
US5080817A (en) Corrosion inhibitor for 2-cycle engine oils comprising dodecenyl succinic anhydride-propylene glycol esters
SU511024A3 (ru) Смазочна жидкость
US2371852A (en) Lubricant compositions and methods of making the same
US3783132A (en) Compositions comprising phosphate esters and 2,6-diamino-pyridine as an antioxidant
US2501127A (en) Basic zinc salicylate
JPS59108756A (ja) アルカリ土類金属酸化物をベ−スとする被覆組成物