SK280039B6 - Oligomérne zlúčeniny, kompozície s ich obsahom a p - Google Patents
Oligomérne zlúčeniny, kompozície s ich obsahom a p Download PDFInfo
- Publication number
- SK280039B6 SK280039B6 SK1355-93A SK135593A SK280039B6 SK 280039 B6 SK280039 B6 SK 280039B6 SK 135593 A SK135593 A SK 135593A SK 280039 B6 SK280039 B6 SK 280039B6
- Authority
- SK
- Slovakia
- Prior art keywords
- group
- alkyl
- carbon atoms
- unsubstituted
- tert
- Prior art date
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 99
- 239000003381 stabilizer Substances 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 title claims description 40
- 239000011368 organic material Substances 0.000 title abstract description 3
- 230000015556 catabolic process Effects 0.000 claims abstract description 17
- 238000006731 degradation reaction Methods 0.000 claims abstract description 17
- 230000001590 oxidative effect Effects 0.000 claims abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 9
- 239000001301 oxygen Substances 0.000 claims abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 125000003386 piperidinyl group Chemical group 0.000 claims abstract description 3
- -1 benzofuran-2-one compound Chemical class 0.000 claims description 164
- 125000004432 carbon atom Chemical group C* 0.000 claims description 98
- 125000000217 alkyl group Chemical group 0.000 claims description 84
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 50
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 37
- 239000000126 substance Substances 0.000 claims description 25
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 22
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 20
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 20
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 19
- 239000005977 Ethylene Substances 0.000 claims description 19
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000004743 Polypropylene Substances 0.000 claims description 15
- 125000003342 alkenyl group Chemical group 0.000 claims description 15
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 13
- 125000002947 alkylene group Chemical group 0.000 claims description 12
- 125000001589 carboacyl group Chemical group 0.000 claims description 12
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- 229920000573 polyethylene Polymers 0.000 claims description 8
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 7
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
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- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000004434 sulfur atom Chemical group 0.000 claims description 6
- 125000006254 cycloalkyl carbonyl group Chemical group 0.000 claims description 5
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 125000002252 acyl group Chemical group 0.000 claims description 4
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- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 3
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- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 2
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 2
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- 125000005346 substituted cycloalkyl group Chemical group 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000306 recurrent effect Effects 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
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- 238000001035 drying Methods 0.000 description 8
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- 230000008018 melting Effects 0.000 description 8
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- 239000002184 metal Substances 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
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- 239000000243 solution Substances 0.000 description 8
- 239000005062 Polybutadiene Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical class C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
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- 239000004721 Polyphenylene oxide Substances 0.000 description 6
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- 239000002904 solvent Substances 0.000 description 6
- CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
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- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 4
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- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
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- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
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- DGQWBBVMFRJVQF-UHFFFAOYSA-N bis(2-hydroxyethyl) oxalate Chemical compound OCCOC(=O)C(=O)OCCO DGQWBBVMFRJVQF-UHFFFAOYSA-N 0.000 description 4
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- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
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- 150000002815 nickel Chemical class 0.000 description 4
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- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
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- ZZZRZBIPCKQDQR-UHFFFAOYSA-N 2,4-ditert-butyl-6-methylphenol Chemical compound CC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1O ZZZRZBIPCKQDQR-UHFFFAOYSA-N 0.000 description 3
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 125000003774 valeryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
- C08K5/5373—Esters of phosphonic acids containing heterocyclic rings not representing cyclic esters of phosphonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/529—Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5393—Phosphonous compounds, e.g. R—P(OR')2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH372292 | 1992-12-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
SK135593A3 SK135593A3 (en) | 1994-07-06 |
SK280039B6 true SK280039B6 (sk) | 1999-07-12 |
Family
ID=4262099
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SK1355-93A SK280039B6 (sk) | 1992-12-04 | 1993-12-02 | Oligomérne zlúčeniny, kompozície s ich obsahom a p |
Country Status (14)
Country | Link |
---|---|
US (1) | US5405891A (zh) |
EP (1) | EP0601973B1 (zh) |
JP (1) | JPH06211988A (zh) |
KR (1) | KR940014420A (zh) |
CN (1) | CN1036928C (zh) |
AT (1) | ATE185569T1 (zh) |
BR (1) | BR9304926A (zh) |
CA (1) | CA2110550A1 (zh) |
CZ (1) | CZ284155B6 (zh) |
DE (1) | DE59309835D1 (zh) |
MX (1) | MX9307592A (zh) |
RU (1) | RU2130461C1 (zh) |
SK (1) | SK280039B6 (zh) |
TW (1) | TW252991B (zh) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5616636A (en) * | 1992-03-11 | 1997-04-01 | Sandoz Ltd. | Phosphonite-hals and phosphite-hals compounds as stabilizers |
TW330942B (en) * | 1994-04-13 | 1998-05-01 | Ciba Sc Holding Ag | Monomeric and oligomeric bisphenyl-HALS phosphites as stabilizers |
TW350859B (en) * | 1994-04-13 | 1999-01-21 | Ciba Sc Holding Ag | HALS phosphonites as stabilizers |
TW297822B (zh) * | 1994-04-13 | 1997-02-11 | Ciba Geigy Ag | |
TW338768B (en) * | 1994-06-02 | 1998-08-21 | Ciba Sc Holding Ag | Oligometic HALS phosphites and HALS phosphonites as stabilizers |
EP0707035B1 (de) * | 1994-10-12 | 1999-01-13 | Ciba SC Holding AG | HALS-Phosphorinane als Stabilisatoren |
SG91852A1 (en) * | 1998-12-21 | 2002-10-15 | Toyo Boseki | Hindered amine compound, resin composition, polyurethane fiber and production method and use thereof |
US20040030203A1 (en) * | 2002-07-16 | 2004-02-12 | Gorton Earl M. | Method of stabilizing trichloroethane during production |
US7118689B2 (en) * | 2003-08-27 | 2006-10-10 | Ppg Industries Ohio, Inc. | Stabilized polychloroethylenes |
DE602007007789D1 (en) * | 2006-09-08 | 2010-08-26 | Basf Se | Flüssige polymere phosphite und phosphonite als stabilisatoren |
CN101393529B (zh) * | 2008-11-07 | 2011-01-12 | 用友软件股份有限公司 | 一种实现计算机软件多语言支持的方法 |
BR112017002203B1 (pt) * | 2014-08-05 | 2021-10-26 | Basf Se | Composição, processo para proteção de um material orgânico susceptível à degradação oxidativa, térmica ou induzida pela luz, uso de um composto de fórmula ip, i-o ou i-m, e, composto |
CN111450857B (zh) * | 2020-05-13 | 2023-06-13 | 江苏帕睿尼新材料科技有限公司 | 一种催化剂及叔丁基异硫氰酸酯的制备工艺 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE290906C (zh) * | ||||
DE2656766A1 (de) * | 1975-12-19 | 1977-07-07 | Ciba Geigy Ag | Neue phosphit-stabilisatoren |
CH626109A5 (zh) * | 1976-05-11 | 1981-10-30 | Ciba Geigy Ag | |
US4136083A (en) * | 1978-05-16 | 1979-01-23 | Eastman Kodak Company | Piperidinyl hydrogen alkylene or arylene phosphates and metal salts thereof which compounds are useful as ultraviolet stabilizers for organic compositions |
GB2044272B (en) * | 1979-02-05 | 1983-03-16 | Sandoz Ltd | Stabilising polymers |
AU3788189A (en) * | 1988-07-25 | 1990-01-25 | Borg-Warner Specialty Chemicals, Inc. | 3, 9-diphosphaspiroundecanes and process for making3, 9-diphosphaspiroundecanes |
DD290906A5 (de) * | 1988-12-30 | 1991-06-13 | Tu Dresden,Direk. Forschung,De | Verfahren zur stabilisierung von polyolefinen und deren copolymerisaten durch ester der phosphorigen und phosphonigen saeuren |
DE3928291A1 (de) * | 1989-08-26 | 1991-02-28 | Hoechst Ag | Phosphorigsaeure-arylester-amid-halogenide, phosphonigsaeurearylester-amide, verfahren zu ihrer herstellung und deren verwendung zur stabilisierung von kunststoffen |
US5175312A (en) * | 1989-08-31 | 1992-12-29 | Ciba-Geigy Corporation | 3-phenylbenzofuran-2-ones |
GB2247241A (en) * | 1990-08-22 | 1992-02-26 | Sandoz Ltd | Stabilising composition for filled polymeric materials |
RU2071478C1 (ru) * | 1991-03-26 | 1997-01-10 | Циба Гейги АГ | Несимметричные арилфосфиты, полимерная композиция и способ ее получения |
-
1993
- 1993-11-06 TW TW082109565A patent/TW252991B/zh active
- 1993-11-25 AT AT93810823T patent/ATE185569T1/de not_active IP Right Cessation
- 1993-11-25 DE DE59309835T patent/DE59309835D1/de not_active Expired - Fee Related
- 1993-11-25 EP EP93810823A patent/EP0601973B1/de not_active Expired - Lifetime
- 1993-11-30 US US08/159,410 patent/US5405891A/en not_active Expired - Fee Related
- 1993-12-01 KR KR1019930026078A patent/KR940014420A/ko not_active Application Discontinuation
- 1993-12-02 MX MX9307592A patent/MX9307592A/es not_active IP Right Cessation
- 1993-12-02 CA CA002110550A patent/CA2110550A1/en not_active Abandoned
- 1993-12-02 CZ CZ932615A patent/CZ284155B6/cs not_active IP Right Cessation
- 1993-12-02 SK SK1355-93A patent/SK280039B6/sk unknown
- 1993-12-03 BR BR9304926A patent/BR9304926A/pt not_active Application Discontinuation
- 1993-12-03 CN CN93120897A patent/CN1036928C/zh not_active Expired - Fee Related
- 1993-12-03 RU RU93053758A patent/RU2130461C1/ru active
- 1993-12-06 JP JP5339678A patent/JPH06211988A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
TW252991B (zh) | 1995-08-01 |
MX9307592A (es) | 1994-06-30 |
CN1092785A (zh) | 1994-09-28 |
JPH06211988A (ja) | 1994-08-02 |
KR940014420A (ko) | 1994-07-18 |
DE59309835D1 (de) | 1999-11-18 |
CN1036928C (zh) | 1998-01-07 |
RU2130461C1 (ru) | 1999-05-20 |
EP0601973B1 (de) | 1999-10-13 |
SK135593A3 (en) | 1994-07-06 |
CZ261593A3 (en) | 1994-06-15 |
CA2110550A1 (en) | 1994-06-05 |
ATE185569T1 (de) | 1999-10-15 |
EP0601973A1 (de) | 1994-06-15 |
CZ284155B6 (cs) | 1998-08-12 |
BR9304926A (pt) | 1994-07-05 |
US5405891A (en) | 1995-04-11 |
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