SG86363A1 - Fluid bed vinyl acetate catalyst - Google Patents

Fluid bed vinyl acetate catalyst

Info

Publication number
SG86363A1
SG86363A1 SG9906114A SG1999006114A SG86363A1 SG 86363 A1 SG86363 A1 SG 86363A1 SG 9906114 A SG9906114 A SG 9906114A SG 1999006114 A SG1999006114 A SG 1999006114A SG 86363 A1 SG86363 A1 SG 86363A1
Authority
SG
Singapore
Prior art keywords
vinyl acetate
fluid bed
acetate catalyst
bed vinyl
catalyst
Prior art date
Application number
SG9906114A
Other languages
English (en)
Inventor
James Baker Michael
Frederick Salem George
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of SG86363A1 publication Critical patent/SG86363A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/58Platinum group metals with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/63Platinum group metals with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/04Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
SG9906114A 1998-12-08 1999-12-07 Fluid bed vinyl acetate catalyst SG86363A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US20785198A 1998-12-08 1998-12-08

Publications (1)

Publication Number Publication Date
SG86363A1 true SG86363A1 (en) 2002-02-19

Family

ID=22772244

Family Applications (1)

Application Number Title Priority Date Filing Date
SG9906114A SG86363A1 (en) 1998-12-08 1999-12-07 Fluid bed vinyl acetate catalyst

Country Status (15)

Country Link
US (2) US6358882B1 (tr)
EP (1) EP1008385A3 (tr)
JP (1) JP2000176285A (tr)
KR (1) KR100717093B1 (tr)
CN (1) CN1178748C (tr)
BR (1) BR9907490A (tr)
ID (1) ID24003A (tr)
MY (1) MY129802A (tr)
NO (2) NO325524B1 (tr)
RS (1) RS50014B (tr)
RU (1) RU2237517C2 (tr)
SG (1) SG86363A1 (tr)
TR (1) TR199902988A3 (tr)
TW (1) TW476668B (tr)
UA (1) UA65569C2 (tr)

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DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19959064A1 (de) * 1999-12-08 2001-06-13 Basf Ag Trägerkatalysator zur Selektivhydrierung von Alkinen und Dienen
GB0014583D0 (en) 2000-06-14 2000-08-09 Bp Chem Int Ltd Process
EP1190768A1 (de) * 2000-09-26 2002-03-27 Degussa AG Edelmetallkatalysator
GB0026241D0 (en) * 2000-10-26 2000-12-13 Bp Chem Int Ltd Process
US8572910B2 (en) * 2003-05-09 2013-11-05 Tapco International, Inc. Cap-on-cap mounting block
GB0312769D0 (en) * 2003-06-04 2003-07-09 Johnson Matthey Plc Process for selective hydrogenation of acetylenic compounds and catalyst therefor
WO2005005033A2 (en) * 2003-06-30 2005-01-20 New Jersey Institute Of Technology Catalysts and methods for making same
NZ547073A (en) * 2003-12-19 2010-05-28 Celanese Int Corp Layered support material for catalysts
RU2006119185A (ru) * 2003-12-19 2007-12-20 Селаниз Интернэшнл Корпорейшн (Us) Материал носителя для катализаторов, содержащий диоксид циркония
TW201236755A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
JP4551109B2 (ja) * 2004-04-14 2010-09-22 エヌ・イーケムキャット株式会社 触媒の製造方法
US20050234136A1 (en) 2004-04-19 2005-10-20 Holland Brian T Colloidal compositions and methods of preparing same
DE102004050585A1 (de) * 2004-10-15 2006-04-20 Degussa Ag Mikroreaktor und Verfahren zur Synthese von Vinylacetat-Monomer (VAM) in der Gasphase
KR100932575B1 (ko) * 2004-12-20 2009-12-17 셀라니즈 인터내셔날 코포레이션 촉매용 개질된 지지체 물질
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
TW200704436A (en) * 2005-06-24 2007-02-01 Bp Chem Int Ltd Vinyl acetate catalyst and support
US20080108497A1 (en) * 2006-11-08 2008-05-08 Holland Brian T Metal-rich siliceous compositions and methods of producing same
DE102006062331A1 (de) * 2006-12-22 2008-06-26 Uhde Gmbh Herstellung von Vinylchlorid
US7811968B2 (en) * 2007-05-11 2010-10-12 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) * 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025362A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025443A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
US8790608B2 (en) * 2008-09-12 2014-07-29 Nalco Company Siliceous materials having tunable porosity and surface morphology and methods of synthesizing same
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
US8329611B2 (en) 2009-12-16 2012-12-11 Lyondell Chemical Technology, L,P. Titania-containing extrudate
US8273682B2 (en) * 2009-12-16 2012-09-25 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalyst
US8507720B2 (en) * 2010-01-29 2013-08-13 Lyondell Chemical Technology, L.P. Titania-alumina supported palladium catalyst
EP4316656A4 (en) * 2021-03-26 2024-05-22 Asahi Kasei Kabushiki Kaisha CATALYST FOR PRODUCING CARBOXYLIC ACID ESTER, METHOD FOR PRODUCING CARBOXYLIC ACID ESTER AND METHOD FOR PRODUCING A CATALYST FOR PRODUCING CARBOXYLIC ACID ESTER

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1235632A (en) * 1968-10-22 1971-06-16 Knapsack Ag Process for the manufacture of unsaturated esters of carboxylic acids
EP0199930A2 (en) * 1985-03-29 1986-11-05 AlliedSignal Inc. Spray-dried inorganic oxides from non-aqueous gels or solutions
WO1993023438A1 (en) * 1992-05-13 1993-11-25 Joseph Crosfield & Son Ltd. Catalysts and catalyst supports
US5591688A (en) * 1994-02-22 1997-01-07 The Standard Oil Company Process for the preparation of fluid bed vinyl acetate catalyst
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst

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US3918543A (en) * 1973-12-26 1975-11-11 Norman Halem System for employing the change of momentum during vehicle deceleration for accessory power
JPS514118A (en) 1974-06-27 1976-01-14 Kuraray Co Sakusanbiniruno seizohoho
JPS5917098B2 (ja) 1979-01-17 1984-04-19 ジェイエスアール株式会社 共役ジエンモノエステルの製造方法
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TW330160B (en) * 1992-04-08 1998-04-21 Hoechst Ag Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate
DE4323980C1 (de) * 1993-07-16 1995-03-30 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE4323978C1 (de) * 1993-07-16 1995-02-16 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat
DE69534557T2 (de) * 1994-02-22 2006-06-01 The Standard Oil Co., Cleveland Verfahren zur Herstellung eines Katalysators für die Herstellung von Vinylacetat in einem Wirbelbett
ES2135006T3 (es) 1994-06-02 1999-10-16 Standard Oil Co Ohio Procedimiento en lecho fluido para la acetoxilacion de etileno en la produccion de acetato de vinilo.
US5536693A (en) * 1994-06-02 1996-07-16 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
US5550281A (en) 1994-06-02 1996-08-27 Cirjak; Larry M. Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
DE19523271A1 (de) * 1995-06-27 1997-01-02 Hoechst Ag Katalysator und Verfahren zur Herstellung von Vinylacetat
US5691267A (en) * 1996-04-16 1997-11-25 Hoechst Celanese Corporation Two step gold addition method for preparing a vinyl acetate catalyst
GB9622911D0 (en) 1996-11-04 1997-01-08 Bp Chem Int Ltd Process
US5859287A (en) 1997-10-30 1999-01-12 Celanese International Corporation Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals
DE19755022C2 (de) * 1997-12-11 2000-03-09 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat
DE19755023C2 (de) 1997-12-11 2000-03-09 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1235632A (en) * 1968-10-22 1971-06-16 Knapsack Ag Process for the manufacture of unsaturated esters of carboxylic acids
EP0199930A2 (en) * 1985-03-29 1986-11-05 AlliedSignal Inc. Spray-dried inorganic oxides from non-aqueous gels or solutions
WO1993023438A1 (en) * 1992-05-13 1993-11-25 Joseph Crosfield & Son Ltd. Catalysts and catalyst supports
US5591688A (en) * 1994-02-22 1997-01-07 The Standard Oil Company Process for the preparation of fluid bed vinyl acetate catalyst
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst

Also Published As

Publication number Publication date
US6534672B2 (en) 2003-03-18
ID24003A (id) 2000-06-14
NO324572B1 (no) 2007-11-26
TR199902988A2 (tr) 2000-07-21
EP1008385A3 (en) 2001-03-28
US6358882B1 (en) 2002-03-19
NO20052980D0 (no) 2005-06-17
NO325524B1 (no) 2008-06-02
KR20000047965A (ko) 2000-07-25
EP1008385A2 (en) 2000-06-14
TR199902988A3 (tr) 2000-07-21
RU2237517C2 (ru) 2004-10-10
JP2000176285A (ja) 2000-06-27
NO20052980L (no) 2000-06-09
UA65569C2 (en) 2004-04-15
CN1178748C (zh) 2004-12-08
TW476668B (en) 2002-02-21
CN1264621A (zh) 2000-08-30
NO996008L (no) 2000-06-09
US20020062039A1 (en) 2002-05-23
KR100717093B1 (ko) 2007-05-10
MY129802A (en) 2007-04-30
YU63899A (sh) 2001-09-28
NO996008D0 (no) 1999-12-07
RS50014B (sr) 2008-09-29
BR9907490A (pt) 2001-01-16

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