SG47888A1 - Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxylates - Google Patents
Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxylatesInfo
- Publication number
- SG47888A1 SG47888A1 SG1996005045A SG1996005045A SG47888A1 SG 47888 A1 SG47888 A1 SG 47888A1 SG 1996005045 A SG1996005045 A SG 1996005045A SG 1996005045 A SG1996005045 A SG 1996005045A SG 47888 A1 SG47888 A1 SG 47888A1
- Authority
- SG
- Singapore
- Prior art keywords
- dimethyl
- hydrogenation
- low pressure
- benzenedicarboxylates
- cyclohexanedicarboxylates
- Prior art date
Links
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical class COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 title 1
- GGCUUOGRTPMFQK-UHFFFAOYSA-N dimethyl cyclohexane-1,1-dicarboxylate Chemical class COC(=O)C1(C(=O)OC)CCCCC1 GGCUUOGRTPMFQK-UHFFFAOYSA-N 0.000 title 1
- 238000005984 hydrogenation reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/394—Metal dispersion value, e.g. percentage or fraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/076,675 US5286898A (en) | 1993-06-15 | 1993-06-15 | Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates |
Publications (1)
Publication Number | Publication Date |
---|---|
SG47888A1 true SG47888A1 (en) | 1998-04-17 |
Family
ID=22133530
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG1996005045A SG47888A1 (en) | 1993-06-15 | 1994-06-03 | Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxylates |
Country Status (11)
Country | Link |
---|---|
US (1) | US5286898A (fr) |
EP (1) | EP0703894B1 (fr) |
JP (1) | JP3499557B2 (fr) |
KR (1) | KR100390121B1 (fr) |
CN (1) | CN1042327C (fr) |
CA (1) | CA2165207C (fr) |
DE (1) | DE69412827T2 (fr) |
ES (1) | ES2120054T3 (fr) |
SG (1) | SG47888A1 (fr) |
TW (1) | TW265332B (fr) |
WO (1) | WO1994029260A1 (fr) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0922690B1 (fr) | 1996-06-28 | 2003-12-03 | SK NJC Co., Ltd. | Procede de preparation de cyclohexanedimethanol |
EP1042273B1 (fr) * | 1997-12-19 | 2003-05-07 | Basf Aktiengesellschaft | Procede d'hydrogenation d'acides polycarboxyliques de benzene ou de leurs derives a l'aide d'un catalyseur a macropores |
DE19927978A1 (de) * | 1999-06-18 | 2000-12-21 | Basf Ag | Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester |
MXPA02000907A (es) * | 1999-07-28 | 2003-07-14 | S D Chemie Inc | Catalizadores de hidrogenacion tolerantes al azufre. |
DE19939544C1 (de) | 1999-08-20 | 2001-02-15 | Haarmann & Reimer Gmbh | Verfahren zur Herstellung von Methyl-cyclohexyl-propionat |
DE10128242A1 (de) * | 2001-06-11 | 2002-12-12 | Basf Ag | Verfahren zur Hydrierung organischer Verbindungen |
DE10146869A1 (de) | 2001-09-24 | 2003-04-24 | Oxeno Olefinchemie Gmbh | Alicyclische Polycarbonsäureestergemische mit hohem trans-Anteil und Verfahren zu deren Herstellung |
ATE415447T1 (de) * | 2001-09-25 | 2008-12-15 | Exxonmobil Chem Patents Inc | Weich-polyvinylchlorid |
US6803341B2 (en) * | 2002-01-18 | 2004-10-12 | Chinese Petroleum Corporation | Method of a high stability selectable hydrogenate catalyst producing and using for DMCHD manufacturing |
GB0227087D0 (en) * | 2002-11-20 | 2002-12-24 | Exxonmobil Chem Patents Inc | Hydrogenation of benzene polycarboxylic acids or derivatives thereof |
GB0227086D0 (en) * | 2002-11-20 | 2002-12-24 | Exxonmobil Res & Eng Co | Hydrogenation processes |
DE102004063637A1 (de) | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von alicyclischen Carbonsäuren oder deren Derivaten |
DE102004063673A1 (de) * | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas |
US7632962B2 (en) * | 2006-04-26 | 2009-12-15 | Eastman Chemical Company | Hydrogenation process and catalysts |
CN101417950B (zh) * | 2008-10-27 | 2012-05-23 | 中国科学院大连化学物理研究所 | 一种制备1,2-环己烷二甲酸二元酯的方法 |
CN101927166B (zh) * | 2010-07-23 | 2013-01-23 | 南京大学 | 一种担载镍催化剂及其制法和用途 |
CN102381976B (zh) * | 2010-09-01 | 2013-09-04 | 中国石油天然气股份有限公司 | 一种制备1,4-环己烷二甲酸二甲酯的方法 |
CN102476052A (zh) * | 2010-11-29 | 2012-05-30 | 中国石油化工股份有限公司 | 一种负载型钌催化剂及其制备方法 |
CN102796001A (zh) * | 2011-05-25 | 2012-11-28 | 江苏恒祥化工有限责任公司 | 无溶剂制备1,4-环己烷二甲酸二甲酯 |
TWI421240B (zh) | 2011-12-12 | 2014-01-01 | Ind Tech Res Inst | 苯多羧酸或其衍生物形成環己烷多元酸酯之氫化方法 |
CN102631925B (zh) * | 2012-03-30 | 2015-03-25 | 中国科学院山西煤炭化学研究所 | 一种苯羧酸酯加氢催化剂及其制备方法和应用 |
ITMI20121641A1 (it) * | 2012-10-02 | 2014-04-03 | Polynt S P A | Procedimento per l'idrogenazione di esteri di acidi carbossilici aromatici a dare loro omologhi saturi, nuovi usi per detti omologhi, e nuove miscele polimeriche plastificate. |
US9090553B2 (en) | 2012-10-05 | 2015-07-28 | Basf Se | Process for preparing cyclohexanepolycarboxylic acid derivatives having a low proportion of by-products |
EP2716623A1 (fr) | 2012-10-05 | 2014-04-09 | Basf Se | Procédé de fabrication de dérivés d'acide de polycarbonate cyclohexane avec part étroite de produits annexes |
CN102921409A (zh) * | 2012-10-26 | 2013-02-13 | 中国海洋石油总公司 | 一种加氢生产1,2环己烷二羧酸酯的催化剂的制法 |
CN102935365B (zh) * | 2012-11-12 | 2014-12-03 | 中国石油化工股份有限公司 | 一种制备1,4-环己烷二甲酸二甲酯的催化剂及方法 |
CN103157468A (zh) * | 2013-03-14 | 2013-06-19 | 北京化工大学 | 一种低含量负载型钌-钯双金属加氢催化剂及其制备方法 |
CN104649864A (zh) * | 2013-11-19 | 2015-05-27 | 中国石油天然气股份有限公司 | 一种对苯二甲酸二烷基酯加氢生产1,4-环己烷二甲醇的方法 |
US9340482B2 (en) | 2013-12-30 | 2016-05-17 | Eastman Chemical Company | Processes for making cyclohexane compounds |
US9346737B2 (en) | 2013-12-30 | 2016-05-24 | Eastman Chemical Company | Processes for making cyclohexane compounds |
US9328050B1 (en) | 2014-12-23 | 2016-05-03 | Eastman Chemical Company | Processes for making hydroxymethylbenzoic acid compounds |
KR101905165B1 (ko) * | 2015-04-01 | 2018-10-05 | 한화케미칼 주식회사 | 프탈레이트 화합물의 수소화 촉매의 재생 방법 |
TWI577658B (zh) * | 2015-05-06 | 2017-04-11 | 中國石油化學工業開發股份有限公司 | 1,4-環己烷二甲酸二甲酯及1,4-環己烷二甲醇之製法 |
KR101780405B1 (ko) * | 2015-09-24 | 2017-09-20 | 롯데케미칼 주식회사 | 1,4-사이클로헥산디카르복실산의 제조 방법 |
CN106866415A (zh) * | 2015-12-12 | 2017-06-20 | 中国科学院大连化学物理研究所 | 一种脂环族羧酸酯的制造方法 |
CN109562355A (zh) | 2016-08-18 | 2019-04-02 | 芝加哥大学 | 用于高效有机转化的金属氧化物负载的地球丰富的金属催化剂 |
KR101883993B1 (ko) * | 2016-09-29 | 2018-07-31 | 롯데케미칼 주식회사 | 1,3-사이클로헥산디카르복시산의 제조 방법 |
FR3059253B1 (fr) * | 2016-11-29 | 2020-01-17 | IFP Energies Nouvelles | Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3. |
FR3059252B1 (fr) * | 2016-11-29 | 2018-11-16 | IFP Energies Nouvelles | Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique |
KR102506281B1 (ko) * | 2017-11-29 | 2023-03-06 | 한화솔루션 주식회사 | 프탈레이트 화합물의 수소화 방법 |
TWI684585B (zh) * | 2018-11-14 | 2020-02-11 | 中國石油化學工業開發股份有限公司 | 1,4-環己烷二甲酸二甲酯之製法 |
CN112916022A (zh) * | 2021-01-21 | 2021-06-08 | 西南化工研究设计院有限公司 | 一种选择性加氢催化剂及其制备方法和应用 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2675390A (en) * | 1950-05-19 | 1954-04-13 | Edgar F Rosenblatt | Hydrogenation of cyclic-compounds |
GB817736A (en) * | 1955-08-26 | 1959-08-06 | Chimiotherapie Lab Franc | Esters of trans-hexahydroterephthalic acid and of the mono-acid chloride of trans-hexahydroterephthalic acid |
US2794030A (en) * | 1955-10-18 | 1957-05-28 | Union Carbide & Carbon Corp | Aliphatic esters of 4, 5-epoxycyclohexane-1, 2-dicarboxylic acids |
US3027398A (en) * | 1960-02-01 | 1962-03-27 | Du Pont | Process for preparing dimethyl 1, 4-cyclohexanedicarboxylate |
DE1154096B (de) * | 1962-02-23 | 1963-09-12 | Witten Gmbh Chem Werke | Verfahren zur Herstellung von 1, 4-Cyclohexandicarbonsaeure-dialkylestern |
NL6405867A (fr) * | 1963-05-29 | 1964-11-30 | ||
US3334149A (en) * | 1964-07-21 | 1967-08-01 | Eastman Kodak Co | Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite |
US3444237A (en) * | 1966-03-23 | 1969-05-13 | Grace W R & Co | Esters of cyclohexane-1,2,4-tricarboxylic acid |
US4024173A (en) * | 1967-09-02 | 1977-05-17 | Dynamit Nobel Aktiengesellschaft | Process for the manufacture of cyclohexene dicarboxylic acid esters |
US3824193A (en) * | 1972-03-30 | 1974-07-16 | Eastman Kodak Co | Alkaline reactivation of alumina supported palladium catalysts |
DE2823165A1 (de) * | 1978-05-26 | 1979-11-29 | Bayer Ag | Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern |
JP2717265B2 (ja) * | 1988-06-03 | 1998-02-18 | 東都化成株式会社 | 熱硬化性樹脂組成物 |
-
1993
- 1993-06-15 US US08/076,675 patent/US5286898A/en not_active Expired - Lifetime
-
1994
- 1994-02-07 TW TW083101008A patent/TW265332B/zh not_active IP Right Cessation
- 1994-06-03 JP JP50197295A patent/JP3499557B2/ja not_active Expired - Lifetime
- 1994-06-03 DE DE69412827T patent/DE69412827T2/de not_active Expired - Lifetime
- 1994-06-03 WO PCT/US1994/006266 patent/WO1994029260A1/fr active IP Right Grant
- 1994-06-03 KR KR1019950705692A patent/KR100390121B1/ko not_active IP Right Cessation
- 1994-06-03 SG SG1996005045A patent/SG47888A1/en unknown
- 1994-06-03 ES ES94919348T patent/ES2120054T3/es not_active Expired - Lifetime
- 1994-06-03 CA CA002165207A patent/CA2165207C/fr not_active Expired - Fee Related
- 1994-06-03 EP EP94919348A patent/EP0703894B1/fr not_active Expired - Lifetime
- 1994-06-10 CN CN94106440A patent/CN1042327C/zh not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2120054T3 (es) | 1998-10-16 |
CN1042327C (zh) | 1999-03-03 |
EP0703894B1 (fr) | 1998-08-26 |
CN1099745A (zh) | 1995-03-08 |
DE69412827T2 (de) | 1999-01-14 |
KR100390121B1 (ko) | 2003-11-13 |
DE69412827D1 (de) | 1998-10-01 |
JP3499557B2 (ja) | 2004-02-23 |
TW265332B (fr) | 1995-12-11 |
US5286898A (en) | 1994-02-15 |
JPH08511775A (ja) | 1996-12-10 |
EP0703894A1 (fr) | 1996-04-03 |
CA2165207A1 (fr) | 1994-12-22 |
KR960703099A (ko) | 1996-06-19 |
CA2165207C (fr) | 1998-08-18 |
WO1994029260A1 (fr) | 1994-12-22 |
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