SG181860A1 - Compositions comprising tetrafluoropropene and difluoromethane and uses thereof - Google Patents
Compositions comprising tetrafluoropropene and difluoromethane and uses thereof Download PDFInfo
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- SG181860A1 SG181860A1 SG2012045985A SG2012045985A SG181860A1 SG 181860 A1 SG181860 A1 SG 181860A1 SG 2012045985 A SG2012045985 A SG 2012045985A SG 2012045985 A SG2012045985 A SG 2012045985A SG 181860 A1 SG181860 A1 SG 181860A1
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- composition
- compositions
- hfc
- tetrafluoropropene
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 315
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 title claims abstract description 139
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 title abstract description 5
- 238000005057 refrigeration Methods 0.000 claims abstract description 47
- 238000001816 cooling Methods 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 37
- 238000004378 air conditioning Methods 0.000 claims abstract description 36
- 239000012530 fluid Substances 0.000 claims abstract description 25
- 230000008569 process Effects 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000006260 foam Substances 0.000 claims abstract description 4
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 48
- 239000000314 lubricant Substances 0.000 claims description 44
- -1 compatibilizers Substances 0.000 claims description 31
- 239000000654 additive Substances 0.000 claims description 20
- 239000000975 dye Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 16
- 230000000996 additive effect Effects 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 238000001704 evaporation Methods 0.000 claims description 10
- 239000010702 perfluoropolyether Substances 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 7
- 239000002480 mineral oil Substances 0.000 claims description 7
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 4
- 229940123457 Free radical scavenger Drugs 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 229920001289 polyvinyl ether Polymers 0.000 claims description 3
- 239000002516 radical scavenger Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229920013639 polyalphaolefin Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 238000012546 transfer Methods 0.000 abstract description 34
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 abstract description 13
- 239000004604 Blowing Agent Substances 0.000 abstract description 3
- 239000003380 propellant Substances 0.000 abstract description 3
- 230000001629 suppression Effects 0.000 abstract description 2
- 239000003507 refrigerant Substances 0.000 description 91
- 239000007788 liquid Substances 0.000 description 20
- 239000000126 substance Substances 0.000 description 15
- 239000007789 gas Substances 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 13
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 238000010792 warming Methods 0.000 description 11
- 239000000700 radioactive tracer Substances 0.000 description 10
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- 230000008859 change Effects 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 6
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 6
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 5
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- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical class OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
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- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
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- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 4
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- 239000012071 phase Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
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- 239000007850 fluorescent dye Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
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- 238000005461 lubrication Methods 0.000 description 3
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 3
- 239000001272 nitrous oxide Substances 0.000 description 3
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- 239000010452 phosphate Substances 0.000 description 3
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- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 3
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- UNMJLQGKEDTEKJ-UHFFFAOYSA-N (3-ethyloxetan-3-yl)methanol Chemical compound CCC1(CO)COC1 UNMJLQGKEDTEKJ-UHFFFAOYSA-N 0.000 description 2
- FDOPVENYMZRARC-UHFFFAOYSA-N 1,1,1,2,2-pentafluoropropane Chemical compound CC(F)(F)C(F)(F)F FDOPVENYMZRARC-UHFFFAOYSA-N 0.000 description 2
- ZDCWZRQSHBQRGN-UHFFFAOYSA-N 1,1,1,2,3-pentafluoropropane Chemical compound FCC(F)C(F)(F)F ZDCWZRQSHBQRGN-UHFFFAOYSA-N 0.000 description 2
- LKUDPHPHKOZXCD-UHFFFAOYSA-N 1,3,5-trimethoxybenzene Chemical compound COC1=CC(OC)=CC(OC)=C1 LKUDPHPHKOZXCD-UHFFFAOYSA-N 0.000 description 2
- OHBQPCCCRFSCAX-UHFFFAOYSA-N 1,4-Dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1 OHBQPCCCRFSCAX-UHFFFAOYSA-N 0.000 description 2
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- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- AQZRARFZZMGLHL-UHFFFAOYSA-N 2-(trifluoromethyl)oxirane Chemical compound FC(F)(F)C1CO1 AQZRARFZZMGLHL-UHFFFAOYSA-N 0.000 description 2
- YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F5/00—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B3/00—Self-contained rotary compression machines, i.e. with compressor, condenser and evaporator rotating as a single unit
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Lubricants (AREA)
- Fire-Extinguishing Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
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| US28850409P | 2009-12-21 | 2009-12-21 | |
| PCT/US2010/061611 WO2011084813A1 (en) | 2009-12-21 | 2010-12-21 | Compositions comprising tetrafluoropropene and difluoromethane and uses thereof |
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| SG181860A1 true SG181860A1 (en) | 2012-08-30 |
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|---|---|---|---|
| SG2012045985A SG181860A1 (en) | 2009-12-21 | 2010-12-21 | Compositions comprising tetrafluoropropene and difluoromethane and uses thereof |
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| Country | Link |
|---|---|
| US (1) | US20120267564A1 (enExample) |
| EP (1) | EP2516578B1 (enExample) |
| JP (1) | JP5730900B2 (enExample) |
| KR (5) | KR20190053291A (enExample) |
| CN (2) | CN102712838A (enExample) |
| AR (1) | AR079667A1 (enExample) |
| AU (1) | AU2010339656B2 (enExample) |
| BR (1) | BR112012015265B1 (enExample) |
| CA (1) | CA2782587C (enExample) |
| ES (1) | ES2590034T3 (enExample) |
| MX (2) | MX337867B (enExample) |
| MY (1) | MY158739A (enExample) |
| RU (1) | RU2012131163A (enExample) |
| SG (1) | SG181860A1 (enExample) |
| TW (1) | TWI507379B (enExample) |
| WO (1) | WO2011084813A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2950065B1 (fr) * | 2009-09-11 | 2012-02-03 | Arkema France | Fluide refrigerant binaire |
| EP2528983B1 (en) * | 2010-01-27 | 2020-12-02 | Daikin Industries, Ltd. | Use of refrigerant composition comprising difluoromethane (hfc32) and 2,3,3,3-tetrafluoropropene (hfo1234yf) |
| JP2012236884A (ja) * | 2011-05-10 | 2012-12-06 | Fujitsu General Ltd | 混合冷媒とそれを用いた空気調和機 |
| TWI585065B (zh) | 2011-08-26 | 2017-06-01 | 杜邦股份有限公司 | 含四氟丙烯之組成物及其使用方法 |
| FR2979419B1 (fr) | 2011-08-30 | 2018-03-30 | Arkema France | Fluides de transfert de chaleur supercritiques a base de tetrafluoropropene |
| US20130158250A1 (en) * | 2011-12-16 | 2013-06-20 | Honeywell International, Inc. | Method of deacidifying cellulose based materials |
| FR2988215B1 (fr) | 2012-03-16 | 2014-02-28 | Schneider Electric Ind Sas | Melange d'hydrofluoroolefine et d'hydrofluorocarbure pour ameliorer la tenue a l'arc interne dans les appareils electriques moyenne et haute tension |
| TW201410856A (zh) * | 2012-08-23 | 2014-03-16 | Du Pont | 含四氟丙烯及二氟甲烷的冷媒混合物及其運用 |
| TW201412965A (zh) | 2012-08-23 | 2014-04-01 | Du Pont | 含四氟丙烯、二氟甲烷、及可選擇地含二氟乙烷的冷媒混合物及其運用 |
| CN104603228B (zh) * | 2012-09-04 | 2018-04-06 | 大金工业株式会社 | 含有2,3,3,3‑四氟丙烯的混合制冷剂的填充方法 |
| US20140165631A1 (en) * | 2012-12-14 | 2014-06-19 | GM Global Technology Operations LLC | Refrigeration Compositions, Refrigeration Systems and Methods of Making, Operating and Using the Same |
| EP2972014A4 (en) * | 2013-03-15 | 2016-10-26 | Honeywell Int Inc | LOW GWP CALOPOROUS COMPOSITIONS |
| TWI682992B (zh) * | 2013-10-10 | 2020-01-21 | 杜邦股份有限公司 | 含二氟甲烷、五氟乙烷、及四氟丙烯的冷媒混合物及其用途 |
| US10035937B2 (en) * | 2014-05-05 | 2018-07-31 | Honeywell International Inc. | Low GWP heat transfer compositions |
| JP6433226B2 (ja) * | 2014-10-03 | 2018-12-05 | Ｊｘｔｇエネルギー株式会社 | 冷凍機油及び冷凍機用作動流体組成物 |
| EP3218443B1 (en) * | 2014-11-11 | 2021-03-10 | Trane International Inc. | Hvac system comprising refrigerant compositions and methods |
| US10267542B2 (en) | 2015-04-02 | 2019-04-23 | Carrier Corporation | Wide speed range high-efficiency cold climate heat pump |
| CN108699428A (zh) * | 2016-02-29 | 2018-10-23 | 科慕埃弗西有限公司 | 包含二氟甲烷、五氟乙烷、四氟乙烷、四氟丙烯和二氧化碳的制冷剂混合物及其用途 |
| US10774021B2 (en) * | 2016-08-30 | 2020-09-15 | University Of Ottawa | Process for preparation of hydrofluoroalkenes by selective catalytic consecutive hydrodefluorination |
| CA3043542C (en) * | 2017-01-13 | 2023-01-10 | Honeywell International Inc. | Refrigerant, heat transfer compositions, methods, and systems |
| JP7057065B2 (ja) * | 2017-02-06 | 2022-04-19 | 株式会社神戸製鋼所 | ボイルオフガス回収システム |
| TWI843706B (zh) * | 2017-09-19 | 2024-06-01 | 美商哈尼威爾國際公司 | 傳熱方法、系統和組成物 |
| US20220195279A1 (en) * | 2017-10-12 | 2022-06-23 | The Chemours Company Fc, Llc | Compositions containing difluoromethane, tetrafluoropropene, and carbon dioxide and uses thereof |
| TWI794296B (zh) * | 2017-10-12 | 2023-03-01 | 美商科慕Ｆｃ有限責任公司 | 含有二氟甲烷、四氟丙烯和二氧化碳的組合物及其用途 |
| TWI791624B (zh) * | 2017-10-12 | 2023-02-11 | 美商科慕Ｆｃ有限責任公司 | 含二氟甲烷、四氟丙烯和二氧化碳之組合物及其用途 |
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| GB201901890D0 (en) * | 2019-02-11 | 2019-04-03 | Mexichem Fluor Sa De Cv | Compositions |
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| WO2020236536A1 (en) * | 2019-05-17 | 2020-11-26 | The Chemours Company Fc, Llc | Refrigerant compositions for refrigerant compressor systems |
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| JP2012251767A (ja) * | 2012-07-30 | 2012-12-20 | Mitsubishi Electric Corp | 混合冷媒とそれを用いた冷凍サイクル装置 |
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- 2010-12-21 KR KR1020197013351A patent/KR20190053291A/ko not_active Ceased
- 2010-12-21 BR BR112012015265-3A patent/BR112012015265B1/pt active IP Right Grant
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| ES2590034T3 (es) | 2016-11-17 |
| JP5730900B2 (ja) | 2015-06-10 |
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| BR112012015265B1 (pt) | 2021-08-10 |
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| BR112012015265A2 (pt) | 2020-09-01 |
| KR20170106654A (ko) | 2017-09-21 |
| AU2010339656B2 (en) | 2015-07-23 |
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| MX2012007230A (es) | 2012-07-17 |
| JP2013515156A (ja) | 2013-05-02 |
| EP2516578B1 (en) | 2016-06-22 |
| WO2011084813A1 (en) | 2011-07-14 |
| KR20210122889A (ko) | 2021-10-12 |
| KR20190053291A (ko) | 2019-05-17 |
| MY158739A (en) | 2016-11-15 |
| CA2782587C (en) | 2018-04-24 |
| TW201130783A (en) | 2011-09-16 |
| AU2010339656A1 (en) | 2012-06-14 |
| KR20120123354A (ko) | 2012-11-08 |
| CA2782587A1 (en) | 2011-07-14 |
| EP2516578A1 (en) | 2012-10-31 |
| AR079667A1 (es) | 2012-02-08 |
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