SG11201402190SA - Synthesis of high activity large crystal zsm-5 - Google Patents

Synthesis of high activity large crystal zsm-5

Info

Publication number
SG11201402190SA
SG11201402190SA SG11201402190SA SG11201402190SA SG11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA
Authority
SG
Singapore
Prior art keywords
synthesis
high activity
large crystal
crystal zsm
activity large
Prior art date
Application number
SG11201402190SA
Other languages
English (en)
Inventor
Wenyih Frank Lai
Merci A Hamilton
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201402190SA publication Critical patent/SG11201402190SA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38Type ZSM-5
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/12After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201402190SA 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5 SG11201402190SA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161565635P 2011-12-01 2011-12-01
PCT/US2012/066588 WO2013081994A1 (fr) 2011-12-01 2012-11-27 Synthèse d'une zsm-5 à cristaux de grande dimension, de haute activité

Publications (1)

Publication Number Publication Date
SG11201402190SA true SG11201402190SA (en) 2014-09-26

Family

ID=47279156

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201402190SA SG11201402190SA (en) 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5

Country Status (9)

Country Link
US (1) US8900547B2 (fr)
EP (1) EP2785645B1 (fr)
JP (1) JP5990594B2 (fr)
KR (1) KR101858310B1 (fr)
CN (1) CN103958411B (fr)
BR (1) BR112014012577A2 (fr)
CA (1) CA2855875C (fr)
SG (1) SG11201402190SA (fr)
WO (1) WO2013081994A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102220082B1 (ko) * 2019-07-23 2021-02-25 노경태 신규 구조 및 타래형 모폴로지를 갖는 알루미노실리케이트 구조체, 이의 제조방법 및 이를 고정상으로 충진한 hplc 컬럼
CN114426455A (zh) * 2020-09-28 2022-05-03 中国石油化工股份有限公司 一种苯和乙烯烷基化反应
CN114620743A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种大晶粒rho-sapo分子筛、其制备方法及其应用
FR3141080A1 (fr) 2022-10-19 2024-04-26 Arkema France Procédé de synthèse de zéolithe zsm-5 en continu

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3676063A (en) * 1971-03-11 1972-07-11 Nalco Chemical Co Process for preparing synthetic crystalline zeolitic sodium aluminosilicate
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
NZ193928A (en) 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
JPH0227283B2 (ja) * 1982-10-01 1990-06-15 Toray Industries Ketsushoseiaruminoshirikeetozeoraitonoseizoho
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
JP2618021B2 (ja) * 1988-10-03 1997-06-11 工業技術院長 真球状ペンタシル型ゼオライト粉体の合成方法
JP2844098B2 (ja) * 1989-12-20 1999-01-06 旭化成工業株式会社 Zsm―5微粒子体の製造法
US5164169A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Zeolite Beta
WO1996040426A2 (fr) * 1995-06-06 1996-12-19 Mobil Oil Corporation Cristal de grande dimension zsm-5, sa synthese et son utilisation
US20020011429A1 (en) * 1997-09-30 2002-01-31 Akira Iino Iron-containing crystalline aluminosilicate
EP1385622B1 (fr) * 2001-05-10 2014-07-09 Albemarle Netherlands B.V. Procédé continu de conversion efficiente de particules solides inorganiques
KR100528672B1 (ko) * 2002-12-30 2005-11-15 학교법인 건국대학교 유기 템플레이트 배제 하에서 가변 온도를 이용하여zsm-5를 제조하는 방법
AU2003286975A1 (en) * 2002-12-30 2004-07-22 Sk Corporation Method of preparing zsm-5 using variable temperature without organic template
US9296619B2 (en) * 2008-02-22 2016-03-29 Exxonmobil Chemical Patents Inc. Large crystal molecular sieves and their manufacture
CN101722033A (zh) * 2008-10-28 2010-06-09 中国石油化工股份有限公司 核壳型芳烃转化催化剂及其制备方法和用途

Also Published As

Publication number Publication date
KR101858310B1 (ko) 2018-05-15
JP2015507591A (ja) 2015-03-12
CN103958411A (zh) 2014-07-30
EP2785645A1 (fr) 2014-10-08
US8900547B2 (en) 2014-12-02
EP2785645B1 (fr) 2017-06-14
US20130144100A1 (en) 2013-06-06
CA2855875A1 (fr) 2013-06-06
JP5990594B2 (ja) 2016-09-14
WO2013081994A1 (fr) 2013-06-06
BR112014012577A2 (pt) 2017-06-06
CN103958411B (zh) 2016-08-24
KR20140108665A (ko) 2014-09-12
CA2855875C (fr) 2018-08-14

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