SE8102878L - PROCEDURE FOR PERFLUORING THE CYCLIC PULP - Google Patents

PROCEDURE FOR PERFLUORING THE CYCLIC PULP

Info

Publication number
SE8102878L
SE8102878L SE8102878A SE8102878A SE8102878L SE 8102878 L SE8102878 L SE 8102878L SE 8102878 A SE8102878 A SE 8102878A SE 8102878 A SE8102878 A SE 8102878A SE 8102878 L SE8102878 L SE 8102878L
Authority
SE
Sweden
Prior art keywords
fluorinated
polycyclic
fluorination
perfluorination
perfluorinated
Prior art date
Application number
SE8102878A
Other languages
Swedish (sv)
Other versions
SE448371B (en
Inventor
R E Moore
Original Assignee
Suntech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suntech filed Critical Suntech
Publication of SE8102878L publication Critical patent/SE8102878L/en
Publication of SE448371B publication Critical patent/SE448371B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C23/00—Compounds containing at least one halogen atom bound to a ring other than a six-membered aromatic ring
    • C07C23/18—Polycyclic halogenated hydrocarbons
    • C07C23/20—Polycyclic halogenated hydrocarbons with condensed rings none of which is aromatic
    • C07C23/38—Polycyclic halogenated hydrocarbons with condensed rings none of which is aromatic with three condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C23/00—Compounds containing at least one halogen atom bound to a ring other than a six-membered aromatic ring
    • C07C23/18—Polycyclic halogenated hydrocarbons
    • C07C23/20—Polycyclic halogenated hydrocarbons with condensed rings none of which is aromatic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C23/00—Compounds containing at least one halogen atom bound to a ring other than a six-membered aromatic ring
    • C07C23/18—Polycyclic halogenated hydrocarbons
    • C07C23/20—Polycyclic halogenated hydrocarbons with condensed rings none of which is aromatic
    • C07C23/32—Polycyclic halogenated hydrocarbons with condensed rings none of which is aromatic with a bicyclo ring system containing eight carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Paper (AREA)

Abstract

A process for the preparation of perfluorinated, polycyclic hydrocarbons in which, as starting material, partially fluorinated, non-aromatisable, polycyclic hydrocarbons are employed and are fluorinated in the gas phase by means of cobalt trifluoride in a two-step process. In the first step of the gas-phase fluorination, the temperature is not more than 50 DEG C above the boiling point of the fluorinated material, and the degree of fluorination, based on the perfluorination, is not more than 75 - 95%. In the second step, the fluorination is continued at a higher temperature to give the perfluorinated, polycyclic hydrocarbon. In this way, a perfluorination is successfully carried out without the cyclic structure of the polycyclic hydrocarbon being opened. The partially fluorinated starting material can be prepared by fluorinating an optionally partially chlorinated or brominated polycyclic hydrocarbon or a derivative thereof containing carbonyl groups, carboxyl groups or hydroxyl groups in the liquid phase.

Claims (2)

PATENTKRAV 1. FArfarande fir perfluorering av icke-aromatiserbara polycykliska kolvdten, kAnnetecknat av att man:CLAIMS 1. A process for perfluorination of non-aromatizable polycyclic pistons, characterized in that: 1. fluorerar ett partiellt fluorerat polycykliskt kol- vAte i Angfas med CoF3 i en reaktionszon vid en temperatur, corn ar hogst ca °C leer kokpunkten fir det fluorerado materialet, till bildning av ett higfluorerat material med en fluoreringsgrad son motsvarar bigot Cu 75-955 av perfluorering; och1. fluorinates a partially fluorinated polycyclic carbonate in Angfas with CoF3 in a reaction zone at a temperature of at most about ° C below the boiling point of the fluorinated material, to form a highly fluorinated material with a degree of fluorination corresponding to bigot Cu 75-955 of perfluorination; and 2. utvinner och recirkulerar nAmnda higfluorerade mate- rial till namnda reaktionszon och bringdr del i my kontakt med CoF3 ± angfas rid temperaturer, son it ca 100°C higre An de corn first anvAndes, till bildning av Ott i huvudsak perfluorerat polycykliskt kolvAte.2. extracts and recycles said high-fluorinated material to said reaction zone and brings part of my contact with CoF3 ± angfas rid temperatures, son it about 100 ° C higher than the corn first used, to form Ott's mainly perfluorinated polycyclic carbonate.
SE8102878A 1977-02-25 1981-05-07 PROCEDURE FOR PERFLUORING THE NON-AROMATIZABLE POLYCYCLIC CULVET SE448371B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US77187377A 1977-02-25 1977-02-25

Publications (2)

Publication Number Publication Date
SE8102878L true SE8102878L (en) 1981-05-07
SE448371B SE448371B (en) 1987-02-16

Family

ID=25093219

Family Applications (2)

Application Number Title Priority Date Filing Date
SE7802153A SE428206B (en) 1977-02-25 1978-02-24 PROCEDURE FOR PERFLUORING THE NON-AROMATIZABLE POLYCYCLIC CULVET
SE8102878A SE448371B (en) 1977-02-25 1981-05-07 PROCEDURE FOR PERFLUORING THE NON-AROMATIZABLE POLYCYCLIC CULVET

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SE7802153A SE428206B (en) 1977-02-25 1978-02-24 PROCEDURE FOR PERFLUORING THE NON-AROMATIZABLE POLYCYCLIC CULVET

Country Status (13)

Country Link
JP (1) JPS53116359A (en)
BE (1) BE864328A (en)
CA (1) CA1122597A (en)
CH (1) CH637910A5 (en)
DE (1) DE2808112A1 (en)
DK (1) DK84878A (en)
FI (1) FI69831C (en)
FR (1) FR2381732A1 (en)
GB (1) GB1597914A (en)
IT (1) IT1095441B (en)
NL (1) NL7802145A (en)
NO (2) NO153607C (en)
SE (2) SE428206B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5821628A (en) * 1981-07-29 1983-02-08 Dainippon Ink & Chem Inc Norbornadiene derivative and its preparation
EP0271272B1 (en) * 1986-12-01 1992-04-15 Tokuyama Corporation Process for preparation of perfluoro organic compounds
JP2010215524A (en) * 2009-03-13 2010-09-30 Fujifilm Corp Fluorobicyclo[2.2.2]octane compound, method for producing the same, and use thereof
JP2010215523A (en) * 2009-03-13 2010-09-30 Fujifilm Corp Fluorobicyclo[2.2.2]-2-octene compound, method for producing the same, and use thereof
RU2451006C1 (en) * 2011-05-05 2012-05-20 Общество с ограниченной ответственностью "ГалоПолимер Кирово-Чепецк" (ООО "ГалоПолимер Кирово-Чепецк") Method of producing perfluorocycloalkanes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3641167A (en) * 1965-03-17 1972-02-08 Sun Oil Co Highly fluorinated alkyladamantanes
US4041086A (en) * 1972-02-07 1977-08-09 Sun Ventures, Inc. Process of manufacture of flourinated alkyladamantanes

Also Published As

Publication number Publication date
SE428206B (en) 1983-06-13
FI69831B (en) 1985-12-31
JPS6254088B2 (en) 1987-11-13
NO153607B (en) 1986-01-13
FR2381732B1 (en) 1983-11-25
NO153965C (en) 1986-06-25
NO780651L (en) 1978-08-28
BE864328A (en) 1978-08-28
NO153607C (en) 1986-04-23
DE2808112C2 (en) 1989-04-27
FR2381732A1 (en) 1978-09-22
FI780610A (en) 1978-08-26
SE7802153L (en) 1978-08-26
FI69831C (en) 1986-05-26
NL7802145A (en) 1978-08-29
GB1597914A (en) 1981-09-16
NO153965B (en) 1986-03-17
JPS53116359A (en) 1978-10-11
DE2808112A1 (en) 1978-08-31
CA1122597A (en) 1982-04-27
IT7820651A0 (en) 1978-02-24
CH637910A5 (en) 1983-08-31
IT1095441B (en) 1985-08-10
DK84878A (en) 1978-08-26
SE448371B (en) 1987-02-16
NO841238L (en) 1978-08-28

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