SA519401394B1 - مكون محفز لبلمرة أوليفين، ومحفز، واستخدامه - Google Patents

مكون محفز لبلمرة أوليفين، ومحفز، واستخدامه

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Publication number
SA519401394B1
SA519401394B1 SA519401394A SA519401394A SA519401394B1 SA 519401394 B1 SA519401394 B1 SA 519401394B1 SA 519401394 A SA519401394 A SA 519401394A SA 519401394 A SA519401394 A SA 519401394A SA 519401394 B1 SA519401394 B1 SA 519401394B1
Authority
SA
Saudi Arabia
Prior art keywords
catalyst
olefin polymerization
catalyst component
formula
electron donor
Prior art date
Application number
SA519401394A
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English (en)
Inventor
لي تشانجزيو
ما تشانجيو
وانج جون
هو جيانجون
شين جيانهوا
ما جيزينج
ما جينج
زهانج زهيهوي
كاي زياوزيا
جاو مينجزهي
ليو هايتاو
Original Assignee
بكين ريسيرتش انستيتيوت اوف كيميكال اندستري، تشاينا بتروليم آند كيميكال كوربوريشن
تشاينا بيتروليم آند كيميكالز كوربوريشن
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201610846996.7A external-priority patent/CN107868147B/zh
Priority claimed from CN201610847666.XA external-priority patent/CN107868150B/zh
Priority claimed from CN201610846984.4A external-priority patent/CN107868152B/zh
Priority claimed from CN201610847648.1A external-priority patent/CN107868148B/zh
Application filed by بكين ريسيرتش انستيتيوت اوف كيميكال اندستري، تشاينا بتروليم آند كيميكال كوربوريشن, تشاينا بيتروليم آند كيميكالز كوربوريشن filed Critical بكين ريسيرتش انستيتيوت اوف كيميكال اندستري، تشاينا بتروليم آند كيميكال كوربوريشن
Publication of SA519401394B1 publication Critical patent/SA519401394B1/ar

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

يتعلق الاختراع الحالي بمكون محفز لبلمرة الأوليفين catalyst component for olefin polymerization. يشتمل مكون المحفز على المغنيسيوم magnesium والتيتانيوم titanium والهالوجين halogen ومانح داخلي للإلكترون internal electron donor. يتضمن مانح الإلكترون الداخلي مركب إيمين imine له مجموعة كيتون ketone كما هو موضح في الصيغة I. الصيغة I تم الكشف أيضاً عن طريقة لتحضير المكون المحفز، ومحفز لبلمرة الأوليفين catalyst for olefin polymerization يحتوي على مكون المحفز. عندما يتم استخدام المحفز في تفاعل بلمرة الأوليفين olefin polymerization reaction وخاصة تفاعل بلمرة البروبين propene polymerization reaction ، حيث يكون للمحفز نشاط عالي طويل الأمد واستجابة جيدة للهيدروجين hydrogen ، ويكون للبوليمر polymer الذي تم الحصول عليه خصائص بمؤشر متماثل الترتيب قابل للتعديل وتوزيع للوزن الجزيئي واسع نسبيا.
SA519401394A 2016-09-23 2019-03-23 مكون محفز لبلمرة أوليفين، ومحفز، واستخدامه SA519401394B1 (ar)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN201610846996.7A CN107868147B (zh) 2016-09-23 2016-09-23 一种用于烯烃聚合的催化剂组分、催化剂及其应用
CN201610847666.XA CN107868150B (zh) 2016-09-23 2016-09-23 一种用于烯烃聚合的催化剂组分、催化剂及其应用
CN201610846984.4A CN107868152B (zh) 2016-09-23 2016-09-23 一种用于烯烃聚合的催化剂组分、催化剂及其应用
CN201610847648.1A CN107868148B (zh) 2016-09-23 2016-09-23 一种用于烯烃聚合的催化剂组分、催化剂及其应用
PCT/CN2017/103045 WO2018054363A1 (zh) 2016-09-23 2017-09-22 用于烯烃聚合的催化剂组分、催化剂及其应用

Publications (1)

Publication Number Publication Date
SA519401394B1 true SA519401394B1 (ar) 2022-04-13

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Country Status (9)

Country Link
US (1) US10662268B2 (ar)
EP (1) EP3517553B1 (ar)
JP (1) JP7178992B2 (ar)
KR (1) KR102397320B1 (ar)
ES (1) ES2969670T3 (ar)
FI (1) FI3517553T3 (ar)
RU (1) RU2758673C2 (ar)
SA (1) SA519401394B1 (ar)
WO (1) WO2018054363A1 (ar)

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CN112759677B (zh) * 2019-10-21 2023-08-15 中国石油化工股份有限公司 一种用于烯烃聚合的固体催化剂组分、催化剂及其应用
CN112759673B (zh) * 2019-10-21 2023-02-28 中国石油化工股份有限公司 一种烯烃聚合用催化剂、催化剂组分及其应用
CN114478855B (zh) * 2020-10-26 2023-10-10 中国石油化工股份有限公司 用于制备烯烃聚合催化剂组分的组合物及烯烃聚合催化剂组分

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RU2758673C2 (ru) 2021-11-01
EP3517553A4 (en) 2020-05-13
EP3517553B1 (en) 2023-11-08
WO2018054363A1 (zh) 2018-03-29
JP2019529655A (ja) 2019-10-17
KR20190057339A (ko) 2019-05-28
JP7178992B2 (ja) 2022-11-28
KR102397320B1 (ko) 2022-05-11
FI3517553T3 (fi) 2024-02-02
ES2969670T3 (es) 2024-05-21
US20190256623A1 (en) 2019-08-22
RU2019111854A (ru) 2020-10-23
US10662268B2 (en) 2020-05-26
EP3517553A1 (en) 2019-07-31
RU2019111854A3 (ar) 2020-11-23

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