RU95117121A - Катализатор окисления, способ его получения (варианты), способ получения оксимов, способ гидроксилирования ароматических углеводородов, каталитический способ окисления углеводородов - Google Patents
Катализатор окисления, способ его получения (варианты), способ получения оксимов, способ гидроксилирования ароматических углеводородов, каталитический способ окисления углеводородовInfo
- Publication number
- RU95117121A RU95117121A RU95117121/04A RU95117121A RU95117121A RU 95117121 A RU95117121 A RU 95117121A RU 95117121/04 A RU95117121/04 A RU 95117121/04A RU 95117121 A RU95117121 A RU 95117121A RU 95117121 A RU95117121 A RU 95117121A
- Authority
- RU
- Russia
- Prior art keywords
- preparing
- oxidation
- catalysts
- versions
- aromatic compounds
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
- C07C249/08—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reaction of hydroxylamines with carbonyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/32—Oximes
- C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
- C07C251/44—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups being part of a ring other than a six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Изобретение относится к новым катализаторам окисления, а также к способу их получения и применению. Эти новые катализаторы окисления содержат кристаллизованные in situ на активном угле или оксидах металлов силикалиты титана. Содержание силикалита титана предпочтительно составляют 30-60 масс. %. Атомное соотношение Si/Ti в нанесенной на носитель фазе составляет 10-100. Эти катализаторы пригодны в особенности для реакций окисления с помощью НОв мягких условиях, т.е. при температурах 20-120С и давлениях, которые равны или выше, чем атмосферное давление.
Claims (1)
- Изобретение относится к новым катализаторам окисления, а также к способу их получения и применению. Эти новые катализаторы окисления содержат кристаллизованные in situ на активном угле или оксидах металлов силикалиты титана. Содержание силикалита титана предпочтительно составляют 30-60 масс. %. Атомное соотношение Si/Ti в нанесенной на носитель фазе составляет 10-100. Эти катализаторы пригодны в особенности для реакций окисления с помощью Н2О2 в мягких условиях, т.е. при температурах 20-120oС и давлениях, которые равны или выше, чем атмосферное давление.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4240691A DE4240691C2 (de) | 1992-12-03 | 1992-12-03 | Verfahren zur Herstellung von Oximen |
DE4240692A DE4240692C2 (de) | 1992-12-03 | 1992-12-03 | Oxidationskatalysator aus auf Aktivkohle geträgertem Titansilikalit |
DEP4240692.7 | 1992-12-03 | ||
DEP4240693.5 | 1992-12-03 | ||
DE19924240698 DE4240698C2 (de) | 1992-12-03 | 1992-12-03 | Verfahren zur Herstellung von Oximen |
DEP4240698.6 | 1992-12-03 | ||
DEP4240691.9 | 1992-12-03 | ||
DE19924240693 DE4240693C2 (de) | 1992-12-03 | 1992-12-03 | Oxidationskatalysator auf der Basis eines Titansilikalits und Verfahren zu dessen Herstellung |
PCT/DE1993/001117 WO1994012277A1 (de) | 1992-12-03 | 1993-11-24 | Oxidationskatalysatoren |
Publications (2)
Publication Number | Publication Date |
---|---|
RU95117121A true RU95117121A (ru) | 1997-06-10 |
RU2107545C1 RU2107545C1 (ru) | 1998-03-27 |
Family
ID=27435648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU95117121A RU2107545C1 (ru) | 1992-12-03 | 1993-11-24 | Катализатор окисления, способ его получения (варианты), способ получения оксимов, способ гидроксилирования ароматических углеводородов и каталитический способ окисления углеводородов |
Country Status (17)
Country | Link |
---|---|
US (1) | US5736479A (ru) |
EP (1) | EP0671977B1 (ru) |
JP (1) | JPH08504125A (ru) |
KR (1) | KR950704044A (ru) |
CN (1) | CN1042101C (ru) |
AT (1) | ATE143831T1 (ru) |
AU (1) | AU671336B2 (ru) |
BR (1) | BR9307586A (ru) |
CA (1) | CA2149894C (ru) |
CZ (1) | CZ114495A3 (ru) |
DE (1) | DE59304146D1 (ru) |
FI (1) | FI952716A (ru) |
HU (1) | HU214200B (ru) |
PL (1) | PL173731B1 (ru) |
RO (1) | RO113812B1 (ru) |
RU (1) | RU2107545C1 (ru) |
WO (1) | WO1994012277A1 (ru) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5453511A (en) * | 1993-12-23 | 1995-09-26 | Arco Chemical Technology, L.P. | Bis-piperidinium compounds |
US5354875A (en) * | 1993-12-23 | 1994-10-11 | Uop | Epoxidation of olefins using a titania-supported titanosilicate |
BE1010716A3 (fr) * | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs de type silicalite au titane. |
DE19731627A1 (de) * | 1997-07-23 | 1999-01-28 | Degussa | Granulate, enthaltend Titansilikalit-l |
GB2331071A (en) * | 1997-11-11 | 1999-05-12 | Solvay | Manufacture of micro spherical zeolite containing catalyst particles |
KR20020043946A (ko) * | 2000-12-05 | 2002-06-12 | 이근석 | 산화 촉매 및 그 제조방법, 그 산화 촉매를 재활용하는방법 및 그 산화 촉매를 이용한 폐수 처리 방법 |
JP4574348B2 (ja) | 2002-05-31 | 2010-11-04 | 中國石油化工股▲分▼有限公司 | カルボニル化合物のアンモオキシム化法 |
TWI324990B (en) * | 2002-06-28 | 2010-05-21 | Sumitomo Chemical Co | Method for producing cyclohexanone oxime |
JP4534428B2 (ja) * | 2003-04-09 | 2010-09-01 | 住友化学株式会社 | シクロヘキサノンオキシムの製造方法 |
CN100390159C (zh) * | 2003-11-28 | 2008-05-28 | 大连理工大学 | 用氢气和氧气的等离子体进行丙烯环氧化的装置和方法 |
JP4552435B2 (ja) * | 2003-12-22 | 2010-09-29 | 住友化学株式会社 | オキシムの製造方法 |
ITMI20042169A1 (it) * | 2004-11-12 | 2005-02-12 | Polimeri Europa Spa | Processo continuo per la preparazione di fenolo da benzene in reattore a letto fisso |
CN100443177C (zh) * | 2005-01-31 | 2008-12-17 | 中国石油化工股份有限公司 | 一种乙苯氧化脱氢催化剂 |
CN101371989B (zh) * | 2007-08-22 | 2010-09-22 | 中国石油化工股份有限公司 | 一种钛硅分子筛催化剂及其制备方法和应用 |
MX2010010523A (es) * | 2008-03-26 | 2011-11-02 | Auterra Inc | Catalizadores de sulfaoxidación y métodos y sistemas para usar los mismos. |
CN101759530B (zh) * | 2008-12-25 | 2015-07-29 | 中国石油化工股份有限公司 | 一种苯二酚的制备方法 |
CN114669325B (zh) * | 2022-04-19 | 2023-07-18 | 清华大学 | 一种负载型ts-1催化剂的制备方法及其应用 |
CN115957736A (zh) * | 2022-12-27 | 2023-04-14 | 胜华新能源科技(东营)有限公司 | 一种复合催化剂及其制备方法和应用 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4163756A (en) * | 1978-04-11 | 1979-08-07 | Allied Chemical Corporation | Direct oximation of ketones |
US4225511A (en) * | 1978-04-11 | 1980-09-30 | Allied Chemical Corporation | Direct oximation of ketones using gallia catalysts |
IT1127311B (it) * | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
US4281194A (en) * | 1980-02-28 | 1981-07-28 | Allied Chemical Corporation | Process for ammoximation of cyclohexanone |
IT1150699B (it) * | 1982-03-19 | 1986-12-17 | Anic Spa | Procedimento per la ossidrilazione di idrocarburi aromatici |
IT1152301B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'ossidazione di composti vinilbenzenici a beta-feniladeidi |
IT1152298B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'ossidazione di alcooli ad aldeidi e/o chetoni |
IT1152296B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per la sintesi di monometileteri dei glicoli |
IT1152299B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'espossidazione di composti olefinici |
IT1184316B (it) * | 1985-02-05 | 1987-10-28 | Enichem Sintesi | Procedimento per la monoepossidazione di composti contenenti due doppi legami |
IT1214622B (it) * | 1985-07-10 | 1990-01-18 | Montedipe Spa | Processo catalitico per laproduzione di cicloesanonossima. |
IT1207519B (it) * | 1985-12-19 | 1989-05-25 | Eniricerche Spa | Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio. |
JPH0610181B2 (ja) * | 1986-11-14 | 1994-02-09 | モンテデイペ・ソチエタ・ペル・アツイオニ | オキシム製造のための接触方法 |
IT1222022B (it) * | 1987-07-14 | 1990-08-31 | Montedipe Spa | Metodo per la preparazione di un catalizzatore per l' ammossimazione di composti carbonilici |
IT1222868B (it) * | 1987-10-12 | 1990-09-12 | Montedipe Spa | Metodo per la preparazione di titanio silicaliti |
US4800187A (en) * | 1987-10-28 | 1989-01-24 | Corning Glass Works | Method of crystallizing a zeolite on the surface of a monolithic ceramic substrate |
FR2622574B1 (fr) * | 1987-10-29 | 1990-02-23 | Rhone Poulenc Chimie | Procede d'hydroxylation de phenols et d'ethers de phenols |
US5254746A (en) * | 1987-10-29 | 1993-10-19 | Rhone-Poulenc Chimie | Hydroxylation of phenols/phenol ethers |
IT1217899B (it) * | 1988-06-23 | 1990-03-30 | Montedipe Spa | Processo catalitico per la produzione di ossime |
IT1243772B (it) * | 1990-08-01 | 1994-06-28 | Eniricerche Spa | Procedimento per l'ossidazione di composti paraffinici con ossigeno |
JPH05105420A (ja) * | 1991-03-29 | 1993-04-27 | Ngk Insulators Ltd | ゼオライト結晶体の合成膜およびその製造方法 |
US5214168A (en) * | 1992-04-30 | 1993-05-25 | Arco Chemical Technology, L.P. | Integrated process for epoxide production |
-
1993
- 1993-11-24 JP JP6512646A patent/JPH08504125A/ja active Pending
- 1993-11-24 US US08/436,409 patent/US5736479A/en not_active Expired - Fee Related
- 1993-11-24 HU HU9501616A patent/HU214200B/hu not_active IP Right Cessation
- 1993-11-24 PL PL93309252A patent/PL173731B1/pl unknown
- 1993-11-24 CA CA002149894A patent/CA2149894C/en not_active Expired - Fee Related
- 1993-11-24 RU RU95117121A patent/RU2107545C1/ru active
- 1993-11-24 AU AU55594/94A patent/AU671336B2/en not_active Ceased
- 1993-11-24 WO PCT/DE1993/001117 patent/WO1994012277A1/de not_active Application Discontinuation
- 1993-11-24 CZ CZ951144A patent/CZ114495A3/cs unknown
- 1993-11-24 RO RO95-00976A patent/RO113812B1/ro unknown
- 1993-11-24 DE DE59304146T patent/DE59304146D1/de not_active Expired - Fee Related
- 1993-11-24 AT AT94900719T patent/ATE143831T1/de not_active IP Right Cessation
- 1993-11-24 EP EP94900719A patent/EP0671977B1/de not_active Expired - Lifetime
- 1993-11-24 KR KR1019950702289A patent/KR950704044A/ko not_active Application Discontinuation
- 1993-11-24 BR BR9307586-3A patent/BR9307586A/pt not_active IP Right Cessation
- 1993-12-02 CN CN93121650A patent/CN1042101C/zh not_active Expired - Fee Related
-
1995
- 1995-06-02 FI FI952716A patent/FI952716A/fi unknown
Also Published As
Publication number | Publication date |
---|---|
FI952716A0 (fi) | 1995-06-02 |
FI952716A (fi) | 1995-06-02 |
HU9501616D0 (en) | 1995-08-28 |
WO1994012277A1 (de) | 1994-06-09 |
US5736479A (en) | 1998-04-07 |
ATE143831T1 (de) | 1996-10-15 |
RO113812B1 (ro) | 1998-11-30 |
JPH08504125A (ja) | 1996-05-07 |
PL309252A1 (en) | 1995-10-02 |
RU2107545C1 (ru) | 1998-03-27 |
BR9307586A (pt) | 1999-08-31 |
CA2149894C (en) | 1999-04-27 |
HUT72816A (en) | 1996-05-28 |
KR950704044A (ko) | 1995-11-17 |
PL173731B1 (pl) | 1998-04-30 |
AU5559494A (en) | 1994-06-22 |
CZ114495A3 (en) | 1995-12-13 |
EP0671977B1 (de) | 1996-10-09 |
DE59304146D1 (de) | 1996-11-14 |
AU671336B2 (en) | 1996-08-22 |
HU214200B (hu) | 1998-01-28 |
CN1097151A (zh) | 1995-01-11 |
EP0671977A1 (de) | 1995-09-20 |
CA2149894A1 (en) | 1994-06-09 |
CN1042101C (zh) | 1999-02-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU95117121A (ru) | Катализатор окисления, способ его получения (варианты), способ получения оксимов, способ гидроксилирования ароматических углеводородов, каталитический способ окисления углеводородов | |
EP1402948A4 (en) | CATALYST FOR THE HYDROGEN TREATMENT OF GAS OIL, METHOD FOR THE PRODUCTION THEREOF AND METHOD FOR THE HYDROGENATION OF GAS OIL | |
RU93004628A (ru) | Способ активации предшественников катализаторов дегидрирования с2-с5 парафинов, каталитическая композиция, активированная этим способом, и ее применение для дегидрирования с2-с5-парафинов | |
CN86107489A (zh) | 有载体金属催化剂及其应用方法 | |
KR950702514A (ko) | 몰리브덴을 함유하는 촉매를 사용하여 부타디엔을 스티렌, 에텔벤젠 또는 이들 둘 다로 전환시키는 방법(Process for converting butadiene to styrene or ethylbenzene or both using catalysts containing molybdenum) | |
WO2000013789A8 (de) | Keramischer katalysator zur selektiven zersetzung von n2o und verfahren zu dessen herstellung | |
AU4702297A (en) | Fischer-tropsch catalyst and process for preparing hydrocarbons | |
NL1015329C2 (nl) | Massa voor het verwijderen van arseen en kwik uit koolwaterstoffen op basis van op een drager aangebracht nikkel. | |
Shouro et al. | Characterization of active sites working on FSM-16 during the vapor-phase Beckmann rearrangement of cyclohexanone oxime | |
DE69622054D1 (de) | Verfahren zum aktivieren von halogenierten trägerkatalysatoren | |
JPH10506366A (ja) | アンモニア又は相応するアミン、水素及び酸素からヒドロキシルアミンを製造する方法 | |
AU2002350847A1 (en) | Method for catalytic decomposition of organic hydroperoxides | |
AU1777292A (en) | Non-selective oxidation catalyst and method of preparation | |
JPH04219139A (ja) | 炭化水素複分解反応用触媒 | |
JP3485622B2 (ja) | アンモニア合成触媒およびアンモニア合成方法 | |
FI913439A0 (fi) | Metateskatalysator foer olefiner. | |
MY119867A (en) | Hydroperoxide decomposition process | |
MXPA02010372A (es) | Procedimiento para activacion de catalizador para la hidroxilacion de aromaticos. | |
Takahashi et al. | 27-P-16-Effect of oxygen concentration on catalyst deactivation rate in vapor phase beckmann rearrangement over acid catalysts | |
Wilkenhöner et al. | 27-P-17-On the role of the titanium active site in the phenol/anisole hydroxylation over titanium substituted crystalline silicates | |
ES2090839T3 (es) | Preparacion de 8-hidroxicimeno por deshidrogenacion. | |
KR20010005583A (ko) | 배향된 산화몰리브덴으로부터 제조된 변성 옥시탄화몰리브덴계 촉매 및 이를 제조하는 방법 | |
Valente et al. | 27-P-15-Liquid-phase oxidation of cyclohexane in the presence of chromium and iron ETS-10 materials | |
SU1341830A1 (ru) | Способ активации катализатора для гидрогенизации, изомеризации и гидрокрекинга углеводородов | |
JPH08257362A (ja) | 芳香族カルボン酸の製造に際して生成する排ガスの処理方法 |