RU94006017A - Способ карбонилирования аллиловых бутенолов и их сложных эфиров - Google Patents
Способ карбонилирования аллиловых бутенолов и их сложных эфировInfo
- Publication number
- RU94006017A RU94006017A RU94006017/04A RU94006017A RU94006017A RU 94006017 A RU94006017 A RU 94006017A RU 94006017/04 A RU94006017/04 A RU 94006017/04A RU 94006017 A RU94006017 A RU 94006017A RU 94006017 A RU94006017 A RU 94006017A
- Authority
- RU
- Russia
- Prior art keywords
- carbonylation
- carbon monoxide
- butenols
- allyl
- complex esters
- Prior art date
Links
- 238000005810 carbonylation reaction Methods 0.000 title claims 2
- 150000002148 esters Chemical class 0.000 title claims 2
- -1 ALLYL Chemical class 0.000 title 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N Adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 2
- 229910052741 iridium Inorganic materials 0.000 claims 2
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- UIUWNILCHFBLEQ-UHFFFAOYSA-N pent-3-enoic acid Chemical compound CC=CCC(O)=O UIUWNILCHFBLEQ-UHFFFAOYSA-N 0.000 claims 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N pentenoic acid group Chemical class C(C=CCC)(=O)O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Claims (1)
- Настоящее изобретение касается карбонилирования с помощью моноокиси углерода аллиловых бутенолов и/или их сложных карбоновых эфиров. Оно состоит во взаимодействии моноокиси углерода с по меньшей мере одним из названных аллиловых бутенолов и карбоновых сложных эфиров при повышенной температуре под давлением, которое выше атмосферного давления, в присутствии иридиевого катализатора и иодистого или бромистого промотора, молярное отношение промотор/иридий заключается между 0,1/1 и 20/1. Этот способ позволяет получать пентенойные кислоты, в частности 3-пентенойную кислоту, которая может быть гидроксикарбонилирована моноокисью углерода и водой до адипиновой кислоты.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9302482 | 1993-02-26 | ||
| FR9302482A FR2701945B1 (fr) | 1993-02-26 | 1993-02-26 | Procédé de carbonylation des buténols allyliques et de leurs esters. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU94006017A true RU94006017A (ru) | 1995-09-27 |
| RU2118309C1 RU2118309C1 (ru) | 1998-08-27 |
Family
ID=9444631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU94006017A RU2118309C1 (ru) | 1993-02-26 | 1994-02-25 | Способ карбонилирования аллиловых бутенолов и/или их сложных эфиров |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US5380938A (ru) |
| EP (1) | EP0612713B1 (ru) |
| JP (1) | JP2552248B2 (ru) |
| KR (1) | KR0145239B1 (ru) |
| CN (1) | CN1041304C (ru) |
| BR (1) | BR9400669A (ru) |
| CA (1) | CA2116501C (ru) |
| CZ (1) | CZ287699B6 (ru) |
| DE (1) | DE69403831T2 (ru) |
| ES (1) | ES2104318T3 (ru) |
| FR (1) | FR2701945B1 (ru) |
| MX (1) | MX9401360A (ru) |
| PL (1) | PL175552B1 (ru) |
| RU (1) | RU2118309C1 (ru) |
| SG (1) | SG43093A1 (ru) |
| SK (1) | SK281592B6 (ru) |
| TW (1) | TW264469B (ru) |
| UA (1) | UA29412C2 (ru) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2730225B1 (fr) * | 1995-02-02 | 1997-04-11 | Rhone Poulenc Chimie | Procede de preparation d'iodures d'iridium et leur utilisation comme catalyseurs |
| GB0222618D0 (en) * | 2002-09-30 | 2002-11-06 | Bp Chem Int Ltd | Process |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3427344A (en) * | 1963-07-29 | 1969-02-11 | Jiro Tsuji | Process for the manufacture of unsaturated carboxylic acid esters |
| CA1026355A (en) * | 1972-04-12 | 1978-02-14 | Hoechst Aktiengesellschaft | PROCESS FOR THE MANUFACTURE OF VINYL ACETIC ACID AND OPTIONALLY OF .alpha.-BUTYROLACTONE |
| US4000170A (en) * | 1974-07-29 | 1976-12-28 | Monsanto Company | Production of carboxylic acids by controlling the active form of iridium catalyst in response to infrared absorption spectra |
| DE3544765C2 (de) * | 1985-12-18 | 1994-04-07 | Roehm Gmbh | Verfahren zur Herstellung von ungesättigten aliphatischen Carbonsäureanhydriden |
| GB9002491D0 (en) * | 1990-02-05 | 1990-04-04 | Shell Int Research | Carbonylation catalyst system |
| US5166421A (en) * | 1991-03-18 | 1992-11-24 | E. I. Du Pont De Nemours And Company | Process for the manufacture of adipic acid |
-
1993
- 1993-02-26 FR FR9302482A patent/FR2701945B1/fr not_active Expired - Fee Related
-
1994
- 1994-02-10 UA UA94005087A patent/UA29412C2/ru unknown
- 1994-02-10 DE DE69403831T patent/DE69403831T2/de not_active Expired - Fee Related
- 1994-02-10 EP EP94420043A patent/EP0612713B1/fr not_active Expired - Lifetime
- 1994-02-10 ES ES94420043T patent/ES2104318T3/es not_active Expired - Lifetime
- 1994-02-10 SG SG1996003484A patent/SG43093A1/en unknown
- 1994-02-23 MX MX9401360A patent/MX9401360A/es not_active IP Right Cessation
- 1994-02-24 CZ CZ1994421A patent/CZ287699B6/cs not_active IP Right Cessation
- 1994-02-24 US US08/201,020 patent/US5380938A/en not_active Expired - Lifetime
- 1994-02-24 BR BR9400669A patent/BR9400669A/pt not_active IP Right Cessation
- 1994-02-24 SK SK220-94A patent/SK281592B6/sk unknown
- 1994-02-24 PL PL94302363A patent/PL175552B1/pl not_active IP Right Cessation
- 1994-02-25 JP JP6051109A patent/JP2552248B2/ja not_active Expired - Fee Related
- 1994-02-25 RU RU94006017A patent/RU2118309C1/ru not_active IP Right Cessation
- 1994-02-25 CN CN94102517A patent/CN1041304C/zh not_active Expired - Fee Related
- 1994-02-25 CA CA002116501A patent/CA2116501C/fr not_active Expired - Fee Related
- 1994-02-26 KR KR1019940003593A patent/KR0145239B1/ko not_active IP Right Cessation
- 1994-03-30 TW TW083102740A patent/TW264469B/zh active
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