RU2742275C1 - Радикальная полимеризация этилена, инициируемая парой высокопроизводительных органических пероксидов - Google Patents
Радикальная полимеризация этилена, инициируемая парой высокопроизводительных органических пероксидов Download PDFInfo
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- RU2742275C1 RU2742275C1 RU2018107561A RU2018107561A RU2742275C1 RU 2742275 C1 RU2742275 C1 RU 2742275C1 RU 2018107561 A RU2018107561 A RU 2018107561A RU 2018107561 A RU2018107561 A RU 2018107561A RU 2742275 C1 RU2742275 C1 RU 2742275C1
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- Prior art keywords
- initiator
- peroxide
- tert
- luperox
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000005977 Ethylene Substances 0.000 title claims abstract description 24
- 150000001451 organic peroxides Chemical class 0.000 title description 5
- 150000002978 peroxides Chemical class 0.000 claims abstract description 110
- 239000003999 initiator Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 43
- -1 polyethylene Polymers 0.000 claims abstract description 19
- 239000004698 Polyethylene Substances 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 claims abstract description 14
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 40
- 238000006116 polymerization reaction Methods 0.000 claims description 29
- 238000007334 copolymerization reaction Methods 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000003505 polymerization initiator Substances 0.000 claims description 8
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 238000010526 radical polymerization reaction Methods 0.000 claims description 6
- IVOIHMSMNONJSR-UHFFFAOYSA-N 2-methyl-2-[2-(2-methylbutan-2-ylperoxy)butan-2-ylperoxy]butane Chemical group CCC(C)(C)OOC(C)(CC)OOC(C)(C)CC IVOIHMSMNONJSR-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- PHIGUQOUWMSXFV-UHFFFAOYSA-N 2-methyl-2-[2-(2-methylbutan-2-ylperoxy)propan-2-ylperoxy]butane Chemical group CCC(C)(C)OOC(C)(C)OOC(C)(C)CC PHIGUQOUWMSXFV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 239000012963 UV stabilizer Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 230000000181 anti-adherent effect Effects 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000002667 nucleating agent Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000004971 Cross linker Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 5
- 229920001577 copolymer Polymers 0.000 abstract 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 86
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical group CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 57
- 238000006243 chemical reaction Methods 0.000 description 51
- 239000001294 propane Substances 0.000 description 29
- 229920001684 low density polyethylene Polymers 0.000 description 28
- 239000004702 low-density polyethylene Substances 0.000 description 27
- 239000001273 butane Substances 0.000 description 19
- 230000000977 initiatory effect Effects 0.000 description 19
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- 150000002976 peresters Chemical class 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 9
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 7
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 7
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 7
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 229940094933 n-dodecane Drugs 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CARSMBZECAABMO-UHFFFAOYSA-N 3-chloro-2,6-dimethylbenzoic acid Chemical compound CC1=CC=C(Cl)C(C)=C1C(O)=O CARSMBZECAABMO-UHFFFAOYSA-N 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- FPCCSQOGAWCVBH-UHFFFAOYSA-N ketanserin Chemical group C1=CC(F)=CC=C1C(=O)C1CCN(CCN2C(C3=CC=CC=C3NC2=O)=O)CC1 FPCCSQOGAWCVBH-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- HQOVXPHOJANJBR-UHFFFAOYSA-N 2,2-bis(tert-butylperoxy)butane Chemical compound CC(C)(C)OOC(C)(CC)OOC(C)(C)C HQOVXPHOJANJBR-UHFFFAOYSA-N 0.000 description 2
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- HCXVPNKIBYLBIT-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOOC(C)(C)C HCXVPNKIBYLBIT-UHFFFAOYSA-N 0.000 description 1
- SYXTYIFRUXOUQP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy butaneperoxoate Chemical compound CCCC(=O)OOOC(C)(C)C SYXTYIFRUXOUQP-UHFFFAOYSA-N 0.000 description 1
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 1
- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
- VKERWIBXKLNXCY-UHFFFAOYSA-N 3,5,5-trimethyl-2-(2-methylbutan-2-ylperoxy)hexanoic acid Chemical compound CCC(C)(C)OOC(C(O)=O)C(C)CC(C)(C)C VKERWIBXKLNXCY-UHFFFAOYSA-N 0.000 description 1
- KFGFVPMRLOQXNB-UHFFFAOYSA-N 3,5,5-trimethylhexanoyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(=O)CC(C)CC(C)(C)C KFGFVPMRLOQXNB-UHFFFAOYSA-N 0.000 description 1
- XYFRHHAYSXIKGH-UHFFFAOYSA-N 3-(5-methoxy-2-methoxycarbonyl-1h-indol-3-yl)prop-2-enoic acid Chemical compound C1=C(OC)C=C2C(C=CC(O)=O)=C(C(=O)OC)NC2=C1 XYFRHHAYSXIKGH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003911 antiadherent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- NICWAKGKDIAMOD-UHFFFAOYSA-N ethyl 3,3-bis(2-methylbutan-2-ylperoxy)butanoate Chemical compound CCOC(=O)CC(C)(OOC(C)(C)CC)OOC(C)(C)CC NICWAKGKDIAMOD-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012934 organic peroxide initiator Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/38—Mixtures of peroxy-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1559145 | 2015-09-29 | ||
| FR1559145A FR3041645B1 (fr) | 2015-09-29 | 2015-09-29 | Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite |
| PCT/FR2016/052470 WO2017055748A1 (fr) | 2015-09-29 | 2016-09-29 | Polymérisation radicalaire de l'éthylène amorcée par un couple de peroxydes organiques à haute productivité |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2742275C1 true RU2742275C1 (ru) | 2021-02-04 |
Family
ID=54707984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018107561A RU2742275C1 (ru) | 2015-09-29 | 2016-09-29 | Радикальная полимеризация этилена, инициируемая парой высокопроизводительных органических пероксидов |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US10189921B2 (enExample) |
| EP (1) | EP3356429B1 (enExample) |
| JP (2) | JP7018383B2 (enExample) |
| KR (1) | KR101942692B1 (enExample) |
| CN (1) | CN108026216B (enExample) |
| BR (1) | BR112017026325B1 (enExample) |
| CO (1) | CO2018002984A2 (enExample) |
| ES (1) | ES2751726T3 (enExample) |
| FR (1) | FR3041645B1 (enExample) |
| IL (1) | IL256565B (enExample) |
| MX (1) | MX362883B (enExample) |
| MY (1) | MY183260A (enExample) |
| RU (1) | RU2742275C1 (enExample) |
| SA (1) | SA518390892B1 (enExample) |
| SG (1) | SG11201802172RA (enExample) |
| WO (1) | WO2017055748A1 (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3090640B1 (fr) * | 2018-12-21 | 2021-12-31 | Arkema France | Utilisation d’au moins un hémi-peroxyacétal, seul ou association avec d’autres peroxydes, pour amorcer la polymérisation ou la copolymérisation d’éthylène sous haute pression |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2650913A (en) * | 1950-03-23 | 1953-09-01 | Monsanto Chemicals | 2, 2-bis-(tertiary butyl peroxy) butane catalyst for ethylene polymerization |
| EP0259537A2 (en) * | 1986-09-09 | 1988-03-16 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Process for reducing residual monomers in low viscosity polymer-polyols |
| RU2255095C1 (ru) * | 2004-03-09 | 2005-06-27 | Открытое акционерное общество "Ангарский завод полимеров" (ОАО АЗП) | Способ получения полиэтилена |
| FR2946653A1 (fr) * | 2009-06-15 | 2010-12-17 | Arkema France | Procede de fabrication d'une composition melange-maitre comprenant un peroxyde organique |
| WO2012107689A1 (fr) * | 2011-02-10 | 2012-08-16 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3671651A (en) * | 1968-05-07 | 1972-06-20 | Pennwalt Corp | Peroxy compounds containing a haloformate group |
| US3706818A (en) * | 1968-07-17 | 1972-12-19 | Pennwalt Corp | Processes using polyperoxides affording sequential free radical generation |
| JPS63168415A (ja) * | 1987-01-02 | 1988-07-12 | ペンウオルト・コ−ポレ−シヨン | ｔ−アルキルヒドロペルオキシドを用いたアクリル酸誘導体モノマ−の溶液重合方法 |
| DE4038625A1 (de) * | 1990-12-04 | 1992-06-11 | Basf Ag | Substanz- und suspensionspolymerisate auf der basis von methylmethacrylat |
| JP4774172B2 (ja) * | 2001-08-23 | 2011-09-14 | 化薬アクゾ株式会社 | アクリル樹脂の製造方法 |
| KR20100015430A (ko) * | 2007-03-09 | 2010-02-12 | 다우 글로벌 테크놀로지스 인크. | 저밀도 폴리에틸렌 중합체를 제조하기 위한 고압 자유라디칼 중합 방법 및 자유라디칼 개시제 시스템 |
| JP2010150352A (ja) * | 2008-12-24 | 2010-07-08 | Nof Corp | ラジカル重合型熱硬化性樹脂用硬化剤及びそれを含む成形材料 |
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2015
- 2015-09-29 FR FR1559145A patent/FR3041645B1/fr not_active Expired - Fee Related
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2016
- 2016-09-29 WO PCT/FR2016/052470 patent/WO2017055748A1/fr not_active Ceased
- 2016-09-29 MY MYPI2018000354A patent/MY183260A/en unknown
- 2016-09-29 ES ES16785243T patent/ES2751726T3/es active Active
- 2016-09-29 KR KR1020187001713A patent/KR101942692B1/ko not_active Expired - Fee Related
- 2016-09-29 BR BR112017026325-4A patent/BR112017026325B1/pt not_active IP Right Cessation
- 2016-09-29 SG SG11201802172RA patent/SG11201802172RA/en unknown
- 2016-09-29 MX MX2018002770A patent/MX362883B/es active IP Right Grant
- 2016-09-29 CN CN201680056697.1A patent/CN108026216B/zh not_active Expired - Fee Related
- 2016-09-29 RU RU2018107561A patent/RU2742275C1/ru active
- 2016-09-29 JP JP2018504156A patent/JP7018383B2/ja not_active Expired - Fee Related
- 2016-09-29 EP EP16785243.3A patent/EP3356429B1/fr active Active
- 2016-09-29 US US15/763,152 patent/US10189921B2/en active Active
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2017
- 2017-12-25 IL IL256565A patent/IL256565B/en active IP Right Grant
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2018
- 2018-02-07 SA SA518390892A patent/SA518390892B1/ar unknown
- 2018-03-21 CO CONC2018/0002984A patent/CO2018002984A2/es unknown
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2021
- 2021-01-28 JP JP2021011660A patent/JP2021088710A/ja active Pending
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| US2650913A (en) * | 1950-03-23 | 1953-09-01 | Monsanto Chemicals | 2, 2-bis-(tertiary butyl peroxy) butane catalyst for ethylene polymerization |
| EP0259537A2 (en) * | 1986-09-09 | 1988-03-16 | ATOCHEM NORTH AMERICA, INC. (a Pennsylvania corp.) | Process for reducing residual monomers in low viscosity polymer-polyols |
| RU2255095C1 (ru) * | 2004-03-09 | 2005-06-27 | Открытое акционерное общество "Ангарский завод полимеров" (ОАО АЗП) | Способ получения полиэтилена |
| FR2946653A1 (fr) * | 2009-06-15 | 2010-12-17 | Arkema France | Procede de fabrication d'une composition melange-maitre comprenant un peroxyde organique |
| WO2012107689A1 (fr) * | 2011-02-10 | 2012-08-16 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3356429B1 (fr) | 2019-09-11 |
| FR3041645A1 (fr) | 2017-03-31 |
| JP2018528292A (ja) | 2018-09-27 |
| IL256565B (en) | 2021-03-25 |
| MX362883B (es) | 2019-02-22 |
| JP2021088710A (ja) | 2021-06-10 |
| EP3356429A1 (fr) | 2018-08-08 |
| KR101942692B1 (ko) | 2019-01-25 |
| ES2751726T3 (es) | 2020-04-01 |
| KR20180063035A (ko) | 2018-06-11 |
| US20180273660A1 (en) | 2018-09-27 |
| MX2018002770A (es) | 2018-04-13 |
| MY183260A (en) | 2021-02-18 |
| WO2017055748A1 (fr) | 2017-04-06 |
| US10189921B2 (en) | 2019-01-29 |
| CN108026216A (zh) | 2018-05-11 |
| SG11201802172RA (en) | 2018-04-27 |
| JP7018383B2 (ja) | 2022-02-10 |
| BR112017026325A2 (pt) | 2018-08-21 |
| CO2018002984A2 (es) | 2018-05-31 |
| SA518390892B1 (ar) | 2023-02-28 |
| FR3041645B1 (fr) | 2017-09-08 |
| BR112017026325B1 (pt) | 2021-11-09 |
| CN108026216B (zh) | 2021-04-20 |
| IL256565A (en) | 2018-02-28 |
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