RU2689413C2 - Электрический аккумулятор и способ его изготовления - Google Patents
Электрический аккумулятор и способ его изготовления Download PDFInfo
- Publication number
- RU2689413C2 RU2689413C2 RU2017120036A RU2017120036A RU2689413C2 RU 2689413 C2 RU2689413 C2 RU 2689413C2 RU 2017120036 A RU2017120036 A RU 2017120036A RU 2017120036 A RU2017120036 A RU 2017120036A RU 2689413 C2 RU2689413 C2 RU 2689413C2
- Authority
- RU
- Russia
- Prior art keywords
- specified
- cathode
- anode
- membrane
- aluminum
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 63
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 52
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 50
- 150000002500 ions Chemical class 0.000 claims abstract description 38
- 239000012528 membrane Substances 0.000 claims abstract description 36
- 239000003792 electrolyte Substances 0.000 claims abstract description 26
- 239000012535 impurity Substances 0.000 claims abstract description 14
- 229910052738 indium Inorganic materials 0.000 claims abstract description 8
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000005275 alloying Methods 0.000 claims abstract description 7
- 239000001913 cellulose Substances 0.000 claims abstract description 7
- 229920002678 cellulose Polymers 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 29
- 229910002804 graphite Inorganic materials 0.000 claims description 24
- 239000010439 graphite Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 24
- 239000011888 foil Substances 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000011230 binding agent Substances 0.000 claims description 15
- 239000003292 glue Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000003973 paint Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000010419 fine particle Substances 0.000 claims description 6
- 229910020366 ClO 4 Inorganic materials 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000006230 acetylene black Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- ZRGUXTGDSGGHLR-UHFFFAOYSA-K aluminum;triperchlorate Chemical compound [Al+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O ZRGUXTGDSGGHLR-UHFFFAOYSA-K 0.000 claims description 4
- 239000002019 doping agent Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 239000010409 thin film Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000009736 wetting Methods 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 238000009825 accumulation Methods 0.000 claims description 3
- HXEJEQRCKJPCEQ-UHFFFAOYSA-K aluminum;2,3-dihydroxypropanoate Chemical compound [Al+3].OCC(O)C([O-])=O.OCC(O)C([O-])=O.OCC(O)C([O-])=O HXEJEQRCKJPCEQ-UHFFFAOYSA-K 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000004020 conductor Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 230000005012 migration Effects 0.000 claims description 3
- 238000013508 migration Methods 0.000 claims description 3
- 239000012466 permeate Substances 0.000 claims description 3
- 229920000767 polyaniline Polymers 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical class [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- 239000002923 metal particle Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 238000003303 reheating Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 5
- 239000003522 acrylic cement Substances 0.000 claims 2
- 238000004090 dissolution Methods 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000010292 electrical insulation Methods 0.000 claims 1
- 238000009830 intercalation Methods 0.000 claims 1
- 230000002687 intercalation Effects 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000003892 spreading Methods 0.000 claims 1
- 239000011255 nonaqueous electrolyte Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 238000004870 electrical engineering Methods 0.000 abstract 2
- 229960005150 glycerol Drugs 0.000 description 12
- 235000011187 glycerol Nutrition 0.000 description 12
- -1 aluminum ions Chemical class 0.000 description 4
- 238000004146 energy storage Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000001493 electron microscopy Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H01M4/602—Polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Cell Separators (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201414539448A | 2014-11-12 | 2014-11-12 | |
| US14/539,448 | 2014-11-12 | ||
| US14/607,429 | 2015-01-28 | ||
| US14/607,429 US9912008B2 (en) | 2013-11-12 | 2015-01-28 | Electrical energy storage device with non-aqueous electrolyte |
| PCT/CA2015/000573 WO2016074069A1 (en) | 2014-11-12 | 2015-11-12 | Electrical energy storage device with non-aqueous electrolyte |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2017120036A RU2017120036A (ru) | 2018-12-13 |
| RU2017120036A3 RU2017120036A3 (enExample) | 2019-03-28 |
| RU2689413C2 true RU2689413C2 (ru) | 2019-05-28 |
Family
ID=55953491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2017120036A RU2689413C2 (ru) | 2014-11-12 | 2015-11-12 | Электрический аккумулятор и способ его изготовления |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP3218953B1 (enExample) |
| JP (1) | JP2018501607A (enExample) |
| CN (1) | CN107112585A (enExample) |
| CA (1) | CA2967501A1 (enExample) |
| RU (1) | RU2689413C2 (enExample) |
| WO (1) | WO2016074069A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102314575B1 (ko) * | 2018-01-12 | 2021-10-20 | 주식회사 엘지에너지솔루션 | 이차전지의 충방전기 및 이를 포함하는 이차전지의 활성화 공정 장치 |
| KR102854230B1 (ko) * | 2022-09-01 | 2025-09-02 | 성균관대학교산학협력단 | 알루미늄 공기전지용 전해액 및 이를 포함하는 알루미늄 공기전지 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB728719A (en) * | 1952-06-06 | 1955-04-27 | Dry Accumulator Company Ltd | Improvements in or relating to electric storage batteries |
| RU2321922C1 (ru) * | 2004-03-29 | 2008-04-10 | Эл Джи Кем, Лтд. | Электрохимический элемент с двумя типами сепараторов |
| CN103050705A (zh) * | 2013-01-06 | 2013-04-17 | 天津市捷威动力工业有限公司 | 一种钛酸锂表涂负极及使用该种负极的锂离子电池 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1920151A (en) * | 1933-04-22 | 1933-07-25 | Ruben Samuel | Potential producing cell |
| JPS62288815A (ja) * | 1986-02-21 | 1987-12-15 | Sanyo Chem Ind Ltd | 電解液 |
| JPH0652898A (ja) * | 1992-07-30 | 1994-02-25 | Sanyo Electric Co Ltd | アルミニウム二次電池 |
| JPH09120816A (ja) * | 1995-10-26 | 1997-05-06 | Sony Corp | アルミニウム非水電解液二次電池 |
| US6409905B1 (en) * | 2000-11-13 | 2002-06-25 | Kemet Electronics Corporation | Method of and electrolyte for anodizing aluminum substrates for solid capacitors |
| AU2003280692A1 (en) * | 2002-10-31 | 2004-05-25 | Mitsubishi Chemical Corporation | Electrolyte for electrolytic capacitor, electrolytic capacitor and process for producing tetrafluoroaluminate salt of organic onium |
| US7125610B2 (en) * | 2003-03-17 | 2006-10-24 | Kemet Electronics Corporation | Capacitor containing aluminum anode foil anodized in low water content glycerine-phosphate electrolyte without a pre-anodizing hydration step |
| JP5040626B2 (ja) * | 2007-12-07 | 2012-10-03 | 三菱電機株式会社 | 電力貯蔵デバイスセルおよびその制御方法 |
| WO2011137239A1 (en) * | 2010-04-28 | 2011-11-03 | Flexel, Llc | A thin flexible electrochemical energy cell |
| US8951670B2 (en) * | 2010-06-30 | 2015-02-10 | Very Small Particle Company Limited | Adhesion of active electrode materials to metal electrode substrates |
| JP5621505B2 (ja) * | 2010-10-21 | 2014-11-12 | ソニー株式会社 | 電解質および二次電池 |
| US9166222B2 (en) * | 2010-11-02 | 2015-10-20 | Envia Systems, Inc. | Lithium ion batteries with supplemental lithium |
| JP5768967B2 (ja) * | 2011-03-07 | 2015-08-26 | 日産自動車株式会社 | リチウムイオン二次電池用負極活物質、リチウムイオン二次電池用負極及びリチウムイオン二次電池 |
| KR102133614B1 (ko) * | 2012-10-30 | 2020-07-13 | 가부시키가이샤 무라타 세이사쿠쇼 | 알루미늄 2차 전지 및 전자 기기 |
| US10084206B2 (en) * | 2013-11-12 | 2018-09-25 | Alexandre M. Iarochenko | Fast charge apparatus for a battery |
| EP3218956B1 (en) * | 2014-11-12 | 2019-08-07 | Intec Energy Storage Corp. | Fast charge apparatus for a battery |
-
2015
- 2015-11-12 EP EP15858433.4A patent/EP3218953B1/en not_active Not-in-force
- 2015-11-12 CN CN201580072753.6A patent/CN107112585A/zh active Pending
- 2015-11-12 WO PCT/CA2015/000573 patent/WO2016074069A1/en not_active Ceased
- 2015-11-12 CA CA2967501A patent/CA2967501A1/en not_active Abandoned
- 2015-11-12 RU RU2017120036A patent/RU2689413C2/ru not_active IP Right Cessation
- 2015-11-12 JP JP2017526593A patent/JP2018501607A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB728719A (en) * | 1952-06-06 | 1955-04-27 | Dry Accumulator Company Ltd | Improvements in or relating to electric storage batteries |
| RU2321922C1 (ru) * | 2004-03-29 | 2008-04-10 | Эл Джи Кем, Лтд. | Электрохимический элемент с двумя типами сепараторов |
| CN103050705A (zh) * | 2013-01-06 | 2013-04-17 | 天津市捷威动力工业有限公司 | 一种钛酸锂表涂负极及使用该种负极的锂离子电池 |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2017120036A (ru) | 2018-12-13 |
| EP3218953A1 (en) | 2017-09-20 |
| EP3218953A4 (en) | 2018-04-11 |
| RU2017120036A3 (enExample) | 2019-03-28 |
| JP2018501607A (ja) | 2018-01-18 |
| CN107112585A (zh) | 2017-08-29 |
| CA2967501A1 (en) | 2016-05-19 |
| EP3218953B1 (en) | 2019-08-07 |
| WO2016074069A1 (en) | 2016-05-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20201113 |