RU2518061C2 - Твердотельные оксидные топливные элементы с внутренним риформингом - Google Patents
Твердотельные оксидные топливные элементы с внутренним риформингом Download PDFInfo
- Publication number
- RU2518061C2 RU2518061C2 RU2010106177/07A RU2010106177A RU2518061C2 RU 2518061 C2 RU2518061 C2 RU 2518061C2 RU 2010106177/07 A RU2010106177/07 A RU 2010106177/07A RU 2010106177 A RU2010106177 A RU 2010106177A RU 2518061 C2 RU2518061 C2 RU 2518061C2
- Authority
- RU
- Russia
- Prior art keywords
- oxide
- fuel cell
- support membrane
- anode
- catalyst
- Prior art date
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- 239000000446 fuel Substances 0.000 title claims abstract description 170
- 238000002407 reforming Methods 0.000 title claims abstract description 117
- 239000003054 catalyst Substances 0.000 claims abstract description 152
- 239000012528 membrane Substances 0.000 claims abstract description 93
- 230000036961 partial effect Effects 0.000 claims abstract description 60
- 230000003647 oxidation Effects 0.000 claims abstract description 49
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000003792 electrolyte Substances 0.000 claims abstract description 17
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 61
- 239000000203 mixture Substances 0.000 claims description 39
- 239000000725 suspension Substances 0.000 claims description 35
- 229910044991 metal oxide Inorganic materials 0.000 claims description 26
- 150000004706 metal oxides Chemical class 0.000 claims description 25
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 23
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 19
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 19
- 229910052697 platinum Inorganic materials 0.000 claims description 19
- 229910052763 palladium Inorganic materials 0.000 claims description 17
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 14
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- 239000011787 zinc oxide Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 22
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0637—Direct internal reforming at the anode of the fuel cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9058—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of noble metals or noble-metal based alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/880,105 US8435683B2 (en) | 2007-07-19 | 2007-07-19 | Internal reforming solid oxide fuel cells |
| US11/880,105 | 2007-07-19 | ||
| PCT/US2008/008776 WO2009014645A1 (en) | 2007-07-19 | 2008-07-18 | Internal reforming solid oxide fuel cells |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010106177A RU2010106177A (ru) | 2011-08-27 |
| RU2518061C2 true RU2518061C2 (ru) | 2014-06-10 |
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|---|---|---|---|
| RU2010106177/07A RU2518061C2 (ru) | 2007-07-19 | 2008-07-18 | Твердотельные оксидные топливные элементы с внутренним риформингом |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8435683B2 (https=) |
| EP (1) | EP2208250B1 (https=) |
| JP (1) | JP5396386B2 (https=) |
| KR (1) | KR101576627B1 (https=) |
| CN (1) | CN101803097B (https=) |
| AU (1) | AU2008279690B2 (https=) |
| BR (1) | BRPI0814268A2 (https=) |
| CA (1) | CA2694019C (https=) |
| MX (1) | MX2010000759A (https=) |
| RU (1) | RU2518061C2 (https=) |
| WO (1) | WO2009014645A1 (https=) |
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| RU2751535C2 (ru) * | 2019-10-07 | 2021-07-14 | Федеральное государственное унитарное предприятие "Крыловский государственный научный центр" | Мембранно-электродный блок топливного элемента с полимерной мембраной |
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2007
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- 2008-07-18 RU RU2010106177/07A patent/RU2518061C2/ru active
- 2008-07-18 CN CN200880107952.6A patent/CN101803097B/zh active Active
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Cited By (2)
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|---|---|---|---|---|
| RU2743000C2 (ru) * | 2016-12-08 | 2021-02-12 | Серес Интеллектуал Проперти Компани Лимитед | Анод для твердооксидного топливного элемента |
| RU2751535C2 (ru) * | 2019-10-07 | 2021-07-14 | Федеральное государственное унитарное предприятие "Крыловский государственный научный центр" | Мембранно-электродный блок топливного элемента с полимерной мембраной |
Also Published As
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|---|---|
| US20090023050A1 (en) | 2009-01-22 |
| RU2010106177A (ru) | 2011-08-27 |
| EP2208250A4 (en) | 2010-11-24 |
| CN101803097A (zh) | 2010-08-11 |
| CN101803097B (zh) | 2016-03-09 |
| JP2010533957A (ja) | 2010-10-28 |
| JP5396386B2 (ja) | 2014-01-22 |
| EP2208250B1 (en) | 2020-09-02 |
| MX2010000759A (es) | 2010-04-27 |
| US8435683B2 (en) | 2013-05-07 |
| AU2008279690B2 (en) | 2013-11-28 |
| KR101576627B1 (ko) | 2015-12-14 |
| AU2008279690A1 (en) | 2009-01-29 |
| CA2694019C (en) | 2015-10-06 |
| EP2208250A1 (en) | 2010-07-21 |
| WO2009014645A1 (en) | 2009-01-29 |
| BRPI0814268A2 (pt) | 2015-02-03 |
| CA2694019A1 (en) | 2009-01-29 |
| KR20100057619A (ko) | 2010-05-31 |
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