KR101576627B1 - 내부 개질 고체 옥사이드 연료 전지 - Google Patents
내부 개질 고체 옥사이드 연료 전지 Download PDFInfo
- Publication number
- KR101576627B1 KR101576627B1 KR1020107003748A KR20107003748A KR101576627B1 KR 101576627 B1 KR101576627 B1 KR 101576627B1 KR 1020107003748 A KR1020107003748 A KR 1020107003748A KR 20107003748 A KR20107003748 A KR 20107003748A KR 101576627 B1 KR101576627 B1 KR 101576627B1
- Authority
- KR
- South Korea
- Prior art keywords
- fuel cell
- support
- catalyst
- reforming
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0637—Direct internal reforming at the anode of the fuel cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9058—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of noble metals or noble-metal based alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/880,105 US8435683B2 (en) | 2007-07-19 | 2007-07-19 | Internal reforming solid oxide fuel cells |
| US11/880,105 | 2007-07-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20100057619A KR20100057619A (ko) | 2010-05-31 |
| KR101576627B1 true KR101576627B1 (ko) | 2015-12-14 |
Family
ID=40265094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020107003748A Active KR101576627B1 (ko) | 2007-07-19 | 2008-07-18 | 내부 개질 고체 옥사이드 연료 전지 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8435683B2 (https=) |
| EP (1) | EP2208250B1 (https=) |
| JP (1) | JP5396386B2 (https=) |
| KR (1) | KR101576627B1 (https=) |
| CN (1) | CN101803097B (https=) |
| AU (1) | AU2008279690B2 (https=) |
| BR (1) | BRPI0814268A2 (https=) |
| CA (1) | CA2694019C (https=) |
| MX (1) | MX2010000759A (https=) |
| RU (1) | RU2518061C2 (https=) |
| WO (1) | WO2009014645A1 (https=) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8309270B2 (en) * | 2007-08-03 | 2012-11-13 | Cp Sofc Ip, Llc | Solid oxide fuel cell systems with improved gas channeling and heat exchange |
| EP2662917A1 (en) * | 2007-08-31 | 2013-11-13 | Technical University of Denmark | Anode supported solid oxide fuel cell |
| GB2469265B8 (en) * | 2009-04-06 | 2015-06-17 | Re Hydrogen Ltd | Electrode configuration of electrolysers to protect catalyst from oxidation |
| FR2945378B1 (fr) * | 2009-05-11 | 2011-10-14 | Commissariat Energie Atomique | Cellule de pile a combustible haute temperature a reformage interne d'hydrocarbures. |
| WO2011041085A2 (en) * | 2009-09-11 | 2011-04-07 | Washington State University Research Foundation | Catalyst materials and methods for reforming hydrocarbon fuels |
| JP5327807B2 (ja) * | 2009-11-02 | 2013-10-30 | 独立行政法人産業技術総合研究所 | 触媒層を付加したチューブ型電気化学セル及びそれらから構成される電気化学反応システム |
| KR101417915B1 (ko) * | 2009-12-30 | 2014-07-09 | 두산중공업 주식회사 | 연료 전지의 애노드 전극, 이를 구비한 연료 전지 및 그 제조방법 |
| US9216390B2 (en) | 2010-07-15 | 2015-12-22 | Ohio State Innovation Foundation | Systems, compositions, and methods for fluid purification |
| US9561476B2 (en) | 2010-12-15 | 2017-02-07 | Praxair Technology, Inc. | Catalyst containing oxygen transport membrane |
| US20120251922A1 (en) | 2011-03-28 | 2012-10-04 | WATT Fuel Cell Corp | Electrode for a solid oxide fuel cell and method for its manufacture |
| JP5674035B2 (ja) * | 2011-03-31 | 2015-02-18 | 独立行政法人産業技術総合研究所 | 中低温高効率電気化学セル及びそれらから構成される電気化学反応システム |
| US9452548B2 (en) | 2011-09-01 | 2016-09-27 | Watt Fuel Cell Corp. | Process for producing tubular ceramic structures |
| US8652707B2 (en) | 2011-09-01 | 2014-02-18 | Watt Fuel Cell Corp. | Process for producing tubular ceramic structures of non-circular cross section |
| US9486735B2 (en) | 2011-12-15 | 2016-11-08 | Praxair Technology, Inc. | Composite oxygen transport membrane |
| EP2791082B1 (en) * | 2011-12-15 | 2021-01-20 | Praxair Technology, Inc. | Method of producing composite oxygen transport membrane |
| KR101521508B1 (ko) * | 2012-08-13 | 2015-05-19 | 가부시끼가이샤 리켄 | 고체 산화물형 연료 전지의 지지체를 겸하는 연료극 및 연료극 지지형 고체 산화물형 연료 전지 |
| JP5458222B1 (ja) * | 2012-08-13 | 2014-04-02 | 株式会社リケン | 固体酸化物型燃料電池の支持体を兼ねる燃料極および燃料極支持型の固体酸化物型燃料電池 |
| EP2935155B1 (en) | 2012-12-19 | 2019-02-13 | Praxair Technology Inc. | Method for sealing an oxygen transport membrane assembly |
| US9453644B2 (en) | 2012-12-28 | 2016-09-27 | Praxair Technology, Inc. | Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream |
| US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
| US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
| US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
| US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| EP3055054A2 (en) | 2013-10-07 | 2016-08-17 | Praxair Technology Inc. | Ceramic oxygen transport membrane array reactor and reforming method |
| JP2015076210A (ja) * | 2013-10-07 | 2015-04-20 | 株式会社豊田中央研究所 | 電極、並びに、固体酸化物形燃料電池及び電解装置 |
| RU2661581C2 (ru) | 2013-10-08 | 2018-07-17 | Праксайр Текнолоджи, Инк. | Система и способ регулирования температуры в реакторе на основе кислородпроводящих мембран |
| EP2869381A1 (en) * | 2013-11-01 | 2015-05-06 | Danmarks Tekniske Universitet | An integrated catalytic steam reforming fuel cell electrode |
| CA2926757C (en) | 2013-12-02 | 2020-02-25 | Praxair Technology, Inc. | Method and system for producing hydrogen using an oxygen transport membrane based reforming system with secondary reforming |
| CA2937943A1 (en) | 2014-02-12 | 2015-08-20 | Praxair Technology, Inc. | Oxygen transport membrane reactor based method and system for generating electric power |
| KR20160138053A (ko) * | 2014-03-31 | 2016-12-02 | 스미토모덴키고교가부시키가이샤 | 다공질 집전체 및 연료 전지 |
| US10822234B2 (en) | 2014-04-16 | 2020-11-03 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC) |
| WO2016057164A1 (en) | 2014-10-07 | 2016-04-14 | Praxair Technology, Inc | Composite oxygen ion transport membrane |
| WO2016178948A1 (en) * | 2015-05-05 | 2016-11-10 | Ohio University | Electrochemical cells electrochemical methods |
| US10367208B2 (en) | 2015-05-06 | 2019-07-30 | Robert E. Buxbaum | High efficiency fuel reforming and water use in a high temperature fuel-cell system and process for the such thereof |
| US20160351917A1 (en) * | 2015-05-31 | 2016-12-01 | Skyworks Solutions, Inc. | Materials, devices and methods related to solid oxide fuel cells |
| US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| CN105244523B (zh) * | 2015-08-28 | 2018-04-03 | 山西大学 | 一种具有抗积碳功能的固体氧化物燃料电池 |
| BR102015021820B1 (pt) * | 2015-09-04 | 2021-12-07 | Oxiteno S.A. Indústria E Comércio | Sistema de teste para pilhas a combustível de alta temperatura de operação multicombustível, o qual permite a utilização direta de combustíveis carbonosos sem promover a deposição de carbono nos elementos de passagem de combustível |
| US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
| US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
| CN109070014A (zh) | 2016-04-01 | 2018-12-21 | 普莱克斯技术有限公司 | 含催化剂的氧气传送膜 |
| US10381669B2 (en) | 2016-07-13 | 2019-08-13 | Lg Fuel Cell Systems Inc. | Steam reformer for in-block fuel cell reforming |
| WO2018017698A2 (en) * | 2016-07-19 | 2018-01-25 | Georgia Tech Research Corporation | Intermediate-temperature fuel cell tailored for efficient utilization of methane |
| DE112017005364T5 (de) | 2016-10-24 | 2019-07-18 | Precision Combustion, Inc. | Regenerativer festoxidstapel |
| US10164277B2 (en) | 2016-10-25 | 2018-12-25 | Lg Fuel Cell Systems Inc. | Steam reformer bypass line and flow controller |
| US10158135B2 (en) | 2016-10-25 | 2018-12-18 | Lg Fuel Cell Systems Inc. | Steam reformer bypass plenum and flow controller |
| GB2557344B (en) * | 2016-12-08 | 2021-05-19 | Ceres Ip Co Ltd | Anode |
| KR101958429B1 (ko) * | 2017-08-18 | 2019-03-15 | 한국과학기술연구원 | 바이오 가스 개질용 페로브스카이트 촉매 및 이의 제조 방법 |
| KR102002221B1 (ko) * | 2017-09-29 | 2019-07-19 | 부산대학교 산학협력단 | 금 나노입자를 포함하는 페로브스카이트 촉매 및 이의 제조 방법 |
| US11749821B2 (en) * | 2018-03-30 | 2023-09-05 | Osaka Gas Co., Ltd. | Fuel cell device and method for operating fuel cell device |
| US11136238B2 (en) | 2018-05-21 | 2021-10-05 | Praxair Technology, Inc. | OTM syngas panel with gas heated reformer |
| RU2751535C2 (ru) * | 2019-10-07 | 2021-07-14 | Федеральное государственное унитарное предприятие "Крыловский государственный научный центр" | Мембранно-электродный блок топливного элемента с полимерной мембраной |
| CN112751044B (zh) * | 2020-06-05 | 2022-06-17 | 浙江浙能技术研究院有限公司 | 一种固体氧化物燃料电池的阳极材料及其制备方法 |
| CN113019377B (zh) * | 2021-03-11 | 2023-08-08 | 江苏大学 | 一种燃料电池的内重整材料及其制备方法和应用 |
| CN114361471A (zh) * | 2022-01-10 | 2022-04-15 | 国家能源集团新能源有限责任公司 | 一种一体化独立催化层及制备方法和应用 |
| CN114899462B (zh) * | 2022-05-31 | 2024-03-26 | 成都岷山绿氢能源有限公司 | 一种固体氧化物燃料电池 |
| US12341226B1 (en) | 2024-08-07 | 2025-06-24 | Watt Fuel Cell Corp. | Integrated CPOX/stream reformer and fuel cell system |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030077504A1 (en) * | 2001-10-24 | 2003-04-24 | Nissan Motor Co., Ltd. | Unit cell for fuel cell and solid oxide fuel cell |
| US20060172886A1 (en) * | 2005-01-28 | 2006-08-03 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Catalyst support and method of producing the same |
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| US3615164A (en) * | 1968-01-10 | 1971-10-26 | Bernard S Baker | Process for selective removal by methanation of carbon monoxide from a mixture of gases containing carbon dioxide |
| US5733675A (en) * | 1995-08-23 | 1998-03-31 | Westinghouse Electric Corporation | Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer |
| US5747185A (en) | 1995-11-14 | 1998-05-05 | Ztek Corporation | High temperature electrochemical converter for hydrocarbon fuels |
| US6548446B1 (en) * | 1997-07-02 | 2003-04-15 | Engelhard Corporation | Catalyst for selective oxidation of carbon monoxide |
| CN1276921A (zh) * | 1997-10-01 | 2000-12-13 | 阿库门特里斯公司 | 整体固体氧化物燃料电池及其改进型 |
| US6589680B1 (en) * | 1999-03-03 | 2003-07-08 | The Trustees Of The University Of Pennsylvania | Method for solid oxide fuel cell anode preparation |
| US6485852B1 (en) * | 2000-01-07 | 2002-11-26 | Delphi Technologies, Inc. | Integrated fuel reformation and thermal management system for solid oxide fuel cell systems |
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| JP3874334B2 (ja) * | 2000-10-13 | 2007-01-31 | 本田技研工業株式会社 | 燃料電池システム |
| US6793698B1 (en) * | 2001-03-09 | 2004-09-21 | Uop Llc | Fuel processor reactor with integrated pre-reforming zone |
| US6824907B2 (en) | 2002-01-16 | 2004-11-30 | Alberta Reasearch Council, Inc. | Tubular solid oxide fuel cell stack |
| AUPS087502A0 (en) * | 2002-03-04 | 2002-03-28 | Ceramic Fuel Cells Limited | Solid oxide fuel cell |
| JP3997874B2 (ja) * | 2002-09-25 | 2007-10-24 | 日産自動車株式会社 | 固体酸化物形燃料電池用単セル及びその製造方法 |
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| US7732084B2 (en) * | 2004-02-04 | 2010-06-08 | General Electric Company | Solid oxide fuel cell with internal reforming, catalyzed interconnect for use therewith, and methods |
| WO2005079978A1 (ja) * | 2004-02-19 | 2005-09-01 | Idemitsu Kosan Co., Ltd. | 炭化水素の改質触媒、該改質触媒を用いた水素の製造方法及び燃料電池システム |
| RU2346996C2 (ru) | 2004-06-29 | 2009-02-20 | ЮРОПИЭН НИКЕЛЬ ПиЭлСи | Усовершенствованное выщелачивание основных металлов |
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| JP2007335314A (ja) * | 2006-06-16 | 2007-12-27 | Nissan Motor Co Ltd | 単室型固体酸化物形燃料電池、単室型固体酸化物形燃料電池システム及び単室型固体酸化物形燃料電池の運転方法 |
-
2007
- 2007-07-19 US US11/880,105 patent/US8435683B2/en active Active
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2008
- 2008-07-18 CA CA2694019A patent/CA2694019C/en active Active
- 2008-07-18 AU AU2008279690A patent/AU2008279690B2/en active Active
- 2008-07-18 EP EP08794567.1A patent/EP2208250B1/en active Active
- 2008-07-18 WO PCT/US2008/008776 patent/WO2009014645A1/en not_active Ceased
- 2008-07-18 JP JP2010517022A patent/JP5396386B2/ja active Active
- 2008-07-18 BR BRPI0814268-8A2A patent/BRPI0814268A2/pt not_active Application Discontinuation
- 2008-07-18 KR KR1020107003748A patent/KR101576627B1/ko active Active
- 2008-07-18 MX MX2010000759A patent/MX2010000759A/es active IP Right Grant
- 2008-07-18 RU RU2010106177/07A patent/RU2518061C2/ru active
- 2008-07-18 CN CN200880107952.6A patent/CN101803097B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030077504A1 (en) * | 2001-10-24 | 2003-04-24 | Nissan Motor Co., Ltd. | Unit cell for fuel cell and solid oxide fuel cell |
| US20060172886A1 (en) * | 2005-01-28 | 2006-08-03 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Catalyst support and method of producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090023050A1 (en) | 2009-01-22 |
| RU2010106177A (ru) | 2011-08-27 |
| EP2208250A4 (en) | 2010-11-24 |
| CN101803097A (zh) | 2010-08-11 |
| CN101803097B (zh) | 2016-03-09 |
| JP2010533957A (ja) | 2010-10-28 |
| JP5396386B2 (ja) | 2014-01-22 |
| EP2208250B1 (en) | 2020-09-02 |
| MX2010000759A (es) | 2010-04-27 |
| US8435683B2 (en) | 2013-05-07 |
| AU2008279690B2 (en) | 2013-11-28 |
| AU2008279690A1 (en) | 2009-01-29 |
| RU2518061C2 (ru) | 2014-06-10 |
| CA2694019C (en) | 2015-10-06 |
| EP2208250A1 (en) | 2010-07-21 |
| WO2009014645A1 (en) | 2009-01-29 |
| BRPI0814268A2 (pt) | 2015-02-03 |
| CA2694019A1 (en) | 2009-01-29 |
| KR20100057619A (ko) | 2010-05-31 |
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