RU2504556C2 - Каталитические составы, содержащие полуметаллоцены, и продукты полимеризации, полученные с их применением - Google Patents

Каталитические составы, содержащие полуметаллоцены, и продукты полимеризации, полученные с их применением Download PDF

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RU2504556C2
RU2504556C2 RU2011105195/04A RU2011105195A RU2504556C2 RU 2504556 C2 RU2504556 C2 RU 2504556C2 RU 2011105195/04 A RU2011105195/04 A RU 2011105195/04A RU 2011105195 A RU2011105195 A RU 2011105195A RU 2504556 C2 RU2504556 C2 RU 2504556C2
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group
oxide
substituted
activator
present
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RU2011105195A (ru
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Мак П. МАКДЭНИЕЛ
Мэттью Дж. ТОРН
Элизабет А. БЕНХЭМ
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Шеврон Филлипс Кемикал Компани Лп
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
RU2011105195/04A 2008-07-14 2009-07-13 Каталитические составы, содержащие полуметаллоцены, и продукты полимеризации, полученные с их применением RU2504556C2 (ru)

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US12/172,805 US7884165B2 (en) 2008-07-14 2008-07-14 Half-metallocene catalyst compositions and their polymer products
US12/172,805 2008-07-14
PCT/US2009/004047 WO2010008515A1 (en) 2008-07-14 2009-07-13 Half-metallocene catalyst compositions and their polymer products

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2706120C2 (ru) * 2014-10-09 2019-11-14 ШЕВРОН ФИЛЛИПС КЕМИКАЛ КОМПАНИ ЭлПи Каталитические системы на основе фосфинимида титана и иминоимидазолидида титана с подложками-активаторами
RU2730018C2 (ru) * 2015-09-24 2020-08-14 Шеврон Филлипс Кемикал Компани Лп Гетерогенные катализаторы циглера-натта с фторированным оксидом алюминия, покрытым диоксидом кремния
RU2730017C2 (ru) * 2015-09-24 2020-08-14 Шеврон Филлипс Кемикал Компани Лп Металлоценовые двойные каталитические системы циглера-натта с активаторами-носителями
RU2759838C2 (ru) * 2017-04-07 2021-11-18 Шеврон Филлипс Кемикал Компани Лп Каталитические системы, содержащие низковалентные титан-алюминиевые комплексы, и полимеры, полученные с применением таких систем

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US7884165B2 (en) * 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
EP2382247B1 (en) * 2009-01-23 2012-10-24 Evonik Oxeno GmbH Pe mib slurry polymerization
US8399580B2 (en) 2010-08-11 2013-03-19 Chevron Philips Chemical Company Lp Additives to chromium catalyst mix tank
US8501651B2 (en) 2010-09-24 2013-08-06 Chevron Phillips Chemical Company Lp Catalyst systems and polymer resins having improved barrier properties
US8828529B2 (en) 2010-09-24 2014-09-09 Chevron Phillips Chemical Company Lp Catalyst systems and polymer resins having improved barrier properties
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
CN103030724B (zh) * 2011-09-30 2015-07-22 中国石油化工股份有限公司 一种α-烯烃与带有极性基团的烯烃的共聚反应方法
US8865846B2 (en) 2012-09-25 2014-10-21 Chevron Phillips Chemical Company Lp Metallocene and half sandwich dual catalyst systems for producing broad molecular weight distribution polymers
US8821800B2 (en) 2012-10-18 2014-09-02 Chevron Phillips Chemical Company Lp System and method for catalyst preparation
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
EP2917267B1 (en) 2012-11-07 2016-09-07 Chevron Phillips Chemical Company LP Low density polyolefin resins ad films made therefrom
US8912285B2 (en) 2012-12-06 2014-12-16 Chevron Phillips Chemical Company Lp Catalyst system with three metallocenes for producing broad molecular weight distribution polymers
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8703886B1 (en) * 2013-02-27 2014-04-22 Chevron Phillips Chemical Company Lp Dual activator-support catalyst systems
EP2787014A1 (en) * 2013-04-05 2014-10-08 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
US9181370B2 (en) 2013-11-06 2015-11-10 Chevron Phillips Chemical Company Lp Low density polyolefin resins with low molecular weight and high molecular weight components, and films made therefrom
CN105566545B (zh) * 2014-10-13 2019-02-19 中国石油化工股份有限公司 一种烯烃共聚物及其制备方法
US9303106B1 (en) 2014-10-17 2016-04-05 Chevron Phillips Chemical Company Lp Processes for preparing solid metallocene-based catalyst systems
US9707549B1 (en) 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
JP6439761B2 (ja) * 2016-08-09 2018-12-19 トヨタ自動車株式会社 NOx吸蔵還元触媒の製造方法
BR112019024773B1 (pt) * 2017-05-25 2022-07-19 Chevron Phillips Chemical Company Lp Processo para produzir uma composição de polímero com estabilidade de cor de longo prazo, método para melhorar a estabilidade de cor de longo prazo de uma composição de polímero, composição de polímero e artigo de fabricação compreendendo a referida composição
US10697889B2 (en) 2017-07-21 2020-06-30 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10030086B1 (en) 2017-07-21 2018-07-24 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10358506B2 (en) 2017-10-03 2019-07-23 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE copolymers with improved processability
US10679734B2 (en) 2018-03-29 2020-06-09 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10507445B2 (en) 2018-03-29 2019-12-17 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2067981C1 (ru) * 1989-09-13 1996-10-20 Эксон Кемикэл Патентс Инк. Координационные соединения моноциклопентадиенила с переходными металлами, способ их получения и каталитическая система для получения полиолефинов
US20050113243A1 (en) * 2003-11-21 2005-05-26 Thorn Matthew G. Catalyst compositions for producing polyolefins in the absence of cocatalysts

Family Cites Families (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3242099A (en) 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US4060480A (en) 1971-09-03 1977-11-29 Chevron Research Company Hydrocarbon hydroconversion process employing hydroxy-aluminum stabilized catalysts supports
US4501885A (en) 1981-10-14 1985-02-26 Phillips Petroleum Company Diluent and inert gas recovery from a polymerization process
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4452910A (en) 1982-06-15 1984-06-05 Standard Oil Company (Indiana) Chromium expanded smectite clay
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4939217A (en) 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US6825369B1 (en) 1989-09-14 2004-11-30 The Dow Chemical Company Metal complex compounds
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
US5575979A (en) 1991-03-04 1996-11-19 Phillips Petroleum Company Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator
AU650787B2 (en) 1991-12-09 1994-06-30 Phillips Petroleum Company Process for preparing a pillared chain silicate clay
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
ATE194361T1 (de) 1992-09-04 2000-07-15 Bp Chem Int Ltd Katalysatorzusammensetzungen und verfahren zur herstellung von polyolefinen
US5635573A (en) 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
JPH0733821A (ja) 1993-07-22 1995-02-03 Nippon Oil Co Ltd オレフィン類重合用触媒成分
US5576259A (en) 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
ES2155095T5 (es) 1993-10-21 2006-04-16 Exxonmobil Oil Corporation Mezclas de poliolefinas con distribucion bimodal de pesos moleculares.
US5455314A (en) 1994-07-27 1995-10-03 Phillips Petroleum Company Method for controlling removal of polymerization reaction effluent
IT1272939B (it) 1995-02-01 1997-07-01 Enichem Spa Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine
EP0727443B1 (en) 1995-02-20 2001-01-17 Tosoh Corporation Catalyst for olefin polymerization and process for producing olefin polymers
EP0728773B1 (en) 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Catalysts for olefin polymerization and a process for preparing olefin polymers therewith
TW326450B (en) 1995-06-28 1998-02-11 Mitsui Petroleum Chemicals Ind Ethylene copolymer rubber, vulcanizable rubber composition containing the copolymer rubber, and process for preparing the same
DE19535014C2 (de) * 1995-09-21 1999-03-04 Stein Ind Anlagen Inh Christel Verfahren zum Einbringen von körnigen Feststoffen in Metallschmelzen
WO1997035893A1 (en) 1996-03-27 1997-10-02 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
DE69738304T2 (de) 1996-12-09 2008-09-18 Mitsubishi Chemical Corp. Katalysator zur Alpha-Olefinpolymerisation
US5906955A (en) 1996-12-20 1999-05-25 Tosoh Corporation Catalyst for polymerization of an olefin, and method for producing an olefin polymer
US5739220A (en) * 1997-02-06 1998-04-14 Fina Technology, Inc. Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation
WO1999002571A1 (fr) 1997-07-09 1999-01-21 Maruzen Petrochemical Co., Ltd. Composants catalytiques destines a la polymerisation d'olefines, catalyseurs de polymerisation, et procede de polymerisation d'olefines a l'aide de ces derniers
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
US6159889A (en) 1997-12-09 2000-12-12 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6127302A (en) 1997-12-09 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US5962362A (en) 1997-12-09 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
KR100531628B1 (ko) 1998-03-20 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 연속적인 슬러리 중합반응의 휘발물질 제거
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6107230A (en) 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
DE69939738D1 (de) * 1998-05-18 2008-11-27 Chevron Phillips Chemical Co Katalysatorzusammensetzung für monomerpolymerisation
SG72966A1 (en) 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
PL345752A1 (en) 1998-07-29 2002-01-02 Union Carbide Chem Plastic Unbridged monocyclopentadienyl metal complex catalyst having improved tolerance of modified methylaluminoxane
EP0989139A1 (en) 1998-09-25 2000-03-29 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst for olefin polymerization by reacting with particulate solids with functional groups
US6294494B1 (en) 1998-12-18 2001-09-25 Phillips Petroleum Company Olefin polymerization processes and products thereof
US6262191B1 (en) 1999-03-09 2001-07-17 Phillips Petroleum Company Diluent slip stream to give catalyst wetting agent
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6376415B1 (en) 1999-09-28 2002-04-23 Phillips Petroleum Company Organometal catalyst compositions
US6395666B1 (en) 1999-09-29 2002-05-28 Phillips Petroleum Company Organometal catalyst compositions
US6391816B1 (en) 1999-10-27 2002-05-21 Phillips Petroleum Organometal compound catalyst
US6548441B1 (en) 1999-10-27 2003-04-15 Phillips Petroleum Company Organometal catalyst compositions
US6613712B1 (en) 1999-11-24 2003-09-02 Phillips Petroleum Company Organometal catalyst compositions with solid oxide supports treated with fluorine and boron
KR100348761B1 (ko) 1999-11-26 2002-08-13 금호석유화학 주식회사 공액디엔을 포함하는 중합체의 선택적 수소화 방법
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6469117B1 (en) 1999-12-14 2002-10-22 Jianxin Kuang Dialkenyl-tricyclic-nonaromatic/olefin polymers
HUP0203789A2 (en) 1999-12-16 2003-04-28 Phillips Petroleum Co Organometal compound catalyst
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6524987B1 (en) 1999-12-22 2003-02-25 Phillips Petroleum Company Organometal catalyst compositions
US6632894B1 (en) 1999-12-30 2003-10-14 Phillips Petroleum Company Organometal catalyst compositions
US6667274B1 (en) 1999-12-30 2003-12-23 Phillips Petroleum Company Polymerization catalysts
US6576583B1 (en) 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
US6528448B1 (en) 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
US6388017B1 (en) 2000-05-24 2002-05-14 Phillips Petroleum Company Process for producing a polymer composition
DE60314262T2 (de) 2002-08-22 2008-01-31 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
US20040059070A1 (en) * 2002-09-19 2004-03-25 Whitte William M. Process and apparatus for controlling molecular weight distribution and short chain branching for olefin polymers
US6982306B2 (en) 2003-11-26 2006-01-03 Chevron Phillips Chemical Company, L.P. Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7884163B2 (en) * 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US7884165B2 (en) 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
BR122013014965B1 (pt) * 2009-06-16 2019-10-29 Chevron Phillps Chemical Company Lp composições compreendendo polialfaolefina e composições compreendendo produto oligomérico alfa olefina
EP2485839A1 (en) * 2009-10-06 2012-08-15 Chevron Phillips Chemical Company LP Oligomerization of olefin waxes using metallocene-based catalyst systems

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2067981C1 (ru) * 1989-09-13 1996-10-20 Эксон Кемикэл Патентс Инк. Координационные соединения моноциклопентадиенила с переходными металлами, способ их получения и каталитическая система для получения полиолефинов
US20050113243A1 (en) * 2003-11-21 2005-05-26 Thorn Matthew G. Catalyst compositions for producing polyolefins in the absence of cocatalysts

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
Antinolo A. et al. Synthesis of zirconium(IV) monocyclopentadienyl-aryloxy complexes and their use in catalytic ethylene polymerization. X-ray structure of -C5Me5)Zr{2,6-OC6H3(CH3)2}3, Organometallics, 2000, 19, 2837-2843. *
Arevalo Silvia et al. Ethylene polymerization behavior of monometallic complexes and metallodendrimers based on cyclopentadienyl-aryloxy titanium, Journal of organometallic chemistry, 690 (2005) 4620-4627. *
Arevalo Silvia et al. Ethylene polymerization behavior of monometallic complexes and metallodendrimers based on cyclopentadienyl-aryloxy titanium, Journal of organometallic chemistry, 690 (2005) 4620-4627. Antinolo A. et al. Synthesis of zirconium(IV) monocyclopentadienyl-aryloxy complexes and their use in catalytic ethylene polymerization. X-ray structure of -C5Me5)Zr{2,6-OC6H3(CH3)2}3, Organometallics, 2000, 19, 2837-2843. Matthew G. Thorn et al. Synthesis, characterization, and one-electron reduction of mixed-cyclopentadienyl/aryloxide titanium dichlorides, Organometallics, 2000, 19, 5636-5642. Arevalo Silvia et al. Synthesis of aryloxo cyclopentadienyl group 4 metal-containing dendrimers, Organometallics, 2003, 22, 5109-5113. *
Arevalo Silvia et al. Synthesis of aryloxo cyclopentadienyl group 4 metal-containing dendrimers, Organometallics, 2003, 22, 5109-5113. *
Matthew G. Thorn et al. Synthesis, characterization, and one-electron reduction of mixed-cyclopentadienyl/aryloxide titanium dichlorides, Organometallics, 2000, 19, 5636-5642. *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2706120C2 (ru) * 2014-10-09 2019-11-14 ШЕВРОН ФИЛЛИПС КЕМИКАЛ КОМПАНИ ЭлПи Каталитические системы на основе фосфинимида титана и иминоимидазолидида титана с подложками-активаторами
RU2730018C2 (ru) * 2015-09-24 2020-08-14 Шеврон Филлипс Кемикал Компани Лп Гетерогенные катализаторы циглера-натта с фторированным оксидом алюминия, покрытым диоксидом кремния
RU2730017C2 (ru) * 2015-09-24 2020-08-14 Шеврон Филлипс Кемикал Компани Лп Металлоценовые двойные каталитические системы циглера-натта с активаторами-носителями
RU2759838C2 (ru) * 2017-04-07 2021-11-18 Шеврон Филлипс Кемикал Компани Лп Каталитические системы, содержащие низковалентные титан-алюминиевые комплексы, и полимеры, полученные с применением таких систем

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