RU2480863C2 - Металлокерамическая анодная структура (варианты) и ее применение - Google Patents
Металлокерамическая анодная структура (варианты) и ее применение Download PDFInfo
- Publication number
- RU2480863C2 RU2480863C2 RU2008134998/07A RU2008134998A RU2480863C2 RU 2480863 C2 RU2480863 C2 RU 2480863C2 RU 2008134998/07 A RU2008134998/07 A RU 2008134998/07A RU 2008134998 A RU2008134998 A RU 2008134998A RU 2480863 C2 RU2480863 C2 RU 2480863C2
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- Prior art keywords
- phase
- ceramic
- conductive phase
- electrically conductive
- anode structure
- Prior art date
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 99
- 239000002184 metal Substances 0.000 title claims abstract description 99
- 239000000758 substrate Substances 0.000 claims abstract description 80
- 238000005470 impregnation Methods 0.000 claims abstract description 60
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 57
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 36
- 239000004094 surface-active agent Substances 0.000 claims abstract description 35
- 239000002243 precursor Substances 0.000 claims abstract description 31
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 27
- 239000000956 alloy Substances 0.000 claims abstract description 27
- 239000000725 suspension Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 10
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 70
- 239000003792 electrolyte Substances 0.000 claims description 47
- 239000001301 oxygen Substances 0.000 claims description 34
- 229910052760 oxygen Inorganic materials 0.000 claims description 34
- -1 oxygen ion Chemical class 0.000 claims description 27
- 239000000446 fuel Substances 0.000 claims description 24
- 238000010304 firing Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 18
- 239000011195 cermet Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 13
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000002019 doping agent Substances 0.000 claims description 11
- 238000005245 sintering Methods 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052772 Samarium Inorganic materials 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000003546 flue gas Substances 0.000 claims description 4
- 239000010955 niobium Substances 0.000 claims description 4
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- IRGHYODJVHIXDW-UHFFFAOYSA-N [Sr].[Ti].[Nb] Chemical compound [Sr].[Ti].[Nb] IRGHYODJVHIXDW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- VIIJTIRNANJGHH-UHFFFAOYSA-N strontium vanadium Chemical compound [V].[Sr] VIIJTIRNANJGHH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 3
- 230000006872 improvement Effects 0.000 abstract description 2
- 238000000137 annealing Methods 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 54
- 229910002490 Ce0.9Gd0.1O2–δ Inorganic materials 0.000 description 23
- 239000002245 particle Substances 0.000 description 18
- 239000010935 stainless steel Substances 0.000 description 16
- 229910001220 stainless steel Inorganic materials 0.000 description 16
- 239000002131 composite material Substances 0.000 description 13
- 239000010408 film Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 10
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 10
- 230000008595 infiltration Effects 0.000 description 10
- 238000001764 infiltration Methods 0.000 description 10
- 229910000604 Ferrochrome Inorganic materials 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000002105 nanoparticle Substances 0.000 description 9
- 229920002415 Pluronic P-123 Polymers 0.000 description 8
- 238000005266 casting Methods 0.000 description 8
- 230000010287 polarization Effects 0.000 description 8
- MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(iii) nitrate Chemical compound [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 6
- 229910002119 nickel–yttria stabilized zirconia Inorganic materials 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 210000003371 toe Anatomy 0.000 description 4
- 238000013183 transoesophageal echocardiography Methods 0.000 description 4
- 239000013504 Triton X-100 Substances 0.000 description 3
- 229920004890 Triton X-100 Polymers 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910002367 SrTiO Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 229920004897 Triton X-45 Polymers 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 2
- 238000001453 impedance spectrum Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 1
- 229910017563 LaCrO Inorganic materials 0.000 description 1
- MOCSSSMOHPPNTG-UHFFFAOYSA-N [Sc].[Y] Chemical compound [Sc].[Y] MOCSSSMOHPPNTG-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000010344 co-firing Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 1
- 229940075613 gadolinium oxide Drugs 0.000 description 1
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000011533 mixed conductor Substances 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- VSSLEOGOUUKTNN-UHFFFAOYSA-N tantalum titanium Chemical compound [Ti].[Ta] VSSLEOGOUUKTNN-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- RVRKDGLTBFWQHH-UHFFFAOYSA-N yttrium zirconium Chemical compound [Y][Zr][Y] RVRKDGLTBFWQHH-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Catalysts (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electrolytic Production Of Metals (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200701245 | 2007-08-31 | ||
| DKPA200701245 | 2007-08-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008134998A RU2008134998A (ru) | 2010-03-10 |
| RU2480863C2 true RU2480863C2 (ru) | 2013-04-27 |
Family
ID=39816598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008134998/07A RU2480863C2 (ru) | 2007-08-31 | 2008-08-29 | Металлокерамическая анодная структура (варианты) и ее применение |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8500842B2 (cg-RX-API-DMAC10.html) |
| EP (1) | EP2031675B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP5192944B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR20090023255A (cg-RX-API-DMAC10.html) |
| CN (1) | CN101383418B (cg-RX-API-DMAC10.html) |
| AT (1) | ATE519241T1 (cg-RX-API-DMAC10.html) |
| AU (1) | AU2008207645B2 (cg-RX-API-DMAC10.html) |
| CA (1) | CA2639175A1 (cg-RX-API-DMAC10.html) |
| DK (1) | DK2031675T3 (cg-RX-API-DMAC10.html) |
| ES (1) | ES2367885T3 (cg-RX-API-DMAC10.html) |
| RU (1) | RU2480863C2 (cg-RX-API-DMAC10.html) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010107228A2 (ko) * | 2009-03-16 | 2010-09-23 | 한국과학기술연구원 | 기공 경사 구조의 나노 기공성 층을 포함하는 연료극 지지형 고체 산화물 연료 전지 및 그 제조 방법 |
| US9240597B2 (en) * | 2010-10-13 | 2016-01-19 | University Of South Carolina | Ni modified ceramic anodes for direct-methane solid oxide fuel cells |
| WO2012062341A1 (en) | 2010-11-11 | 2012-05-18 | The Technical University Of Denmark | Solid oxide cell stack and method for preparing same |
| US8962147B2 (en) * | 2010-12-03 | 2015-02-24 | Federal-Mogul Corporation | Powder metal component impregnated with ceria and/or yttria and method of manufacture |
| WO2013060669A1 (en) * | 2011-10-24 | 2013-05-02 | Technical University Of Denmark | A modified anode/electrolyte structure for a solid oxide electrochemical cell and a method for making said structure |
| KR20140096310A (ko) * | 2011-10-24 | 2014-08-05 | 테크니칼 유니버시티 오브 덴마크 | 고체 산화물 전기화학 전지를 위한 고 성능 연료 전극 |
| US9062384B2 (en) | 2012-02-23 | 2015-06-23 | Treadstone Technologies, Inc. | Corrosion resistant and electrically conductive surface of metal |
| US9631286B2 (en) | 2012-04-13 | 2017-04-25 | Danmarks Tekniske Universitet | High performance reversible electrochemical cell for H2O electrolysis or conversion of CO2 and H2O to fuel |
| RU2510385C1 (ru) * | 2012-10-01 | 2014-03-27 | Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук | Твердооксидный композитный материал для мембран электрохимических устройств |
| TWI482660B (zh) * | 2012-12-11 | 2015-05-01 | Ind Tech Res Inst | 電極及其製備方法 |
| US9525179B2 (en) | 2013-03-13 | 2016-12-20 | University Of Maryland, College Park | Ceramic anode materials for solid oxide fuel cells |
| CN103280339A (zh) * | 2013-04-12 | 2013-09-04 | 上海大学 | 一种用于超级电容器的氧化铈电极的制备方法 |
| US9181148B2 (en) * | 2013-05-22 | 2015-11-10 | Saudi Arabian Oil Company | Ni/CGO and Ni-Ru/CGO based pre-reforming catalysts formulation for methane rich gas production from diesel processing for fuel cell applications |
| EP2808932A1 (en) | 2013-05-31 | 2014-12-03 | Topsøe Fuel Cell A/S | Metal-supported solid oxide cell |
| GB2517927B (en) * | 2013-09-04 | 2018-05-16 | Ceres Ip Co Ltd | Process for forming a metal supported solid oxide fuel cell |
| CN104710845A (zh) * | 2013-12-13 | 2015-06-17 | 通用电气公司 | 组合物及其相应的装置、方法 |
| GB2524638B (en) * | 2015-02-06 | 2016-04-06 | Ceres Ip Co Ltd | Electrolyte forming process |
| US20180200695A1 (en) * | 2017-01-18 | 2018-07-19 | Saudi Arabian Oil Company | Structured catalysts for pre-reforming hydrocarbons |
| US10953388B1 (en) | 2019-12-27 | 2021-03-23 | Saudi Arabian Oil Company | Ni—Ru—CgO based pre-reforming catalyst for liquid hydrocarbons |
| US12322811B2 (en) * | 2021-07-29 | 2025-06-03 | Nissan North America, Inc. | Metal-supported anode for solid oxide fuel cell |
| CN114583226B (zh) * | 2022-03-31 | 2024-07-12 | 电堆科技(合肥)有限公司 | 一种金属支撑质子导体固体氧化物电池及其制备方法 |
| CN119213587A (zh) * | 2022-04-06 | 2024-12-27 | 联邦科学技术研究组织 | 电极组合物 |
| CN121360818B (zh) * | 2025-12-22 | 2026-03-24 | 崇义章源钨业股份有限公司 | 一种钨铈合金丝及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU277044A1 (ru) * | Ю. М. Позин, Е. И. Гамаскин , Ш. Вогман | Металлокерамический отрицательный электрод | ||
| US5312582A (en) * | 1993-02-04 | 1994-05-17 | Institute Of Gas Technology | Porous structures from solid solutions of reduced oxides |
| RU2125324C1 (ru) * | 1996-11-11 | 1999-01-20 | Горина Лилия Федоровна | Способ изготовления единичного высокотемпературного топливного элемента и его компонентов: катода, электролита, анода, токопрохода, интерфейсного и электроизолирующего слоев |
| US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
| RU2236722C1 (ru) * | 2003-06-10 | 2004-09-20 | Мятиев Ата Атаевич | Электрод-электролитная пара на основе двуокиси церия (варианты), способ ее изготовления (варианты) и органогель |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3377265A (en) * | 1964-11-16 | 1968-04-09 | Mobil Oil Corp | Electrochemical electrode |
| JPH01186561A (ja) * | 1988-01-14 | 1989-07-26 | Hitachi Ltd | 燃料電池 |
| JPH01189866A (ja) * | 1988-01-25 | 1989-07-31 | Hitachi Ltd | 溶融塩型燃料電池用アノードとその製造方法 |
| DK167163B1 (da) | 1991-02-13 | 1993-09-06 | Risoe Forskningscenter | Fastoxidbraendselscelle til oxidation af ch4 |
| US6752979B1 (en) | 2000-11-21 | 2004-06-22 | Very Small Particle Company Pty Ltd | Production of metal oxide particles with nano-sized grains |
| EP1530814A4 (en) * | 2002-06-06 | 2009-05-27 | Univ Pennsylvania | CERAMIC ANODES AND PROCESS FOR PRODUCING THESE ANODES |
| US20040185327A1 (en) * | 2002-12-16 | 2004-09-23 | Gorte Raymond J. | High performance ceramic anodes and method of producing the same |
| JP4709652B2 (ja) * | 2003-12-24 | 2011-06-22 | ピレリ・アンド・チ・ソチエタ・ペル・アツィオーニ | 固体酸化物燃料電池 |
| US20050221163A1 (en) * | 2004-04-06 | 2005-10-06 | Quanmin Yang | Nickel foam and felt-based anode for solid oxide fuel cells |
| WO2005122300A2 (en) | 2004-06-10 | 2005-12-22 | Risoe National Laboratory | Solid oxide fuel cell |
| KR100924700B1 (ko) * | 2005-01-12 | 2009-11-03 | 테크니칼 유니버시티 오브 덴마크 | 소결 중 수축률 및 공극률이 조절된 다층 구조물의 제조방법, 상기 제조방법에 따라 제조된 다층 구조물 및 상기 다층 구조물을 포함하는 고체 산화물 연료전지 |
| DK1844517T3 (da) * | 2005-02-02 | 2010-07-19 | Univ Denmark Tech Dtu | Fremgangsmåde til fremstilling af en reversibel faststof-brændselscelle |
| EP1875534A4 (en) | 2005-04-21 | 2011-09-14 | Univ California | PRELIMINARY INFILTRATION AND COATING PROCESS |
| DK1760817T3 (da) * | 2005-08-31 | 2013-10-14 | Univ Denmark Tech Dtu | Reversibel fastoxidbrændselscellestak og fremgangsmåde til fremstilling af samme |
-
2008
- 2008-08-21 DK DK08014830.7T patent/DK2031675T3/da active
- 2008-08-21 EP EP08014830A patent/EP2031675B1/en not_active Not-in-force
- 2008-08-21 AT AT08014830T patent/ATE519241T1/de not_active IP Right Cessation
- 2008-08-21 ES ES08014830T patent/ES2367885T3/es active Active
- 2008-08-27 US US12/199,571 patent/US8500842B2/en not_active Expired - Fee Related
- 2008-08-28 CA CA002639175A patent/CA2639175A1/en not_active Abandoned
- 2008-08-28 JP JP2008219434A patent/JP5192944B2/ja not_active Expired - Fee Related
- 2008-08-29 RU RU2008134998/07A patent/RU2480863C2/ru not_active IP Right Cessation
- 2008-08-29 AU AU2008207645A patent/AU2008207645B2/en not_active Ceased
- 2008-08-29 CN CN200810130977.XA patent/CN101383418B/zh not_active Expired - Fee Related
- 2008-08-29 KR KR1020080084905A patent/KR20090023255A/ko not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU277044A1 (ru) * | Ю. М. Позин, Е. И. Гамаскин , Ш. Вогман | Металлокерамический отрицательный электрод | ||
| US5312582A (en) * | 1993-02-04 | 1994-05-17 | Institute Of Gas Technology | Porous structures from solid solutions of reduced oxides |
| RU2125324C1 (ru) * | 1996-11-11 | 1999-01-20 | Горина Лилия Федоровна | Способ изготовления единичного высокотемпературного топливного элемента и его компонентов: катода, электролита, анода, токопрохода, интерфейсного и электроизолирующего слоев |
| US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
| RU2236722C1 (ru) * | 2003-06-10 | 2004-09-20 | Мятиев Ата Атаевич | Электрод-электролитная пара на основе двуокиси церия (варианты), способ ее изготовления (варианты) и органогель |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2031675B1 (en) | 2011-08-03 |
| RU2008134998A (ru) | 2010-03-10 |
| JP5192944B2 (ja) | 2013-05-08 |
| KR20090023255A (ko) | 2009-03-04 |
| AU2008207645A1 (en) | 2009-03-19 |
| CA2639175A1 (en) | 2009-02-28 |
| HK1130118A1 (en) | 2009-12-18 |
| ES2367885T3 (es) | 2011-11-10 |
| US8500842B2 (en) | 2013-08-06 |
| AU2008207645B2 (en) | 2012-04-19 |
| CN101383418A (zh) | 2009-03-11 |
| CN101383418B (zh) | 2014-06-25 |
| EP2031675A1 (en) | 2009-03-04 |
| ATE519241T1 (de) | 2011-08-15 |
| DK2031675T3 (da) | 2011-11-14 |
| JP2009110934A (ja) | 2009-05-21 |
| US20090061272A1 (en) | 2009-03-05 |
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