RU2104288C1 - Катализатор полимеризации олефинов и способ полимеризации этилена - Google Patents
Катализатор полимеризации олефинов и способ полимеризации этилена Download PDFInfo
- Publication number
- RU2104288C1 RU2104288C1 RU93046712/04A RU93046712A RU2104288C1 RU 2104288 C1 RU2104288 C1 RU 2104288C1 RU 93046712/04 A RU93046712/04 A RU 93046712/04A RU 93046712 A RU93046712 A RU 93046712A RU 2104288 C1 RU2104288 C1 RU 2104288C1
- Authority
- RU
- Russia
- Prior art keywords
- chromium
- catalyst
- carrier
- silicon dioxide
- ethylene
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000005977 Ethylene Substances 0.000 title claims abstract description 18
- 238000006116 polymerization reaction Methods 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 17
- 150000001336 alkenes Chemical class 0.000 title claims description 10
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims abstract description 84
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 44
- 239000011651 chromium Substances 0.000 claims abstract description 44
- 239000011148 porous material Substances 0.000 claims abstract description 43
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 17
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 230000003197 catalytic effect Effects 0.000 claims abstract description 12
- 150000001845 chromium compounds Chemical class 0.000 claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 229940117975 chromium trioxide Drugs 0.000 claims abstract description 7
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 7
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 claims abstract description 7
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 claims abstract description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 abstract description 11
- 238000005336 cracking Methods 0.000 abstract description 5
- 229920001038 ethylene copolymer Polymers 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 5
- 239000000969 carrier Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- OLGHJTHQWQKJQQ-UHFFFAOYSA-N 3-ethylhex-1-ene Chemical compound CCCC(CC)C=C OLGHJTHQWQKJQQ-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UMMBKZGNPHABPI-UHFFFAOYSA-N [Si].[Ti].[Mg] Chemical compound [Si].[Ti].[Mg] UMMBKZGNPHABPI-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- -1 ethylene, propylene, 1-butene Chemical class 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000012686 granular polymerization Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/958668 | 1992-10-08 | ||
| US07/958,668 US5486584A (en) | 1992-10-08 | 1992-10-08 | Chromium catalyst compositions |
| US07/958,668 | 1992-10-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU93046712A RU93046712A (ru) | 1996-08-10 |
| RU2104288C1 true RU2104288C1 (ru) | 1998-02-10 |
Family
ID=25501177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU93046712/04A RU2104288C1 (ru) | 1992-10-08 | 1993-10-07 | Катализатор полимеризации олефинов и способ полимеризации этилена |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US5486584A (enExample) |
| EP (1) | EP0591968B1 (enExample) |
| JP (1) | JP3198206B2 (enExample) |
| KR (1) | KR100278751B1 (enExample) |
| CN (3) | CN1036924C (enExample) |
| AT (1) | ATE155146T1 (enExample) |
| AU (1) | AU654445B2 (enExample) |
| CA (1) | CA2100144C (enExample) |
| DE (1) | DE69312005T2 (enExample) |
| DK (1) | DK0591968T3 (enExample) |
| ES (1) | ES2104017T3 (enExample) |
| HU (1) | HU212809B (enExample) |
| MX (1) | MX9306146A (enExample) |
| NO (1) | NO301375B1 (enExample) |
| RU (1) | RU2104288C1 (enExample) |
| SG (1) | SG48772A1 (enExample) |
| TW (1) | TW259796B (enExample) |
| YU (1) | YU63593A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2262512C2 (ru) * | 1999-11-04 | 2005-10-20 | Филлипс Петролеум Компани | Хромсодержащий катализатор на основе диоксида кремния, способ его получения и способ получения полиэтилена с использованием данного катализатора |
| RU2557661C2 (ru) * | 2009-11-10 | 2015-07-27 | Инеос Коммершиал Сервисиз Юк Лимитед | Способ полимеризации олефинов |
| US11548958B2 (en) | 2019-05-24 | 2023-01-10 | Chevron Phillips Chemical Company Lp | Preparation of large pore silicas and uses thereof in chromium catalysts for olefin polymerization |
| RU2790065C1 (ru) * | 2019-05-24 | 2023-02-14 | Шеврон Филлипс Кемикал Компани Лп | Получение диоксидов кремния с крупными порами и их применение в хромовых катализаторах для полимеризации олефинов |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5714424A (en) * | 1995-01-09 | 1998-02-03 | W. R. Grace & Co.-Conn. | Multi-component polyolefin catalysts |
| EP0849293A1 (en) * | 1996-12-20 | 1998-06-24 | Fina Research S.A. | Production of polyethylene having a bimodal molecular weight distribution |
| AU5630198A (en) * | 1997-03-07 | 1998-09-10 | Phillips Petroleum Company | A process for polymerizing olefins |
| EP1041089A1 (en) | 1999-03-29 | 2000-10-04 | Fina Research S.A. | Production of polyethylene |
| US6569960B2 (en) | 1999-07-27 | 2003-05-27 | Phillips Petroleum Company | Process to produce polymers |
| GB9928176D0 (en) | 1999-11-29 | 2000-01-26 | Borealis Polymers Oy | Polymer |
| US6696388B2 (en) * | 2000-01-24 | 2004-02-24 | E. I. Du Pont De Nemours And Company | Gel catalysts and process for preparing thereof |
| EP1138604A1 (en) | 2000-03-30 | 2001-10-04 | Fina Research S.A. | Glossy plastic containers |
| ES2225586T3 (es) * | 2000-07-05 | 2005-03-16 | Basell Polyolefine Gmbh | Catalizador de cromo soportado, titanizado, y su empleo para la obtrencion de homopolimeros y copolimeros de etileno. |
| EP1300240A1 (en) * | 2001-10-02 | 2003-04-09 | Atofina Research S.A. | High ESCR glossy plastic containers |
| JP4048043B2 (ja) * | 2001-11-02 | 2008-02-13 | 日揮株式会社 | 硫化カルボニル及びシアン化水素の分解触媒及び分解方法 |
| AU2003226163A1 (en) * | 2003-03-31 | 2004-11-23 | Exxonmobil Chemical Patents Inc. | Catalyst activation method and activated catalyst |
| US6982304B2 (en) | 2003-12-22 | 2006-01-03 | Union Carbide Chemicals & Plastics Technology Corporation | Blow molding resins with improved ESCR |
| WO2011002497A1 (en) | 2009-06-29 | 2011-01-06 | Chevron Phillips Chemical Company Lp | Dual metallocene catalyst systems for decreasing melt index and increasing polymer production rates |
| US8207280B2 (en) * | 2009-06-29 | 2012-06-26 | Chevron Phillips Chemical Company Lp | Use of hydrogen scavenging catalysts to control polymer molecular weight and hydrogen levels in a polymerization reactor |
| US8399580B2 (en) | 2010-08-11 | 2013-03-19 | Chevron Philips Chemical Company Lp | Additives to chromium catalyst mix tank |
| WO2012086780A1 (ja) * | 2010-12-24 | 2012-06-28 | 日本ポリエチレン株式会社 | 改良された分岐度分布を有するポリエチレン |
| US10301409B2 (en) | 2011-03-30 | 2019-05-28 | Japan Polyethylene Corporation | Ethylene-based polymer, manufacturing method of ethylene-based polymer and manufacturing method of catalyst for polymerization, and molded article of hollow plastics containing ethylene-based polymer and use thereof |
| CN109160963B (zh) * | 2018-08-28 | 2021-05-04 | 吉化集团吉林市天龙催化剂有限公司 | 一种乙烯聚合用镁改性铬系催化剂及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4981927A (en) * | 1987-05-20 | 1991-01-01 | National Distillers And Chemical Corporation | Chromium catalyst compositions and polymerization utilizing same |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3135809A (en) * | 1960-07-21 | 1964-06-02 | Southern Res Inst | Isomerization process |
| US3225023A (en) * | 1962-11-30 | 1965-12-21 | Phillips Petroleum Co | Process for controlling melt index |
| US3624063A (en) * | 1969-07-10 | 1971-11-30 | Phillips Petroleum Co | Ethylene polymerization using catalyst of controlled particle size |
| US3798202A (en) * | 1971-10-12 | 1974-03-19 | Phillips Petroleum Co | Polyolefin production |
| US3978002A (en) * | 1972-12-04 | 1976-08-31 | National Petro Chemicals Corporation | Catalyst useful for olefin polymerization process |
| US4025707A (en) * | 1974-03-28 | 1977-05-24 | Phillips Petroleum Company | Mixed hydrocarbyloxide treated catalyst activated at different temperatures |
| USRE31443E (en) * | 1977-12-05 | 1983-11-15 | Phillips Petroleum Company | Treatment of silica |
| US4248735A (en) * | 1979-06-01 | 1981-02-03 | Phillips Petroleum Company | Treatment of silica |
| US4169926A (en) * | 1978-01-16 | 1979-10-02 | Phillips Petroleum Company | Inorganic hydrogels and uses thereof |
| US4325839A (en) * | 1979-12-21 | 1982-04-20 | Phillips Petroleum Company | Impregnated second valence chromium compound in supported catalyst |
| US4384086A (en) * | 1980-02-06 | 1983-05-17 | Phillips Petroleum Company | Large pore volume olefin polymerization catalysts |
| US4806513A (en) * | 1984-05-29 | 1989-02-21 | Phillips Petroleum Company | Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same |
| US4560733A (en) * | 1984-10-01 | 1985-12-24 | Phillips Petroleum Company | Polymerization and catalyst |
| US4735931A (en) * | 1986-06-16 | 1988-04-05 | Phillips Petroleum Company | In situ comonomer generation in olefin polymerization |
| US5198400A (en) * | 1987-05-20 | 1993-03-30 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
| CA1307619C (en) * | 1987-05-20 | 1992-09-15 | Louis J. Rekers | Chromium catalyst compositions and polymerization utilizing same |
| CA1309801C (en) * | 1987-09-18 | 1992-11-03 | Elizabeth A. Boggs | Process for olefin polymerization |
| US4981831A (en) * | 1988-07-25 | 1991-01-01 | Phillips Petroleum Company | Twice-aged porous inorganic oxides, catalysts, and polymerization processes |
| JPH02105806A (ja) * | 1988-10-13 | 1990-04-18 | Nippon Oil Co Ltd | エチレン重合体の製造方法 |
| US4967029A (en) * | 1989-09-07 | 1990-10-30 | Mobil Oil Corporation | Liquid lubricants from alpha-olefin and styrene copolymers |
| US4988657A (en) * | 1989-10-06 | 1991-01-29 | Phillips Petroleum Company | Process for olefin polymerization |
| US5034364A (en) * | 1989-11-09 | 1991-07-23 | Mobil Oil Corporation | Multiple chromium compound-containing catalyst composition and olefin polymerization therewith |
-
1992
- 1992-10-08 US US07/958,668 patent/US5486584A/en not_active Expired - Lifetime
-
1993
- 1993-07-08 CA CA002100144A patent/CA2100144C/en not_active Expired - Fee Related
- 1993-09-13 TW TW082107494A patent/TW259796B/zh active
- 1993-09-13 AU AU46287/93A patent/AU654445B2/en not_active Ceased
- 1993-10-01 MX MX9306146A patent/MX9306146A/es unknown
- 1993-10-02 KR KR1019930020309A patent/KR100278751B1/ko not_active Expired - Fee Related
- 1993-10-05 YU YU63593A patent/YU63593A/sh unknown
- 1993-10-05 CN CN93118646A patent/CN1036924C/zh not_active Expired - Fee Related
- 1993-10-06 NO NO933577A patent/NO301375B1/no unknown
- 1993-10-07 HU HU9302831A patent/HU212809B/hu not_active IP Right Cessation
- 1993-10-07 DE DE69312005T patent/DE69312005T2/de not_active Expired - Fee Related
- 1993-10-07 EP EP93116245A patent/EP0591968B1/en not_active Expired - Lifetime
- 1993-10-07 AT AT93116245T patent/ATE155146T1/de not_active IP Right Cessation
- 1993-10-07 DK DK93116245.7T patent/DK0591968T3/da active
- 1993-10-07 RU RU93046712/04A patent/RU2104288C1/ru not_active IP Right Cessation
- 1993-10-07 SG SG1996001511A patent/SG48772A1/en unknown
- 1993-10-07 ES ES93116245T patent/ES2104017T3/es not_active Expired - Lifetime
- 1993-10-08 JP JP25314293A patent/JP3198206B2/ja not_active Expired - Fee Related
-
1995
- 1995-06-07 US US08/486,872 patent/US5595953A/en not_active Expired - Fee Related
-
1996
- 1996-08-26 CN CN96111936A patent/CN1100068C/zh not_active Expired - Fee Related
- 1996-08-26 CN CN96111935A patent/CN1150954A/zh active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4981927A (en) * | 1987-05-20 | 1991-01-01 | National Distillers And Chemical Corporation | Chromium catalyst compositions and polymerization utilizing same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2262512C2 (ru) * | 1999-11-04 | 2005-10-20 | Филлипс Петролеум Компани | Хромсодержащий катализатор на основе диоксида кремния, способ его получения и способ получения полиэтилена с использованием данного катализатора |
| RU2557661C2 (ru) * | 2009-11-10 | 2015-07-27 | Инеос Коммершиал Сервисиз Юк Лимитед | Способ полимеризации олефинов |
| US11548958B2 (en) | 2019-05-24 | 2023-01-10 | Chevron Phillips Chemical Company Lp | Preparation of large pore silicas and uses thereof in chromium catalysts for olefin polymerization |
| RU2790065C1 (ru) * | 2019-05-24 | 2023-02-14 | Шеврон Филлипс Кемикал Компани Лп | Получение диоксидов кремния с крупными порами и их применение в хромовых катализаторах для полимеризации олефинов |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2100144A1 (en) | 1994-04-09 |
| NO301375B1 (no) | 1997-10-20 |
| HU9302831D0 (en) | 1994-01-28 |
| KR940009215A (ko) | 1994-05-20 |
| CA2100144C (en) | 1998-12-29 |
| HUT69750A (en) | 1995-09-28 |
| DK0591968T3 (da) | 1998-01-26 |
| HU212809B (en) | 1996-11-28 |
| JPH06199920A (ja) | 1994-07-19 |
| JP3198206B2 (ja) | 2001-08-13 |
| US5595953A (en) | 1997-01-21 |
| ES2104017T3 (es) | 1997-10-01 |
| EP0591968B1 (en) | 1997-07-09 |
| EP0591968A3 (en) | 1994-11-30 |
| ATE155146T1 (de) | 1997-07-15 |
| TW259796B (enExample) | 1995-10-11 |
| NO933577D0 (no) | 1993-10-06 |
| MX9306146A (es) | 1994-04-29 |
| NO933577L (no) | 1994-04-11 |
| AU4628793A (en) | 1994-04-21 |
| CN1167121A (zh) | 1997-12-10 |
| EP0591968A2 (en) | 1994-04-13 |
| CN1100068C (zh) | 2003-01-29 |
| KR100278751B1 (ko) | 2001-01-15 |
| CN1036924C (zh) | 1998-01-07 |
| US5486584A (en) | 1996-01-23 |
| CN1085566A (zh) | 1994-04-20 |
| DE69312005D1 (de) | 1997-08-14 |
| CN1150954A (zh) | 1997-06-04 |
| YU63593A (sh) | 1996-07-24 |
| AU654445B2 (en) | 1994-11-03 |
| DE69312005T2 (de) | 1997-10-30 |
| SG48772A1 (en) | 1998-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2104288C1 (ru) | Катализатор полимеризации олефинов и способ полимеризации этилена | |
| CA1082675A (en) | Fused ring catalyst and ethylene polymerization process therewith | |
| KR950009110B1 (ko) | 에틸렌과 고급 알파-올레핀의 공중합체 및 그의 제조방법 | |
| US6372867B1 (en) | Process for the gas phase polymerization of olefins | |
| EP0480377B1 (en) | High-temperature slurry polymerization of ethylene | |
| EP0882740A1 (en) | Titanated chromium-based catalysts to produce polyethylene exhibiting better environmental stress crack resistance | |
| EP0882743B1 (en) | Titanated chromium-based catalysts to produce polyethylene | |
| GB1583803A (en) | Olefin polymerisation process and silica-supported catalyst therefor | |
| RU97111880A (ru) | Способ получения полиэтилена | |
| RU98116125A (ru) | Способ получения композиции этиленовых полимеров | |
| US4988657A (en) | Process for olefin polymerization | |
| US5364915A (en) | Ethylene polymerization process | |
| US4246139A (en) | Silica production | |
| US5670438A (en) | Catalyst compositions and catalytic processes | |
| US4369295A (en) | Impregnated second valence chromium compound in supported catalyst | |
| US4325839A (en) | Impregnated second valence chromium compound in supported catalyst | |
| EP0870773B1 (en) | Ethylene polymerization process in the presence of a chromium oxide catalyst | |
| JPH04122706A (ja) | エチレンのガス相(共−)重合化方法 | |
| US4180481A (en) | Manufacture of a supported chromium oxide catalyst for olefin polymerization | |
| JP2000026524A (ja) | ポリエチレンの製造 | |
| US4378306A (en) | Surface heat treatment of silica-containing catalyst base | |
| JP4392064B2 (ja) | プロピレン重合体、その製造に用いる触媒、製造法および使用法 | |
| US4434280A (en) | Polymerization process using surface heat treated silica-containing catalyst base | |
| RU2177954C1 (ru) | Способ получения полиэтилена низкого давления | |
| JP2806434B2 (ja) | エチレン系重合体の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20031008 |