RU2103063C1 - Способ регенерации катализатора алкилирования изопарафинов олефинами - Google Patents

Способ регенерации катализатора алкилирования изопарафинов олефинами Download PDF

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Publication number
RU2103063C1
RU2103063C1 RU93050201A RU93050201A RU2103063C1 RU 2103063 C1 RU2103063 C1 RU 2103063C1 RU 93050201 A RU93050201 A RU 93050201A RU 93050201 A RU93050201 A RU 93050201A RU 2103063 C1 RU2103063 C1 RU 2103063C1
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RU
Russia
Prior art keywords
sulfone
mixture
catalyst
alkylation
crm
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RU93050201A
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English (en)
Russian (ru)
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RU93050201A (ru
Inventor
Гордон Абботт Рональд
Дэн Истмэн Алан
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Филлипс Петролеум Компани
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Publication of RU93050201A publication Critical patent/RU93050201A/ru
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0222—Sulfur-containing compounds comprising sulfonyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1206—Hydrogen fluoride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Fats And Perfumes (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
RU93050201A 1992-06-26 1993-06-24 Способ регенерации катализатора алкилирования изопарафинов олефинами RU2103063C1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/904938 1992-06-26
US07/904,938 US5276245A (en) 1992-06-26 1992-06-26 Alkylation catalyst regeneration

Publications (2)

Publication Number Publication Date
RU93050201A RU93050201A (ru) 1996-04-27
RU2103063C1 true RU2103063C1 (ru) 1998-01-27

Family

ID=25420006

Family Applications (1)

Application Number Title Priority Date Filing Date
RU93050201A RU2103063C1 (ru) 1992-06-26 1993-06-24 Способ регенерации катализатора алкилирования изопарафинов олефинами

Country Status (27)

Country Link
US (2) US5276245A (enExample)
EP (1) EP0576024B1 (enExample)
JP (1) JPH06198200A (enExample)
KR (1) KR100240381B1 (enExample)
CN (1) CN1039310C (enExample)
AT (1) ATE141187T1 (enExample)
AU (1) AU656467B2 (enExample)
BR (1) BR9302357A (enExample)
CA (1) CA2092928C (enExample)
CZ (1) CZ284220B6 (enExample)
DE (1) DE69303992T2 (enExample)
DK (1) DK0576024T3 (enExample)
ES (1) ES2093323T3 (enExample)
FI (1) FI932931L (enExample)
GR (1) GR3021012T3 (enExample)
HU (1) HU214781B (enExample)
MX (1) MX9303218A (enExample)
NO (1) NO302607B1 (enExample)
PH (1) PH30031A (enExample)
PL (1) PL299449A1 (enExample)
RU (1) RU2103063C1 (enExample)
SG (1) SG48762A1 (enExample)
SK (1) SK281666B6 (enExample)
TR (1) TR27289A (enExample)
TW (1) TW251280B (enExample)
YU (1) YU48387B (enExample)
ZA (1) ZA933692B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2403965C2 (ru) * 2005-01-31 2010-11-20 Конокофиллипс Компани Способ алкилирования с повторным взаимодействием в резервуаре для отстаивания

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5569807A (en) * 1992-05-01 1996-10-29 Phillips Petroleum Company Isoparaffin-olefin alkylation
US5276245A (en) * 1992-06-26 1994-01-04 Phillips Petroleum Company Alkylation catalyst regeneration
US5306859A (en) * 1992-08-27 1994-04-26 Phillips Petroleum Company Alkylation catalyst regeneration utilizing polyvinylpyridine and amine substituted styrene divinylbenzene copolymer contact materials
DK173114B1 (da) * 1994-06-02 2000-01-31 Topsoe Haldor As Fremgangsmåde til genvinding af brugt sulfonsyrekatalysator samt anvendelse af fremgangsmåden
US5689030A (en) * 1996-03-06 1997-11-18 Phillips Petroleum Company Method for prolonging the life of alkylation product stream defluorinator beds
US6943276B1 (en) * 2002-06-12 2005-09-13 Uop Llc Alkylation process with efficient effluent refrigeration
US9776877B2 (en) * 2014-12-11 2017-10-03 Uop Llc Separation of conjunct polymer from volatile regenerant for ionic liquid regeneration

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0184375B1 (en) * 1984-11-28 1989-05-31 Mobil Oil Corporation Solvent extraction and purification of acid soluble oil from an hf alkylation unit

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
US2820835A (en) * 1955-08-18 1958-01-21 Standard Oil Co Catalytic reactions of olefins
US4024203A (en) * 1969-11-24 1977-05-17 Institut Francais Du Petrole Oligomerization of unsaturated hydrocarbons with acid catalysts
FR2081989A5 (enExample) * 1969-11-24 1971-12-10 Inst Francais Du Petrole
US3871969A (en) * 1971-12-01 1975-03-18 Phillips Petroleum Co Apparatus for purifying HF
US3864423A (en) * 1972-08-21 1975-02-04 Phillips Petroleum Co Alkylation of hydrocarbons
US3920767A (en) * 1974-05-29 1975-11-18 Phillips Petroleum Co Isoparaffin-olefin alkylation using hf-ethyl fluoride catalysis with recovery of ethyl fluorine and alkylation of secondary and tertiary alkyl fluorides
US3975164A (en) * 1975-02-05 1976-08-17 Phillips Petroleum Company Apparatus for purifying HF catalyst in an alkylation process
US4008289A (en) * 1975-07-07 1977-02-15 Universal Oil Products Company Adsorbent treating method
US4209656A (en) * 1978-10-23 1980-06-24 Texaco Inc. Sulfuric acid catalyzed alkylation process
US4575567A (en) * 1982-07-06 1986-03-11 Uop Inc. Adsorbent regeneration in etherification processes
US4534865A (en) * 1984-04-24 1985-08-13 Sundberg Donald C Method and apparatus for reducing levels of organics in liquids
US4783567A (en) * 1987-11-23 1988-11-08 Uop Inc. HF alkylation process
US5276245A (en) * 1992-06-26 1994-01-04 Phillips Petroleum Company Alkylation catalyst regeneration

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0184375B1 (en) * 1984-11-28 1989-05-31 Mobil Oil Corporation Solvent extraction and purification of acid soluble oil from an hf alkylation unit

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2403965C2 (ru) * 2005-01-31 2010-11-20 Конокофиллипс Компани Способ алкилирования с повторным взаимодействием в резервуаре для отстаивания

Also Published As

Publication number Publication date
SG48762A1 (en) 1998-05-18
DK0576024T3 (da) 1996-09-02
KR940000150A (ko) 1994-01-03
CZ127493A3 (en) 1994-01-19
AU3862393A (en) 1994-01-27
FI932931A7 (fi) 1993-12-27
SK281666B6 (sk) 2001-06-11
CA2092928A1 (en) 1993-12-27
EP0576024B1 (en) 1996-08-14
NO302607B1 (no) 1998-03-30
CN1080881A (zh) 1994-01-19
NO932334D0 (no) 1993-06-24
PL299449A1 (en) 1994-03-21
AU656467B2 (en) 1995-02-02
EP0576024A1 (en) 1993-12-29
NO932334L (no) 1993-12-27
HUT67670A (en) 1995-04-28
YU44193A (sh) 1996-02-19
CA2092928C (en) 2000-02-22
TW251280B (enExample) 1995-07-11
GR3021012T3 (en) 1996-12-31
HU9301860D0 (en) 1993-09-28
TR27289A (tr) 1994-12-28
FI932931L (fi) 1993-12-27
YU48387B (sh) 1998-07-10
ATE141187T1 (de) 1996-08-15
CN1039310C (zh) 1998-07-29
FI932931A0 (fi) 1993-06-24
SK64893A3 (en) 1994-01-12
BR9302357A (pt) 1994-01-11
ZA933692B (en) 1993-12-15
HU214781B (hu) 1998-05-28
US5347067A (en) 1994-09-13
CZ284220B6 (cs) 1998-09-16
DE69303992D1 (de) 1996-09-19
JPH06198200A (ja) 1994-07-19
US5276245A (en) 1994-01-04
ES2093323T3 (es) 1996-12-16
PH30031A (en) 1996-11-08
DE69303992T2 (de) 1997-01-02
MX9303218A (es) 1994-01-31
KR100240381B1 (ko) 2000-01-15

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