RU2020120485A - Emm-31 материалы, и способы, и их применения - Google Patents

Emm-31 материалы, и способы, и их применения Download PDF

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RU2020120485A
RU2020120485A RU2020120485A RU2020120485A RU2020120485A RU 2020120485 A RU2020120485 A RU 2020120485A RU 2020120485 A RU2020120485 A RU 2020120485A RU 2020120485 A RU2020120485 A RU 2020120485A RU 2020120485 A RU2020120485 A RU 2020120485A
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Кёрк Д. ШМИТТ
Аллен У. БЁРТОН
Хильда Б. ВРОМАН
Карл Дж. СТРОМАЙЕР
Саймон К. УЭСТОН
Майкл А. Марелла
Росс МЭЙБОН
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ЭкссонМобил Рисерч энд Энджиниринг Компани
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
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    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
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    • C07D207/06—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with radicals, containing only hydrogen and carbon atoms, attached to ring carbon atoms
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    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/037—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements with quaternary ring nitrogen atoms
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • C01—INORGANIC CHEMISTRY
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    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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    • C—CHEMISTRY; METALLURGY
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    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams

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  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (43)

1. Кристаллический материал, имеющий на рентгенодифрактограмме по меньшей мере 6 пиков, выбранных из Таблицы 1:
Figure 00000001
в котором удалена часть структуронаправляющего агента, присутствующего в материале, или он весь.
2. Кристаллический материал, имеющий каркас, определяемый следующими взаимосвязями, приведенными в таблице 2, для тетраэдрических (Т) атомов в элементарной ячейке, причем тетраэдрические (Т) атомы соединены мостиковыми атомами:
Figure 00000002
Figure 00000003
Figure 00000004
Figure 00000005
,
в котором удалена часть структуронаправляющего агента, присутствующего в материале, или он весь.
3. Материал по п. 1 или 2, имеющий объем микропор от 0,10 до 0,25 куб. см/г.
4. Материал по любому из пп. 1-3, имеющий С-центрическую элементарную ячейку: а-параметр 17,9±0,5
Figure 00000006
, b-параметр 21,4±0,5
Figure 00000006
и с-параметр 20,0±0,5
Figure 00000006
.
5. Материал по любому из пп. 1 -4, который подходит для адсорбции от 60 до 150 мг/г н-гексана или от 40 до 100 мг/г мезитилена.
6. Материал по п. 1 или 2, имеющий пики рентгенодифрактограммы, выбранные из:
Figure 00000007
и (i) имеет объем микропор от 0,10 до 0,25 куб. см/г; (ii) имеет С-центрическую элементарную ячейку: а-параметр 17,9±0,5
Figure 00000006
, b-параметр 21,4±0,5
Figure 00000006
и с-параметр 20,0±0,5
Figure 00000006
; или (iii) подходит для адсорбции от 60 до 150 мг/г н-гексана или от 40 до 100 мг/г мезитилена.
7. Материал по любому из пп. 1-6, имеющий формулу I:
Figure 00000008
в которой 0,0005≤v≤0,1, X представляет собой трехвалентный элемент, и Y представляет собой четырехвалентный элемент.
8. Материал по п. 7, в котором молярное отношение Y к X составляет от 5 до 25, когда X является В.
9. Материал по п. 7, в котором молярное отношение Y к X составляет от 100 до 500, когда X является Al.
10. Свежеизготовленный кристаллический материал, имеющий на рентгенодифрактограмме по меньшей мере 3 пика, выбранных из таблицы 3:
Figure 00000009
.
11. Материал по п. 10, имеющий С-центрическую элементарную ячейку: а-параметр 17,9±0,5
Figure 00000006
, b-параметр 21,3±0,5
Figure 00000006
и с-параметр 20,2±0,5
Figure 00000006
.
12. Материал по п. 10 или 11, имеющий формулу II:
Figure 00000010
в которой 0,01≤n≤0,3, 0,0005≤v≤0,1, G является органическим структуронаправляющим агентом, X представляет собой трехвалентный элемент, и Y представляет собой четырехвалентный элемент.
13. Материал по п. 12, в котором молярное отношение Y к X составляет от 10 до 40, когда X является В.
14. Материал по п. 12 или 13, в котором молярное отношение G к Y составляет от 0,1 до 0,2.
15. Способ получения материала по любому из пп. 10-14, включающий смешивание композиции, содержащий источник гидроксид-ионов, источник оксида четырехвалентного элемента Y, источник трех валентного элемента X и структуронаправляющий агент (G), содержащий биспирролидиниевый дикатион.
16. Способ по п. 15, дополнительно включающий удаление части или всего структуронаправляющего агента.
17. Способ по п. 15 или 16, в котором органический структуронаправляющий агент (G) включает следующую структуру:
Figure 00000011
(Соединение Е), в котором А является ионом.
18. Способ по п. 17, в котором оба А иона являются гидроксид-ионами.
19. Способ по любому из пп. 15-17, в котором материал, имеющий X, являющийся В, и Y, являющийся Si, приводят в контакт с источником Al в условиях, достаточных для обмена В в каркасе на Al.
20. Соединение, представляющее собой структуронаправляющий агент, имеющее следующую структуру соединения Е:
Figure 00000012
(Соединение Е), в котором А является ионом.
21. Способ получения соединения Е по п. 20, включающий превращение соединения 7:
Figure 00000013
соединение 7 в соединение Е.
22. Способ получения соединения Е по п. 20, включающий превращение соединения 6:
Figure 00000014
соединение 6 в соединение Е.
23. Способ превращения органического соединения в продукт превращения, включающий приведение органического соединения в контакт с материалом по любому из пп. 1-9.
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US7648694B2 (en) * 2008-10-10 2010-01-19 Chevron U.S.A. Inc. Method for preparing SSZ-26/33 zeolites using novel structure directing agents
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US8202506B2 (en) * 2009-11-17 2012-06-19 Exxonmobil Research And Engineering Company High activity small crystal ZSM-12
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ES2620631T3 (es) * 2011-08-04 2017-06-29 Exxonmobil Chemical Patents Inc. Material de tamiz molecular EMM-23, su síntesis y uso
US8647602B2 (en) * 2012-06-08 2014-02-11 Chevron U.S.A. Inc. Method for making aluminosilicate zeolite SSZ-56
CN106660815B (zh) * 2014-09-03 2020-01-21 埃克森美孚研究工程公司 一种新的合成晶体材料emm-26、其制备及其用途
RU2721569C2 (ru) * 2015-12-04 2020-05-20 ЭкссонМобил Рисерч энд Энджиниринг Компани EMM-28 - новый синтетический кристаллический материал, его получение и применение
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