RU2019113769A - Молекулы, применимые в качестве пестицидов, и связанные с ними промежуточные продукты, композиции и способы - Google Patents

Молекулы, применимые в качестве пестицидов, и связанные с ними промежуточные продукты, композиции и способы Download PDF

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RU2019113769A
RU2019113769A RU2019113769A RU2019113769A RU2019113769A RU 2019113769 A RU2019113769 A RU 2019113769A RU 2019113769 A RU2019113769 A RU 2019113769A RU 2019113769 A RU2019113769 A RU 2019113769A RU 2019113769 A RU2019113769 A RU 2019113769A
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alkyl
group
haloalkyl
substituted
cycloalkyl
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RU2019113769A
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RU2777557C2 (ru
RU2019113769A3 (ru
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Рональд Дж. ХЕМСТРА
Рональд РОСС
Тимоти П. Мартин
Николас ВЕРМЕЛЕН
Джон Ф. Дэубл
Джозеф Д. ЭККЕЛЬБАРДЖЕР
Алекс НОЛАН
Кейтлин ГРЕЙ
Дэвид А. ДЕМЕТЕР
Рики ХАНТЕР
Тони К. ТРАЛЛИНГЕР
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ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/57—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C233/59—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of rings other than six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/66—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/24—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
    • C07C237/40—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having the nitrogen atom of the carboxamide group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
    • C07C237/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/52—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the nitrogen atom of at least one of the carboxamide groups further acylated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
    • C07C243/38—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/19—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and carboxyl groups, other than cyano groups, bound to the same saturated acyclic carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/45—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C255/46—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of non-condensed rings
    • C—CHEMISTRY; METALLURGY
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    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/58—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/58—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton
    • C07C255/60—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton at least one of the singly-bound nitrogen atoms being acylated
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    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/18—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by doubly-bound oxygen atoms
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    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
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    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/22—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
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    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
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    • C07C271/26—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
    • C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
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    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/62—Compounds containing any of the groups, X being a hetero atom, Y being any atom, e.g. N-acylcarbamates
    • C07C271/66—Y being a hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C281/00—Derivatives of carbonic acid containing functional groups covered by groups C07C269/00 - C07C279/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
    • C07C281/02—Compounds containing any of the groups, e.g. carbazates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C281/00—Derivatives of carbonic acid containing functional groups covered by groups C07C269/00 - C07C279/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
    • C07C281/06—Compounds containing any of the groups, e.g. semicarbazides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/10—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of a saturated carbon skeleton containing rings
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C311/21—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
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    • C07C311/48—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups having nitrogen atoms of sulfonamide groups further bound to another hetero atom
    • C—CHEMISTRY; METALLURGY
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    • C07C317/24—Sulfones; Sulfoxides having sulfone or sulfoxide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C337/00—Derivatives of thiocarbonic acids containing functional groups covered by groups C07C333/00 or C07C335/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
    • C07C337/06—Compounds containing any of the groups, e.g. thiosemicarbazides
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/76—Nitrogen atoms to which a second hetero atom is attached
    • C07D213/77—Hydrazine radicals
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    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Claims (80)

1. Молекула следующей формулы
Figure 00000001
Формула 1
в которой:
(A) R1 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, SF5 и (C1-C3)галогеналкил;
(B) R2 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, SF5 и (C1-C3)галогеналкил;
(C) R3 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, SF5 и (C1-C3)галогеналкил;
(D) R4 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, SF5 и (C1-C3)галогеналкил;
(E) R5 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, SF5 и (C1-C3)галогеналкил;
(F) R6 означает H;
(G) R7 выбран из группы, включающей F, Cl и Br;
(H) R8 выбран из группы, включающей F, Cl и Br;
(I) R9 означает H;
(J) Q1 выбран из группы, включающей O и S;
(K) Q2 выбран из группы, включающей O и S;
(L) R10 выбран из группы, включающей H, (C1-C3) алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)алкил-O(C1-C3)алкил и (C1-C3)алкил-OC(=O)(C1-C3)алкил;
(M) R11 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, (C1-C3)алкил, (C1-C3)галогеналкил и (C1-C3)алкоксигруппу;
(N) R12 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, (C1-C3)алкил, (C1-C3)галогеналкил и (C1-C3)алкоксигруппу;
(O) R13 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, (C1-C3)алкил, (C1-C3)галогеналкил и (C1-C3)алкоксигруппу;
(P) R14 выбран из группы, включающей H, F, Cl, Br, I, CN, NO2, (C1-C3)алкил, (C1-C3)галогеналкил и (C1-C3)алкоксигруппу;
(Q) X3 означает:
(1) N(R15a)(R15b), где
(a) указанный R15a выбран из группы, включающей H, (C1-C3)алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)галогеналкил, (C1-C3)алкилфенил, (C1-C3)алкил-O(C1-C3)алкил, (C1-C3)алкил-OC(=O)(C1-C3)алкил и C(=O)(C1-C3)алкил и
(b) указанный R15b означает замещенный или незамещенный фенил, указанный замещенный фенил содержит один или большее количество заместителей, выбранных из группы, включающей H, F, Cl, Br, I, CN, NO2, NH2, OH, SF5, (C1-C3)алкил, (C1-C3)галогеналкил, (C2-C3)алкенил, (C2-C3)галогеналкенил, (C1-C3)алкоксигруппу, (C=O)O(C1-C3)алкил, O(C=O)(C1-C3)алкил, N(R15c)2, N=CHN(R15c)(X4), N(R15c)C(=O)O(X4), N(R15c)S(=O)2(X4), N(S(=O)2(C1-C3)алкил)2, N(R15c)C(=O)N(R15c)2, N(R15c)C(=O)N(R15c)X4, N(R15c)C(=S)N(R15c)2, N(R15c)C(=S)N(R15c)X4, N(R15c)(C1-C3)алкил-X4, N(R15c)(CH(O(C1-C3)алкил)2), N(R15c)((C1-C3)алкил-OC(=O)(C1-C3)алкил), N(R15c)((C1-C3)алкил-C(=O)N(R15c)2), N(R15c)C(=O)(R15c), N(R15c)C(=O)X4, N(R15c)(C(=O))2X4, N(R15c)(C(=O))2OX4, N(R15c)(C(=O))2N(R15c)X4, N(C(=O)O(C1-C6)алкил)2, N(R15c)C(=O)O(C1-C6)алкил, N(R15c)C(=O)N(R15c)C(=O)O(R15c), N(R15C)(C(=O)O(C1-C6)алкил), N(R15C)(C(=O)O(C1-C6)галогеналкил), N((C1-C3)алкил-OC(=O)(C1-C6)алкил)(C(=O)(C1-C6)алкил), N((C1-C3)алкил-O(C1-C6)алкил)(C(=O)O(C1-C6)алкил) и N(R15c)C(=S)X4,
(1) указанные R15c каждый независимо выбран из группы, включающей H, (C1-C3)алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)галогеналкил, (C2-C3)галогеналкенил, (C1-C3)алкилфенил, (C1-C3)алкил-O(C1-C3)алкил, (C1-C3)алкил-OC(=O)(C1-C3)алкил, C(=O)(C1-C3)алкил и фенил, необязательно для N(R15c)2 указанный N(R15c)2 означает гетерогидрокарбильное кольцо, содержащее 1 кольцевой атом азота и от 3 до 5 кольцевых атомов углерода, где указанное кольцо может быть насыщенным или ненасыщенным,
(2) указанный X4 выбран из группы, включающей (C1-C6)алкил, (C1-C6)галогеналкил, (C1-C3)алкил-O(C1-C3)алкил, O(C1-C6)алкил, (C3-C6)циклоалкил, (C1-C6)алкилфенил, фенил, арил и гетероциклил, каждый из которых может содержать один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, NO2, NH2, оксогруппу, (C1-C3)алкил, (C1-C3)галогеналкил, NH(C1-C3)алкил, N((C1-C3)алкил)2, O(C1-C6)алкил, O(C1-C6)галогеналкил, N(R15c)C(=O)O(C1-C6)алкил, N(R15c)S(=O)2(R15c), S(=O)2(R15c), (C1-C3)алкил-O(C1-C3)алкил, (C3-C6)циклоалкил,
где в (1)(a) и (1)(b) каждый указанный алкил, алкенил, алкинил, циклоалкил, фенил, арил и гетероциклил может содержать один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, NO2, NH2, NH(C1-C3)алкил, N((C1-C3)алкил)2, O(C1-C6)алкил, (C1-C3)алкил-O(C1-C3)алкил и (C3-C6)циклоалкил;
(2) N(R16a)(R16b), где
(a) указанный R16a выбран из группы, включающей H, (C1-C3)алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)галогеналкил, (C1-C3)алкил-O(C1-C3)алкил, (C1-C3)алкил-OC(=O)(C1-C3)алкил и C(=O)(C1-C3)алкил,
(b) указанный R16b означает замещенный или незамещенный (C1-C8)алкил, указанный замещенный (C1-C8)алкил содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, NO2, O(C1-C8)алкил, (C3-C8)циклоалкил, (C1-C8)алкилфенил, (C2-C8)алкенил, (C2-C8)алкинил, S(C1-C8)алкил, S(O)(C1-C8)алкил, S(O)2(C1-C8)алкил, O-фенил, O(C2-C8)алкенил, O(C1-C8)алкил(C3-C8)циклоалкил, O(C1-C8)алкилфенил, O(C1-C8)алкил(C3-C8)циклоалкил, O(C1-C8)алкил, C(=O)O(C1-C8)алкил, OC(=O)(C1-C8)алкил, C(=O)N(R16a)(C1-C8)алкил, N(R16a)C(=O)(C1-C8)алкил, S(C1-C8)алкил, S(O)(C1-C8)алкил, S(O)2(C1-C8)алкил, S(O)2NH2 и N(R16a)S(O)2(C1-C8)алкил,
где в (2)(a) и (2)(b) каждый алкил, алкенил, алкинил, циклоалкил и фенил может содержать один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, NH2, NO2, (C1-C8)алкил, (C1-C8)алкоксигруппу, (C1-C8)галогеналкил, N((C1-C8)алкил)2 и C(=O)O(C1-C8)алкил;
(3) N(R17a)(N(R17b)(R17c)), где
(a) указанный R17a выбран из группы, включающей H, (C1-C3)алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)галогеналкил, (C1-C3)алкил-O(C1-C3)алкил,(C1-C3)алкил-OC(=O)(C1-C3)алкил и C(=O)(C1-C3)алкил,
(b) указанный R17b выбран из группы, включающей H, (C1-C3)алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)галогеналкил, (C1-C3)алкил-O(C1-C3)алкил,(C1-C3)алкил-OC(=O)(C1-C3)алкил и C(=O)(C1-C3)алкил,
(c) указанный R17c выбран из группы, включающей H, замещенный или незамещенный фенил, замещенный или незамещенный гетероциклил, замещенный или незамещенный (C1-C8)алкил, замещенный или незамещенный (C3-C8)циклоалкил, C(=O)X5 и C(=S)X5,
(1) указанный X5 выбран из группы, включающей замещенный или незамещенный фенил, замещенный или незамещенный гетероциклил, замещенный или незамещенный (C1-C8)алкил, O(C1-C8)алкил, O(C1-C8)галогеналкил, O(замещенный и незамещенный)фенил, N(R17a)(C1-C8)алкил, N(R17a)(C1-C8)галогеналкил, N(R17a)(C3-C8)циклоалкил, N(R17a)(замещенный и незамещенный фенил) и (C3-C6)циклоалкил,
(2) указанный замещенный фенил в (3)(c) содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, NO2, OH, (C1-C3)алкоксигруппу и (C1-C3)алкил,
(3) указанный замещенный гетероциклил в (3)(c) содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, NO2, OH, (C1-C3)алкоксигруппу и (C1-C3)алкил,
(4) указанный замещенный (C1-C8)алкил в (3)(c) содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, NO2, NH2, O(C1-C8)алкил, (C3-C8)циклоалкил, фенил, (C2-C8)алкенил, (C2-C8)алкинил, S(C1-C8)алкил, S(O)(C1-C8)алкил, S(O)2(C1-C8)алкил, O-фенил, O(C2-C8)алкенил, O(C1-C8)алкил(C3-C8)циклоалкил, O(C1-C8)алкилфенил, O(C1-C8)алкил(C3-C8)циклоалкил, C(=O)NH(C1-C8)алкил, NHC(=O)(C1-C8)алкил, S(O)2NH2, NH(C1-C3)алкил, N((C1-C3)алкил)2,
(5) указанный замещенный (C3-C8)циклоалкил содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, (C1-C3)алкоксигруппу и (C1-C3)алкил,
где в (2)(a), (2)(b) и (2)(c) каждый алкил, алкенил, алкинил, циклоалкил, галогеналкил, фенил и гетероциклил необязательно может содержать один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, NH2, NO2, (C1-C8)алкил, (C1-C8)алкоксигруппу, (C1-C8)галогеналкил, N((C1-C8)алкил)2 и C(=O)O(C1-C8)алкил, необязательно (N(R17b)(R17c)) означает гетерогидрокарбильное кольцо, содержащее 1 кольцевой атом азота и от 3 до 5 кольцевых атомов углерода, где указанное кольцо может быть насыщенным или ненасыщенным;(4) N(R18a)(N=C(R18b)(R18c)
(a) указанный R18a выбран из группы, включающей H, (C1-C3)алкил, (C2-C3)алкенил, (C2-C3)алкинил, (C1-C3)алкил-O(C1-C3)алкил,(C1-C3)алкил-OC(=O)(C1-C3)алкил и C(=O)(C1-C3)алкил,
(b) указанный R18b выбран из группы, включающей H и (C1-C3)алкил,
(c) указанный R18c выбран из группы, включающей замещенный или незамещенный фенил, замещенный или незамещенный гетероциклил, замещенный или незамещенный (C1-C8)алкил, замещенный или незамещенный (C3-C8)циклоалкил,
(1) указанный замещенный фенил в (4)(c) содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, NO2, OH, (C1-C3)алкоксигруппу, (C1-C3)алкил, (C1-C3)галогеналкоксигруппу и (C1-C3)галогеналкил,
(2) указанный замещенный гетероциклил в (4)(c) содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, NO2, OH, (C1-C3)алкоксигруппу, (C1-C3)алкил, (C1-C3)галогеналкоксигруппу и (C1-C3)галогеналкил,
(3) указанный замещенный (C1-C8)алкил содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, NO2, O(C1-C8)алкил, (C3-C8)циклоалкил, фенил, (C2-C8)алкенил, (C2-C8)алкинил, S(C1-C8)алкил, S(O)(C1-C8)алкил, S(O)2(C1-C8)алкил, O-фенил, O(C2-C8)алкенил, O(C1-C8)алкил(C3-C8)циклоалкил, O(C1-C8)алкилфенил, O(C1-C8)алкил(C3-C8)циклоалкил, C(=O)NH(C1-C8)алкил, NHC(=O)(C1-C8)алкил и S(O)2NH2,
(4) указанный замещенный (C3-C8)циклоалкил содержит один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, (C1-C3)алкоксигруппу и (C1-C3)алкил,
где в (4)(a), (4)(b) и (4)(c) каждый алкил, алкенил, алкинил, циклоалкил, галогеналкил, фенил и гетероциклил может содержать один или большее количество заместителей, выбранных из группы, включающей F, Cl, Br, I, CN, OH, NH2, NO2, (C1-C8)алкил, (C1-C8)алкоксигруппу, (C1-C8)галогеналкил, N((C1-C8)алкил)2 и C(=O)O(C1-C8)алкил, необязательно C(R18b)(R18c) означает гидрокарбильное кольцо, содержащее от 3 до 5 кольцевых атомов углерода, где указанное кольцо может быть насыщенным или ненасыщенным, необязательно один или большее количество указанных кольцевых атомов углерода могут представлять собой атом азота, кислорода или серы;
и N-оксиды, сельскохозяйственно приемлемые соли присоединения с кислотами, производные солей, сольваты, сложноэфирные производные, кристаллические полиморфные формы, изотопы, разделенные стереоизомеры, таутомеры, про-инсектициды молекул формулы 1.
2. Молекула по п. 1, где указанная молекула имеет следующую формулу
Figure 00000002
Формула 2.
3. Молекула по любому из предыдущих пунктов, в которой R1, R2, R3, R4, R5 все независимо выбраны из группы, включающей H, F, Cl, Br, SF5 и CF3.
4. Молекула по любому из предыдущих пунктов, в которой R7 и R8 означает Cl.
5. Молекула по любому из предыдущих пунктов, в которой R12 выбран из группы, включающей H, F, Cl, CH3 и CF3.
6. Молекула по любому из предыдущих пунктов, в которой R13 выбран из группы, включающей F, Cl, CH3 и OCH3.
7. Молекула по любому из предыдущих пунктов, в которой R14 выбран из группы, включающей H, F и Cl.
8. Молекула по п.п. 1 или 2, в которой:
R1 выбран из группы, включающей H, F, Cl, Br, SF5 и CF3;
R2 выбран из группы, включающей H, F, Cl, Br, SF5 и CF3;
R3 выбран из группы, включающей H, F, Cl, Br, SF5 и CF3;
R4 выбран из группы, включающей H, F, Cl, Br, SF5 и CF3;
R5 выбран из группы, включающей H, F, Cl, Br, SF5 и CF3;
R7 означает Cl;
R8 означает Cl;
Q1 означает O;
Q2 означает O;
R10 означает H;
R11 означает H;
R12 выбран из группы, включающей H, F, Cl, CH3 и CF3;
R13 выбран из группы, включающей F, Cl, CH3 и OCH3; и
R14 выбран из группы, включающей H, F и Cl.
9. Молекула по любому из предыдущих пунктов, в которой X3 означает N(R15a)(R15b).
10. Молекула по любому из пп. 1-8, в которой X3 означает N(R16a)(R16b).
11. Молекула по любому из пп. 1-8, в которой X3 означает N(R17a)(N(R17b)(R17c)).
12. Молекула по любому из пп. 1-8, в которой X3 означает N(R18a)(N=C(R18b)(R18c).
13. Молекула, выбранная из таблицы 2.
14. Композиция, содержащая молекулу по любому из пп. 1-13, дополнительно включающую активный ингредиент.
15. Способ борьбы с вредителем, включающий нанесение на участок пестицидно эффективного количества молекулы по любому из пп. 1-13 или композиции по п. 14.
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