RU2019109042A - Полиолефины с низкой зольностью и способ их получения - Google Patents
Полиолефины с низкой зольностью и способ их получения Download PDFInfo
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- RU2019109042A RU2019109042A RU2019109042A RU2019109042A RU2019109042A RU 2019109042 A RU2019109042 A RU 2019109042A RU 2019109042 A RU2019109042 A RU 2019109042A RU 2019109042 A RU2019109042 A RU 2019109042A RU 2019109042 A RU2019109042 A RU 2019109042A
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- olefin
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- 238000000034 method Methods 0.000 title claims 15
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 229920000098 polyolefin Polymers 0.000 title claims 2
- 229920000642 polymer Polymers 0.000 claims 10
- 150000001336 alkenes Chemical class 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 8
- 229910052782 aluminium Inorganic materials 0.000 claims 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 6
- 238000006116 polymerization reaction Methods 0.000 claims 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 229910052710 silicon Inorganic materials 0.000 claims 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 3
- 229910052749 magnesium Inorganic materials 0.000 claims 3
- 239000011777 magnesium Substances 0.000 claims 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 3
- 239000010703 silicon Substances 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- 239000010936 titanium Substances 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 2
- 229910052723 transition metal Inorganic materials 0.000 claims 2
- 150000003624 transition metals Chemical class 0.000 claims 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 239000003990 capacitor Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 229920005629 polypropylene homopolymer Polymers 0.000 claims 1
- 239000002210 silicon-based material Substances 0.000 claims 1
- 150000003623 transition metal compounds Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/10—Homopolymers or copolymers of propene
- C09D123/12—Polypropene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G2/00—Details of capacitors not covered by a single one of groups H01G4/00-H01G11/00
- H01G2/10—Housing; Encapsulation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/14—Organic dielectrics
- H01G4/18—Organic dielectrics of synthetic material, e.g. derivatives of cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Emergency Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (21)
1. Способ полимеризации, включающий:
контактирование олефина или смеси олефина и одного или нескольких сополимеризуемых мономеров в условиях полимеризации с каталитической композицией, содержащей:
один или несколько катализаторов полимеризации; и
агент регулирования селективности, содержащий, по меньшей мере, одно кремнийсодержащее соединение, имеющее, по меньшей мере, одну C1-C10-алкокси-группу, связанную с атомом кремния; и
получение полимера с общей зольностью меньше чем 15 ч/млн.
2. Способ по п. 1, в котором каталитическая композиция дополнительно содержит некоторое количество одного или несколько соединений агента из C2-C13-моно- или поликарбоксилатных сложных эфиров алифатических C2-C7-монокарбоновых кислот и их инертно замещенные производные.
3. Способ по п. 1, в котором каталитическая композиция содержит алюминийсодержащее соединение и соединение переходного металла, где отношение алюминия к переходному металлу составляет приблизительно 50 или меньше.
4. Способ по п. 3, в котором отношение алюминия к переходному металлу составляет приблизительно 25 или меньше.
5. Способ по п. 1, в котором производительность катализатора находится в интервале между 200 и 500 т/кг.
6. Способ по п. 1, в котором общая зольность составляет меньше чем 5 ч/млн.
7. Способ по п. 1, в котором полимер имеет, по меньшей мере, одно из следующих свойств: содержание титана от 30 до 300 ч/млрд, содержание кремния от 1 до 50 ч/млрд, содержание алюминия от 0,2 до 6 ч/млн или содержание магния от 0,1 до 1 ч/млн.
8. Способ по п. 1, в котором олефином является пропилен.
9. Способ по п. 1, в котором полимер имеет текучесть расплава от 0,5 до 400 г/10 мин, измеренную в соответствии со стандартом ASTM D-1238-01 при 230°C с нагрузкой 2,16 кг, полимеров на основе пропилена.
10. Способ по п. 1, в котором текучесть расплава составляет от 0,5 до 6 г/10 мин.
11. Способ по п. 1, в котором контактирование олефина или смеси олефина и одного или нескольких сополимеризуемых сомономеров в условиях полимеризации проходит в первом реакторе полимеризации с образованием активного полимера на основе олефина, и этот способ также включает контактирование в условиях полимеризации активного полимера на основе олефина, по меньшей мере, с одним олефином во втором реакторе полимеризации с образованием полимера с общей зольностью меньше чем 15 ч/млн.
12. Способ по п. 1, в котором полимер представляет собой не требующий промывки полимер на основе пропилена.
13. Способ по п. 1, также включающий нанесение покрытия на электротехническую деталь с помощью полимера.
14. Композиция, содержащая полиолефин и имеющая общую зольность меньше чем 15 ч/млн и, по меньшей мере, одно из следующих свойств: содержание титана от 30 до 300 ч/млрд, содержание кремния от 1 до 50 ч/млрд, содержание алюминия от 0,2 до 6 ч/млн или содержание магния от 0,1 до 1 ч/млн.
15. Полипропиленовый гомополимер с общей зольностью меньше чем 15 ч/млн и, по меньшей мере, с одним из следующих свойств: содержание титана от 30 до 300 ч/млрд, содержание кремния от 1 до 50 ч/млрд, содержание алюминия от 0,2 до 6 ч/млн или содержание магния от 0,1 до 1 ч/млн.
16. Изделие, содержащее композицию по п. 14.
17. Конденсаторная пленка, содержащая композицию по п. 14.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662381070P | 2016-08-30 | 2016-08-30 | |
| US62/381,070 | 2016-08-30 | ||
| PCT/US2017/049377 WO2018045030A1 (en) | 2016-08-30 | 2017-08-30 | Polyolefins with low ash content and method of making same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2019109042A true RU2019109042A (ru) | 2020-10-01 |
| RU2019109042A3 RU2019109042A3 (ru) | 2020-12-09 |
| RU2778642C2 RU2778642C2 (ru) | 2022-08-22 |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2018045020A1 (en) | 2018-03-08 |
| KR20190057289A (ko) | 2019-05-28 |
| MX2019002378A (es) | 2019-09-04 |
| BR112019003864A2 (pt) | 2019-06-18 |
| SG11201901662UA (en) | 2019-03-28 |
| JP7196074B2 (ja) | 2022-12-26 |
| JP2019524979A (ja) | 2019-09-05 |
| WO2018045030A1 (en) | 2018-03-08 |
| US11236222B2 (en) | 2022-02-01 |
| CO2019001885A2 (es) | 2019-05-31 |
| JP2019524980A (ja) | 2019-09-05 |
| KR20190059270A (ko) | 2019-05-30 |
| CN115160459A (zh) | 2022-10-11 |
| US20190300744A1 (en) | 2019-10-03 |
| CN109843939A (zh) | 2019-06-04 |
| RU2019109043A (ru) | 2020-10-01 |
| CN109843933A (zh) | 2019-06-04 |
| CN109843939B (zh) | 2024-04-26 |
| US11993700B2 (en) | 2024-05-28 |
| CA3035247A1 (en) | 2018-03-08 |
| US20220119632A1 (en) | 2022-04-21 |
| US20190194438A1 (en) | 2019-06-27 |
| RU2019109042A3 (ru) | 2020-12-09 |
| US11591458B2 (en) | 2023-02-28 |
| EP3507312A1 (en) | 2019-07-10 |
| RU2019109043A3 (ru) | 2021-04-30 |
| KR20230112746A (ko) | 2023-07-27 |
| KR102632778B1 (ko) | 2024-02-02 |
| EP3507312A4 (en) | 2020-06-03 |
| EP3507311A1 (en) | 2019-07-10 |
| BR112019003864B1 (pt) | 2023-02-14 |
| EP3507311A4 (en) | 2020-07-08 |
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