RU2018139015A - Сополимеры, содержащие полиалкиленоксидные группы и четвертичные атомы азота - Google Patents

Сополимеры, содержащие полиалкиленоксидные группы и четвертичные атомы азота Download PDF

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RU2018139015A
RU2018139015A RU2018139015A RU2018139015A RU2018139015A RU 2018139015 A RU2018139015 A RU 2018139015A RU 2018139015 A RU2018139015 A RU 2018139015A RU 2018139015 A RU2018139015 A RU 2018139015A RU 2018139015 A RU2018139015 A RU 2018139015A
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mass
monomer
carbon atoms
alkyl
methyl
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Аарон ФЛОРЕС-ФИГУЭРОА
Мартин РЮБЕНАКЕР
Райнер Добрава
Маркус Вилли Конрад БРИМ
Дитер БЁК
Франк ХЮЛЬСКЕТТЕР
Гленн УОРД
Джеймс Гудвин
Мелисса КАТБЕРТСОН
Стефано СКЬЯЛЛА
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Басф Се
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    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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  • Polymers & Plastics (AREA)
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Claims (32)

1. Сополимер, содержащий в сополимеризованной форме:
(А) от 60 до 99% масс. по меньшей мере одного моноэтиленненасыщенного полиалкиленоксидного мономера формулы I:
Figure 00000001
в которой переменные имеют следующие значения:
X означает -СН2- или -СО-, если Y означает -О-, или означает -СО-, если Y означает -NH-,
Y означает -О- или -NH-,
R1 означает водород или метил,
R2 означают одинаковые или разные алкиленовые радикалы с 2-6 атомами углерода, которые могут быть упорядочены блочно или статистически,
R3 означает водород или алкил с 1-4 атомами углерода,
n означает целое число от 25 до 75,
(B) от 1 до 40% масс. по меньшей мере одного кватернизованного азотсодержащего моноэтиленненасыщенного мономера, выбранного из группы, включающей мономеры формул IIa-IId:
Figure 00000002
Figure 00000003
Figure 00000004
Figure 00000005
в которых переменные имеют следующие значения:
R означает ал кил с 1-4 атомами углерода или бензил,
R' означает водород или метил,
Y означает -О- или -NH-,
А означает алкилен с 1-6 атомами углерода,
X- означает галогенид, алкилсульфат с 1-4 атомами углерода, алкилсульфонат с 1-4 атомами углерода или алкилкарбонат с 1-4 атомами углерода,
(C) от 0 до 10% масс. анионных моноэтиленненасыщенных мономеров, и
(D) от 0 до 30% масс. других неионных моноэтиленненасыщенных мономеров
и обладающий средней молекулярной массой Mw>100000.
2. Сополимер по п. 1, содержащий в качестве мономера (А) в сополимеризованной форме по меньшей мере один мономер формулы I, в которой переменные имеют следующие значения:
X означает -СО-,
Y означает -О-,
R1 означает водород или метил,
R2 означает этилен, пропилен или их смеси,
R3 означает метил,
n означает целое число от 51 до 65.
3. Сополимер по п. 1, содержащий в сополимеризованной форме от 60 до 98% масс. мономера (А), от 1 до 39% масс. мономера (В) и от 1 до 39% масс. мономера (С).
4. Сополимер по п. 1, причем массовое отношение (А) к (В) составляет ≥ 2:1 и причем в случае, если сополимер содержит мономер (С) в сополимеризованной форме, массовое отношение (В) к (С) также составляет ≥ 2:1.
5. Сополимер по одному из пп. 1-4, причем общий результирующий заряд указанного сополимера является катионным.
RU2018139015A 2016-04-08 2017-03-31 Сополимеры, содержащие полиалкиленоксидные группы и четвертичные атомы азота RU2736718C2 (ru)

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PCT/EP2017/057757 WO2017174468A1 (en) 2016-04-08 2017-03-31 Copolymers comprising polyalkylene oxide groups and quaternary nitrogen atoms

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