RU2018136235A - Гербициды - Google Patents

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RU2018136235A
RU2018136235A RU2018136235A RU2018136235A RU2018136235A RU 2018136235 A RU2018136235 A RU 2018136235A RU 2018136235 A RU2018136235 A RU 2018136235A RU 2018136235 A RU2018136235 A RU 2018136235A RU 2018136235 A RU2018136235 A RU 2018136235A
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hydrogen
haloalkyl
compound
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RU2018136235A
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RU2760349C2 (ru
RU2018136235A3 (ru
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Нил Брайан Картер
Эмма БРИГГЗ
Джеймс Алан Моррис
Меллони МОРРИС
Джозеф Эндрю ТЕЙТ
Джеффри Стивен Уэйлс
Джон УИЛЬЯМС
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Зингента Партисипейшнс Аг
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/89—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members with hetero atoms directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pyridine Compounds (AREA)

Claims (44)

1. Соединение формулы (I):
Figure 00000001
или его соль, где
X1 представляет собой N или CR1;
R1 выбран из группы, состоящей из водорода, галогена, циано, C1-C6алкила, C3-C6циклоалкила, C2-C6алкенила, C2-C6алкинила, C1-C6алкокси, -С(O)OC1-C6алкила, -S(O)pC1-C6алкила, NR6R7, C1-C6галогеналкокси и C1-C6галогеналкила;
R2 выбран из группы, состоящей из галогена, циано, нитро, C1-C6алкила, C1-C6 галогеналкила, C2-C6алкенила, C2-C6алкинила, C3-C6циклоалкила, -C(O)OC1-C6алкила, -S(O)р(C1-C6алкила), C1-C6алкокси, C1-C6 галогеналкокси и фенила;
R3 представляет собой -C(O)X2R12;
X2 представляет собой О или NR10;
если X2 представляет собой О, то R12 выбран из группы, состоящей из C1-C6алкила, CrалкоксиCsалкила, C1-C6галогеналкила, CrалкоксиCsгалогеналкила, CrалкилтиоCsалкила, C2-C6алкенила, C2-C6алкинила и -(CRaRb)qR11;
если X2 представляет собой NR10, то R12 выбран из группы, состоящей из водорода, C1-C6алкила, C1-C6алкокси, C1-C6галогеналкила, C1-C6галогеналкокси, СrалкилтиоСsалкила, C2-C6алкенила, C2-C6алкинила и -(CRaRb)qR11;
R10 выбран из группы, состоящей из водорода, C1-C6алкила, C3-C6циклоалкила;
или R10 и R12 вместе с атомом азота, к которому они присоединены, могут образовывать 5-, 6- или 7-членное кольцо, необязательно содержащее 1-3 дополнительных гетероатома, каждый из которых независимо выбран из О, N или S, где, если указанное кольцо содержит серу в кольце, указанная сера в кольце находится в форме S(O)p;
R4 выбран из группы, состоящей из водорода, C1-C6алкила, C1-C6алкокси, C1-C6галогеналкила, C1-C6галогеналкокси, C3-C6циклоалкила, C3-C6алкенила, C3-C6алкинила, -C(O)R9 и -(CRaRb)qR5;
Ra представляет собой водород или C1-С2алкил;
Rb представляет собой водород или C1-С2алкил;
R5 представляет собой циано, -С(O)OC1-C6алкил, -C3-C6циклоалкил, -арил или -гетероарил, где указанные арил и гетероарил необязательно замещены 1-3 независимыми R8;
R6 и R7 независимо выбраны из группы, состоящей из водорода и C1-C6алкила;
каждый R8 независимо выбран из группы, состоящей из галогена, C1-C6алкила и C1-C6алкокси-, C1-C6галогеналкила, C1-C6 галогеналкокси-, циано и S(O)р(C1-C6алкила);
R9 выбран из группы, состоящей из водорода, C1-C6алкила, C1-C6алкокси, C1-C6 галогеналкила, C1-C6галогеналкокси, C2-C6алкенила, C2-C6алкинила и -(CRaRb)qR11;
или R4 и R10 вместе с атомами, к которым они присоединены, образуют 5-7-членную кольцевую систему, необязательно содержащую 1-3 гетероатома, независимо выбранных из S, О и N;
или R4 и R12 вместе с атомами, к которым они присоединены, образуют 5-7-членную кольцевую систему, необязательно содержащую 1-3 гетероатома, независимо выбранных из S, О и N;
R11 представляет собой циано, -C3-C6циклоалкил или -арильное, -гетероарильное или -гетероциклильное кольцо, где указанное кольцо необязательно замещено 1-3 независимыми R8, и где, если указанное кольцо содержит серу в кольце, указанная сера в кольце находится в форме S(O)p;
n равняется 0 или 1;
р равняется 0, 1 или 2;
q равняется 0, 1, 2, 3, 4, 5 или 6;
r равняется 1, 2, 3, 4 или 5, s равняется 1, 2, 3, 4 или 5, и сумма r + s меньше или равняется 6;
при условии, что соединение формулы (I) не является
(i) трет-бутил-N-[2-метил-6-(3-пиридил)-3-пиридил]карбаматом или
(ii) 1-амино-1-этил-3-[2-метил-6-(3-пиридил)-3-пиридил]мочевиной.
2. Соединение формулы (I) по п. 1, где X1 представляет собой N.
3. Соединение формулы (I) по п. 1, где X1 представляет собой CR1, и R1 выбран из группы, состоящей из водорода, циано, галогена, C1-С3алкила, C3-С4алкинила, C1-С3алкокси, C1-C3 галогеналкила, C1-C3галогеналкокси и C1-C3 тиоалкила.
4. Соединение формулы (I) по любому из предыдущих пунктов, где R2 представляет собой галоген, циано, C1-C6алкил, C1-C6 галогеналкил, С(O)OC1-C6алкил или фенил.
5. Соединение формулы (I) по любому из предыдущих пунктов, где X2 представляет собой О.
6. Соединение формулы (I) по п. 5, где R12 выбран из группы, состоящей из водорода, C1-C6алкила, CrалкоксиCsалкила, C1-C6галогеналкила, CrалкоксиCsгалогеналкила, CrалкилтиоCsалкила, C2-C6алкенила, C2-C6алкинила и -(CRaRb)qR11.
7. Соединение формулы (I) по любому из пп. 1-4, где X2 представляет собой NR10.
8. Соединение формулы (I) по п. 7, где R10 представляет собой водород или C1-C6алкил;
или где R10 вместе с R4 и атомами, к которым R10 и R4 присоединены, образуют 5-7-членную кольцевую систему, необязательно содержащую 1-3 дополнительных гетероатома, независимо выбранных из S, О и N;
или где R10 вместе с R12 и атомом азота, к которому R10 и R12 присоединены, образуют 5-7-членную кольцевую систему, необязательно содержащую 1-3 дополнительных гетероатома, независимо выбранных из S в форме S(O)p, О и N.
9. Соединение формулы (I) по любому из предыдущих пунктов, где R4 выбран из группы, состоящей из водорода, метила, этила, аллила, бут-2-инила, C(O)R9 и -(CH2)qR5.
10. Гербицидная композиция, содержащая гербицидно эффективное количество соединения по любому из предыдущих пунктов и приемлемое с точки зрения сельского хозяйства вспомогательное средство для составления.
11. Гербицидная композиция по п. 10, дополнительно содержащая по меньшей мере один дополнительный пестицид.
12. Гербицидная композиция по п. 11, где дополнительный пестицид представляет собой гербицид или антидот гербицида.
13. Способ контроля сорняков в месте произрастания, предусматривающий применение по отношению к месту произрастания достаточного для контроля сорняков количества композиции по любому из пп. 10-12.
14. Применение соединения формулы (I) по любому из пп. 1-9 в качестве гербицида.
RU2018136235A 2016-03-23 2017-03-16 Гербициды RU2760349C2 (ru)

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Application Number Priority Date Filing Date Title
GB1604979.3 2016-03-23
GBGB1604979.3A GB201604979D0 (en) 2016-03-23 2016-03-23 Improvements in or relating to organic compounds
GB1606639.1 2016-04-15
GB201606639 2016-04-15
PCT/EP2017/056286 WO2017162522A1 (en) 2016-03-23 2017-03-16 Herbicides

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RU2018136235A3 RU2018136235A3 (ru) 2020-04-23
RU2760349C2 RU2760349C2 (ru) 2021-11-24

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KR102390392B1 (ko) 2022-04-22
US20210127673A1 (en) 2021-05-06
RU2760349C2 (ru) 2021-11-24
CA3016123A1 (en) 2017-09-28
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ES2899104T3 (es) 2022-03-10
BR112018069397B1 (pt) 2022-08-23
CN108779107B (zh) 2022-04-26
RU2018136235A3 (ru) 2020-04-23
AU2017239000B2 (en) 2021-07-29
AU2017239000A1 (en) 2018-09-13
CN108779107A (zh) 2018-11-09
UY37163A (es) 2017-10-31
UA125690C2 (uk) 2022-05-18
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