RU2016148233A - Катализатор дегидрования углеводородов - Google Patents

Катализатор дегидрования углеводородов Download PDF

Info

Publication number
RU2016148233A
RU2016148233A RU2016148233A RU2016148233A RU2016148233A RU 2016148233 A RU2016148233 A RU 2016148233A RU 2016148233 A RU2016148233 A RU 2016148233A RU 2016148233 A RU2016148233 A RU 2016148233A RU 2016148233 A RU2016148233 A RU 2016148233A
Authority
RU
Russia
Prior art keywords
compound
mass
catalyst
calculated
dehydrogenation
Prior art date
Application number
RU2016148233A
Other languages
English (en)
Russian (ru)
Other versions
RU2016148233A3 (enExample
Inventor
Флорина Корина ПАТКАС
Бернд ХИНРИКСЕН
Мартин ДИТЕРЛЕ
Original Assignee
Басф Се
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of RU2016148233A publication Critical patent/RU2016148233A/ru
Publication of RU2016148233A3 publication Critical patent/RU2016148233A3/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8898—Manganese, technetium or rhenium containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/889—Manganese, technetium or rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
RU2016148233A 2014-05-09 2015-05-06 Катализатор дегидрования углеводородов RU2016148233A (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14167665.0 2014-05-09
EP14167665 2014-05-09
PCT/EP2015/059907 WO2015169825A1 (de) 2014-05-09 2015-05-06 Katalysator für die dehydrierung von kohlenwasserstoffen

Publications (2)

Publication Number Publication Date
RU2016148233A true RU2016148233A (ru) 2018-06-09
RU2016148233A3 RU2016148233A3 (enExample) 2018-12-10

Family

ID=50678082

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2016148233A RU2016148233A (ru) 2014-05-09 2015-05-06 Катализатор дегидрования углеводородов

Country Status (6)

Country Link
US (1) US10315970B2 (enExample)
EP (1) EP3140267B1 (enExample)
JP (1) JP6596445B2 (enExample)
CN (1) CN106536043B (enExample)
RU (1) RU2016148233A (enExample)
WO (1) WO2015169825A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6720086B2 (ja) * 2014-05-09 2020-07-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 炭化水素の脱水素化のための改良された触媒
CN107790150B (zh) * 2016-09-06 2020-10-16 中国石油化工股份有限公司 生产烷烯基芳烃的催化剂
EP3868468B1 (en) * 2018-10-16 2025-08-27 China Petroleum & Chemical Corporation Catalyst for dehydrogenation of alkyl aromatic hydrocarbon and preparation method therefor
RU2726125C1 (ru) * 2020-01-10 2020-07-09 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Катализатор для дегидрирования алкилароматических углеводородов
DE102020112372A1 (de) * 2020-05-07 2021-11-11 Clariant International Ltd Verfahren zur herstellung von katalysatoren mit 3d-drucktechnik
EP4015078A1 (en) * 2020-12-15 2022-06-22 Clariant International Ltd Process of producing alkenylaromatic compound using dehydrogenation catalyst
CN115888745B (zh) * 2021-09-30 2025-09-26 中国石油化工股份有限公司 脱氢催化剂及其制备方法和应用以及烷基芳烃脱氢制烯基芳烃的方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58177148A (ja) 1982-04-13 1983-10-17 Mitsubishi Petrochem Co Ltd スチレン製造用触媒
DE3442636A1 (de) 1984-11-22 1986-05-22 Süd-Chemie AG, 8000 München Dehydrierungskatalysator
JPS6434445A (en) * 1985-02-20 1989-02-03 Dow Chemical Co Dehydrogenating catalyst improved in humidity resistance and its production
US4758543A (en) 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
DE19535416A1 (de) 1995-09-23 1997-03-27 Basf Ag Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen
JPH10273452A (ja) * 1997-03-31 1998-10-13 Idemitsu Petrochem Co Ltd アルキル芳香族炭化水素の脱水素反応用触媒およびその製造方法ならびにこれを用いたビニル芳香族炭化水素の製造方法
IT1293531B1 (it) 1997-08-01 1999-03-01 Sud Chemie Mt S R L Ex Monteca Catalizzatori per la deidrogenazione dell'etilbenzene a stirene
DE19814080A1 (de) 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung
EP1027928B1 (de) * 1999-02-10 2006-03-01 Basf Aktiengesellschaft Katalysator zur Dehydrierung von Ethylbenzol zu Styrol
JP2008520685A (ja) * 2004-11-18 2008-06-19 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 低蒸気対油プロセス条件下でアルケニル芳香族化合物を製造するための改良された方法
US8003837B2 (en) * 2005-07-22 2011-08-23 Basf Se Catalysts for dehydrogenation and/or hydrogenation of hydrocarbons, processes for preparing the same, and uses therefor
RU2302293C1 (ru) 2006-05-06 2007-07-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Катализатор, способ его приготовления и способ дегидрирования алкилароматических углеводородов
JP5096751B2 (ja) 2007-01-26 2012-12-12 クラリアント触媒株式会社 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法
RU2325229C1 (ru) 2007-03-15 2008-05-27 Открытое акционерное общество "Нижнекамскнефтехим" Катализатор для дегидрирования алкилароматических углеводородов
CA2685700A1 (en) * 2007-05-03 2008-11-13 Shell Internationale Research Maarschappij B.V. A catalyst, its preparation and use
US20130165723A1 (en) * 2011-12-22 2013-06-27 Basf Se Catalyst for the dehydrogenation of hydrocarbons
JP6720086B2 (ja) * 2014-05-09 2020-07-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 炭化水素の脱水素化のための改良された触媒

Also Published As

Publication number Publication date
JP6596445B2 (ja) 2019-10-23
CN106536043B (zh) 2020-07-31
US10315970B2 (en) 2019-06-11
EP3140267A1 (de) 2017-03-15
US20170121241A1 (en) 2017-05-04
RU2016148233A3 (enExample) 2018-12-10
WO2015169825A1 (de) 2015-11-12
JP2017517388A (ja) 2017-06-29
EP3140267B1 (de) 2021-03-31
CN106536043A (zh) 2017-03-22

Similar Documents

Publication Publication Date Title
RU2016148233A (ru) Катализатор дегидрования углеводородов
RU2016148232A (ru) Улучшенный катализатор дегидрирования углеводородов
JP2017517388A5 (enExample)
JP2017521231A5 (enExample)
JP6725398B2 (ja) Ｓｃｍ−１１モレキュラーシーブ、その製造方法及びその使用
Dedov et al. Oxidative coupling of methane catalyzed by rare earth oxides: Unexpected synergistic effect of the oxide mixtures
JP6669633B2 (ja) Ｓｃｍ−１０モレキュラーシーブ、その製造方法及びその使用
US9713804B2 (en) Catalyst composition for the dehydrogenation of alkanes
AR076026A1 (es) Proceso para la preparacion de catalizadores utiles en la conversion de parafinas en olefinas
RU2015109709A (ru) Оксидный катализатор и способ его получения, а также способы получения ненасыщенного альдегида, диолефина и ненасыщенного нитрила
WO2012121974A3 (en) Refractory mixed-metal oxides and spinel compositions for thermo-catalytic conversion of biomass
KR20140108264A (ko) 알칸 탈수소화에 유용한 아연 및/또는 망간 알루미네이트 촉매
AR076025A1 (es) Catalizadores para la conversion de parafinas en olefinas y sus usos
TW201041841A (en) Method for manufacturing olefin
MY159015A (en) Oxide catalyst, process for production of oxide catalyst, process for production of unsaturated acid, and process for production of unsaturated nitrile
JP6494803B2 (ja) フェライト金属酸化物触媒の製造方法
IN2015DN01735A (enExample)
KR101706851B1 (ko) 다성분계 복합금속산화물 촉매의 제조방법
RU2014129892A (ru) Катализатор для дегидрирования углеводородов
TWI605030B (zh) Composite oxide and its manufacturing method and use
CN103433026A (zh) 一种ZrO2负载的高稳定性耐硫甲烷化催化剂
JP2015506830A5 (enExample)
JP5906167B2 (ja) 金属酸化物触媒、その製造方法及びアルカジエンの製造方法
TW200902149A (en) Y-85 and modified LZ-210 zeolites
RU2016122060A (ru) Оксидный катализатор, способ его изготовления и способ получения ненасыщенного нитрила

Legal Events

Date Code Title Description
FA94 Acknowledgement of application withdrawn (non-payment of fees)

Effective date: 20200701