RU2016119772A - Применение полиалкиленгликоля в качестве присадки для топлива - Google Patents

Применение полиалкиленгликоля в качестве присадки для топлива Download PDF

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RU2016119772A
RU2016119772A RU2016119772A RU2016119772A RU2016119772A RU 2016119772 A RU2016119772 A RU 2016119772A RU 2016119772 A RU2016119772 A RU 2016119772A RU 2016119772 A RU2016119772 A RU 2016119772A RU 2016119772 A RU2016119772 A RU 2016119772A
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fuel
groups
additive
polyalkylene glycol
alkylene
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Людвиг ФЕЛЬКЕЛЬ
Маркус ХАНШ
Томас ХАЙДЕН
Марк ВАЛЬТЕР
Навид КАШАНИ-ШИРАЗИ
Томас ВАЙСС
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Басф Се
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Claims (34)

1. Применение полиалкиленгликоля общей формулы I
Figure 00000001
в которой А представляет собой С3-С20-алкиленовую группу или смесь таких алкиленовых групп, m равно числу от 2 до 100, и р и q каждое представляет собой число от 1 до 100,
в качестве присадки для топлива для уменьшения расхода топлива при работе двигателя внутреннего сгорания с этим топливом.
2. Применение полиалкиленгликоля общей формулы I
Figure 00000002
в которой А представляет собой С3-С20-алкиленовую группу или смесь таких алкиленовых групп, m равно числу от 2 до 100, и р и q каждое представляет собой число от 1 до 100,
в качестве присадки для топлива для минимизации потери мощности в двигателях внутреннего сгорания и для улучшения ускорения двигателей внутреннего сгорания.
3. Применение полиалкиленгликоля общей формулы I
Figure 00000003
в которой А представляет собой С3-С20-алкиленовую группу или смесь таких алкиленовых групп, m равно числу от 2 до 100, и р и q каждое представляет собой число от 1 до 100,
в качестве присадки для топлива для улучшения смазочной способности смазочных масел, содержащихся в двигателе внутреннего сгорания, в целях смазывания посредством работы двигателя внутреннего сгорания с топливом, содержащим эффективное количество по меньшей мере одного из указанных полиалкиленгликолей.
4. Применение по одному из пп. 1-3, где А в общей формуле I представляет собой смесь двух различных типов алкиленовых групп А1 и А2, где А1 обозначает одну или более С3-С7-алкиленовых групп, и А2 обозначает одну или более C8-С20-апкиленовых групп, причем A1 and А2 располагаются статистически или блочным образом.
5. Применение по одному из пп. 1-3, где А в общей формуле I представляет собой C8-С20-алкиленовую группу (А2) или смесь C8-С20-алкиленовых групп (А2), расположенных статистически.
6. Применение по одному из пп. 1-3 полиалкиленгликоля, получаемого алкоксилированием полиэтиленгликолей общей формулы II
Figure 00000004
где m равно числу от 2 до 100,
с 2-200 молями С3-С20-алкиленоксида или смеси таких алкиленоксидов на моль полиэтиленгликоля II, причем продукт алкоксилирования располагается статистически или блочным образом.
7. Топливная композиция содержащая, в основном количестве, бензиновое топливо и, в незначительном количестве, по меньшей мере один полиалкиленгликоль, как описано в пп. 1-6, и по меньшей мере одну присадку для топлива, которая отличается от указанного полиалкиленгликоля и имеет детергентное действие.
8. Топливная композиция по п. 7, содержащая в качестве присадки для топлива, которая отлична от указанного полиалкиленгликоля и имеет детергентное действие, по меньшей мере один представитель (D), выбранный из:
(Da) моно- или полиаминогрупп, имеющих до 6 атомов азота, причем по меньшей мере один атом азота имеет основные свойства;
(Db) нитрогрупп, при необходимости в комбинации с гидроксильными группами;
(Dc) гидроксильных групп в комбинации с моно- или полиаминогруппами, причем по меньшей мере один атом азота имеет основные свойства;
(Dd) карбоксильных групп или их солей с щелочными металлами или щелочноземельными металлами;
(De) сульфогрупп или их солей с щелочными металлами или щелочноземельными металлами;
(Df) полиокси-С2-С4-алкиленовых составляющих с концевыми гидроксильными группами, моно- или полиаминогруппами, причем по меньшей мере один атом азота имеет основные свойства, или концевыми карбаматными группами;
(Dg) карбоксильных сложноэфирных групп;
(Dh) составляющих, полученных из янтарного ангидрида и имеющих гидроксильные и/или амино и/или амидо и/или имидо группы; и/или
(Di) составляющих, полученных посредством реакции Манниха замещенных фенолов с альдегидами и моно- или полиаминами.
9. Топливная композиция по п. 7, дополнительно содержащая, в качестве дополнительной присадки для топлива в незначительном количестве, по меньшей мере одно масло-носитель.
10. Топливная композиция по п. 7, дополнительно содержащая, в качестве дополнительной присадки для топлива, в незначительном количестве, по меньшей мере один третичный гидрокарбиламин формулы NR1R2R3, в которой R1, R2 и R3 представляют собой одинаковые или различные С1-С20-гидрокарбильные остатки, при условии, что общее число атомов углерода в формуле NR1R2R3 не превышает 30.
11. Топливная композиция по одному из пп. 7-10, содержащая по меньшей мере один представитель (D), выбранный из (Da) полиизобутенмоноаминов или полиизобутенполиаминов, имеющих Mn=300-5000, имеющих по меньшей мере 50 мол. % винилиденовых двойных связей и полученных гидроформилированием соответствующего полиизобутена и последующим восстановительным аминированием с аммиаком, моноаминами или полиаминами, в комбинации с по меньшей мере одним минеральным или синтетическим маслом-носителем.
12. Присадочный концентрат, содержащий по меньшей мере один полиалкиленгликоль, как описано в пп. 1-6, и по меньшей мере одну присадку для топлива, которая отличается от полиалкиленгликоля и имеет детергентное действие.
13. Присадочный концентрат по п. 12, содержащий по меньшей мере один представитель (D), выбранный из (Da) полиизобутенмоноаминов или полиизобутенполиаминов, имеющих Mn=300-5000, имеющих по меньшей мере 50 мол. % винилиденовых двойных связей и полученных гидроформилированием соответствующего полиизобутена и последующим восстановительным аминированием с аммиаком, моноаминами или полиаминами, и дополнительно содержащий по меньшей мере одно минеральное или синтетическое масло-носитель.
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