RU2016115074A - Композитные материалы для применения при интенсификации добычи нефти и контроле поступления песка в скважину - Google Patents
Композитные материалы для применения при интенсификации добычи нефти и контроле поступления песка в скважину Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims 3
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- 239000007787 solid Substances 0.000 claims 18
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- 238000012986 modification Methods 0.000 claims 14
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- 238000000034 method Methods 0.000 claims 13
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- 230000015572 biosynthetic process Effects 0.000 claims 5
- 150000002430 hydrocarbons Chemical class 0.000 claims 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 239000011248 coating agent Substances 0.000 claims 4
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 239000000806 elastomer Substances 0.000 claims 3
- 239000012530 fluid Substances 0.000 claims 3
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- 150000002902 organometallic compounds Chemical group 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 244000043261 Hevea brasiliensis Species 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 2
- 239000000853 adhesive Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
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- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
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- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical class O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 239000008186 active pharmaceutical agent Substances 0.000 claims 1
- 229920003232 aliphatic polyester Polymers 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 claims 1
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- 239000007795 chemical reaction product Substances 0.000 claims 1
- 230000008021 deposition Effects 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 229920003049 isoprene rubber Polymers 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
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- 229920000636 poly(norbornene) polymer Polymers 0.000 claims 1
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- 229920000139 polyethylene terephthalate Polymers 0.000 claims 1
- 239000005020 polyethylene terephthalate Substances 0.000 claims 1
- 229920001195 polyisoprene Polymers 0.000 claims 1
- 229920001709 polysilazane Polymers 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
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- 239000010937 tungsten Substances 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/80—Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
- C09K8/805—Coated proppants
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/524—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning organic depositions, e.g. paraffins or asphaltenes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/528—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning inorganic depositions, e.g. sulfates or carbonates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/02—Subsoil filtering
- E21B43/025—Consolidation of loose sand or the like round the wells without excessively decreasing the permeability thereof
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/14—Obtaining from a multiple-zone well
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/267—Methods for stimulating production by forming crevices or fractures reinforcing fractures by propping
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/56—Compositions for consolidating loose sand or the like around wells without excessively decreasing the permeability thereof
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- Environmental & Geological Engineering (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
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- Processes Of Treating Macromolecular Substances (AREA)
- Processing Of Solid Wastes (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Claims (56)
1. Композитный материал для обработки скважины, где композитный материал включает агент для модификации поверхности, который нанесен, по крайней мере, частично на твердую частицу в виде покрытия, и где агент для модификации поверхности содержит содержащий металл якорный фрагмент и гидрофобный хвост, где гидрофобный хвост представляет собой кремнийорганическое соединение, фторированный углеводород или оба компонента - кремнийорганическое соединение и фторированный углеводород, и кроме того, где содержащий металл якорный фрагмент в составе агента для модификации поверхности присоединен к твердой частице.
2. Композитный материал по п. 1, где гидрофобный материал представляет собой производное силана, полисилоксана или полисилазана.
3. Композитный материал по п. 1, где металл в составе содержащего металл якорного фрагмента означает металл группы 3, 4, 5 или 6.
4. Композитный материал по п. 3, где металл в составе содержащего металл якорного фрагмента выбирают из группы, включающей Ti, Zr, La, Hf, Ta, W или Nb.
5. Композитный материал по п. 1, где гидрофобным хвостом является производное кремнийорганического соединения формулы
R1 4-xSiAx или (R1 3Si)yB,
или органо(поли)силоксанов и органо(поли)силазанов формулы:
где R1 могут быть одинаковыми или различными и могут означать углеводородный радикал или замещенный углеводородный радикал, содержащий от 1 до 100 атомов углерода,
А означает водород, галоген, ОН, OR2 или
В означает NR3 3-y,
R2 означает углеводородный или замещенный углеводородный радикал, содержащий от 1 до 12 атомов углерода,
R3 означает водород или R1,
х равен 1, 2 или 3, и
y равен 1 или 2.
6. Композитный материал по п. 1, где фторированный углеводородный радикал характеризуется структурой
где Y означает F или CnF2n+1, m равен от 4 до 20 и т равен от 1 до 6, R2 означает алкил, содержащий от 1 до 4 атомов углерода, а p равен от 0 до 18.
7. Композитный материал по п. 1, где фторированный углеводородный радикал характеризуется структурой
где А означает кислород или химическую связь, n равен от 1 до 6, Y означает F или CnF2n, b равен, по крайней мере, 1, m равен от 0 до 6, а р равен от 0 до 18.
8. Композитный материал по п. 2, где органо(поли)силоксаны и органо(поли)силазаны содержат звенья формулы:
где R1 могут быть одинаковыми или различными и могут означать углеводородный радикал или замещенный углеводородный радикал, содержащий от 1 до 12 атомов углерода, a R3 означает водород или R1.
9. Композитный материал по п. 1, где гидрофобный хвост содержит звенья R5 2SiO2, где R5 означает галоген.
10. Композитный материал по п. 1, дополнительно включающий клейкий агент между твердой частицей и содержащим металл якорным фрагментом для связывания содержащего металл якорного фрагмента с твердой частицей.
11. Композитный материал по п. 10, где клейким агентом является металлоорганическое соединение.
12. Композитный материал по п. 11, где металлоорганическое соединение включает переходный металл, выбранный из группы, включающей титан, цирконий, лантан, гафний, тантал и вольфрам и их смеси.
13. Композитный материал по п. 1, где твердые частицы выбирают из группы, включающей керамику, песок, минералы, скорлупу орехов, гравий, полимерные частицы и их смеси.
14. Композитный материал по п. 13, где полимерные частицы представляют собой шарики или пеллеты из полистирола, нейлона, полистиролдивинилбензола, полиэтилентерефталата или их комбинаций.
15. Композитный материал по п. 13, где твердые частицы дополнительно содержат покрытие из смолы.
16. Твердые частицы расклинивающего агента или агента для контроля выноса песка, содержащие композитный материал по п. 1.
17. Композитный материал по п. 1, где твердые частицы включают эластомер.
18. Композитный материал по п. 17, где эластомер выбирают из группы, включающей природный каучук, сополимеры этилена, пропилена и диена (EPDM), нитрильные каучуки, карбоксилированные сополимеры акрилонитрила и бутадиена, смеси поливинилхлорид-нитрилбутадиена, хлорированный полиэтилен, хлорированный сульфонат полиэтилена, алифатические сложные полиэфиры с хлорированными боковыми цепями, полиакрилатные каучуки, терполимеры этилена и акрилата, сополимеры этилена и пропилена, и необязательно включающие один или более этилен-ненасыщенных мономеров, сополимеры этилена и винилацетата, фторуглеродистые полимеры и сополимеры, поливиниметиловый простой эфир, бутадиеновый каучук, полихлоропреновый каучук, полиизопреновый каучук, полинорборнены, полисульфидные каучуки, полиуретаны, силиконовые каучуки, винилсиликоновые каучуки, фторметилсиликоновый каучук, фторвинилсиликоновые каучуки, фенилметилсиликоновые каучуки, стиролбутадиеновые каучуки, сополимеры изобутилена и изопрена или бутилкаучуки, бромированные сополимеры изобутилена и изопрена и хлорированные сополимеры изобутилена и изопрена и их смеси.
19. Композитный материал по п. 18, где эластомером является природный каучук или полимер, по крайней мере, одного из мономеров, выбранных из группы, включающей винилиденфторид, гексафторпропилен, тетрафторэтилен, хлортрифторэтилен, перфтор(алкилвиниловый простой эфир).
20. Способ обработки скважины, проходящей через подземный пласт, включающий закачивание в скважину композитного материала по п. 1 или формирование композитного материала в скважине in situ.
21. Способ по п. 20, где, по крайней мере, одно из следующих условий имеет приоритетное значение:
(а) агент для модификации поверхности проявляет функцию пассивного противобактериального агента,
(б) агент для модификации поверхности проявляет функцию пассивного подавления или контроля солевых отложений на подземном пласте или внутри него,
(в) агент для модификации поверхности пассивно предотвращает или контролирует отложения органических частиц на подземном пласте или внутри него,
(г) агент для модификации поверхности в составе композитного материала контролирует вынос расклинивающего агента.
22. Способ по п. 20, где композитный материал закачивают в скважину в ходе операции по гидроразрыву, и кроме того где твердые частицы способны выдерживать нагрузки более приблизительно 1500 фунтов на кв.дюйм при температуре выше 150°F.
23. Способ по п. 20, где композитный материал формируется in situ при первом закачивании твердых частиц в скважину, а затем на твердые частицы, по крайней мере, частично наносят покрытие при последующем закачивании агента для модификации поверхности в скважину.
24. Композитный материал для обработки ствола скважины, где композитный материал включает твердые частицы и агент для модификации поверхности, который нанесен, по крайней мере, частично на твердую частицу в виде покрытия, и где агент для модификации поверхности содержит якорный фрагмент и, по крайней мере, один гидрофобный хвост, присоединенный к якорному фрагменту, а якорный фрагмент присоединен к твердой частице.
25. Композитный материал по п. 24, где агент для модификации поверхности представляет собой продукт реакции металлоорганического соединения, включающего содержащий кислород лиганд, и материала, содержащего кремнийорганическое соединение.
26. Композитный материал по п. 24, где агент для модификации поверхности характеризуется формулой Х-М, где М означает содержащий металлорганический лиганд, а X означает гидрофобный хвост.
27. Способ обработки скважины, проходящей через подземный пласт, включающий закачивание в скважину композитного материала по п. 24 или формирование композитного материала in situ в скважине.
28. Способ по п. 27, где композитный материал закачивают в скважину или он формируется in situ в скважине в ходе операции по гидроразрыву или операции по контролю выноса песка.
29. Способ по п. 27, где пласт, через который проходит скважина, содержит множество продуктивных зон и где композитный материал изолирует предварительно определенную продуктивную зону от других зон в скважине.
30. Способ по п. 27, где композитный материал сводит к минимуму потери трубчатого давления на трение в скважине.
31. Способ по п. 27, где количество мелкозернистого материала и/или песка, которые мигрируют в ходе обработки скважины, снижается в присутствии агента для модификации поверхности, которым покрыты твердые частицы.
32. Способ по п. 27, где гидрофобный хвост в составе композитного материала расположен в отдалении от поверхности твердой частицы.
33. Способ по п. 27, где флюид, содержащий композитный материал, закачивают в скважину в ходе операции по гидроразрыву, и где твердыми частицами является расклинивающий агент и, кроме того, величина прочности на раздавливание расклинивающего агента при напряжении смыкания трещины на уровне 1500 фунтов на кв. дюйм AAPI 56 или API RP 60, превосходит величину прочности на раздавливание чистого расклинивающего агента, который в основном идентичен чистому расклинивающему агенту, не содержащему, по крайней мере, частичное покрытие из агента для модификации поверхности.
34. Способ по п. 27, дополнительно включающий добычу углеводородов из скважины и снижение потерь давления на трение в ходе добычи углеводородов.
35. Способ по п. 27, где угол скольжения флюида в скважине на поверхности композитного материала меньше угла скольжения того же самого флюида на поверхности чистой твердой частицы, не содержащей присоединенный к ней агент для модификации поверхности.
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| EP3046991B1 (en) | 2019-10-30 |
| CN105555909A (zh) | 2016-05-04 |
| NZ716773A (en) | 2020-06-26 |
| WO2015042486A1 (en) | 2015-03-26 |
| CN105555909B (zh) | 2019-03-12 |
| CA2922688C (en) | 2018-10-30 |
| CA2922688A1 (en) | 2015-03-26 |
| SA516370766B1 (ar) | 2017-08-08 |
| AU2014321302A1 (en) | 2016-03-03 |
| RU2670802C9 (ru) | 2018-11-26 |
| BR112016005841B1 (pt) | 2022-02-08 |
| BR112016005841A2 (ru) | 2017-08-01 |
| EP3046991A1 (en) | 2016-07-27 |
| CA3009048A1 (en) | 2015-03-26 |
| US20150083415A1 (en) | 2015-03-26 |
| US9562188B2 (en) | 2017-02-07 |
| MX2016002656A (es) | 2016-06-06 |
| AU2014321302B2 (en) | 2017-12-07 |
| RU2670802C2 (ru) | 2018-10-25 |
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