RU2013149720A - METHOD FOR PRODUCING Bicyclo [4.2.1] NONA-2,4-DIENES - Google Patents

METHOD FOR PRODUCING Bicyclo [4.2.1] NONA-2,4-DIENES Download PDF

Info

Publication number
RU2013149720A
RU2013149720A RU2013149720/04A RU2013149720A RU2013149720A RU 2013149720 A RU2013149720 A RU 2013149720A RU 2013149720/04 A RU2013149720/04 A RU 2013149720/04A RU 2013149720 A RU2013149720 A RU 2013149720A RU 2013149720 A RU2013149720 A RU 2013149720A
Authority
RU
Russia
Prior art keywords
dienes
nona
acac
diene
cgt
Prior art date
Application number
RU2013149720/04A
Other languages
Russian (ru)
Other versions
RU2551278C1 (en
Inventor
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов
Гульнара Назифовна Кудикова
Леонард Мухибович Халилов
Original Assignee
Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук filed Critical Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
Priority to RU2013149720/04A priority Critical patent/RU2551278C1/en
Application granted granted Critical
Publication of RU2013149720A publication Critical patent/RU2013149720A/en
Publication of RU2551278C1 publication Critical patent/RU2551278C1/en

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ получения бицикло[4.2.1]нона-2,4-диенов общей формулы (1)где R=H, -(CH)-;R=Me, Bu, Hex, Ph, Bn, -(CH)-, -(CH)-, CHTMS;R=H, -(CH)-, Ph, CHTMSкаталитическим взаимодействием 1,2-диенов с 1,3,5-циклогептатриеном (ЦГТ), отличающийся тем, что в качестве каталитической системы используется Ti(acac)Cl-EtAlCl, в качестве 1,2-диена - соединение общей формулыгде R, R, Rуказаны выше,реакцию проводят при мольном соотношении 1,2-диен:ЦГТ:Ti(асас)Cl:EtAlCl=(10-14):10:(0.1-0.3):4 предпочтительно 12:10:0.2:4, в ампуле при температуре 20-80°C, в бензоле, в течение 6-48 ч.The method of producing bicyclo [4.2.1] nona-2,4-dienes of the general formula (1) where R = H, - (CH) -; R = Me, Bu, Hex, Ph, Bn, - (CH) -, - (CH) -, CHTMS; R = H, - (CH) -, Ph, CHTMS by the catalytic interaction of 1,2-dienes with 1,3,5-cycloheptatriene (CGT), characterized in that Ti (acac is used as a catalytic system ) Cl-EtAlCl, as a 1,2-diene - a compound of the general formula where R, R, R are indicated above, the reaction is carried out at a molar ratio of 1,2-diene: CGT: Ti (acac) Cl: EtAlCl = (10-14): 10: (0.1-0.3): 4 preferably 12: 10: 0.2: 4, in an ampoule at a temperature of 20-80 ° C, in benzene, for 6-48 hours

Claims (1)

Способ получения бицикло[4.2.1]нона-2,4-диенов общей формулы (1)The method of producing bicyclo [4.2.1] nona-2,4-dienes of the general formula (1)
Figure 00000001
Figure 00000001
 где R=H, -(CH2)6-;where R = H, - (CH 2 ) 6 -; R1=Me, Bu, Hex, Ph, Bn, -(CH2)6-, -(CH2)5-, CH2TMS;R 1 = Me, Bu, Hex, Ph, Bn, - (CH 2 ) 6 -, - (CH 2 ) 5 -, CH 2 TMS; R2=H, -(CH2)5-, Ph, CH2TMSR 2 = H, - (CH 2 ) 5 -, Ph, CH 2 TMS каталитическим взаимодействием 1,2-диенов с 1,3,5-циклогептатриеном (ЦГТ), отличающийся тем, что в качестве каталитической системы используется Ti(acac)2Cl2-Et2AlCl, в качестве 1,2-диена - соединение общей формулы
Figure 00000002
catalytic interaction of 1,2-dienes with 1,3,5-cycloheptatriene (CGT), characterized in that Ti (acac) 2 Cl 2 -Et 2 AlCl is used as a catalytic system, and a common compound is used as 1,2-diene formulas
Figure 00000002
 где R, R1, R2 указаны выше,where R, R 1 , R 2 are indicated above, реакцию проводят при мольном соотношении 1,2-диен:ЦГТ:Ti(асас)2Cl2:Et2AlCl=(10-14):10:(0.1-0.3):4 предпочтительно 12:10:0.2:4, в ампуле при температуре 20-80°C, в бензоле, в течение 6-48 ч. the reaction is carried out at a molar ratio of 1,2-diene: TSHT: Ti (acac) 2 Cl 2 : Et 2 AlCl = (10-14): 10: (0.1-0.3): 4 preferably 12: 10: 0.2: 4, in ampoule at a temperature of 20-80 ° C, in benzene, for 6-48 hours
RU2013149720/04A 2013-11-06 2013-11-06 Method of producing bicyclo[4,2,1]nona-2,4-dienes RU2551278C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2013149720/04A RU2551278C1 (en) 2013-11-06 2013-11-06 Method of producing bicyclo[4,2,1]nona-2,4-dienes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2013149720/04A RU2551278C1 (en) 2013-11-06 2013-11-06 Method of producing bicyclo[4,2,1]nona-2,4-dienes

Publications (2)

Publication Number Publication Date
RU2013149720A true RU2013149720A (en) 2015-05-20
RU2551278C1 RU2551278C1 (en) 2015-05-20

Family

ID=53283660

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2013149720/04A RU2551278C1 (en) 2013-11-06 2013-11-06 Method of producing bicyclo[4,2,1]nona-2,4-dienes

Country Status (1)

Country Link
RU (1) RU2551278C1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2726195C2 (en) * 2018-12-14 2020-07-09 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук Method of producing si-containing bicyclo[4_2_1]nona-2,4,7-trienes exhibiting antitumour activity

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1239298B (en) * 1966-03-14 1967-04-27 Shell Int Research Process for the preparation of dimers of bicyclo- [2, 2, 1] -heptadiene- (2, 5)
RU2402513C2 (en) * 2008-04-28 2010-10-27 Государственное образовательное учреждение высшего профессионального образования Иркутский государственный университет Tricyclo-[6;6;0;0]-hexadecadiene-6,10 synthesis method

Also Published As

Publication number Publication date
RU2551278C1 (en) 2015-05-20

Similar Documents

Publication Publication Date Title
AR110055A2 (en) MODULATION OF CHEMIOSENSORY AND LIGAND RECEIVERS RELATED TO THEMSELVES
AR098912A1 (en) SYK INHIBITORS
DOP2016000339A (en) USEFUL HETEROARILO COMPOUNDS AS SUMO ACTIVATOR ENZYME INHIBITORS
CY1121549T1 (en) 1-ARYLCARBONYL-4-OXY-PIPERIDINE COMPOUNDS USED FOR THE TREATMENT OF NEUROGYSTEMATIC DISEASES
AR095347A1 (en) ORGANIC COMPOUNDS
BR112016022785A8 (en) compound, pharmaceutical composition, pharmaceutical kit for treating a cancer, and methods of treating a disease and / or condition and / or disorder and synthesizing a compound
CY1118288T1 (en) PROCESS OF OSTETROL PREPARATION
BR112012029647A2 (en) new pyrimidine derivatives
ES2498768T3 (en) Process for the preparation of a catalyst component, for the polymerization of olefins
BR112013024223A2 (en) polyether compound, curing agent using polyether compound, and production method of polyether compound
RU2013149720A (en) METHOD FOR PRODUCING Bicyclo [4.2.1] NONA-2,4-DIENES
RU2013151209A (en) METHOD FOR PRODUCING Si-CONTAINING Bicyclo [4.2.1] NONA-2,4,7-TRIENES
RU2013148717A (en) METHOD FOR PRODUCING POLYCYCLIC 3-ALKYL (PHENYL) PHOSPHOLAN-3-OXIDES
RU2013151245A (en) METHOD FOR PRODUCING 2-ENDO-Ethyl-5-EXO-Ethylpentacyclo [8.4.0.03,7.04,14.06,11] TETRADECA-8,12-DIENE
RU2013151224A (en) METHOD FOR PRODUCING PENTACYCLO [7.5.0.02,8.05.05,14.07,11] TETRADECA-3,12-DIENE
RU2013151206A (en) METHOD FOR PRODUCING PENTACYCLO [8.4.0.03,7.04,14.06,11] TETRADECA-8,12-DIENE
CR20180414A (en) PROCESS TO PRODUCE 2´-O-FUCOSIL LACTOSE
RU2011123582A (en) METHOD FOR PRODUCING 3- (o-, m-, p-METHOXYPHENYL) -TETRAHYDRO-2H-1, 5, 3-DIOXAZEPINES
RU2011124568A (en) METHOD FOR PRODUCING α, ω-BIS- (1,5,3-DITIAZEPINAN-3-IL) ALKANOV
RU2013152020A (en) METHOD FOR PRODUCING (1,5,3-DITIAZEPAN-3-IL) -ALKANDIOLS
RU2013149722A (en) METHOD FOR PRODUCING BIS- (ENDO-Bicyclo [4.2.1] NONA-2,4-DIENOV)
RU2013151223A (en) METHOD FOR COLLECTING PENTACYCLO [7.5.0.02,8.05,14.07,11] TETRADECA-3,12-DIENE AND PENTACYCLO [8.4.0.03,7.04,14.06,11] TETRADECA-8,12-DIENE
PL409927A1 (en) Cis-dichloro(imidazo[1,2-a]pyridin-2-yl-methanamine)platinum (II) trihydrate and method for producing it
RU2018144401A (en) METHOD FOR PRODUCING Si-CONTAINING BICYCLO [4.2.1] NONA-2,4,7-TRIENES MANIFESTING ANTITUMOR ACTIVITY
RU2012128422A (en) METHOD FOR PRODUCING 1-ALKINYL ADAMANTANES

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20151107