RU2012128422A - METHOD FOR PRODUCING 1-ALKINYL ADAMANTANES - Google Patents

METHOD FOR PRODUCING 1-ALKINYL ADAMANTANES Download PDF

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Publication number
RU2012128422A
RU2012128422A RU2012128422/04A RU2012128422A RU2012128422A RU 2012128422 A RU2012128422 A RU 2012128422A RU 2012128422/04 A RU2012128422/04 A RU 2012128422/04A RU 2012128422 A RU2012128422 A RU 2012128422A RU 2012128422 A RU2012128422 A RU 2012128422A
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RU
Russia
Prior art keywords
producing
lewis acid
adamantanes
alkinyl
trimethylsilylalkine
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RU2012128422/04A
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Russian (ru)
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RU2507189C1 (en
Inventor
Валерий Викторович Коншин
Анна Алексеевна Турмасова
Джамиля Наибовна Коншина
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Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кубанский государственный университет" (ФГБОУ ВПО "КубГУ")
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Priority to RU2012128422/04A priority Critical patent/RU2507189C1/en
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Abstract

Способ получения 1-алкиниладамантанов из производных адамантана и ацетиленовых соединений при катализе кислотой Льюиса, взятых в эквимольных количествах, отличающийся тем, что в качестве исходных компонентов использован 1-адамантанол и 1-алкин или 1-триметилсилилалкин, которые нагревают при температуре кипения 1,2-дихлорэтана в присутствии 5 мол.% трифлата галлия в качестве кислоты Льюиса, до полного расходования исходных соединений.The method of producing 1-alkynyladamantanes from derivatives of adamantane and acetylenic compounds under catalysis by Lewis acid, taken in equimolar amounts, characterized in that 1-adamantanol and 1-alkine or 1-trimethylsilylalkine are used as starting components, which are heated at a boiling point of 1.2 -dichloroethane in the presence of 5 mol.% gallium triflate as a Lewis acid, until the initial compounds are completely consumed.

Claims (1)

Способ получения 1-алкиниладамантанов из производных адамантана и ацетиленовых соединений при катализе кислотой Льюиса, взятых в эквимольных количествах, отличающийся тем, что в качестве исходных компонентов использован 1-адамантанол и 1-алкин или 1-триметилсилилалкин, которые нагревают при температуре кипения 1,2-дихлорэтана в присутствии 5 мол.% трифлата галлия в качестве кислоты Льюиса, до полного расходования исходных соединений. The method of producing 1-alkynyladamantanes from derivatives of adamantane and acetylenic compounds under catalysis by Lewis acid, taken in equimolar amounts, characterized in that 1-adamantanol and 1-alkine or 1-trimethylsilylalkine are used as starting components, which are heated at a boiling point of 1.2 -dichloroethane in the presence of 5 mol.% gallium triflate as a Lewis acid, until the initial compounds are completely consumed.
RU2012128422/04A 2012-07-05 2012-07-05 Method of obtaining 1-alkynyl adamantanes RU2507189C1 (en)

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RU2012128422/04A RU2507189C1 (en) 2012-07-05 2012-07-05 Method of obtaining 1-alkynyl adamantanes

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RU2012128422/04A RU2507189C1 (en) 2012-07-05 2012-07-05 Method of obtaining 1-alkynyl adamantanes

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RU2012128422A true RU2012128422A (en) 2014-01-10
RU2507189C1 RU2507189C1 (en) 2014-02-20

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2661482C1 (en) * 2017-12-04 2018-07-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный университет" (ФГБОУ ВО "КубГУ") Method of producing (1-adamantyl)furanes

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU376346A1 (en) * 1971-01-28 1973-04-05 METHOD OF GETTING THE MIXTURE OF METHILADAMANTANS
JP2006225293A (en) * 2005-02-16 2006-08-31 Sumitomo Chemical Co Ltd Reactive monomer, method for producing the same, heat-resistant polymer, coating liquid for forming heat-resistant organic film, and method for producing heat-resistant organic film

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Effective date: 20200706