RU2012128422A - METHOD FOR PRODUCING 1-ALKINYL ADAMANTANES - Google Patents
METHOD FOR PRODUCING 1-ALKINYL ADAMANTANES Download PDFInfo
- Publication number
- RU2012128422A RU2012128422A RU2012128422/04A RU2012128422A RU2012128422A RU 2012128422 A RU2012128422 A RU 2012128422A RU 2012128422/04 A RU2012128422/04 A RU 2012128422/04A RU 2012128422 A RU2012128422 A RU 2012128422A RU 2012128422 A RU2012128422 A RU 2012128422A
- Authority
- RU
- Russia
- Prior art keywords
- producing
- lewis acid
- adamantanes
- alkinyl
- trimethylsilylalkine
- Prior art date
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Способ получения 1-алкиниладамантанов из производных адамантана и ацетиленовых соединений при катализе кислотой Льюиса, взятых в эквимольных количествах, отличающийся тем, что в качестве исходных компонентов использован 1-адамантанол и 1-алкин или 1-триметилсилилалкин, которые нагревают при температуре кипения 1,2-дихлорэтана в присутствии 5 мол.% трифлата галлия в качестве кислоты Льюиса, до полного расходования исходных соединений.The method of producing 1-alkynyladamantanes from derivatives of adamantane and acetylenic compounds under catalysis by Lewis acid, taken in equimolar amounts, characterized in that 1-adamantanol and 1-alkine or 1-trimethylsilylalkine are used as starting components, which are heated at a boiling point of 1.2 -dichloroethane in the presence of 5 mol.% gallium triflate as a Lewis acid, until the initial compounds are completely consumed.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2012128422/04A RU2507189C1 (en) | 2012-07-05 | 2012-07-05 | Method of obtaining 1-alkynyl adamantanes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2012128422/04A RU2507189C1 (en) | 2012-07-05 | 2012-07-05 | Method of obtaining 1-alkynyl adamantanes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012128422A true RU2012128422A (en) | 2014-01-10 |
| RU2507189C1 RU2507189C1 (en) | 2014-02-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012128422/04A RU2507189C1 (en) | 2012-07-05 | 2012-07-05 | Method of obtaining 1-alkynyl adamantanes |
Country Status (1)
| Country | Link |
|---|---|
| RU (1) | RU2507189C1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2661482C1 (en) * | 2017-12-04 | 2018-07-17 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный университет" (ФГБОУ ВО "КубГУ") | Method of producing (1-adamantyl)furanes |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU376346A1 (en) * | 1971-01-28 | 1973-04-05 | METHOD OF GETTING THE MIXTURE OF METHILADAMANTANS | |
| JP2006225293A (en) * | 2005-02-16 | 2006-08-31 | Sumitomo Chemical Co Ltd | Reactive monomer, method for producing the same, heat-resistant polymer, coating liquid for forming heat-resistant organic film, and method for producing heat-resistant organic film |
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2012
- 2012-07-05 RU RU2012128422/04A patent/RU2507189C1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| RU2507189C1 (en) | 2014-02-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200706 |