RU2011145368A - Регулирование состава синтез-газа в установке парового риформинга метана - Google Patents

Регулирование состава синтез-газа в установке парового риформинга метана Download PDF

Info

Publication number
RU2011145368A
RU2011145368A RU2011145368/05A RU2011145368A RU2011145368A RU 2011145368 A RU2011145368 A RU 2011145368A RU 2011145368/05 A RU2011145368/05 A RU 2011145368/05A RU 2011145368 A RU2011145368 A RU 2011145368A RU 2011145368 A RU2011145368 A RU 2011145368A
Authority
RU
Russia
Prior art keywords
synthesis gas
hydrogen
ratio
carbon
water
Prior art date
Application number
RU2011145368/05A
Other languages
English (en)
Other versions
RU2544666C2 (ru
Inventor
Джозеф М. Норбек
Чен Сён ПАРК
Арун СК Раджу
Кисёк КИМ
Original Assignee
Зе Реджентс Оф Зе Юниверсити Оф Калифорния
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Зе Реджентс Оф Зе Юниверсити Оф Калифорния filed Critical Зе Реджентс Оф Зе Юниверсити Оф Калифорния
Publication of RU2011145368A publication Critical patent/RU2011145368A/ru
Application granted granted Critical
Publication of RU2544666C2 publication Critical patent/RU2544666C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/723—Controlling or regulating the gasification process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/14—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic
    • C10K1/143—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic containing amino groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • C10K1/165—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids at temperatures below zero degrees Celsius
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/005—Reducing the tar content by partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/006—Reducing the tar content by steam reforming
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1642—Controlling the product
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/06—Modeling or simulation of processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0966—Hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643—Conversion of synthesis gas to energy
    • C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675—Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1853—Steam reforming, i.e. injection of steam only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Industrial Gases (AREA)

Abstract

1. Способ превращения углеродсодержащего материала в суспензии, содержащей воду, в синтез-газ, включающий:одновременное нагревание в реакторе гидрогазификации углеродсодержащего материала в присутствии как водорода, так и воды при температуре и давлении, достаточных для создания потока газообразного продукта, обогащенного метаном и монооксидом углерода;удаление примесей из потока генераторного газа; ипроведение парового метанового риформинга полученного генераторного газа в условиях, при которых образуется синтез-газ, содержащий водород и монооксид углерода в указанном требуемом соотношении.2. Способ по п.1, дополнительно включающий обеспечение предварительно заданного соотношения между водородом и суспензионной водой в реакторе гидрогазификации с обеспечением образования синтез-газа, содержащего водород и монооксид углерода в требуемом соотношении.3. Способ по п.2, отличающийся тем, что водород получают путем отвода части водорода, отделенного от синтез-газа, в суспензионную воду.4. Способ по п.2, отличающийся тем, что водород получают путем отвода части синтез-газа в суспензионную воду без отделения водорода от синтез-газа.5. Способ по п.2, отличающийся тем, что по меньшей мере часть указанной суспензионной воды обеспечивают в форме пара.6. Способ по п.1, отличающийся тем, что стадия одновременного нагревания происходит в отсутствие катализаторов или инжекции воздуха или кислорода.7. Способ по п.2, отличающийся тем, что соотношение между водородом и суспензионной водой определяют путем анализа влияния на соотношение в синтез-газе (а) соотношения между содержанием твердого вещества в углеродсодержащем м�

Claims (26)

1. Способ превращения углеродсодержащего материала в суспензии, содержащей воду, в синтез-газ, включающий:
одновременное нагревание в реакторе гидрогазификации углеродсодержащего материала в присутствии как водорода, так и воды при температуре и давлении, достаточных для создания потока газообразного продукта, обогащенного метаном и монооксидом углерода;
удаление примесей из потока генераторного газа; и
проведение парового метанового риформинга полученного генераторного газа в условиях, при которых образуется синтез-газ, содержащий водород и монооксид углерода в указанном требуемом соотношении.
2. Способ по п.1, дополнительно включающий обеспечение предварительно заданного соотношения между водородом и суспензионной водой в реакторе гидрогазификации с обеспечением образования синтез-газа, содержащего водород и монооксид углерода в требуемом соотношении.
3. Способ по п.2, отличающийся тем, что водород получают путем отвода части водорода, отделенного от синтез-газа, в суспензионную воду.
4. Способ по п.2, отличающийся тем, что водород получают путем отвода части синтез-газа в суспензионную воду без отделения водорода от синтез-газа.
5. Способ по п.2, отличающийся тем, что по меньшей мере часть указанной суспензионной воды обеспечивают в форме пара.
6. Способ по п.1, отличающийся тем, что стадия одновременного нагревания происходит в отсутствие катализаторов или инжекции воздуха или кислорода.
7. Способ по п.2, отличающийся тем, что соотношение между водородом и суспензионной водой определяют путем анализа влияния на соотношение в синтез-газе (а) соотношения между содержанием твердого вещества в углеродсодержащем материале и суспензионной водой и (b) соотношения между содержанием водорода и углерода в углеродсодержащем материале.
8. Способ по п.7, отличающийся тем, что указанный анализ представляет собой анализ чувствительности с применением моделирующей компьютерной программы, которая устанавливает связь между отношением водорода к монооксиду углерода в синтез-газе и коэффициентами конверсии углерода в углеродсодержащем материале.
9. Способ по п.8, отличающийся тем, что компьютерная программа представляет собой моделирующую программу.
10. Способ по п.9, отличающийся тем, что компьютерная программа использует равновесный процесс ASPEN PLUS™.
11. Способ по п.2, отличающийся тем, что паровой риформинг метана проводят в условиях, при которых состав полученного синтез-газа характеризуется мольным соотношением H2:CO в диапазоне примерно от 0,5:1 до 16:1.
12. Способ по п.1, отличающийся тем, что углеродсодержащий материал включает городские отходы, биомассу, древесину, уголь, твердые вещества биологического происхождения или природный или синтетический полимер.
13. Способ по п.1, согласно которому синтез-газ, полученный при паровом риформинге метана, подают в реактор Фишера-Тропша в условиях, при которых образуется жидкое топливо.
14. Способ по п.1, отличающийся тем, что примеси удаляют из потока генераторного газа при температуре выше температуры кипения воды при рабочем давлении.
15. Способ по п.14, отличающийся тем, что температура составляет от примерно 700°С до примерно 900°С.
16. Способ по п.1, отличающийся тем, что примеси удаляют из потока генераторного газа по существу при указанном давлении.
17. Способ по п.16, отличающийся тем, что давление составляет примерно от 132 psi (0,91 МПа) до 560 psi (3,86 МПа).
18. Способ по п.1, дополнительно включающий:
автотермический риформинг газа, обогащенного метаном, при температуре и давлении, достаточных для создания потока синтез-газа, обогащенного водородом и монооксидом углерода; и
проведение конденсации указанного синтез-газа и удаление полученной воды.
19. Способ по п.18, отличающийся тем, что поток синтез-газа, образующийся при конденсации, нагревают по существу до температуры, при которой примеси удаляют из потока синтез-газа.
20. Способ по п.18, отличающийся тем, что примеси удаляют из потока синтез-газа при от примерно 250°С до примерно 400°С.
21. Способ по п.19, отличающийся тем, что температура автотермической реакции составляет от примерно 550°С до примерно 750°С.
22. Способ по п.18, отличающийся тем, что конденсация потока синтез-газа происходит по существу при давлении, при котором примеси удаляют из потока синтез-газа.
23. Способ по п.18, отличающийся тем, что поток обогащенного метаном генераторного газа получают в ходе паровой гидрогазификации.
24. Способ по п.23, отличающийся тем, что давление при паровой гидрогазификации, автотермическом риформинге, конденсации и удалении примесей является по существу одинаковым на протяжении всех процессов.
25. Способ по п.24, отличающийся тем, что указанное по существу одинаковое давление находится в диапазоне примерно от 150 psi (1,03 МПа) до 500 psi (3,45 МПа).
26. Способ по п.18, отличающийся тем, что поток обогащенного метаном газа реагирует при автотермическом риформинге с потоком кислорода, разбавленным азотом, содержание кислорода в котором находится в диапазоне примерно от 15 об.% до 25 об.%.
RU2011145368/05A 2009-03-09 2010-03-04 Регулирование состава синтез-газа в установке парового риформинга метана RU2544666C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/400,640 2009-03-09
US12/400,640 US8603430B2 (en) 2002-02-05 2009-03-09 Controlling the synthesis gas composition of a steam methane reformer
PCT/US2010/026179 WO2010104732A2 (en) 2009-03-09 2010-03-04 Controlling the synthesis gas composition of a steam methane reformer

Publications (2)

Publication Number Publication Date
RU2011145368A true RU2011145368A (ru) 2013-05-20
RU2544666C2 RU2544666C2 (ru) 2015-03-20

Family

ID=42729023

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2011145368/05A RU2544666C2 (ru) 2009-03-09 2010-03-04 Регулирование состава синтез-газа в установке парового риформинга метана

Country Status (6)

Country Link
US (1) US8603430B2 (ru)
CN (1) CN102428023A (ru)
AU (1) AU2010222913B2 (ru)
CA (1) CA2762406A1 (ru)
RU (1) RU2544666C2 (ru)
WO (1) WO2010104732A2 (ru)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7024800B2 (en) 2004-07-19 2006-04-11 Earthrenew, Inc. Process and system for drying and heat treating materials
US7024796B2 (en) * 2004-07-19 2006-04-11 Earthrenew, Inc. Process and apparatus for manufacture of fertilizer products from manure and sewage
US7685737B2 (en) 2004-07-19 2010-03-30 Earthrenew, Inc. Process and system for drying and heat treating materials
US7610692B2 (en) 2006-01-18 2009-11-03 Earthrenew, Inc. Systems for prevention of HAP emissions and for efficient drying/dehydration processes
US9212059B2 (en) 2007-12-13 2015-12-15 Gyco, Inc. Method and apparatus for improving the efficiency of an SMR process for producing syngas while reducing the CO2 in a gaseous stream
US7932298B2 (en) * 2007-12-13 2011-04-26 Gyco, Inc. Method and apparatus for reducing CO2 in a stream by conversion to a syngas for production of energy
US8937103B2 (en) * 2007-12-13 2015-01-20 Gyco, Inc. Method for reducing CO2 in a gaseous stream by conversion to a Syngas for production of energy
US8679439B2 (en) * 2008-08-18 2014-03-25 Syngest, Inc. Process for producing ammonia from biomass
WO2010137028A2 (en) * 2009-05-28 2010-12-02 Concord Blue Technology Pvt. Ltd. A process for generating energy from organic materials and/or biomass
IN2012DN02366A (ru) * 2009-09-22 2015-08-21 Univ California
IT1403189B1 (it) * 2011-01-05 2013-10-15 High Tech En Sro Sistema e metodo per la produzione di syngas da materiale a base carbonica
FR2971789B1 (fr) * 2011-02-22 2013-02-22 Areva Methode de production de methanol ou d'hydrocarbures a partir d'une matiere carbonee, avec une etape de reformage dont les conditions de fontionnement sont ajustees selectivement
KR101110681B1 (ko) 2011-08-12 2012-03-13 한국기계연구원 고함수 연료 처리 및 발전 시스템
WO2014025904A2 (en) 2012-08-07 2014-02-13 Langley Justin Method for the integration of carbochlorination into a staged reforming operation as an alternative to direct residue oxidation for the recovery of valuable metals
CN103838265B (zh) * 2014-03-07 2016-09-28 西北化工研究院 一种用于在生产合成气时控制氢气与一氧化碳比值的控制系统
CN104017604B (zh) * 2014-06-25 2016-03-30 清华大学 一种生物质气化催化重整制生物氢的装置及方法
CN104850681B (zh) * 2015-04-16 2018-01-05 中国石油天然气股份有限公司 注入的蒸汽、氮气混合物的温度、压力、干度的计算方法
AU2017324397B2 (en) 2016-09-09 2020-02-27 Shell Internationale Research Maatschappij B.V. Process for the preparation of hydrogen
AT519060B1 (de) 2016-09-09 2018-07-15 Baumit Beteiligungen Gmbh Verfahren zum Brennen von Kalk oder Zement mit Synthesegas
CN109401787B (zh) * 2018-12-04 2021-04-23 青岛科技大学 一种耦合化学链制氧的煤合成气制备方法
CN110054152B (zh) * 2019-04-10 2021-03-05 北京科技大学 一种转炉煤气在线提质处理方法
JP7036852B2 (ja) * 2020-03-19 2022-03-15 本田技研工業株式会社 燃料製造システム
JP7098675B2 (ja) 2020-03-19 2022-07-11 本田技研工業株式会社 燃料製造システム
IT202100018125A1 (it) * 2021-07-09 2023-01-09 Agenzia Naz Per Le Nuove Tecnologie Lenergia E Lo Sviluppo Economico Sostenibile Enea Processo e impianto di trattamento dei rifiuti a matrice carboniosa
CN113903405A (zh) * 2021-09-26 2022-01-07 清华大学 用于预测柴油自热重整反应的模拟系统、预测方法及介质
CA3234067A1 (en) 2021-10-07 2023-04-13 Sund Group S.R.O. A process for production of fossil free hydrocarbons from lignocellulosic material.

Family Cites Families (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3153091B2 (ja) 1994-03-10 2001-04-03 株式会社荏原製作所 廃棄物の処理方法及びガス化及び熔融燃焼装置
US2987387A (en) 1958-12-30 1961-06-06 Texaco Inc Method for the production of carbon monoxide from solid fuels
US3985519A (en) 1972-03-28 1976-10-12 Exxon Research And Engineering Company Hydrogasification process
NL171597C (nl) 1972-12-15 1983-04-18 Shell Int Research Werkwijze en inrichting voor de bereiding van gas door partiele verbranding gevolgd door carbureren.
SU784791A3 (ru) * 1973-03-09 1980-11-30 Институт Оф Газ Текнолоджи (Фирма) Способ получени жидких и газообразных углеводородов из горючих сланцев
US3847567A (en) 1973-08-27 1974-11-12 Exxon Research Engineering Co Catalytic coal hydrogasification process
US3926775A (en) 1973-11-01 1975-12-16 Wilburn C Schroeder Hydrogenation of coal
JPS5156284A (en) 1974-11-13 1976-05-17 Hitachi Ltd Chitsusosankabutsu oyobi anmonia ofukumu haigasuchuno anmonianodobunsekiho oyobi sono sochi
US3957460A (en) 1975-09-09 1976-05-18 The United States Of America As Represented By The United States Energy Research And Development Administration Oxidation of coal-water slurry feed to hydrogasifier
US4012311A (en) 1975-10-30 1977-03-15 Cities Service Company Short residence time low pressure hydropyrolysis of carbonaceous materials
US4158697A (en) 1975-12-29 1979-06-19 Clean Energy Corporation Coal treatment apparatus
US4073698A (en) 1976-06-04 1978-02-14 Energetics Science, Inc. Method and device for the detection and measurement of carbon monoxide in the presence of hydrogen
US4118204A (en) 1977-02-25 1978-10-03 Exxon Research & Engineering Co. Process for the production of an intermediate Btu gas
US4372755A (en) 1978-07-27 1983-02-08 Enrecon, Inc. Production of a fuel gas with a stabilized metal carbide catalyst
US4211540A (en) 1978-12-29 1980-07-08 Fluor Corporation Process for the manufacture of fuel gas
US4244706A (en) 1979-09-10 1981-01-13 The United States Of America As Represented By The United States Department Of Energy Process for gasifying carbonaceous material from a recycled condensate slurry
US4341530A (en) 1979-12-05 1982-07-27 The United States Of America As Represented By The Department Of Energy Slurry atomizer for a coal-feeder and dryer used to provide coal at gasifier pressure
DK144602C (da) 1979-12-18 1982-09-27 Haldor Topsoe As Fremgangsmaade til fremstilling af en gasblanding med hoejt indhold af c2-kulbrinter
US4385905A (en) 1980-04-04 1983-05-31 Everett Metal Products, Inc. System and method for gasification of solid carbonaceous fuels
DE3033796A1 (de) 1980-09-09 1982-04-22 Bayer Ag, 5090 Leverkusen Elektrochemischer sensor zum nachweis reduzierender gase, insbesondere von kohlenmonoxid, hydrazin und wasserstoff in luft
US4397888A (en) 1981-01-14 1983-08-09 Westinghouse Electric Corp. Thick film sensor for hydrogen and carbon monoxide
US4526903A (en) 1981-01-23 1985-07-02 Dut Pty Limited Process for the production of synthesis gas from coal
US4833171A (en) 1981-01-27 1989-05-23 Sweeney Maxwell P Synthesis gas system
US4348487A (en) 1981-11-02 1982-09-07 Exxon Research And Engineering Co. Production of methanol via catalytic coal gasification
US4560547A (en) 1982-06-28 1985-12-24 Institute Of Gas Technology Production of hydrogen from oil shale
US4483691A (en) 1982-09-30 1984-11-20 Engelhard Corporation Production of synthetic natural gas from coal gasification liquid by-products
AU559953B2 (en) 1982-09-30 1987-03-26 International Control Automation Finance Sa Carbon monoxide detector
US4597776A (en) 1982-10-01 1986-07-01 Rockwell International Corporation Hydropyrolysis process
CA1300885C (en) 1986-08-26 1992-05-19 Donald S. Scott Hydrogasification of biomass to produce high yields of methane
US5427762A (en) 1987-05-27 1995-06-27 Hydrocarb Corporation Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol
US4983296A (en) 1989-08-03 1991-01-08 Texaco Inc. Partial oxidation of sewage sludge
US5354547A (en) 1989-11-14 1994-10-11 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
US5250175A (en) 1989-11-29 1993-10-05 Seaview Thermal Systems Process for recovery and treatment of hazardous and non-hazardous components from a waste stream
US5656044A (en) 1992-05-07 1997-08-12 Hylsa S.A. De C.V. Method and apparatus for gasification of organic materials
US5344848A (en) * 1993-05-27 1994-09-06 Meyer Steinberg Process and apparatus for the production of methanol from condensed carbonaceous material
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US5439580A (en) 1993-11-05 1995-08-08 The Ohio State University Solid-state gas sensor for carbon monoxide and hydrogen
US5741440A (en) * 1994-02-28 1998-04-21 Eastman Chemical Company Production of hydrogen and carbon monoxide
US5560900A (en) * 1994-09-13 1996-10-01 The M. W. Kellogg Company Transport partial oxidation method
US5496859A (en) 1995-01-28 1996-03-05 Texaco Inc. Gasification process combined with steam methane reforming to produce syngas suitable for methanol production
US6053954A (en) 1996-06-14 2000-04-25 Energy & Environmental Research Center Methods to enhance the characteristics of hydrothermally prepared slurry fuels
US6044689A (en) 1997-04-24 2000-04-04 Ngk Insulators, Ltd. Apparatus for sensing low concentration NOx, chamber used for apparatus for sensing low concentration NOx; gas sensor element and method of manufacturing the same; and ammonia removing apparatus and NOx sensor utilizing this apparatus
US6025403A (en) * 1997-07-07 2000-02-15 Mobil Oil Corporation Process for heat integration of an autothermal reformer and cogeneration power plant
US20030022035A1 (en) 1997-11-07 2003-01-30 Galloway Terry R. Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
US5989398A (en) 1997-11-14 1999-11-23 Motorola, Inc. Calorimetric hydrocarbon gas sensor
US6168768B1 (en) 1998-01-23 2001-01-02 Exxon Research And Engineering Company Production of low sulfer syngas from natural gas with C4+/C5+ hydrocarbon recovery
ITMI980865A1 (it) 1998-04-23 1999-10-23 Eniricerche S P A Ora Enitecno Procedimento per la preparazione di idrocarburi da gas di sintesi
GB9817526D0 (en) 1998-08-13 1998-10-07 Ici Plc Steam reforming
US6257980B1 (en) * 1998-12-24 2001-07-10 B.I.S., L.L.C. Method and apparatus for identifying a winner in a bingo game
US6225358B1 (en) 1999-02-16 2001-05-01 Syntroleum Corporation System and method for converting light hydrocarbons to heavier hydrocarbons with improved water disposal
IL152456A0 (en) * 2000-04-24 2003-05-29 Shell Int Research Method for treating a hydrocarbon-cotaining formation
US6495610B1 (en) 2000-06-19 2002-12-17 Imperial Chemical Industries Plc Methanol and hydrocarbons
US6612269B2 (en) 2000-08-11 2003-09-02 The Regents Of The University Of California Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels
US6527980B1 (en) 2000-10-12 2003-03-04 Air Products And Chemicals, Inc. Reforming with intermediate reactant injection
JP2002155288A (ja) 2000-11-21 2002-05-28 Yukuo Katayama 石炭ガス化方法
US6550310B1 (en) 2000-11-28 2003-04-22 Honeywell International Inc. Catalytic adsorption and oxidation based carbon monoxide sensor and detection method
US6685754B2 (en) * 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
MY136087A (en) * 2001-10-22 2008-08-29 Shell Int Research Process to reduce the temperature of a hydrogen and carbon monoxide containing gas and heat exchanger for use in said process
GB0129054D0 (en) 2001-12-05 2002-01-23 Accentus Plc Catalytic reactor and process
US20080016770A1 (en) 2006-07-18 2008-01-24 Norbeck Joseph M Method for high energy density biomass-water slurry
CZ2004930A3 (cs) 2002-02-05 2005-02-16 The Regents Of The University Of California Způsob výroby kapalného syntetického paliva z uhlíkatých materiálů pro dopravní prostředky a zařízení k provádění způsobu
US20080031809A1 (en) * 2006-07-18 2008-02-07 Norbeck Joseph M Controlling the synthesis gas composition of a steam methane reformer
US7500997B2 (en) * 2002-02-05 2009-03-10 The Regents Of The University Of California Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials
US8143319B2 (en) * 2006-07-18 2012-03-27 The Regents Of The University Of California Method and apparatus for steam hydro-gasification with increased conversion times
US7619012B2 (en) 2006-07-18 2009-11-17 The Regents Of The University Of California Method and apparatus for steam hydro-gasification in a fluidized bed reactor
US8349288B2 (en) * 2006-12-06 2013-01-08 The Regents Of The University Of California Process for enhancing the operability of hot gas cleanup for the production of synthesis gas from steam-hydrogasification producer gas
US6774148B2 (en) * 2002-06-25 2004-08-10 Chevron U.S.A. Inc. Process for conversion of LPG and CH4 to syngas and higher valued products
US20050165261A1 (en) 2003-03-14 2005-07-28 Syntroleum Corporation Synthetic transportation fuel and method for its production
US7056487B2 (en) 2003-06-06 2006-06-06 Siemens Power Generation, Inc. Gas cleaning system and method
US7108842B2 (en) 2004-01-15 2006-09-19 Conocophillips Company Process for the catalytic partial oxidation of H2S using staged addition of oxygen

Also Published As

Publication number Publication date
AU2010222913A1 (en) 2012-02-02
WO2010104732A2 (en) 2010-09-16
AU2010222913B2 (en) 2015-02-12
US8603430B2 (en) 2013-12-10
US20090221721A1 (en) 2009-09-03
RU2544666C2 (ru) 2015-03-20
CA2762406A1 (en) 2010-09-16
CN102428023A (zh) 2012-04-25
WO2010104732A3 (en) 2011-01-13

Similar Documents

Publication Publication Date Title
RU2011145368A (ru) Регулирование состава синтез-газа в установке парового риформинга метана
AU2009223177B2 (en) Hydrocarbon synthesis
GB2464045A (en) Process for the generation of a synthesis gas
RU2012142686A (ru) Применение ископаемых топлив для увеличения преимуществ синтетических топлив на основе биомассы
DK1648817T3 (da) Fremgangsmåde til udvinding af brint fra en metanholdig gas, især naturgas, og anlæg til udövelse af fremgangsmåden
JP2010511772A5 (ru)
KR101429973B1 (ko) 수소와 일산화탄소의 농도비가 낮은 합성가스를 이용한 합성천연가스 제조장치 및 제조방법
WO2009111332A3 (en) Reduced carbon footprint steam generation processes
GB201213063D0 (en) Improved hydrocarbon production process
NO20054084L (no) Fremgangsmate for fremstilling av hydrokarboner med lang kjede fra naturgass
DK2706103T3 (en) Process for gasifying a charge of carbonaceous material with improved efficiency
KR101818783B1 (ko) 이-단 가스 발생 장치로 저 메탄 합성가스의 생산
WO2011038046A4 (en) A method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor
CN104326859B (zh) 一种煤制芳烃的系统及方法
CA2731376A1 (en) Enhancement of fischer-tropsch process for hydrocarbon fuel formulation
JP5763054B2 (ja) 鉄と、ｃｏ及びｈ２含有の粗製合成ガスとを同時に製造する方法
KR20210097189A (ko) 스팀/co2 개질에 의한 수소 및 ft 생성물의 제조
CN105883851A (zh) 一种新型气化与热解耦合煤气多联产工艺
EA201391783A1 (ru) Способ получения углеводородной композиции
MX2023008632A (es) Conversion de biogas en alcoholes mixtos.
RU2008102833A (ru) Получение продуктов из отходящих газов нефтепереработки
CN103484181A (zh) 一种煤制代用天然气的系统及工艺
CN1724369A (zh) 电石炉尾气用于合成氨或甲醇生产的工艺
JP5535818B2 (ja) バイオマスガス化ガス精製システム及び方法、メタノール製造システム及び方法
GB2489362A (en) Two stage process for the conversion of synthesis gas using a cobalt catalyst the first stage and a supported ruthenium in the second stage

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20180305