RU2009141370A - РАДИАЦИОННО-СШИВАЕМЫЕ И ТЕРМИЧЕСКИ-СШИВАЕМЫЕ ПОЛИУРЕТАНОВЫЕ СИСТЕМЫ НА ОСНОВЕ ПОЛИ(ε-КАПРОЛАКТОН)ПОЛИСЛОЖНОЭФИРНЫХ ПОЛИОЛОВ - Google Patents

РАДИАЦИОННО-СШИВАЕМЫЕ И ТЕРМИЧЕСКИ-СШИВАЕМЫЕ ПОЛИУРЕТАНОВЫЕ СИСТЕМЫ НА ОСНОВЕ ПОЛИ(ε-КАПРОЛАКТОН)ПОЛИСЛОЖНОЭФИРНЫХ ПОЛИОЛОВ Download PDF

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RU2009141370A
RU2009141370A RU2009141370/04A RU2009141370A RU2009141370A RU 2009141370 A RU2009141370 A RU 2009141370A RU 2009141370/04 A RU2009141370/04 A RU 2009141370/04A RU 2009141370 A RU2009141370 A RU 2009141370A RU 2009141370 A RU2009141370 A RU 2009141370A
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polyurethane compositions
compositions according
poly
caprolactone
polyols
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Николас ШТЕККЕЛЬ (DE)
Николас ШТЕККЕЛЬ
Фридрих-Карл БРУДЕР (DE)
Фридрих-Карл БРУДЕР
Майке НИСТЕН (DE)
Майке НИСТЕН
Харальд БЛЮМ (DE)
Харальд БЛЮМ
Стефани СТРЭЗИСАР (US)
Стефани СТРЭЗИСАР
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Байер МатириальСайенс АГ (DE)
Байер Матириальсайенс Аг
Байер МатириальСайенс ЛЛСИ (US)
Байер МатириальСайенс ЛЛСИ
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/63Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/631Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyesters and/or polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269Lactones
    • C08G18/4277Caprolactone and/or substituted caprolactone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/63Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/638Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the use of compounds having carbon-to-carbon double bonds other than styrene and/or olefinic nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7875Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/7887Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring having two nitrogen atoms in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/798Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/245Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • G03H2001/026Recording materials or recording processes
    • G03H2001/0264Organic recording material
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/2403Layers; Shape, structure or physical properties thereof
    • G11B7/24035Recording layers
    • G11B7/24044Recording layers for storing optical interference patterns, e.g. holograms; for storing data in three dimensions, e.g. volume storage

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1. Полиуретановые композиции, содержащие ! A) один или более полиизоцианатов, ! B) один или более полиолов, содержащих, по меньшей мере, один поли(ε-капролактон)поли-сложноэфирный полиол, ! C) одно или более соединений, имеющих группы, которые при актиничном облучении реагируют с соединениями, ненасыщенными по этиленовому типу (радиационно-отверждаемые соединения), с полимеризацией, ! D) необязательно один или более свободнорадикальных стабилизаторов и ! E) один или более фотоинициаторов. !2. Полиуретановые композиции по п.1, в которых, по меньшей мере, 60 мас.% полиизоцианатов компонента A) основано на алифатических и/или циклоалифатических ди- и/или триизоцианатах. ! 3. Полиуретановые композиции по п.1, в которых доля поли(ε-капролактон)поли-сложноэфирных полиолов, из расчета на полиолы компонента B), составляет, по меньшей мере, 20 мас.%. ! 4. Полиуретановые композиции по п.1, в которых поли(ε-капролактон)поли-сложноэфирные полиолы компонента В) имеют среднечисловые молярные массы от 500 до 2000 г/моль и среднюю OH функциональность от 1.5 до 4. ! 5. Полиуретановые композиции по п.1, в которых молярное соотношение NCO и OH групп составляет от 0.95 до 1.25. ! 6. Полиуретановые композиции по п.1, в которых одно или более соединений из группы, состоящей из 9-винилкарбазола, винилнафталина, диакрилата бисфенола A, диакрилата тетрабромбисфенола A, 1,4-бис(2-тионафтил)-2-бутилакрилата, пентабромфенилакрилата, нафтилакрилата и пропан-2,2-диилбис[(2,6-дибром-4,1-фенилен)окси(2-{[3,3,3-трис(4-хлорфенил)пропаноил]окси}пропан-3,1-диил)оксиэтан-2,1-диил]диакрилата, применяется в C). ! 7. Полимерные пластмассы, полученные из полиуретановых композиций по п.1. ! 8. Полимерные пластм�

Claims (11)

1. Полиуретановые композиции, содержащие
A) один или более полиизоцианатов,
B) один или более полиолов, содержащих, по меньшей мере, один поли(ε-капролактон)поли-сложноэфирный полиол,
C) одно или более соединений, имеющих группы, которые при актиничном облучении реагируют с соединениями, ненасыщенными по этиленовому типу (радиационно-отверждаемые соединения), с полимеризацией,
D) необязательно один или более свободнорадикальных стабилизаторов и
E) один или более фотоинициаторов.
2. Полиуретановые композиции по п.1, в которых, по меньшей мере, 60 мас.% полиизоцианатов компонента A) основано на алифатических и/или циклоалифатических ди- и/или триизоцианатах.
3. Полиуретановые композиции по п.1, в которых доля поли(ε-капролактон)поли-сложноэфирных полиолов, из расчета на полиолы компонента B), составляет, по меньшей мере, 20 мас.%.
4. Полиуретановые композиции по п.1, в которых поли(ε-капролактон)поли-сложноэфирные полиолы компонента В) имеют среднечисловые молярные массы от 500 до 2000 г/моль и среднюю OH функциональность от 1.5 до 4.
5. Полиуретановые композиции по п.1, в которых молярное соотношение NCO и OH групп составляет от 0.95 до 1.25.
6. Полиуретановые композиции по п.1, в которых одно или более соединений из группы, состоящей из 9-винилкарбазола, винилнафталина, диакрилата бисфенола A, диакрилата тетрабромбисфенола A, 1,4-бис(2-тионафтил)-2-бутилакрилата, пентабромфенилакрилата, нафтилакрилата и пропан-2,2-диилбис[(2,6-дибром-4,1-фенилен)окси(2-{[3,3,3-трис(4-хлорфенил)пропаноил]окси}пропан-3,1-диил)оксиэтан-2,1-диил]диакрилата, применяется в C).
7. Полимерные пластмассы, полученные из полиуретановых композиций по п.1.
8. Полимерные пластмассы по п.7, где полимерные пластмассы представляют собой слои или литье.
9. Полимерные пластмассы по п.7, где полимерные пластмассы имеют температуру стеклования ниже -40°C.
10. Голографические среды, содержащие полиуретановые композиции по п.1.
11. Голографические среды, содержащие, по меньшей мере, одну полимерную пластмассу по любому из пп.7-9.
RU2009141370/04A 2007-04-11 2008-03-28 РАДИАЦИОННО-СШИВАЕМЫЕ И ТЕРМИЧЕСКИ-СШИВАЕМЫЕ ПОЛИУРЕТАНОВЫЕ СИСТЕМЫ НА ОСНОВЕ ПОЛИ(ε-КАПРОЛАКТОН)ПОЛИСЛОЖНОЭФИРНЫХ ПОЛИОЛОВ RU2009141370A (ru)

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IL200996A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer formulations having a low crosslinking density
WO2010037515A1 (de) * 2008-10-01 2010-04-08 Bayer Materialscience Ag Medien für volumenholographische aufzeichnung basierend auf sich selbstentwickelndem polymer
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US20080311483A1 (en) 2008-12-18
IL201036A0 (en) 2010-05-17
TW200906882A (en) 2009-02-16
KR20100015472A (ko) 2010-02-12
JP2010523776A (ja) 2010-07-15
BRPI0809620A2 (pt) 2014-09-16
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