RU2007124714A - Способ синтеза высокомолекулярных спиртов - Google Patents
Способ синтеза высокомолекулярных спиртов Download PDFInfo
- Publication number
- RU2007124714A RU2007124714A RU2007124714/04A RU2007124714A RU2007124714A RU 2007124714 A RU2007124714 A RU 2007124714A RU 2007124714/04 A RU2007124714/04 A RU 2007124714/04A RU 2007124714 A RU2007124714 A RU 2007124714A RU 2007124714 A RU2007124714 A RU 2007124714A
- Authority
- RU
- Russia
- Prior art keywords
- synthesis
- calcium phosphate
- molecular alcohols
- hydroxyapatite
- contacted
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
- C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (4)
1. Способ синтеза высокомолекулярного спирта с четным числом атомов углерода, равным 4 и более, в котором осуществляют контактирование этанола с фосфатом кальция в течение времени контактирования 0,4 секунды или более.
2. Способ синтеза 1-бутанола, в котором осуществляют контактирование этанола с фосфатом кальция в течение времени контактирования 0,4 секунды или более при температуре 200-350°С.
3. Способ синтеза высокомолекулярного спирта, по п.1, в котором фосфат кальция является гидроксиапатитом.
4. Способ синтеза 1-бутанола по п.2, в котором фосфат кальция является гидроксиапатитом.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004351307 | 2004-12-03 | ||
JP2004-351307 | 2004-12-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2007124714A true RU2007124714A (ru) | 2009-01-10 |
RU2422428C2 RU2422428C2 (ru) | 2011-06-27 |
Family
ID=36565161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2007124714/04A RU2422428C2 (ru) | 2004-12-03 | 2005-12-02 | Способ синтеза высокомолекулярных спиртов |
Country Status (10)
Country | Link |
---|---|
US (1) | US8080695B2 (ru) |
EP (1) | EP1829851B1 (ru) |
JP (1) | JP4903582B2 (ru) |
KR (2) | KR20070085516A (ru) |
CN (2) | CN101065345A (ru) |
AU (1) | AU2005310507B2 (ru) |
BR (1) | BRPI0515805B1 (ru) |
CA (1) | CA2589125C (ru) |
RU (1) | RU2422428C2 (ru) |
WO (1) | WO2006059729A1 (ru) |
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US7700810B2 (en) | 2007-08-22 | 2010-04-20 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst |
WO2009026523A1 (en) | 2007-08-22 | 2009-02-26 | E.I. Du Pont De Nemours And Company | Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate |
JP5382902B2 (ja) * | 2007-08-24 | 2014-01-08 | 株式会社サンギ | 化学工業原料及び燃料組成物の合成方法 |
US8603201B2 (en) | 2007-08-24 | 2013-12-10 | Kabushiki Kaisha Sangi | Method of synthesizing chemical industry raw materials and fuel compositions |
WO2009034719A1 (ja) | 2007-09-13 | 2009-03-19 | Sangi Co., Ltd. | アルコールを原料とする組成物の製造方法 |
WO2009064828A1 (en) * | 2007-11-13 | 2009-05-22 | E. I. Du Pont De Nemours And Company | Process for making a composition comprising at least two different dialkyl ethers |
JP5849259B2 (ja) * | 2008-02-21 | 2016-01-27 | 国立大学法人高知大学 | 触媒およびアルコールの合成法 |
US8318989B2 (en) | 2008-12-22 | 2012-11-27 | E I Du Pont De Nemours And Company | Process for producing guerbet alcohols using water tolerant basic catalysts |
BRPI0903506B1 (pt) * | 2009-08-17 | 2017-12-19 | Kabushiki Kaisha Sangi | A method of synthesis of alcohol for the synthesis of butanol from ethanol ?? |
WO2011031928A1 (en) * | 2009-09-11 | 2011-03-17 | E. I. Du Pont De Nemours And Company | Conversion of ethanol to a reaction product comprising 1-butanol using hydroxyapatite catalysts |
US9211529B2 (en) | 2009-09-11 | 2015-12-15 | E I Du Pont De Nemours And Company | Conversion of ethanol to a reaction product comprising 1-butanol using hydroxyapatite catalysts |
FR2951161B1 (fr) * | 2009-10-13 | 2012-03-02 | Total Raffinage Marketing | Procede de production de distillat a partir d'une charge hydrocarbonee comprenant une condensation d'alcool |
FR2951163B1 (fr) * | 2009-10-13 | 2012-09-28 | Total Raffinage Marketing | Procede de production de distillat par oligomerisation catalytique d'olefines en presence de composes oxygenes |
US9447018B2 (en) | 2009-10-20 | 2016-09-20 | Greenyug, Llc | Ethyl acetate production |
CN102596883B (zh) * | 2009-10-29 | 2015-03-25 | 三仪股份有限公司 | 不饱和羧酸和/或其衍生物的合成方法 |
CN101823938B (zh) * | 2010-04-23 | 2012-12-05 | 浙江大学 | 正丁醇催化缩合制备异辛醇的方法 |
DE102010024099A1 (de) | 2010-06-17 | 2011-12-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Katalytische Konversion von Alkoholen und Aldehyden |
WO2012035772A1 (en) * | 2010-09-15 | 2012-03-22 | Kabushiki Kaisha Sangi | Method for producing alcohol by guerbet reaction |
CN103209764B (zh) * | 2010-11-11 | 2016-04-20 | 璐彩特国际英国有限公司 | 用于生产烯键式不饱和羧酸或酯的方法及其催化剂 |
US8431753B2 (en) | 2011-03-09 | 2013-04-30 | E I Du Pont De Nemours And Company | Conversion of butanol to a reaction product comprising 2-ethylhexanol using hydroxyapatite catalysts |
FR2980791A1 (fr) | 2011-10-03 | 2013-04-05 | Rhodia Operations | Procede de preparation d'un melange d'alcools |
FR2984312A1 (fr) * | 2011-12-20 | 2013-06-21 | Rhodia Operations | Procede de preparation d'un melange d'alcools |
FR2984313B1 (fr) * | 2011-12-20 | 2014-01-17 | Rhodia Operations | Procede de preparation d'un melange d'alcools |
US9079851B2 (en) | 2012-02-01 | 2015-07-14 | Greenyug, Llc | Ethyl acetate production |
EP2679303B1 (en) | 2012-06-29 | 2020-11-11 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Catalyst and its preparation process for obtaining higher alcohols |
EP2679304A1 (en) | 2012-06-29 | 2014-01-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide |
US8809594B2 (en) | 2012-09-21 | 2014-08-19 | Eastman Chemical Company | Dual catalyst system for the self-condensation of alcohols |
US9024090B2 (en) | 2012-12-19 | 2015-05-05 | Celanese International Corporation | Catalysts and processes for producing butanol |
US20140171693A1 (en) | 2012-12-19 | 2014-06-19 | Celanese International Corporation | Coated Hydrotalcite Catalysts and Processes for Producing Butanol |
US8962897B2 (en) | 2012-12-19 | 2015-02-24 | Celanese International Corporation | Catalysts and processes for producing butanol |
FR3001728B1 (fr) | 2013-02-04 | 2015-11-13 | Adisseo France Sas | Procede de preparation d’une olefine par conversion catalytique d’au moins un alcool |
WO2014130465A1 (en) * | 2013-02-19 | 2014-08-28 | Greenyug, Llc | Production of higher alcohols |
JP2014040415A (ja) * | 2013-08-06 | 2014-03-06 | Sangi Co Ltd | 化学工業原料及び燃料組成物の合成方法 |
BR112016012629B1 (pt) | 2013-12-04 | 2020-12-01 | Rescurve, Llc | método e sistema de destilação reativa |
US9018426B1 (en) | 2013-12-19 | 2015-04-28 | Celanese International Corporation | Processes for producing multi-carbon alcohols |
ES2732019T3 (es) | 2013-12-27 | 2019-11-20 | Abengoa Bioenergia Nuevas Tecnologias Sa | Proceso para la preparación de alcoholes superiores a partir de alcoholes inferiores por condensación de Guerbet |
EP2889281A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
EP2889282A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
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EP2889280A1 (en) | 2013-12-27 | 2015-07-01 | Abengoa Bioenergía Nuevas Tecnologías, S. A. | Process for the preparation of n-butanol from ethanol and acetaldehyde |
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BR112017010149B1 (pt) | 2014-11-14 | 2021-01-05 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | método para preparar n-octanol por condensação de guerbet, instalação para fabricar n-butanol, n-octanol e ndecanol a partir de uma fonte de etanol e uma fonte de n-hexanol e processo contínuo para preparar n-butanol e n-octanol |
ES2570227B1 (es) * | 2014-11-14 | 2017-04-19 | Abengoa Bioenergia Nuevas Tecnologias, S.A. | Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet |
CA3225290A1 (en) | 2015-08-19 | 2017-02-23 | Viridis Chemical, Llc | Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols |
US9834501B2 (en) | 2016-01-28 | 2017-12-05 | Eastman Chemical Company | Efficient synthesis of methacroelin and other alpha, beta—unsaturated aldehydes from methanol and an aldehyde |
US9828322B2 (en) | 2016-01-28 | 2017-11-28 | Eastman Chemical Company | Efficient synthesis of methacroelin and other alpha, beta-unsaturated aldehydes over a regenerable anatase titania catalyst |
WO2018039609A1 (en) * | 2016-08-25 | 2018-03-01 | Rescurve, Llc | Production of higher alcohols |
CN108117480B (zh) * | 2016-11-26 | 2021-09-03 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇和乙醇混合液制备异丁醇的方法 |
CN109529897B (zh) * | 2018-12-04 | 2020-07-31 | 西南化工研究设计院有限公司 | 一种生产正丁醇的钯镓双金属催化剂及其制备方法及应用 |
KR20240035991A (ko) * | 2021-07-12 | 2024-03-19 | 옴야 인터내셔널 아게 | 표면-반응된 탄산칼슘 촉매를 사용하여 알콜을 제조하는 방법 |
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US2645667A (en) * | 1951-10-01 | 1953-07-14 | Phillips Petroleum Co | Condensation of alcohols in the presence of calcium hydroxide |
DE3236307C2 (de) * | 1982-09-30 | 1985-11-14 | IMA - Klessmann GmbH & Co KG, 4830 Gütersloh | Maschine zum Bohren und Einsetzen von Beschlagteilen in plattenförmige Werkstücke |
JPH11217343A (ja) | 1998-01-30 | 1999-08-10 | Sangi Co Ltd | 化学工業原料及びハイオク燃料の合成法 |
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2005
- 2005-12-02 KR KR1020077012087A patent/KR20070085516A/ko active Search and Examination
- 2005-12-02 KR KR1020087031303A patent/KR101113050B1/ko active IP Right Grant
- 2005-12-02 EP EP05811784.7A patent/EP1829851B1/en active Active
- 2005-12-02 BR BRPI0515805-2A patent/BRPI0515805B1/pt active IP Right Grant
- 2005-12-02 JP JP2006546656A patent/JP4903582B2/ja active Active
- 2005-12-02 AU AU2005310507A patent/AU2005310507B2/en active Active
- 2005-12-02 CA CA2589125A patent/CA2589125C/en active Active
- 2005-12-02 WO PCT/JP2005/022217 patent/WO2006059729A1/ja active Application Filing
- 2005-12-02 RU RU2007124714/04A patent/RU2422428C2/ru active
- 2005-12-02 CN CNA2005800400535A patent/CN101065345A/zh active Pending
- 2005-12-02 CN CN201210270715.XA patent/CN102911010B/zh active Active
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2007
- 2007-06-04 US US11/757,588 patent/US8080695B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JPWO2006059729A1 (ja) | 2008-06-05 |
CN102911010B (zh) | 2016-03-02 |
BRPI0515805A (pt) | 2008-08-05 |
US8080695B2 (en) | 2011-12-20 |
EP1829851B1 (en) | 2013-06-19 |
AU2005310507A1 (en) | 2006-06-08 |
AU2005310507B2 (en) | 2010-02-25 |
KR101113050B1 (ko) | 2012-03-14 |
JP4903582B2 (ja) | 2012-03-28 |
BRPI0515805B1 (pt) | 2015-07-28 |
EP1829851A1 (en) | 2007-09-05 |
CA2589125A1 (en) | 2006-06-08 |
CN101065345A (zh) | 2007-10-31 |
KR20090009330A (ko) | 2009-01-22 |
CA2589125C (en) | 2010-10-19 |
US20070255079A1 (en) | 2007-11-01 |
CN102911010A (zh) | 2013-02-06 |
RU2422428C2 (ru) | 2011-06-27 |
WO2006059729A1 (ja) | 2006-06-08 |
KR20070085516A (ko) | 2007-08-27 |
EP1829851A4 (en) | 2009-11-25 |
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