RU2006137285A - Мембрана для отделения со2 и метод ее получения - Google Patents
Мембрана для отделения со2 и метод ее получения Download PDFInfo
- Publication number
- RU2006137285A RU2006137285A RU2006137285/04A RU2006137285A RU2006137285A RU 2006137285 A RU2006137285 A RU 2006137285A RU 2006137285/04 A RU2006137285/04 A RU 2006137285/04A RU 2006137285 A RU2006137285 A RU 2006137285A RU 2006137285 A RU2006137285 A RU 2006137285A
- Authority
- RU
- Russia
- Prior art keywords
- membrane
- polyvinylamine
- molecular weight
- substrate
- membrane according
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title claims abstract 26
- 238000000034 method Methods 0.000 title claims abstract 5
- 238000000926 separation method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000003431 cross linking reagent Substances 0.000 claims abstract 4
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- 239000000203 mixture Substances 0.000 claims abstract 2
- 239000000758 substrate Substances 0.000 claims 6
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 2
- 239000003085 diluting agent Substances 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- KVBCYCWRDBDGBG-UHFFFAOYSA-N azane;dihydrofluoride Chemical compound [NH4+].F.[F-] KVBCYCWRDBDGBG-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000012510 hollow fiber Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000003457 sulfones Chemical class 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
- B01D69/142—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes with "carriers"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0006—Organic membrane manufacture by chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/40—Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/15—Use of additives
- B01D2323/16—Swelling agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/30—Cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/34—Molecular weight or degree of polymerisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Carbon And Carbon Compounds (AREA)
Claims (16)
1. Мембрана, включающая подложку, покрытую сшитым поливиниламином, где сшивающий агент представляет собой соединение, содержащее фтор.
2. Мембрана по п.1, где поливиниламин включает воду.
3. Мембрана по п.1, где поливиниламин мембраны набухает под действием водяного пара или содержащего воду разбавителя.
4. Мембрана по п.1, где структура подложки представляет собой мембрану из плоского листа или мембрану в виде полого волокна.
5. Мембрана по п.1, где подложка представляет собой мембрану с молекулярно-массовым отсечением в интервале от примерно 20000 до примерно 40000.
6. Мембрана по п.1, где подложка представляет собой мембрану, имеющую молекулярно-массовое отсечение приблизительно 10000, или примерно 15000, или, например, примерно 20000, меньшее, чем молекулярная масса поливиниламина.
7. Мембрана по п.1, где подложка изготовлена из поливинилсульфона.
8. Мембрана по п.1, где молекулярная масса указанного поливиниламина составляет примерно 30000, или более 50000, или, например, более 70000, или даже более 100000.
9. Мембрана по п.8, где молекулярная масса указанного поливиниламина менее 150000.
10. Мембрана по п.1, где сшивающий агент выбирают из группы, включающей фторид аммония, дифторид аммония и фтороводородную кислоту.
11. Мембрана по п.10, где сшивающий агент представляет собой фторид аммония.
12. Способ изготовления мембраны, включающий
получение поливиниламина;
нанесение покрытия указанного поливиниламина на структуру подложки для получения мембраны;
сшивание поливиниламина мембраны с помощью соединения, содержащего фтор.
13. Способ по п.12, кроме того, включающий
набухание упомянутого поливиниламина названной мембраны в результате действия на поливиниламин паров воды или содержащего воду разбавителя.
14. Способ по п.12, где поливиниламин имеет молекулярную массу более 30000, или более 50000, например, более 70000.
15. Способ по п.12, где молекулярная масса указанного поливиниламина менее 150000.
16. Применение мембраны по п.1 для отделения CO2 от газовых смесей.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20041199A NO322564B1 (no) | 2004-03-22 | 2004-03-22 | Komposittmembran, fremgangsmate til fremstilling derav, samt anvendelse derav for separasjon av CO2 fra gassblandinger. |
| NO20041199 | 2004-03-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006137285A true RU2006137285A (ru) | 2008-04-27 |
| RU2388527C2 RU2388527C2 (ru) | 2010-05-10 |
Family
ID=34825279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006137285/04A RU2388527C2 (ru) | 2004-03-22 | 2005-03-18 | Мембрана для отделения co2 и метод ее получения |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20080156188A1 (ru) |
| EP (1) | EP1740291B1 (ru) |
| AT (1) | ATE413913T1 (ru) |
| DE (1) | DE602005010995D1 (ru) |
| ES (1) | ES2317211T3 (ru) |
| NO (1) | NO322564B1 (ru) |
| PL (1) | PL1740291T3 (ru) |
| RU (1) | RU2388527C2 (ru) |
| WO (1) | WO2005089907A1 (ru) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7832398B2 (en) | 2005-12-29 | 2010-11-16 | General Elecrtic Company | Arrangement in connection with an anaesthesia/ventilation system for a patient and a gas separation unit for an anaesthesia/ventilation system |
| DE102006042348A1 (de) | 2006-09-08 | 2008-03-27 | Dräger Medical AG & Co. KG | Verfahren und Vorrichtung zur Separation von Kohlendioxid aus einem Atemgasgemisch mittels Fixed Site Carrier Membran |
| EP1897607A1 (en) | 2006-09-11 | 2008-03-12 | NTNU Technology Transfer AS | Membrane |
| US7914875B2 (en) | 2007-10-29 | 2011-03-29 | Corning Incorporated | Polymer hybrid membrane structures |
| US20090110907A1 (en) * | 2007-10-29 | 2009-04-30 | Jiang Dayue D | Membranes Based On Poly (Vinyl Alcohol-Co-Vinylamine) |
| GB0901699D0 (en) * | 2009-02-02 | 2009-03-11 | Ntnu Technology Transfer As | gas seperation membrane |
| RU2446864C1 (ru) * | 2010-08-09 | 2012-04-10 | Общество с ограниченной ответственностью "Научно-производственное предприятие "Технофильтр" | Состав для получения полимерной гидрофильной микрофильтрационной мембраны и способ получения полимерной гидрофильной микрофильтрационной мембраны |
| US8956696B2 (en) | 2011-02-10 | 2015-02-17 | Inficon Gmbh | Ultra-thin membrane for chemical analyzer and related method for forming membrane |
| KR101063697B1 (ko) * | 2011-05-25 | 2011-09-07 | 한국가스공사연구개발원 | Ｄｍｅ 제조 공정에 적용되는 이산화탄소/수소 분리막 |
| CA2895224A1 (en) | 2012-12-22 | 2014-06-26 | Dmf Medical Incorporated | An anesthetic circuit having a hollow fiber membrane |
| KR101401054B1 (ko) * | 2013-01-14 | 2014-05-29 | (주)세프라텍 | 초산 투과증발용 복합막 및 이의 제조방법 |
| US10186724B2 (en) * | 2015-02-04 | 2019-01-22 | Bloom Energy Corporation | Carbon dioxide separator, fuel cell system including same, and method of operating the fuel cell system |
| US20180133663A1 (en) * | 2016-11-17 | 2018-05-17 | Uop Llc | High selectivity chemically cross-linked rubbery membranes and their use for separations |
| RU2655140C1 (ru) * | 2017-02-02 | 2018-05-23 | Публичное акционерное общество криогенного машиностроения (ПАО "Криогенмаш") | Половолоконная композитная газоразделительнгая мембрана и способ ее получения |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973410A (en) * | 1989-11-29 | 1990-11-27 | Air Products And Chemicals, Inc. | Crosslinked vinylamine polymer in enhanced oil recovery |
| US5131927A (en) * | 1991-04-22 | 1992-07-21 | Union Carbide Industrial Gases Technology Corporation | Reactive treatment of composite gas separation membranes |
| DK100592D0 (da) * | 1992-08-10 | 1992-08-10 | Mouritsen & Elsner Aps | Metode til kemisk kobling paa faste faser |
| AU672824B2 (en) * | 1992-08-20 | 1996-10-17 | E.I. Du Pont De Nemours And Company | Crosslinked polymeric ammonium salts |
| US6315968B1 (en) * | 1995-01-18 | 2001-11-13 | Air Products And Chemicals, Inc. | Process for separating acid gases from gaseous mixtures utilizing composite membranes formed from salt-polymer blends |
| WO1999006138A1 (en) * | 1997-08-01 | 1999-02-11 | Exxon Research And Engineering Company | Co2-selective membrane process and system for reforming a fuel to hydrogen for a fuel cell |
| US6431280B2 (en) * | 1998-12-21 | 2002-08-13 | Geoffrey Stanley Bayliss | Method for placement of blocking gels or polymers at specific depths of penetration into oil and gas, and water producing formations |
| CN1190258C (zh) * | 2001-12-26 | 2005-02-23 | 天津大学 | Co2气体分离复合膜的制备方法 |
-
2004
- 2004-03-22 NO NO20041199A patent/NO322564B1/no not_active IP Right Cessation
-
2005
- 2005-03-18 RU RU2006137285/04A patent/RU2388527C2/ru not_active IP Right Cessation
- 2005-03-18 DE DE602005010995T patent/DE602005010995D1/de active Active
- 2005-03-18 US US10/592,938 patent/US20080156188A1/en not_active Abandoned
- 2005-03-18 EP EP05722103A patent/EP1740291B1/en not_active Not-in-force
- 2005-03-18 ES ES05722103T patent/ES2317211T3/es active Active
- 2005-03-18 AT AT05722103T patent/ATE413913T1/de not_active IP Right Cessation
- 2005-03-18 WO PCT/NO2005/000098 patent/WO2005089907A1/en active Application Filing
- 2005-03-18 PL PL05722103T patent/PL1740291T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20080156188A1 (en) | 2008-07-03 |
| NO20041199L (no) | 2005-09-23 |
| NO322564B1 (no) | 2006-10-23 |
| NO20041199D0 (no) | 2004-03-22 |
| PL1740291T3 (pl) | 2009-04-30 |
| ATE413913T1 (de) | 2008-11-15 |
| EP1740291B1 (en) | 2008-11-12 |
| WO2005089907A1 (en) | 2005-09-29 |
| ES2317211T3 (es) | 2009-04-16 |
| EP1740291A1 (en) | 2007-01-10 |
| DE602005010995D1 (de) | 2008-12-24 |
| RU2388527C2 (ru) | 2010-05-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20200319 |